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PT.

International Paint Indonesia

Safety Data Sheet


HTA342 INTERBOND 2340 UPC OLIVE GREY PART A
Version Number 10 Revision Date 10/18/18

1. Product and company identification

1.1. Product identifier INTERBOND 2340 UPC OLIVE GREY PART A


Product Code HTA342
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Refer Technical Data Sheet.
For professional use only.
Application Method Refer Technical Data Sheet.
1.3. Details of the supplier of the safety data
sheet Importer or
Manufacturer PT. International Paint Indonesia
Cikarang Industrial Estate
Jl. Jababeka Raya Blok E 9-11
17530, Cikarang, Indonesia

Telephone No. 021 8934270


Fax No. 021 8934275
1.4. Emergency telephone number (24 hour) 021 8934270
For Poisons Advice telephone For Advice to Doctors & Hospitals only

2. Hazard identification of the product

2.1. Classification of the substance or mixture


Flam. Liq. 3;H226 Flammable liquid and vapour.
Skin Irrit. 2;H315 Causes skin irritation.
Eye Dam. 1;H318 Causes serious eye damage.
Skin Sens. 1;H317 May cause an allergic skin reaction. Aquatic
Chronic 2;H411 Toxic to aquatic life with long lasting effects.

2.2. Label elements


Using the Toxicity Data listed in section 11 & 12 the product is labelled as follows.

Danger
H226 Flammable liquid and vapour.
H313 May be harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H411 Toxic to aquatic life with long lasting effects.

[Prevention]:
P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P235
Keep cool.
P240 Ground / bond container and receiving equipment.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P260 Do not breathe mist / vapours / spray.
P261 Avoid breathing dust / fume / gas / mist / vapours / spray. P262 Do
not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace. P273
Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
[Response]:
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician. P302+352 IF
ON SKIN: Wash with soap and water.
P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin
with water / shower.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and
easy to do - continue rinsing.
P310 Immediately call a POISON CENTER or doctor / physician. P312 Call
a POISON CENTER or doctor / physician if you feel unwell. P321 Specific
treatment (see information on this label).
P331 Do NOT induce vomiting.
P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P362
Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P370+378 In case of fire: Use alcohol resistant foam, CO2, powder, water spray for extinction. Do not use water jet.
P391 Collect spillage.
[Storage]:
P403+233 Store in a well ventilated place. Keep container tightly closed.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.
2.3. Other hazards
This product contains no PBT/vPvB chemicals.

3. Composition/information on ingredients

This product contains the following hazardous substances.


Ingredient/Chemical Designations Weight % GHS Classification Notes
Epoxy Resin 25- <50 Eye Irrit. 2;H319 [1]
CAS Number: 0025068-38-6 Skin Irrit. 2;H315
Skin Sens. 1;H317
Aquatic Chronic 2;H411
Xylene 10- <25 Flam. Liq. 3;H226 [1][2]
CAS Number: 0001330-20-7 Acute Tox. 4;H332
Acute Tox. 4;H312
Skin Irrit. 2;H315
Asp. Tox. 1;H304
Eye Irrit. 2;H319
STOT SE 3;H335
Aluminium, alkyls 2.5- <10 Water [1][2]
CAS Number: 0007429-90-5 react. 2;H261
Pyr. Sol. 1;H250
Solvent naphtha (petroleum), light aromatic 2.5- <10 Flam. Liq. 3;H226 [1]
CAS Number: 0064742-95-6 Asp. Tox. 1;H304
STOT SE 3;H335
STOT SE 3;H336
Aquatic Chronic 2;H411
n-Butanol 2.5- <10 Flam. Liq. 3;H226 [1][2]
CAS Number: 0000071-36-3 Acute Tox. 4;H302
STOT SE 3;H335
Skin Irrit. 2;H315
Eye Dam. 1;H318
STOT SE 3;H336
Ethyl Benzene 1- <2.5 Flam. Liq. 2;H225 [1][2]
CAS Number: 0000100-41-4 Acute Tox. 4;H332
STOT RE 2;H373
Asp. Tox. 1;H304
Skin Irrit. 2;H315
Eye Irrit. 2;H319
STOT SE 3;H335
Amorphous fumed silica 1- <2.5 [1]
CAS Number: 0112945-52-5
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.

*The full texts of the Hazard (H) phrases are shown in Section 16.

There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence do not require
reporting in this section.

4. First aid measures

4.1. Description of first aid measures


General
In all cases of doubt, or when symptoms persist, seek medical attention.

Never give anything by mouth to an unconscious person.


Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If
unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.

Skin Contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin cleanser. Do
NOT use solvents or thinners.

Eye Contact
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical
attention.

Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

4.2. Most important symptoms and effects, both acute and delayed
No data available
4.3. Indication of any immediate medical attention and special treatment needed and notes
for physician
No data available

5. Fire-fighting measures

5.1. Extinguishing media


Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray. Do not

use - water jet.

Note; Fire will produce dense black smoke. Decomposition products may be hazardous to health. Avoid exposure and
use breathing apparatus as appropriate.

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from
fire fighting to enter drains or water courses.
5.2. Special hazards arising from the substance or mixture
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon monoxide,
carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.
5.3. Advice for fire-fighters
Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from
fire fighting to enter drains or water courses.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill
or spillage in a confined space evacuate the area and check that solvent vapour levels are below the Lower
Explosive Limit before re-entering.
6.2. Environmental precautions
Do not allow spills to enter drains or watercourses.
6.3. Methods and material for containment and cleaning up
Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containers
outside buildings and dispose of according to the Waste Regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents. Do

not allow spills to enter drains or watercourses.

If drains, sewers, streams or lakes are contaminated, inform the local water company immediately. In the case of
contamination of rivers, streams or lakes the Environmental Protection Agency should also be informed.

7. Handling and storage


7.1. Precautions for safe handling
Handling
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Areas of storage, preparation and application should be ventilated to prevent the creation
of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational
exposure limits.

In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and
electrical equipment are protected to the appropriate standard.
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Areas of storage, preparation and application should be ventilated to prevent the creation
of flammable or explosive concentrations of vapour in air and avoid vapour concentrations higher than the occupational
exposure limits.

7.2. Conditions for safe storage, including any incompatibilities


Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Use personal
protection as shown in section 8.

Smoking, eating and drinking should be prohibited in all preparation and application areas. Never use

pressure to empty a container; containers are not pressure vessels.


This product is a flammable liquid. Refer to local storage and handling regulations pertaining to this type of material.
There are no exposure scenarios, see details in section 1.

7.3. Specific end use(s)


Store in a well ventilated, dry place away from sources of heat and direct sunlight.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack more
than 3 pallets high.

Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to prevent
leakage. Keep in the original container or one of the same material.

Prevent unauthorised access.


All sources of ignition (hot surfaces, sparks, open flames etc) should be excluded from areas of preparation and
application. All electrical equipment (including torches) should be protected (Ex) to the appropriate standard.

The product may charge electrostatically. Always use earthing leads when pouring solvents and transferring
product. Operators should wear clothing which does not generate static (at least 60% natural fibre) and antistatic
footwear; floors should be of conducting type.

8. Exposure controls and personal protection

8.1. Control parameters


Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Long term (8hr time


Material Short term (15 min. ave) Comments
weighted average)
ppm mg/m³ ppm mg/M3
Aluminium, alkyls - - - 2
Ethyl Benzene 125 543 100 434
n-Butanol 50 152 - -
Xylene 150 651 100 434
Key to notification

(P) Peak exposure limit


(R) Suppliers Recommended Limit
(Sk) There is a risk of absorption through unbroken skin (Sen)
Sensitiser
(Cat1) Category 1 - established human carcinogen
(Cat2) Category 2 - probable human carcinogen
(Cat3) Category 3 - substances suspected of having carcinogenic potential

DNEL/PNEC values
No Data Available

8.2. Exposure controls


Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust
ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any
vapour below occupational exposure limits suitable respiratory protection must be worn.

Eye Protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids. Eyewear should
comply with an approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes. An eye

wash station is suggested as a good work place practice.

Skin Protection
Gloves of an appropriate material should be worn during mixing and application.

Other
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams may help
to protect areas which are difficult to cover such as the face and neck. They should however not be applied once
exposure has occurred. Petroleum jelly based types such as Vaseline should not be used. All parts of the body should
be washed after contact.

Respiratory Protection
When concentrations exceed the exposure limits shown above, workers must wear appropriate approved respirators.
Provision of other controls such as exhaust ventilation should be considered if practical.

Thermal hazards
No Data Available

9. Physical and chemical properties

Appearance Metallic Coloured Liquid


Odour Smell of Solvent
Odour threshold Not Measured
pH N/A
Melting point / freezing point (°C) Not Measured
Initial boiling point and boiling range (°C)
Flash Point (°C) 28
Evaporation rate (Ether = 1) Not Measured
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 1.1
Upper Explosive Limit: 11.3
Vapour pressure (Pa) Not Measured
Vapour Density Heavier than air.
Specific Gravity 1.31
Solubility in Water Immiscible
Partition coefficient n-octanol/water (Log Kow) Not Measured
Autoignition temperature (℃) Not Measured
Decomposition temperature Not Measured
Viscosity (cSt) N/A

9.2. Other information


No further information

10. Stability and reactivity

10.1. Reactivity
No data available
10.2. Chemical stability
Stable under recommended storage and handling conditions (see section 7). When exposed to high temperatures may
produce hazardous decomposition products such as carbon monoxide, carbon dioxide, oxides of nitrogen and smoke.

Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible exothermic
reactions.
10.3. Possibility of hazardous reactions
May react exothermically with: oxidising agents, strong alkalis, strong acids.
10.4. Conditions to avoid
Stable under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
Keep away from the following materials: oxidising agents, strong alkalis, strong acids.
10.6. Hazardous decomposition products
Fire will produce dense black smoke. Decomposition products may include the following materials: carbon monoxide,
carbon dioxide, smoke, oxides of nitrogen.
Avoid exposure and use breathing apparatus as appropriate.

11. Toxicological information

Acute toxicity

Exposure to solvent vapour concentrations from the component solvents in excess of the stated occupational exposure
limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse
effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue,
muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in
dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed
through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.
Based on the properties of the epoxy constituents and considering toxicological data on similar preparations this
preparation may be an irritant and a skin and respiratory sensitiser. Low molecular weight epoxy constituents are
irritating to eyes, mucousmembranes and skin. Repeated skin contact may lead to irritation and sensitisation, possibly
with cross-sensitisation to other epoxies.

The preparation has been assessed using the Acute Toxicity Data listed below, and classified for toxicological
hazards accordingly. See section 2 for details.

Inhalation Inhalation
Oral LD50, Skin LD50,
Ingredient Vapour LD50, Dust/Mist LD50,
mg/kg mg/kg
mg/L/4hr mg/L/4hr
Aluminium, alkyls - (7429-90-5) Not Available Not Available Not Available Not Available
Amorphous fumed silica - (112945-52-5) 3,160.00, Rat Not Available Not Available Not Available
Epoxy Resin - (25068-38-6) 2,000.00, Rat 2,000.00, Rabbit Not Available Not Available
Ethyl Benzene - (100-41-4) 3,500.00, Rat 15,433.00, Rabbit 17.20, Rat Not Available
n-Butanol - (71-36-3) 2,292.00, Rat 3,430.00, Rabbit Not Available Not Available
Solvent naphtha (petroleum), light 6,800.00, Rat 3,400.00, Rabbit Not Available Not Available
aromatic - (64742-95-6)
Xylene - (1330-20-7) 4,299.00, Rat 1,548.00, Rabbit Not Available 20.00, Rat

Item Category Hazard


Acute Toxicity (mouth) Not Classified Not Applicable
Acute Toxicity (skin) Not Classified Not Applicable
Acute Toxicity (inhalation) Not Classified Not Applicable
Skin corrosion/irritation 2 Causes skin irritation.
Eye damage/irritation 1 Causes serious eye damage.
Sensitization (respiratory) Not Classified Not Applicable
Sensitization (skin) 1 May cause an allergic skin reaction.
Germ toxicity Not Classified Not Applicable
Carcinogenicity Not Classified Not Applicable
Reproductive Toxicity Not Classified Not Applicable
Specific target organ systemic toxicity Not Classified Not Applicable
(single exposure)
Specific target organ systemic Toxicity Not Classified Not Applicable
(repeated exposure)
Aspiration hazard Not Classified Not Applicable

12. Ecological information

12.1. Toxicity
The preparation has been assessed according to the GHS criteria and is classified as dangerous for the environment,
using the toxicity data listed below.

There are no data available on the product itself.

The product should not be allowed to enter drains or water courses.

Aquatic Ecotoxicity
96 hr LC50 fish, 48 hr EC50 crustacea, ErC50 algae,
Ingredient
mg/l mg/l mg/l
Epoxy Resin - (25068-38-6) 3.10, Pimephales 1.40, Daphnia magna Not Available
promelas
Xylene - (1330-20-7) Not Available Not Available Not Available
Aluminium, alkyls - (7429-90-5) 0.12, Oncorhynchus 3.50, Daphnia magna Not Available
mykiss
Solvent naphtha (petroleum), light 9.22, Oncorhynchus 6.14, Daphnia magna 19.00 (72 hr), Selenastrum
aromatic - (64742-95-6) mykiss capricornutum
n-Butanol - (71-36-3) 1,328.00, Daphnia 500.00 (96 hr), Scenedesmus
1,376.00, Pimephales magna subspicatus
promelas
Ethyl Benzene - (100-41-4) 4.20, Oncorhynchus 2.93, Daphnia magna
mykiss 3.60 (96 hr), Pseudokirchneriella
subcapitata
Amorphous fumed silica - (112945- Not Available Not Available Not Available
52-5)

12.2. Persistence and degradability


There is no data available on the preparation itself.
12.3. Bioaccumulative potential
Not Measured
12.4. Mobility in soil
No data available
12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
12.6. Other adverse effects
No data available

13. Disposal considerations

13.1. Waste treatment methods


Do not allow into drains or water courses. Wastes and empty containers should be disposed of in accordance with
State and Federal regulations.

Using information provided in this data sheet advice should be obtained from the local Waste Regulation Authority as
to whether special waste regulations apply.

14. Transport information

14.1. UN number 1263


14.2. UN proper shipping name Paint
14.3. Transport hazard class(es)

Road and Rail Transport UN1263, Paint, CLASS 3, PG III, HAZCHEM *3Y

IMDG Class/Div 3 Sub Class


reference :

Ems F-E,S-E
ICAO/ Class Sub

14.4. Packing group III

14.5. Environmental hazards

Road and
Rail Environmentally Hazardous: Yes
Transport

IMDG
reference :
Marine Pollutant: Yes ( Epoxy Resin )

14.6. Special precautions for user


No further information
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not Applicable

15. Regulatory information

This product and all its components complies with the chemical and transport regulations from the country listed in
section 1.3.
Other regulatory information specific to the hazardous chemical(s):

None noted.

16. Other information

The information on this SDS is based upon the present state of our knowledge and on current law. The product
should not be used for purposes other than shown in the product data sheet without first obtaining written
advice.

It is always the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Safety Data Sheet is required according to legislation. The full

text of the phrases appearing in section 3 is:

H225 Highly flammable liquid and vapour.


H226 Flammable liquid and vapour.
H250 Catches fire spontaneously if exposed to air. H261 In
contact with water releases flammable gases. H302 Harmful
if swallowed.
H304 May be fatal if swallowed and enters airways. H312
Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H319 Causes serious eye irritation. H332
Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness and dizziness.
H372 Causes damage to organs through prolonged or repeated exposure. H373 May
cause damage to organs through prolonged or repeated exposure. H411 Toxic to
aquatic life with long lasting effects.

This SDS is valid for 5 years from the revised date on page
1. The revision date is in American format (e.g. MM/DD/YY).

End of document

All information concerning this product and/or suggestions for handling and use contained herein are offered in
good faith and are believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or
sufficiency of such information.
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

1. Product and company identification

Product Name INTERNATIONAL THINNER-EQPT CLEANER


Product Code GTA007
Intended use Refer Technical Data Sheet.
For professional use only.
Application Method Refer Technical Data Sheet.
Company Name PT. International Paint Indonesia
Cikarang Industrial Estate
Jl. Jababeka Raya Blok E 9-11
17530, Cikarang, Indonesia

Telephone No. 021 8934270


Fax No. 021 8934275
24 hour Emergency Telephone No. 021 8934270
For Poisons Advice telephone For Advice to Doctors & Hospitals only

2. Hazard identification of the product

Danger
All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 1
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER
GHS Classification;
Item Category Hazard
Flammability 3 Flammable liquid and vapour
Acute Toxicity (mouth) 5 May be harmful if swallowed
Acute Toxicity (skin) 5 May be harmful in contact with skin
Acute Toxicity (inhalation) Not classified Not applicable
Acute Toxicity (ingestion) Not classified Not applicable
Skin corrosion/irritation 2 Causes skin irritation
Eye damage/irritation Not classified Not applicable
Sensitization (respiratory) Not classified Not applicable
Sensitization (skin) Not classified Not applicable
Germ toxicity Not classified Not applicable
Specific target organ systemic toxicity (single
1 No target organs for this category
exposure)

2 May cause damage to the kidneys, liver and central nervous


system.
3 No target organs for this category
Specific target organ systemic Toxicity (repeated 2 May cause damage to skin through prolonged or repeated
exposure) exposure.
Aspiration hazard Not classified Not applicable
Harmfulness to aquatic Environment (acute) Not classified Not applicable
Harmfulness to aquatic Environment (long term Not classified Not applicable
effect)
Carcinogenicity Not classified Not applicable
Reproductive Toxicity Not classified Not applicable
Organic Peroxide Not classified Not applicable

S. Phrases;
S9 - Keep container in a well-ventilated place. S23
- Do not breathe vapour/spray.
S36/37 - Wear suitable protective clothing and gloves. S51
- Use only in well-ventilated areas.

Further information is given in section 11.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 2
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

3. Composition/information on ingredients

Mixture : Mixture

This product contains the following hazardous substances.


Ingredient CAS Number Concentration Range%
Xylene 0001330-20-7 >50
Ethyl Benzene 0000100-41-4 10-25

4. First aid measures

General
In all cases of doubt, or when symptoms persist, seek medical attention. Never

give anything by mouth to an unconscious person.

Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the
recovery position and obtain immediate medical attention. Give nothing by mouth.

Eye Contact
Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical attention.

Skin Contact
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognised skin cleanser. Do NOT use solvents or
thinners.

Ingestion
If accidentally swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 3
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

5. Fire-fighting measures

Recommended extinguishing media; alcohol resistant foam, CO2, powder, water spray. Do not

use - water jet.

Note; Fire will produce dense black smoke. Decomposition products may be hazardous to health. Avoid exposure and use breathing
apparatus as appropriate.

Cool closed containers exposed to fire by spraying them with water. Do not allow run off water and contaminants from fire fighting to enter
drains or water courses.

6. Accidental release measures

Remove sources of ignition, do not turn lights or unprotected electrical equipment on or off. In case of a major spill or spillage in a confined
space evacuate the area and check that solvent vapour levels are below the Lower Explosive Limit before re-entering.
Ventilate the area and avoid breathing vapours. Take the personal protective measures listed in section 8.

Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in closed containers outside buildings
and dispose of according to relevant State and Federal regulations. (See section 13).

Clean, preferably with a detergent. Do not use solvents. Do

not allow spills to enter drains or watercourses.

If drains, sewers, streams or lakes are contaminated, inform the relevant Environment Protection Agency.

Empty containers may contain product residues, including flammable or explosive vapours. Do not cut, puncture or weld on or near containers.
All label warnings must be observed until the containers have been cleaned or reconditioned.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 4
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

7. Handling and storage

Handling
This coating contains solvents. Solvent vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures
with air. Areas of storage, preparation and application should be ventilated to prevent the creation of flammable or explosive concentrations
of vapour in air and avoid vapour concentrations higher than the occupational exposure limits.

In Storage
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment
are protected to the appropriate standard.

In Use
Avoid skin and eye contact. Avoid inhalation of vapours and spray mists. Observe label precautions. Use personal protection as shown in
section 8.

Smoking, eating and drinking should be prohibited in all preparation and application areas. Never

use pressure to empty a container; containers are not pressure vessels.


All sources of ignition (hot surfaces, sparks, open flames etc) should be excluded from areas of preparation and application. All electrical
equipment (including torches) should be protected (Ex) to the appropriate standard.

The product may charge electrostatically. Always use earthing leads when pouring solvents and transferring product. Operators should wear
clothing which does not generate static (at least 60% natural fibre) and antistatic footwear; floors should be of conducting type.

Storage
Store in a well ventilated, dry place away from sources of heat and direct sunlight.

Store on concrete or other impervious floor, preferably with bunding to contain any spillage. Do not stack more than 3 pallets high.

Keep container tightly closed. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Keep in the
original container or one of the same material.

Prevent unauthorised access.


This product is a flammable liquid. Refer to local storage and handling regulations pertaining to this type of material.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 5
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

8. Exposure controls and personal protection

Engineering Measures
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general
extraction. If these are not sufficient to maintain concentrations of particulates and any vapour below occupational exposure limits suitable
respiratory protection must be worn.

Exposure Limits
Exposure standards are those provided by the ACGIH (American Conference of Government Industrial Hygenists).

Material Short term (15 min. ave) Long term (8hr time weighted average)
ppm mg/M3 ppm mg/M3
Ethyl Benzene 125 543 100 434
Xylene 150 651 100 434
Key to notification

(P) Peak exposure limit


(R) Suppliers Recommended Limit
(Sk) There is a risk of absorption through unbroken skin
(Sen) Sensitiser
(Cat1) Category 1 - established human carcinogen
(Cat2) Category 2 - probable human carcinogen
(Cat3) Category 3 - substances suspected of having carcinogenic potential

Personal Protection

Respiratory Protection
When concentrations exceed the exposure limits shown above, workers must wear appropriate approved respirators. Provision of
other controls such as exhaust ventilation should be considered if practical.

Eye Protection
Wear safety eyewear, e.g. safety spectacles, goggles or visors to protect against the splash of liquids. Eyewear should comply with an
approved standard.

Wear a full face shield if mixing or pouring operations pose a risk of splashes. An

eye wash station is suggested as a good work place practice.

Hand Protection
Gloves of an appropriate material should be worn during mixing and application.

Skin Protection
Overalls which cover the body, arms and legs should be worn. Skin should not be exposed. Barrier creams may help to protect areas which
are difficult to cover such as the face and neck. They should however not be applied once exposure has occurred. Petroleum jelly based
types such as Vaseline should not be used. All parts of the body should be washed after contact.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 6
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

9. Physical and chemical properties

Physical State Liquid


Colour Colourless
Flash Point (C) 26
Autoignition temperature (℃) 500
Viscosity (cSt) N/A
Specific Gravity 0.865
Solvent Weight % 78.00
Vapour Density Heavier than air.
pH Not Applicable
Lower Explosive Limit (%v/v air) 1.1
Solubility in Water Immiscible
R.A.Q. to ventilate to 10% of the LEL (M3/l) 128
Odour Smell of Solvent

10. Stability and reactivity

Stable under recommended storage and handling conditions (see section 7). When exposed to high temperatures may produce hazardous
decomposition products such as carbon monoxide, carbon dioxide, oxides of nitrogen and smoke.

Keep away from oxidising agents, strongly alkaline and strongly acid materials in order to avoid possible exothermic reactions.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 7
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

11. Toxicological information

Inhalation Vapour LD50, mg/L/4hr


Oral LD50, mg/kg Skin LD50, mg/kg
Ingredient 17.20, Rat - Category: 4 29.08, rat - Category: NA

Ethyl Benzene - (0000100-41-4) 3,500.00, Rat - Category: 5 15,354.00, Rabbit - Category: NA


Xylene - (0001330-20-7) 4,300.00, rat - Category: 5 1,700.00, rat - Category: 4

There are no data available on the product itself.


Exposure to solvent vapour concentrations from the component solvents in excess of the stated occupational exposure limits may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous
system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and
possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation
and soreness with possible reversible damage.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 8
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

12. Ecological

There are no data available on the product itself.

The product should not be allowed to enter drains or water courses.

13. Disposal considerations

Do not allow into drains or water courses. Wastes and empty containers should be disposed of in accordance with State and Federal
regulations.

Using information provided in this data sheet advice should be obtained from the local Waste Regulation Authority as to whether special
waste regulations apply.

14. Transport information

Transport only in accordance with the following regulations:


Road and Rail 1263, Paint related material, 3, III, 3[Y]
Transport

IMDG reference : Class/Div 3 Subsidiary Class


Proper Shipping Name Paint Related Material
UN No 1263
Ems F-E,S-E
Packaging Group III
Marine Pollutant No

ICAO/IATA Shipping Name Paint Related Material


Class 3
UN No 1263
Packaging Group III

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 9
PT. International Paint

Safety Data Sheet


GTA007
INTERNATIONAL THINNER-EQPT
CLEANER

15. Regulatory

The product complies with these local regulations.

16. Other information

The information on this SDS is based upon the present state of our knowledge and on current law.
The product should not be used for purposes other than shown in the product data sheet without first obtaining written advice. It is always

the responsibility of the user to take all necessary steps to meet the demands of applicable legislation.

The information in this Safety Data Sheet is required according to legislation.

All information concerning this product and/or suggestions for handling and use contained herein are offered in good faith and are
believed to be reliable. Akzo Nobel however makes no warranty as to the accuracy of and/or sufficiency of such information.

Page 10
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
SAFETY DATA SHEET

Jotun Thinner No. 10


SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product
identifier Product : Jotun Thinner No. 10
name
Product code : 549
Product description : Solvent.
Product type : Liquid.
Other means of : Not available.
identification

1.2 Relevant identified uses of the substance or mixture and uses advised
against Use in coatings - Consumer use: Apply this product only as specified on the label.
Use in coatings - Industrial use
Use in coatings - Professional use

See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).

1.3 Details of the supplier of the safety data sheet


Jotun Paints (Europe) Ltd.
Stather Road Flixborough,
Scunthorpe North
Lincolnshire
DN15 8RR
England

Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
SDSJotun@jotun.com

1.4 Emergency telephone number


Contact NHS Direct; phone 0845 4647 or 111. Open 24/7.

SECTION 2: Hazards identification


2.1 Classification of the substance or
mixture Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Acute Tox. 4, H312
Skin Irrit. 2, H315
Eye Irrit. 2, H319
STOT SE 3, H335
STOT RE 2, H373 (hearing organs)
Asp. Tox. 1, H304
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. See Section
11 for more detailed information on health effects and symptoms.

2.2 Label elements

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Jotun Thinner No. 10

SECTION 2: Hazards identification


Hazard pictograms :

Signal word : Danger.


Hazard statements : H226 - Flammable liquid and vapour. H312
- Harmful in contact with skin. H319 -
Causes serious eye irritation. H315 - Causes
skin irritation.
H304 - May be fatal if swallowed and enters airways. H335 -
May cause respiratory irritation.
H373 - May cause damage to organs through prolonged or repeated exposure. (hearing
organs)
Precautionary statements
General : P102 - Keep out of reach of children.
Prevention : P280 - Wear protective gloves. Wear eye or face protection. Wear protective clothing.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P271 - Use only outdoors or in a well-ventilated area. P260 -
Do not breathe vapour or spray.
P304 + P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
Response : P301 + P310 + P331 - IF SWALLOWED: Immediately call a POISON CENTER or
physician. Do NOT induce vomiting.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P403 - Store in a well-ventilated place. P235 -
Keep cool.
Storage :
P501 - Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Disposal :
Hazardous ingredients : xylene
ethylbenzene
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Special packaging requirements
Containers to be fitted : Yes, applicable.
with child-resistant
fastenings
Tactile warning of : Yes, applicable.
danger

2.3 Other hazards


Other hazards which do : None known.
not result in classification

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Jotun Thinner No. 10

SECTION 3: Composition/information on
3.2 Mixtures : Mixture
Product/ingredient name Identifiers Weight % Regulation (EC) No. Type
1272/2008 [CLP]
xylene REACH #: ≥50 - ≤72 Flam. Liq. 3, H226 [1] [2]
01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
Asp. Tox. 1, H304
ethylbenzene REACH #: ≥10 - ≤24 Flam. Liq. 2, H225 [1] [2]
01-2119489370-35 Acute Tox. 4, H332
EC: 202-849-4 STOT RE 2, H373 (hearing
CAS: 100-41-4 organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
n-butyl acetate REACH #: ≥10 - <20 Flam. Liq. 3, H226 [1] [2]
01-2119485493-29 STOT SE 3, H336
EC: 204-658-1 EUH066
CAS: 123-86-4
See Section 16 for the full
text of the H statements
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or
have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures


4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and seek medical
advice.
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart
for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or
Skin contact use recognised skin cleanser. Do NOT use solvents or thinners.
: If swallowed, seek medical advice immediately and show the container or label.
Ingestion Keep person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or self-
contained breathing apparatus. It may be dangerous to the person providing aid to give
mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before
removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and


delayed Over-exposure signs/symptoms

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Jotun Thinner No. 10

SECTION 4: First aid measures


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following: respiratory
tract irritation
coughing
Skin contact : Adverse symptoms may include the following: irritation
redness
: Adverse symptoms may include the following: nausea or
Ingestion vomiting
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have
been ingested or inhaled.
Specific treatments : No specific treatment.
See toxicological information (Section 11)

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture


Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may cause a
substance or health hazard.
mixture
: Decomposition products may include the following materials: carbon monoxide, carbon
Hazardous combustion dioxide, smoke, oxides of nitrogen.
products

5.3 Advice for firefighters


Special protective : Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or
actions for fire-fighters watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or
precautions sewers, inform the appropriate authorities in accordance with local regulations.

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Jotun Thinner No. 10

SECTION 6: Accidental release measures


6.3 Methods and : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
material for containment vermiculite or diatomaceous earth and place in container for disposal according to local
and cleaning up regulations (see Section 13). Preferably clean with a detergent. Avoid using solvents.

: See Section 1 for emergency contact information.


6.4 Reference to See Section 8 for information on appropriate personal protective equipment. See
other sections Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for
any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the
occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been
excluded. Electrical equipment should be protected to the appropriate standard.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should
wear antistatic footwear and clothing and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this
mixture. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on
appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one. Comply
with the health and safety at work laws.
Do not allow to enter drains or watercourses.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed respirator during the
spraying process and until such time as the particulates and solvent vapour concentration has fallen below the exposure limits.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away
from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage.

7.3 Specific end use(s)


Recommendations : Not available.
Industrial sector : Not available.
specific solutions

SECTION 8: Exposure controls/personal protection


The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).
8.1 Control parameters
Occupational exposure
limits

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SECTION 8: Exposure controls/personal protection


Product/ingredient name Exposure limit values
xylene EH40/2005 WELs (United Kingdom (UK), 8/2018). Absorbed
through skin.
STEL: 441 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 8/2018). Absorbed
through skin.
STEL: 552 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.
TWA: 441 mg/m³ 8 hours.
n-butyl acetate EH40/2005 WELs (United Kingdom (UK), 8/2018).
STEL: 966 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 724 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.

Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere or
procedures biological monitoring may be required to determine the effectiveness of the ventilation or
other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European
Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use
of procedures for the assessment of exposure to chemical and biological agents) European
Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be required.

DNELs/DMELs
Product/ingredient name Exposure Value Population Effects
xylene Short term 289 mg/m³ Workers Systemic
Inhalation
Short term 289 mg/m³ Workers Local
Inhalation
Long term Dermal 180 mg/kg Workers Systemic
bw/day
Long term 77 mg/m³ Workers Systemic
Inhalation
Long term Dermal 108 mg/kg Consumers Systemic
bw/day
Long term 14.8 mg/m³ Consumers Systemic
Inhalation Long
term Oral 1.6 mg/kg Consumers Systemic
bw/day 293
ethylbenzene Short term mg/m³ Workers Local
Inhalation
Long term Dermal 180 mg/kg Workers Systemic
bw/day
Long term 77 mg/m³ Workers Systemic
Inhalation Long
term Inhalation 15 mg/m³ Consumers Systemic
Long term Oral
Consumers Systemic

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1.6 mg/kg
n-butyl acetate Short term Workers Systemic
bw/day 960
Inhalation
mg/m³

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Jotun Thinner No. 10

SECTION 8: Exposure controls/personal protection


Short term 960 mg/m³ Workers Local
Inhalation
Long term 480 mg/m³ Workers Systemic
Inhalation
Long term 480 mg/m³ Workers Local
Inhalation
Short term 859.7 mg/ Consumers Systemic
Inhalation m³
Short term 859.7 mg/ Consumers Local
Inhalation m³
Long term 102.34 mg/ Consumers Systemic
Inhalation m³
Long term 102.34 mg/ Consumers Local
Inhalation m³
PNECs
Product/ingredient name Compartment Detail Value Method Detail
xylene Fresh water 0.327 mg/l -
Marine 0.327 mg/l -
Sewage Treatment 6.58 mg/l -
Plant
Fresh water sediment 12.46 mg/kg dwt -
Marine water sediment 12.46 mg/kg dwt -
Soil 2.31 mg/kg dwt -
ethylbenzene Fresh water 0.1 mg/l -
Marine 0.01 mg/l -
Sewage Treatment 9.6 mg/l -
Plant
Fresh water sediment 13.7 mg/kg dwt -
Soil 2.68 mg/kg dwt -
Secondary Poisoning 20 mg/kg -
n-butyl acetate Fresh water 0.18 mg/l -
Marine 0.018 mg/l -
Sewage Treatment 35.6 mg/l -
Plant
Fresh water sediment 0.981 mg/kg dwt -
Marine water sediment 0.0981 mg/kg dwt -
Soil 0.0903 mg/kg dwt -

8.2 Exposure controls


Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be achieved by the
controls use of local exhaust ventilation and good general extraction. If these are not sufficient to
maintain concentrations of particulates and solvent vapours below the OEL, suitable
respiratory protection must be worn.
Individual protection
measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,
: smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers are
close to the workstation location.
Safety eyewear complying to EN 166 should be used when a risk assessment indicates
Eye/face protection : this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a
higher degree of protection: chemical splash goggles.

Skin protection

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Jotun Thinner No. 10

SECTION 8: Exposure controls/personal protection


Gloves : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product. The
instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical damage
and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be applied once
exposure has occurred.
Wear suitable gloves tested to EN374.
Recommended, gloves(breakthrough time) > 8 hours: Teflon, polyvinyl alcohol (PVA), 4H
May be used, gloves(breakthrough time) 4 - 8 hours: butyl rubber, nitrile rubber
Not recommended, gloves(breakthrough time) < 1 hour: neoprene, PVC, Viton®, PE

For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this product is
the most appropriate and takes into account the particular conditions of use, as included in the
user's risk assessment.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin : Appropriate footwear and any additional skin protection measures should be selected based
protection on the task being performed and the risks involved and should be approved by a specialist
before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter when
spraying this product, according to EN 14387(as filter combination A2-P2). In confined
spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical
properties Appearance
Physical state : Liquid.
Colour : Clear.
Odour : Characteristic.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point/freezing point : Not applicable.
Initial boiling point and : Lowest known value: 126°C (258.8°F) (n-butyl acetate). Weighted average: 135.
boiling range 13°C (275.2°F)
Flash point : Closed cup: 27°C
Evaporation rate : Highest known value: 1 (n-butyl acetate) Weighted average: 0.81compared with butyl
acetate
Flammability (solid, gas) : Not applicable.
Upper/lower flammability or : 0.8 - 7.6%
explosive limits

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SECTION 9: Physical and chemical properties


Vapour pressure : Highest known value: 1.5 kPa (11.3 mm Hg) (at 20°C) (n-butyl acetate).
Weighted average: 1.03 kPa (7.73 mm Hg) (at 20°C)
Vapour density : Highest known value: 4 (Air = 1) (n-butyl acetate). Weighted average: 3.73 (Air = 1)
: 0.871 g/cm³
Density : Insoluble in the following materials: cold water and hot water.
Solubility(ies) : Not available.
Partition coefficient: n-
octanol/ water
: Lowest known value: 415°C (779°F) (n-butyl acetate).
Auto-ignition temperature
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): <0.205 cm2/s (<20.5 mm2/s)
Explosive properties : Not available.
Oxidising properties : Not available.

9.2 Other information


No additional information.

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions: oxidising
agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide, carbon
decomposition products dioxide, smoke, oxides of nitrogen.

SECTION 11: Toxicological information


11.1 Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Vapour Rat 20 mg/l 4 hours
LD50 Oral Rat 4300 mg/kg -
TDLo Dermal Rabbit 4300 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat - Male 17.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
n-butyl acetate LC50 Inhalation Vapour Rat >21.1 mg/l 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 13100 mg/kg -
Acute toxicity estimates
Route ATE value
Dermal 1629.6 mg/kg
Inhalation (vapours) 21.56 mg/l
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Skin - Mild irritant Rat - 8 hours 60 -
microliters

Date of issue/Date of : 31.10.2019 Date of previous : Version 1


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Jotun Thinner No. 10

SECTION 11: Toxicological information


Sensitisation
Based on available data, the classification criteria are not met.
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
xylene Category 3 Not applicable. Respiratory tract
irritation Narcotic
n-butyl acetate Category 3 Not applicable. effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
ethylbenzene Category 2 Not determined hearing organs
Aspiration hazard
Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1 ASPIRATION
ethylbenzene HAZARD - Category 1
Other information : None identified.

SECTION 12: Ecological information


12.1 Toxicity
There are no data available on the mixture itself. Do
not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is not
classified as hazardous to the environment.
Product/ingredient name Result Species Exposure
ethylbenzene Acute EC50 7.2 mg/l Algae 48 hours
Acute EC50 2.93 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
No known significant effects or critical hazards.

12.2 Persistence and degradability


Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
ethylbenzene - - Readily

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 to 25.9 low
ethylbenzene 3.6 - low
n-butyl acetate 2.3 - low

Date of issue/Date of : 31.10.2019 Date of previous : Version 11/


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Jotun Thinner No. 10

SECTION 12: Ecological information

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


PBT : Not applicable.
vPvB : Not applicable.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for
any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Dispose of surplus and non- recyclable products via a licensed
waste disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste : Yes.
Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer
apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
European waste : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances
catalogue (EWC)
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from the
relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or national
legal provisions.
Type of packaging European waste catalogue (EWC)
CEPE Paint Guidelines packaging containing residues of or contaminated by hazardous substances
15 01 10*

Special precautions : This material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product residues may
create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or
grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal
of spilt material and runoff and contact with soil, waterways, drains and sewers.

Date of issue/Date of : 31.10.2019 Date of previous : Version 12/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Jotun Thinner No. 10

SECTION 14: Transport information


ADR/RID ADN IMDG IATA
14.1 UN number UN1263 UN1263 UN1263 UN1263

14.2 UN proper Paint related material Paint related material Paint related material Paint related material
shipping name
14.3 Transport 3 3 3 3
hazard class(es)

14.4 Packing III III III III


group
14.5 No. No. No. No.
Environmental
hazards

Additional information
ADR/RID : Hazard identification number 30
Tunnel code (D/E)
IMDG : Emergency schedules F-E, S-E

14.6 Special precautions : Transport within user’s premises: always transport in closed containers that are upright
for user and secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.

14.7 Transport in bulk : Not applicable.


according to Annex II of
Marpol and the IBC
Code

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high
concern None of the components are
listed.
Annex XVII - : Not applicable.
Restrictions on the
manufacture, placing on
the market and use of
certain dangerous
substances, mixtures
and articles
Other EU regulations
VOC : The provisions of Directive 2004/42/EC on VOC apply to this product. Refer to the
product label and/or technical data sheet for further information.
VOC for Ready-for- : Not applicable.
Use Mixture
Europe inventory : All components are listed or exempted.

Date of issue/Date of : 31.10.2019 Date of previous : Version 13/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Ozone depleting substances (1005/2009/EU)
Not listed.

Date of issue/Date of : 31.10.2019 Date of previous : Version 14/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Jotun Thinner No. 10

SECTION 15: Regulatory information


Prior Informed Consent (PIC) (649/2012/EU)
Not listed.

Seveso Directive
This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on major
accident hazards.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol (Annexes A, B, C, E)
Not listed.
Stockholm Convention on Persistent Organic Pollutants
Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals


Not listed.

15.2 Chemical safety : Not applicable.


assessment

SECTION 16: Other information


Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DMEL = Derived Minimal Effect Level DNEL
= Derived No Effect Level
EUH statement = CLP-specific Hazard statement PBT =
Persistent, Bioaccumulative and Toxic PNEC =
Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Acute Tox. 4, H312 Calculation method
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method
STOT SE 3, H335 Calculation method
STOT RE 2, H373 (hearing organs) Calculation method
Asp. Tox. 1, H304 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated

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Jotun Thinner No. 10

SECTION 16: Other information


exposure.
Full text of classifications [CLP/GHS]
Acute Tox. 4, H312 Acute Tox. 4, H332 Asp. Tox. 1, H304ACUTE
EUH066
TOXICITY (dermal) - Category 4 ACUTE TOXICITY (inhalation) - Cat
Eye Irrit. 2, H319 Flam. Liq. 2, H225 Flam. Liq. 3, H226
Repeated
Skin Irrit.
exposure
2, H315may
STOTcause
REskin
2, H373
dryness or cracking. SERIOUS EYE DAMAGE
FLAMMABLE LIQUIDS - Category 3
STOT SE 3, H335 STOT SE 3, H336 SKIN CORROSION/IRRITATION - Category 2 SPECIFIC TARGET ORGAN T
EXPOSURE - Category 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Narcotic effects) - Category 3

Date of printing : 31.10.2019


Date of issue/ Date : 31.10.2019
of revision
Date of previous : 12.02.2019
issue Version : 2
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing
and practical experience. Jotun's products are considered as semi-finished goods and as such, products
are often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of
the product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

Date of issue/Date of : 31.10.2019 Date of previous : Version 16/


Anne

Jotun Thinner No. 10


Exposure Scenario: Use in coatings Industrial use
-
Sector of Use Process Category : Industrial use
Environmental release category(ies) : PROC05 PROC08a
: ERC4

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by
hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures


Control of worker exposure
Frequency and duration of use General - Operational conditions
: Covers daily exposures up to 8 hours
General - Risk management measures : Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls t

Type of activity or process Risk management measures


Preparation of material for application : Provide a good standard of controlled ventilation (10 to 15 air changes per hour).
Equipment cleaning and maintenance : Drain down system prior to equipment break-in or maintenance.

Control of environmental exposure


Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations. See
treatment of waste for disposal Section 13 for additional waste treatment information.
Conditions and measures related to
external recovery of waste : External recovery and recycling of waste should comply with applicable local and/or national regulations.

Additional information
The exposure scenario for the mixture is based on the following substances: REACH #:
01-2119488216-32

Page:
Anne

Jotun Thinner No. 10


Exposure Scenario: Use in coatings Professional use
-
Sector of Use Process Category : Professional use
Environmental release category(ies) : PROC05 PROC08a
: ERC8a ERC8d

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by
hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures


Control of worker exposure
Frequency and duration of use General - Operational conditions
: Covers daily exposures up to 8 hours
General - Risk management measures : Assumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard
: Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. Wear suitable coveralls t

Type of activity or process Risk management measures


Preparation of material for application - : Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out activities
Indoor involving exposure for more than 1 hour.
or
Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to
EN140 with type A/P2 filter or better.
Preparation of material for application - : Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more than 1
Outdoor hour.
or
Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2 filter or
better.
Equipment cleaning and maintenance : Drain down system prior to equipment break-in or maintenance. Avoid carrying out activities involving
exposure for more than 4 hours.

Control of environmental exposure


Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations. See
treatment of waste for disposal Section 13 for additional waste treatment information.
Conditions and measures related to
external recovery of waste : External recovery and recycling of waste should comply with applicable local and/or national regulations.

Additional information
The exposure scenario for the mixture is based on the following substances: REACH #:
01-2119488216-32

Page:
Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 3: Composition/information on ingredients

3.2 Mixtures
.

Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type


zinc powder - zinc dust REACH #: 01-2119467174-37 ≥90 Aquatic Acute 1, H400 (M=1) - [1]
(stabilized) EC: 231-175-3 Aquatic Chronic 1, H410 (M=10)
CAS: 7440-66-6
zinc oxide REACH #: 01-2119463881-32 ≥5 - ≤10 Aquatic Acute 1, H400 (M=1) - [1]
EC: 215-222-5 Aquatic Chronic 1, H410 (M=1)
CAS: 1314-13-2
Index: 030-013-00-7
See Section 16 for the full text of the H statements declared
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as
hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy

SECTION 4: First aid measures

4.1 Description of first aid measures


General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate treatment
(first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seek medical
attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and seek medical
advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest.
Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-
enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and


delayed Potential acute health effects
Eye contact : No known significant effects or critical hazards. No
Inhalation : known significant effects or critical hazards. No
Skin contact : known significant effects or critical hazards. No
Ingestion : known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : No specific data.
Inhalation : No specific data.
Skin contact : No specific data.
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.

Version: Page:
Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 5: Firefighting measures

5.1 Extinguishing media


Extinguishing media :
Recommended: Approved Class D extinguisher or smother with dry sand, dry clay or dry ground limestone.
NOT TO BE USED: WATER. Risk of formation of very flammable and explosive vapours.

5.2 Special hazards arising from the substance or mixture


Hazards from the substance or
This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material
mixture :
must be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products :
Decomposition products may include the following materials: metal oxide/oxides

5.3 Advice for firefighters


Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk
or without suitable training. Exposure to decomposition products may cause a health hazard. Cool closed containers exposed to fire with water. Do not
release runoff from fire to drains or watercourses. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus
(SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming
to European standard EN 469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Do not use water. Violent reaction may occur. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal
risk or without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions


Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large
quantities.

6.3 Methods and materials for containment and cleaning up


Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep
up material and place in a designated, labeled waste container.

6.4 Reference to other sections


See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment. See
Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Open with care, danger of overpressure.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area where this
material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers made from the same
material as the original one.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and ignition sources.
Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids as well as of amines, alcohols and water. No smoking.
Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)


See separate Product Data Sheet for recommendations or industrial sector specific solutions.

Version: Page:
Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Product/ingredient name Exposure limit values

No exposure limit value known.

Recommended monitoring procedures


If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the
effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to
monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres -
Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national
guidance documents for methods for the determination of hazardous substances will also be required.
Derived effect levels
Product/ingredient name Type Exposure Value Population Effects
zinc powder - zinc dust (stabilized) DNEL Long term Dermal 83.3 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 5 mg/m³ Workers Systemic
zinc oxide DNEL Long term Inhalation 5 mg/m³ Workers Systemic
DNEL Long term Dermal 83 mg/kg bw/day Workers Systemic
Predicted effect concentrations
Product/ingredient name Compartment Detail Value Method Detail
zinc powder - zinc dust (stabilized) Fresh water 20.6 µg/l -
Marine 6.1 µg/l -
Sewage Treatment Plant 52 µg/l -
Fresh water sediment 118 mg/kg dwt -
Marine water sediment 56.5 mg/kg dwt -
Soil 35.6 mg/kg dwt -
zinc oxide Fresh water 20.6 µg/l -
Marine 6.1 µg/l -
Sewage Treatment Plant 52 µg/l -
Marine water sediment 56.5 mg/kg dwt -
Soil 35.6 mg/kg dwt -

8.2 Exposure controls


Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work- station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be worn
when soiling is so great that regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following
protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with
side-shields.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality
of the chemical-resistant protective gloves must be chosen as a function of the specific workplace
concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type.
Body protection : Personal protective equipment for the body should be selected based on the task being performed and the risks
involved handling this product.
Respiratory protection :
Environmental exposure
controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.

Version: Page:
Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Physical state :
Solid.
Odor :
Non-characteristic.
pH :
Testing not relevant or not possible due to nature of the product.
Melting point/freezing point :
419.85°C This is based on data for the following ingredient: Zinc
Boiling point/boiling range :
Testing not relevant or not possible due to nature of the product. Non-
Flash point :
flammable.
Evaporation rate :
Testing not relevant or not possible due to nature of the product. Non-
Flammability :
flammable.
Lower and upper explosive No specific data.
(flammable) limits :
Vapor pressure :
Testing not relevant or not possible due to nature of the product.
Vapor density :
Testing not relevant or not possible due to nature of the product.
Specific gravity : 7.1 g/cm³
Solubility(ies) :
Partition coefficient (LogKow) :
Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature :
Testing not relevant or not possible due to nature of the product.
Decomposition temperature :
Testing not relevant or not possible due to nature of the product.
Viscosity :
Explosive properties :
Slightly explosive in the presence of the following materials or conditions: moisture. Testing
Oxidizing properties :
not relevant or not possible due to nature of the product.

9.2 Other information


Solvent(s) % by weight :
Weighted average: 0 %
Water % by weight : Weighted average: 0 %
VOC content :
0 g/l
VOC content, Ready-for-use
Not applicable
mixture :
TOC Content : Weighted average: 0 g/l
Solvent Gas : Weighted average: 0 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability


The product is stable.

10.3 Possibility of hazardous reactions


Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid


No specific data.

10.5 Incompatible materials


Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials, organic materials, acids, alkalis and moisture.

10.6 Hazardous decomposition products


When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: metal oxide/oxides

Version: Page:
Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008


No known significant effects or critical hazards.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
zinc powder - zinc dust (stabilized) LC50 Inhalation Dusts and mists Rat 5.41 mg/l 4 hours
LD50 Oral Rat >2000 mg/kg -
zinc oxide LC50 Inhalation Dusts and mists Rat >5.7 mg/l 4 hours
LD50 Dermal Rat >2000 mg/kg -
LD50 Oral Rat >5000 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
zinc powder - zinc dust (stabilized) 5.41

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
zinc powder - zinc dust (stabilized) Skin - Mild irritant Human - 72 hours 300 Micrograms Intermittent
zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
Skin - Mild irritant Rabbit - 24 hours 500 milligrams
Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)


Product/ingredient name Category Route of exposure Target organs
No known data avaliable in our database.

Specific target organ toxicity (repeated exposure)


Product/ingredient name Category Route of exposure Target organs
No known data avaliable in our database.

Aspiration hazard
Product/ingredient name Result
No known data avaliable in our database.

Information on the likely routes of exposure


Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
11.2 Information on other hazards
Endocrine disrupting properties :
No known data avaliable in our database.
Other information :
No additional known significant effects or critical hazards.

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Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Very toxic to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
zinc powder - zinc dust (stabilized) Acute EC50 0.3 mg/l Marine water Algae 72 hours
Acute EC50 0.354 mg/l Fresh water Daphnia Fish 48 hours
Acute LC50 0.238 - 0.269 mg/l Fresh water Chronic Algae - Pseudokirchneriella subcapitata 96 hours
EC10 27.3 µg/l Fresh water - Exponential growth phase 72 hours
Daphnia - Daphnia magna
Chronic EC10 59.2 µg/l Fresh water Aquatic plants - Ceratophyllum 21 days
Chronic NOEC 9 mg/l Fresh water demersum 3 days
Crustaceans - Palaemon elegans
Chronic NOEC 178 µg/l Marine water Fish - Cyprinus carpio 21 days
Chronic NOEC 2.6 µg/l Fresh water Fish 4 weeks
zinc oxide LC50 0.169 mg/l Algae - Pseudokirchneriella subcapitata 96 hours
Acute EC50 0.17 mg/l - Exponential growth phase 72 hours
Daphnia - Pseudokirchneriella
Acute EC50 1 mg/l subcapitata - Exponential growth phase 48 hours
Daphnia - Daphnia magna - Neonate
Acute LC50 24600 µg/l Fresh water 48 hours

12.2 Persistence and degradability


Product/ingredient name Aquatic half-life Photolysis Biodegradability
zinc oxide - - Not readily

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
zinc oxide 2.2 60960 high

12.4 Mobility in soil


Soil/water partition coefficient
No known data avaliable in our database. No
(KOC) :
Mobility : known data avaliable in our database.

12.5 Results of PBT and vPvB assessment


Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties


No known data avaliable in our database.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose of according to
all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11* Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible.

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Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by sea, IATA
for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN3077 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not regulated as
Class SUBSTANCE, SOLID, N.O.S. (Zinc) a dangerous good when
transported in sizes of ≤5 L or
≤5 kg, provided the packagings
meet the general provisions of
4.1.1.1, 4.1.1.2
and 4.1.1.4 to 4.1.1.8.
IMDG UN3077 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not
Class SUBSTANCE, SOLID, N.O.S. (Zinc). regulated as a
(Zinc) dangerous good when
transported in sizes of
≤5 L or ≤5 kg, provided
the packagings meet the
general provisions of
4.1.1.1, 4.1.1.2 and
4.1.1.4 to 4.1.1.8.
Emergency schedules
F-A, S-F

IATA UN3077 ENVIRONMENTALLY HAZARDOUS 9 III Yes. This product is not regulated as
Class SUBSTANCE, SOLID, N.O.S. (Zinc) a dangerous good when
transported in sizes of ≤5 L or
≤5 kg, provided the packagings
meet the general provisions of
5.0.2.4.1,
5.0.2.6.1.1 and 5.0.2.8.
PG* : Packing group
Env.* : Environmental hazards

14.6 Special precautions for user


Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high
concern None of the components are
listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Not
applicable.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category

E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1

15.2 Chemical Safety Assessment

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Safety Data Sheet
Hempel's Zinc Metal Pigment

SECTION 16: Other information


Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] EUH
statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS] :Aquatic Acute 1 AQUATIC HAZARD (ACUTE) - Category 1
Aquatic Chronic 1 AQUATIC HAZARD (LONG-TERM) - Category 1
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
AQUATIC HAZARD (ACUTE) Calculation method
AQUATIC HAZARD (LONG-TERM) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides guidance on
health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee of the technical
preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: Page:
Safe Use of Mixture
Information
This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the product's Safety
Data Sheet and labels.

General description of the process covered


Indoor or outdoor spray painting by professionals or with brush, roller, putty knife, dipping etc. with good general room ventilation
This safe use information is
: Professional spray painting and/or low-energy painting, local effect Health
linked to
hazard: Not classified.

Sector(s) of use : Industrial uses - Professional uses


Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use
: Indoor or outdoor use

Risk management measures (RMM)


Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes
per hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection None
application hours ventilation - Outdoors according to EN 166.

Loading of application PROC08a More than 4 Good general room 3-5 None None None
equipment and handling hours ventilation - Outdoors
of coated parts before
curing

Professional application of PROC10 More than 4 Good general room 3-5 None None None
coatings by brush or roller hours ventilation - Outdoors

Professional application of PROC11 More than 4 Good general room 3-5 None Use eye protection None
coatings by spraying hours ventilation - Outdoors according to EN 166.

Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation - Outdoors
technologies

Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection None
hours ventilation - Outdoors according to EN 166.

Waste management PROC08a More than 4 Local exhaust 3-5 None None None
hours ventilation - Outdoors
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.

Page:
Safe Use of Mixture
Information
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.

Page:
Safety Data Sheet
Hempadur Avantguard 750

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 - Indonesia

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Product name : Hempadur Avantguard 750 Base
Product identity : 1736U19840
Product type : epoxy zinc primer

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : metal industry
Ready-for-use mixture : 1736G = 1736U 17 Vol/ 97043 3 Vol
Identified uses : Industrial applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details :
HEMPEL (INDONESIA) BEKASI Emergency telephone number (with hours of operation)
Jalan Raya Sultan Agung Km. 27
Pondok Ungu - Bekasi 17132 See Section 4 of the safety data sheet (first aid
Indonesia measures).
Tel.: + 62 21 8843385
Indonesia.ID@hempel.com
Date of issue : 19 April 2021
Date of previous issue : 11 May 2019.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Product definition : Mixture
GHS Classification
FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Signal word : Hazard


Warning
statements :
H226 - Flammable liquid and vapor.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H319 - Causes serious eye irritation.
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention :
Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-
sparking tools. Take action to prevent static discharges. Avoid release to the environment. Avoid breathing vapor.
Wash thoroughly after handling.
Response :
Collect spillage. Take off contaminated clothing and wash it before reuse. IF ON SKIN: Wash with plenty of
water. If skin irritation or rash occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice or attention.
Storage :
Store in a well-ventilated place. Keep cool.
Disposal :
Dispose of contents and container in accordance with all local, regional, national and international regulations.

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Safety Data Sheet
Hempadur Avantguard 750

SECTION 2: Hazards identification


Hazardous ingredients :
zinc powder - zinc dust (stabilized)
middle molecular epoxy resin MMW 700-1200
xylene
butan-1-ol
oxirane, mono[(C12-14-alkyloxy)methyl] derivs.

2.3 Other hazards


Other hazards which do not result in
None known.
classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % GHS Classification

zinc powder - zinc dust (stabilized) 7440-66-6 ≥50 - ≤75 AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
middle molecular epoxy resin MMW 25068-38-6 ≥5 - ≤10 SKIN CORROSION/IRRITATION - Category 2
700-1200 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SKIN SENSITIZATION - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 2
xylene 1330-20-7 ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
zinc oxide 1314-13-2 ≥3 - ≤5 AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
butan-1-ol 71-36-3 ≥1 - <3 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
ethylbenzene 100-41-4 ≥1 - ≤3 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
- Category 2
ASPIRATION HAZARD - Category 1
oxirane, mono[(C12-14-alkyloxy) 68609-97-2 ≥1 - ≤3 SKIN CORROSION/IRRITATION - Category 2
methyl] derivs. SKIN SENSITIZATION - Category 1
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as
hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures


General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate treatment
(first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Seek immediate medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and seek medical
advice.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest.
Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-
enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the
person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed

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Safety Data
Hempel's Thinner 08450

SECTION 14: Transport information

14.1 14.2 14.3 14.4 14.5


UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT RELATED MATERIAL 3 III No.


Class

IMDG UN1263 PAINT RELATED MATERIAL 3 III No. Emergency schedules


Class F-E, S-E

IATA UN1263 PAINT RELATED MATERIAL 3 III No. -


Class

PG* : Packing group


Env.* : Environmental hazards

14.6 Special precautions for user


Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

SECTION 16: Other information


Abbreviations and acronyms :
ATE = Acute Toxicity Estimate
GHS = Globally Harmonized System of Classification and Labelling of Chemicals DNEL =
Derived No Effect Level
PNEC = Predicted No Effect Concentration RRN =
REACH Registration Number
GHS Classification

Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (dermal) - Category 4 Calculation method
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method
ASPIRATION HAZARD - Category 1 Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides guidance on
health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee of the technical
preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: Page:
Safety Data Sheet
Hempel's Accelerator &

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830 - Indonesia

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1 Product identifier
Product name : Hempel's Accelerator & Thinner
Product identity : 0870M00000
Product type : thinner

1.2 Relevant identified uses of the substance or mixture and uses advised
against Field of application : buildings and metal industry. ships and shipyards.
Identified uses : Industrial applications, Professional applications.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details :
HEMPEL (INDONESIA) BEKASI Emergency telephone number (with hours of operation)
Jalan Raya Sultan Agung Km. 27
Pondok Ungu - Bekasi 17132 See Section 4 of the safety data sheet (first aid
Indonesia measures).
Tel.: + 62 21 8843385
Indonesia.ID@hempel.com
Date of issue : 19 April 2021
Date of previous issue : 29 June 2017.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Product definition : Mixture
GHS Classification
FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (inhalation) - Category 4 SKIN
CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 See
Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Signal word : Hazard


Warning
statements :
H226 - Flammable liquid and vapor.
H315 - Causes skin irritation.
H319 - Causes serious eye irritation.
H332 - Harmful if inhaled.
H336 - May cause drowsiness or dizziness.
Precautionary statements :
Prevention :
Wear protective gloves. Wear eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-
sparking tools. Take action to prevent static discharges. Avoid breathing vapor. Wash thoroughly after handling.
IF INHALED: Call a POISON CENTER or doctor if you feel unwell. Take off contaminated clothing and wash it
Response :
before reuse. IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice or attention.
Store in a well-ventilated place. Keep container tightly closed. Keep cool.
Storage :
Dispose of contents and container in accordance with all local, regional, national and international regulations.
Disposal :
1-methoxy-2-propanol
xylene
Hazardous ingredients :
zinc chloride

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Safety Data Sheet
Hempel's Accelerator &

SECTION 2: Hazards identification

2.3 Other hazards


Other hazards which do not result in
None known.
classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Product/ingredient name Identifiers % GHS Classification

1-methoxy-2-propanol 107-98-2 ≥25 - ≤50 FLAMMABLE LIQUIDS - Category 3


SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
xylene 1330-20-7 ≥25 - ≤46 FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (dermal) - Category 4
ACUTE TOXICITY (inhalation) - Category 4
SKIN CORROSION/IRRITATION - Category 2
ethylbenzene 100-41-4 ≥5 - <10 FLAMMABLE LIQUIDS - Category 2
ACUTE TOXICITY (inhalation) - Category 4
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
- Category 2
ASPIRATION HAZARD - Category 1
propan-2-ol 67-63-0 ≥5 - ≤10 FLAMMABLE LIQUIDS - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
zinc chloride 7646-85-7 ≥1 - <2.5 ACUTE TOXICITY (oral) - Category 4
SKIN CORROSION/IRRITATION - Category 1B
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3
AQUATIC HAZARD (ACUTE) - Category 1
AQUATIC HAZARD (LONG-TERM) - Category 1
toluene 108-88-3 <1 FLAMMABLE LIQUIDS - Category 2
SKIN CORROSION/IRRITATION - Category 2
TOXIC TO REPRODUCTION - Category 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Narcotic effects) - Category 3
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)
- Category 2
ASPIRATION HAZARD - Category 1
2-methoxypropanol 1589-47-5 <0.3 FLAMMABLE LIQUIDS - Category 3
SKIN CORROSION/IRRITATION - Category 2
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 1
TOXIC TO REPRODUCTION - Category 1B
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)
(Respiratory tract irritation) - Category 3

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as
hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures


4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an
unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate treatment
(first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 5 minutes,
occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seek medical
attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If
unconscious, place in recovery position and get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest.
Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-
enter the mouth and throat.

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Safety Data Sheet
Hempel's Accelerator &

SECTION 4: First aid measures


Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes
are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation.

4.2 Most important symptoms and effects, both acute and


delayed Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : Harmful if inhaled. Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness.
Causes skin irritation.
Skin contact :
Can cause central nervous system (CNS) depression.
Ingestion :
Over-exposure signs/symptoms
Adverse symptoms may include the following: pain or
Eye contact : irritation
watering
redness
Adverse symptoms may include the following: nausea
Inhalation : or vomiting
headache drowsiness/fatigue
dizziness/vertigo
unconsciousness
Adverse symptoms may include the following:
irritation
Skin contact : redness
No specific data.

Ingestion :

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media


Extinguishing media :
Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be
used: waterjet.

5.2 Special hazards arising from the substance or mixture


Hazards from the substance or
Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a
mixture :
pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
This material is harmful to aquatic life with long lasting effects. Fire water contaminated with this material must
be contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous combustion products :
Decomposition products may include the following materials: carbon oxides halogenated compounds metal
oxide/oxides

5.3 Advice for firefighters


Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk
or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Cool closed
containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should wear appropriate protective
equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for fire-fighters (including
helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

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Safety Data Sheet
Hempel's Accelerator &

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures


Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid breathing
vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or without suitable training. If
the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local regulations.

6.2 Environmental precautions


Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has
caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large
quantities.

6.3 Methods and materials for containment and cleaning up


Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non- combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Use
spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same hazard as the spilled product.

6.4 Reference to other sections


See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment. See
Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


7.1 Precautions for safe handling
Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the product should be used only
in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment should be protected to the appropriate
standard. To dissipate static electricity during transfer, ground drum and connect to receiving container with bonding strap. No sparking tools should be
used.
Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area where this
material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers made from the same
material as the original one.

7.2 Conditions for safe storage, including any incompatibilities


Store in accordance with local regulations. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Keep out of the
reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids. No smoking. Prevent unauthorized access. Containers that are
opened must be carefully resealed and kept upright to prevent leakage.

7.3 Specific end use(s)


See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters


Product/ingredient name Exposure limit values

1-methoxy-2-propanol EU OEL (Europe, 10/2019). Absorbed through skin.


STEL: 568 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 375 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
xylene EU OEL (Europe, 10/2019). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
ethylbenzene EU OEL (Europe, 10/2019). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
propan-2-ol EU OEL (Europe, 2/2010).
(ACGIH) TWA: 200 ppm 8 hours.

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Safety Data Sheet
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SECTION 8: Exposure controls/personal protection


(ACGIH) STEL: 400 ppm 15 minutes.
toluene EU OEL (Europe, 10/2019). Absorbed through skin.
TWA: 192 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
STEL: 384 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.

Recommended monitoring procedures


If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the
effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to
monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and measurement strategy) European Standard EN 14042 (Workplace atmospheres -
Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents) European Standard EN 482
(Workplace atmospheres - General requirements for the performance of procedures for the measurement of chemical agents) Reference to national
guidance documents for methods for the determination of hazardous substances will also be required.

8.2 Exposure controls


Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust lowest possible
and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work- station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be worn
when soiling is so great that regular work clothes do not adequately protect skin against contact with the
product. Safety eyewear should be used when there is a likelihood of exposure.
Hygiene measures :

Eye/face protection :

Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using
lavatory, and at the end of day.
Hand protection :
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is
necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following
protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash
goggles.
Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The quality
of the chemical-resistant protective gloves must be chosen as a function of the specific workplace
concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the appropriate
type. Below listed glove(s) should be regarded as generic advice:

May be used: neoprene rubber, butyl rubber, polyvinyl chloride (PVC), natural rubber (latex) Recommended: Silver
Shield / Barrier / 4H gloves, nitrile rubber, Viton®, polyvinyl alcohol (PVA)

Body protection :
Personal protective equipment for the body should be selected based on the task being performed and the risks
involved handling this product.
Respiratory protection :
Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the
safe working limits of the selected respirator. If working areas have insufficient ventilation: When the product
is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask
equipped with gas filter of type A, when grinding use particle filter of type P. Be sure to use an
approved/certified respirator or equivalent.
Environmental exposure
controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection
legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to
acceptable levels.

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SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties


Physical state :
Liquid.
Color : Transparent
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : -96°C This is based on data for the following ingredient: 1-methoxy-2-propanol Testing not
Boiling point/boiling range : relevant or not possible due to nature of the product.
Flash point : Closed cup: 24°C (75.2°F)
Evaporation rate :
Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and static
discharge, heat and oxidizing materials.
Lower and upper explosive 0.8 - 13.74 vol %
(flammable) limits :
Vapor pressure : 1.133 kPa This is based on data for the following ingredient: 1-methoxy-2-propanol Testing
Vapor density : not relevant or not possible due to nature of the product.
Specific gravity : 0.901 g/cm³
Solubility(ies) : Easily soluble in the following materials: cold water and hot water. Testing
Partition coefficient (LogKow) : not relevant or not possible due to nature of the product. Lowest known value:
Auto-ignition temperature : 270°C (518°F) (1-methoxy-2-propanol).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Testing not relevant or not possible due to nature of the product.
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information


Solvent(s) % by weight :
Weighted average: 97 %
Water % by weight : Weighted average: 0 %
VOC content : 878.3 g/l
TOC Content : Weighted average: 624 g/l
Solvent Gas : Weighted average: 0.227 m³/l

SECTION 10: Stability and reactivity


10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability


The product is stable.

10.3 Possibility of hazardous reactions


Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid


Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of
ignition.

10.5 Incompatible materials


Highly reactive or incompatible with the following materials: oxidizing materials and acids.
Reactive or incompatible with the following materials: reducing materials, organic materials, alkalis and moisture.

10.6 Hazardous decomposition products


When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed: Decomposition products
may include the following materials: carbon oxides halogenated compounds metal oxide/oxides

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Safety Data Sheet
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SECTION 11: Toxicological information

11.1 Information on toxicological effects


Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory system irritation and
adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.
Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of consciousness. Repeated or
prolonged contact with the preparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption through
the skin. If splashed in the eyes, the liquid may cause irritation and reversible damage. Accidental swallowing may cause stomach pain. Chemical lung
inflammation may occur if the product is taken into the lungs via vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
1-methoxy-2-propanol LD50 Dermal Rabbit 13 g/kg -
LD50 Dermal Rabbit >2000 mg/kg -
LD50 Oral Rat 4016 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
propan-2-ol LD50 Dermal Rabbit >5000 mg/kg -
LD50 Intraperitoneal Rabbit 667 mg/kg -
LD50 Oral Rat >5000 mg/kg -
LDLo Oral Human 3570 mg/kg -
zinc chloride LD50 Oral Rat 1100 - 1260 mg/kg -
toluene LC50 Inhalation Vapor Rat >20 mg/l 4 hours
LD50 Oral Rat 636 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
No known significant effects or critical hazards. No
known significant effects or critical hazards.

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
1-methoxy-2-propanol Eyes - Mild irritant Rabbit - 24 hours 500 milligrams
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
Skin - Irritant Rabbit - -
ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams
Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
propan-2-ol Eyes - Moderate irritant Rabbit - 24 hours 100 milligrams
Skin - Mild irritant Rabbit - 500 milligrams
zinc chloride Skin - Severe irritant Rabbit - 120 hours 1 Percent
toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 milligrams
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of exposure Target organs
1-methoxy-2-propanol Category 3 Narcotic effects
propan-2-ol Category 3 Narcotic effects
zinc chloride Category 3 Respiratory tract irritation
toluene Category 3 Narcotic effects
2-methoxypropanol Category 3 Respiratory tract irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 - hearing organs
toluene Category 2 - -
Aspiration hazard

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Safety Data Sheet
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SECTION 11: Toxicological information

Product/ingredient name Result


ethylbenzene ASPIRATION HAZARD - Category 1
toluene ASPIRATION HAZARD - Category 1
Information on the likely routes of exposure
Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Product/ingredient name Carcinogenic effects Mutagenic effects Developmental effects Fertility effects
2-methoxypropanol - - Repr. 1B, H360D -
(Unborn child)
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses. Harmful to aquatic life with long lasting effects.
Product/ingredient name Result Species Exposure
1-methoxy-2-propanol Acute EC50 1000 mg/l Algae - Pseudokirchneriella subcapitata 7 days
(green algae)
Acute EC50 23300 mg/l Daphnia - Daphnia magna (Water flea) Fish - 48 hours
Acute LC50 6812 mg/l Leuciscus idus 96 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Acute Algae - Pseudokirchneriella subcapitata 96 hours
zinc chloride EC50 34 µg/l Fresh water Algae - Chlorella vulgaris - Exponential 72 hours
growth phase
Acute EC50 1.8 mg/l Fresh water Acute Aquatic plants - Lemna aequinoctiales 96 hours
EC50 100 µg/l Fresh water Acute LC50 Daphnia - Daphnia magna Crustaceans - 48 hours
49.99 µg/l Fresh water Acute LC50 Moina irrasa - Neonate Fish - Limanda 48 hours
0.027 mg/l Marine water punctatissima - Pre- larvae 96 hours
Algae - Chlorella sp. - Exponential
Chronic NOEC 20 µg/l Marine water growth phase 72 hours
Crustaceans - Procambarus clarkii -
Chronic NOEC 1000 µg/l Fresh water Intermolt 21 days
Daphnia - Daphnia magna - Juvenile
Chronic NOEC 80 µg/l Fresh water (Fledgling, Hatchling, Weanling) Fish - 21 days
Oncorhynchus mykiss
Chronic NOEC 31.5 µg/l Fresh water Chronic 30 days
Algae - Pseudokirchneriella subcapitata
toluene NOEC <500000 µg/l Fresh water Chronic 96 hours
Daphnia - Daphnia magna
NOEC 1000 µg/l Fresh water 21 days

12.2 Persistence and degradability


Product/ingredient name Test Result Dose Inoculum
1-methoxy-2-propanol OECD 301E Ready 96 % - Readily - 28 days - -
Biodegradability - Modified OECD
Screening Test
xylene OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
ethylbenzene - >70 % - Readily - 28 days - -
propan-2-ol - 86 % - 14 days 100 mg/l -
toluene - 100 % - Readily - 14 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability


1-methoxy-2-propanol - - Readily
xylene - - Readily
ethylbenzene - - Readily
propan-2-ol - - Readily
toluene - - Readily

12.3 Bioaccumulative potential

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Safety Data Sheet
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SECTION 12: Ecological information

Product/ingredient name LogPow BCF Potential


1-methoxy-2-propanol <1 <100 low
xylene 3.12 8.1 - 25.9 low
ethylbenzene 3.6 - low
propan-2-ol 0.05 3 low
zinc chloride 2.2 60960 high
toluene 2.73 90 low

12.4 Mobility in soil


Soil/water partition coefficient
No known data avaliable in our database. No
(KOC) :
Mobility : known data avaliable in our database.

12.5 Results of PBT and vPvB assessment


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects


No known significant effects or critical hazards.

SECTION 13: Disposal considerations


13.1 Waste treatment methods
The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose of according to
all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof container.
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill should only be
considered when recycling is not feasible.

SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by sea, IATA
for transport by air.
14.1 14.2 14.3 14.4 14.5
UN no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT RELATED MATERIAL 3 III No.


Class

IMDG UN1263 PAINT RELATED MATERIAL 3 III No. Emergency schedules


Class F-E, S-E

IATA UN1263 PAINT RELATED MATERIAL 3 III No. -


Class

PG* : Packing group


Env.* : Environmental hazards

14.6 Special precautions for user


Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product
know what to do in the event of an accident or spillage.
14.7 Transport in bulk according to IMO instruments
Not applicable.

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SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

SECTION 16: Other information


Abbreviations and acronyms :
ATE = Acute Toxicity Estimate
GHS = Globally Harmonized System of Classification and Labelling of Chemicals DNEL =
Derived No Effect Level
PNEC = Predicted No Effect Concentration RRN =
REACH Registration Number
GHS Classification

Classification Justification
FLAMMABLE LIQUIDS - Category 3 On basis of test data
ACUTE TOXICITY (inhalation) - Category 4 Calculation method
SKIN CORROSION/IRRITATION - Category 2 Calculation method
SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides guidance on
health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee of the technical
preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

Version: Page:
Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
SAFETY DATA SHEET

Hardtop XP Comp A
SECTION 1: Identification of the substance/mixture and of the company/
undertaking
1.1 Product
identifier Product : Hardtop XP Comp A
name
Product code : 3140
Product description : Paint.
Product type : Liquid.
Other means of : Not available.
identification

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use in coatings - Industrial use Use
in coatings - Professional use
See Annex to the Safety data sheet for additional information in the Exposure Scenario(s).

1.3 Details of the supplier of the safety data sheet


Jotun Paints (Europe) Ltd.
Stather Road Flixborough,
Scunthorpe North
Lincolnshire
DN15 8RR
England

Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
SDSJotun@jotun.com

1.4 Emergency telephone number


Contact NHS Direct; phone 0845 4647 or 111. Open 24/7.

SECTION 2: Hazards identification


2.1 Classification of the substance or
mixture Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226
Skin Irrit. 2, H315
Eye Irrit. 2, H319
Skin Sens. 1, H317
Aquatic Chronic 3, H412
The product is classified as hazardous according to Regulation (EC) 1272/2008 as amended. See Section
11 for more detailed information on health effects and symptoms.

2.2 Label elements


Hazard pictograms :

Date of issue/Date of : 07.05.2020 Date of previous : No previous Version 1/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 2: Hazards identification


Signal word : Warning.
Hazard statements : H226 - Flammable liquid and vapour.
H319 - Causes serious eye irritation.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H412 - Harmful to aquatic life with long lasting effects.
Precautionary statements
General : Not applicable.
Prevention : P280 - Wear protective gloves. Wear eye or face protection.
P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P273 - Avoid release to the environment.
Response : P302 + P352 - IF ON SKIN: Wash with plenty of soap and water. P333 +
P313 - If skin irritation or rash occurs: Get medical attention.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
Storage : P403 - Store in a well-ventilated place. P235 -
Keep cool.
Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazardous ingredients : xylene
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymer with butyl
2-propenoate, comps. with polyethylene glycol hydrogen maleate C9-11-alkyl ethers n-
butyl methacrylate
bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate
Supplemental label : Not applicable.
elements
Annex XVII - Restrictions : Not applicable.
on the manufacture,
placing on the market
and use of certain
dangerous substances,
mixtures and articles
Special packaging requirements
Containers to be fitted : Not applicable.
with child-resistant
fastenings
Tactile warning of : Not applicable.
danger

2.3 Other hazards


Product meets the criteria : This mixture does not contain any substances that are assessed to be a PBT or a vPvB.
for PBT or vPvB according
to Regulation (EC) No.
1907/2006, Annex XIII
Other hazards which do : None known.
not result in
classification

SECTION 3: Composition/information on ingredients


3.2 Mixtures : Mixture

Date of issue/Date of : 07.05.2020 Date of previous : No previous Version 2/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 3: Composition/information on ingredients


Product/ingredient name Identifiers Weight % Regulation (EC) No. Type
1272/2008 [CLP]
xylene REACH #: ≥10 - ≤16 Flam. Liq. 3, H226 [1] [2]
01-2119488216-32 Acute Tox. 4, H312
EC: 215-535-7 Acute Tox. 4, H332
CAS: 1330-20-7 Skin Irrit. 2, H315
Index: 601-022-00-9 Eye Irrit. 2, H319
STOT SE 3, H335
Asp. Tox. 1, H304
n-butyl acetate REACH #: ≤10 Flam. Liq. 3, H226 [1] [2]
01-2119485493-29 STOT SE 3, H336
EC: 204-658-1 EUH066
CAS: 123-86-4
ethylbenzene REACH #: ≤5 Flam. Liq. 2, H225 [1] [2]
01-2119489370-35 Acute Tox. 4, H332
EC: 202-849-4 STOT RE 2, H373 (hearing
CAS: 100-41-4 organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
hydrocarbons, C9, aromatic REACH #: ≤3 Flam. Liq. 3, H226 [1]
01-2119455851-35 STOT SE 3, H335
EC: 918-668-5 STOT SE 3, H336
CAS: 64742-95-6 Asp. Tox. 1, H304
Aquatic Chronic 2, H411
2-Propenoic acid, 2-methyl-, 2- CAS: 1259547-09-5 ≤3 Skin Sens. 1, H317 [1]
(dimethylamino)ethyl ester,
polymer with butyl 2-propenoate,
comps. with polyethylene glycol
hydrogen maleate C9-11-alkyl
ethers
n-butyl methacrylate REACH #: <1 Flam. Liq. 3, H226 [1]
01-2119486394-28 Skin Irrit. 2, H315
EC: 202-615-1 Eye Irrit. 2, H319
CAS: 97-88-1 Skin Sens. 1, H317
Index: 607-033-00-5 STOT SE 3, H335
bis(1,2,2,6,6-pentamethyl- REACH #: ≤0.3 Skin Sens. 1, H317 [1]
4-piperidyl) sebacate 01-2119491304-40 Aquatic Acute 1, H400 (M=1)
EC: 255-437-1 Aquatic Chronic 1, H410
CAS: 41556-26-7 (M=1)
See Section 16 for the full
text of the H statements
declared above.
There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified as hazardous to health or the environment, are PBTs, vPvBs or Substances of equivalent concern, or
have been assigned a workplace exposure limit and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy
Occupational exposure limits, if available, are listed in Section 8.

Date of issue/Date of : 07.05.2020 Date of previous : No previous Version 3/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A
SECTION 4: First aid measures
4.1 Description of first aid measures
General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery position and seek medical
advice.
Eye contact : Remove contact lenses, irrigate copiously with clean, fresh water, holding the eyelids apart
for at least 10 minutes and seek immediate medical advice.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular
or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or
Skin contact use recognised skin cleanser. Do NOT use solvents or thinners.
: If swallowed, seek medical advice immediately and show the container or label.
Ingestion Keep person warm and at rest. Do NOT induce vomiting.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash
contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the CLP
Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2 and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central
nervous system. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact
with the mixture may cause removal of natural fat from the skin, resulting in non- allergic contact dermatitis and absorption
through the skin. Ingestion may cause nausea, diarrhea and vomiting.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following: irritation
redness
: No specific data.
Ingestion
4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The
exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
See toxicological information (Section 11)

SECTION 5: Firefighting measures


5.1 Extinguishing media
Suitable extinguishing : Recommended: alcohol-resistant foam, CO₂, powders, water spray.
media
Unsuitable extinguishing : Do not use water jet.
media

5.2 Special hazards arising from the substance or mixture

Date of issue/Date of : 07.05.2020 Date of previous : No previous Version 4/


Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A
SECTION 5: Firefighting measures
Hazards from the : Fire will produce dense black smoke. Exposure to decomposition products may
substance or mixture cause a health hazard.
Hazardous combustion : Decomposition products may include the following materials: carbon monoxide, carbon
products dioxide, smoke, oxides of nitrogen.

5.3 Advice for firefighters


Special protective : Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or
actions for fire-fighters watercourses.
Special protective : Appropriate breathing apparatus may be required.
equipment for fire-fighters

SECTION 6: Accidental release measures


6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
personnel Refer to protective measures listed in sections 7 and 8.
For emergency responders : If specialised clothing is required to deal with the spillage, take note of any
information in Section 8 on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".

6.2 Environmental : Do not allow to enter drains or watercourses. If the product contaminates lakes, rivers, or
precautions sewers, inform the appropriate authorities in accordance with local regulations.

: Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth,
6.3 Methods and vermiculite or diatomaceous earth and place in container for disposal according to local
material for containment regulations (see Section 13). Preferably clean with a detergent. Avoid using solvents.
and cleaning up

6.4 Reference to : See Section 1 for emergency contact information.


other sections See Section 8 for information on appropriate personal protective equipment. See
Section 13 for additional waste treatment information.

SECTION 7: Handling and storage


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for
any available use-specific information provided in the Exposure Scenario(s).
7.1 Precautions for safe handling
Prevent the creation of flammable or explosive concentrations of vapours in air and avoid vapour concentrations higher than the
occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and other sources of ignition have been
excluded. Electrical equipment should be protected to the appropriate standard.
Mixture may charge electrostatically: always use earthing leads when transferring from one container to another. Operators should
wear antistatic footwear and clothing and floors should be of the conducting type.
Keep away from heat, sparks and flame. No sparking tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or mist arising from the application of this
mixture. Avoid inhalation of dust from sanding.
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Put on
appropriate personal protective equipment (see Section 8).
Never use pressure to empty. Container is not a pressure vessel.
Always keep in containers made from the same material as the original one. Comply
with the health and safety at work laws.
Do not allow to enter drains or watercourses.
Information on fire and explosion protection
Vapours are heavier than air and may spread along floors. Vapours may form explosive mixtures with air.

When operators, whether spraying or not, have to work inside the spray booth, ventilation is unlikely to be sufficient to control
particulates and solvent vapour in all cases. In such circumstances they should wear a compressed air-fed

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 7: Handling and storage


respirator during the spraying process and until such time as the particulates and solvent vapour concentration has fallen below
the exposure limits.
7.2 Conditions for safe storage, including any incompatibilities
Store in accordance with local regulations.
Notes on joint storage
Keep away from: oxidising agents, strong alkalis, strong acids.
Additional information on storage conditions
Observe label precautions. Store in a dry, cool and well-ventilated area. Keep away from heat and direct sunlight. Keep away
from sources of ignition. No smoking. Prevent unauthorised access. Containers that have been opened must be carefully resealed
and kept upright to prevent leakage.

7.3 Specific end use(s)


Recommendations : Not available.
Industrial sector : Not available.
specific solutions

SECTION 8: Exposure controls/personal protection


The list of Identified Uses in Section 1 should be consulted for any available use-specific information provided in the Exposure
Scenario(s).
8.1 Control parameters
Occupational exposure
limits
Product/ingredient name Exposure limit values
xylene EH40/2005 WELs (United Kingdom (UK), 8/2018). Absorbed
through skin.
STEL: 441 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 220 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
n-butyl acetate EH40/2005 WELs (United Kingdom (UK), 8/2018).
STEL: 966 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 724 mg/m³ 8 hours.
TWA: 150 ppm 8 hours.
ethylbenzene EH40/2005 WELs (United Kingdom (UK), 8/2018). Absorbed
through skin.
STEL: 552 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 100 ppm 8 hours.
TWA: 441 mg/m³ 8 hours.
Recommended monitoring : If this product contains ingredients with exposure limits, personal, workplace atmosphere or
procedures biological monitoring may be required to determine the effectiveness of the ventilation or
other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European
Standard EN 689 (Workplace atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use
of procedures for the assessment of exposure to chemical and biological agents) European
Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous substances will also be required.

DNELs/DMELs

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Hardtop XP Comp A

SECTION 8: Exposure controls/personal protection


Product/ingredient name Exposure Value Population Effects
xylene Short term 289 mg/m³ Workers Systemic
Inhalation
Short term 289 mg/m³ Workers Local
Inhalation
Long term Dermal 180 mg/kg Workers Systemic
bw/day
Long term 77 mg/m³ Workers Systemic
Inhalation
Long term Dermal 108 mg/kg General Systemic
bw/day population
[Consumers]
Long term 14.8 mg/m³ General Systemic
Inhalation population
[Consumers]
Long term Oral 1.6 mg/kg General Systemic
bw/day population
[Consumers]
n-butyl acetate Short term 960 mg/m³ Workers Systemic
Inhalation
Short term 960 mg/m³ Workers Local
Inhalation
Long term 480 mg/m³ Workers Systemic
Inhalation
Long term 480 mg/m³ Workers Local
Inhalation
Short term 859.7 mg/ General Systemic
Inhalation m³ population
[Consumers]
Short term 859.7 mg/ General Local
Inhalation m³ population
[Consumers]
Long term 102.34 mg/ General Systemic
Inhalation m³ population
[Consumers]
Long term 102.34 mg/ General Local
Inhalation m³ population
[Consumers]
ethylbenzene Short term 293 mg/m³ Workers Local
Inhalation
Long term Dermal 180 mg/kg Systemic
Workers
bw/day
Long term 77 mg/m³ Systemic
Workers
Inhalation
Long term 15 mg/m³ General Systemic
Inhalation population
[Consumers]
Long term Oral 1.6 mg/kg Systemic
General
bw/day
population
[Consumers]
hydrocarbons, C9, aromatic Long term Dermal 25 mg/kg Systemic
Workers
bw/day 150
Long term mg/m³ Systemic
Workers
Inhalation
Long term Dermal 11 mg/kg Systemic
General
bw/day
population
Long term [Consumers]
32 mg/m³ Systemic
Inhalation General
population
Long term Oral 11 mg/kg [Consumers] Systemic
bw/day General
population
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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 8: Exposure controls/personal protection


[Consumers]
PNECs
Product/ingredient name Compartment Detail Value Method Detail
xylene Fresh water 0.327 mg/l -
Marine 0.327 mg/l -
Sewage Treatment 6.58 mg/l -
Plant
Fresh water sediment 12.46 mg/kg dwt -
Marine water sediment 12.46 mg/kg dwt -
Soil 2.31 mg/kg dwt -
n-butyl acetate Fresh water 0.18 mg/l -
Marine 0.018 mg/l -
Sewage Treatment 35.6 mg/l -
Plant
Fresh water sediment 0.981 mg/kg dwt -
Marine water sediment 0.0981 mg/kg dwt -
Soil 0.0903 mg/kg dwt -
ethylbenzene Fresh water 0.1 mg/l -
Marine 0.01 mg/l -
Sewage Treatment 9.6 mg/l -
Plant
Fresh water sediment 13.7 mg/kg dwt -
Soil 2.68 mg/kg dwt -
Secondary Poisoning 20 mg/kg -

8.2 Exposure controls


Appropriate engineering : Provide adequate ventilation. Where reasonably practicable, this should be achieved by the
controls use of local exhaust ventilation and good general extraction. If these are not sufficient to
maintain concentrations of particulates and solvent vapours below the OEL, suitable
respiratory protection must be worn.
Individual protection
measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating,
: smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Contaminated work clothing should not be allowed out of the workplace. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers are
close to the workstation location.
Safety eyewear complying to EN 166 should be used when a risk assessment indicates
Eye/face protection : this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a
higher degree of protection: chemical splash goggles.

Skin protection
Gloves : There is no one glove material or combination of materials that will give unlimited
resistance to any individual or combination of chemicals.
The breakthrough time must be greater than the end use time of the product. The
instructions and information provided by the glove manufacturer on use, storage,
maintenance and replacement must be followed.
Gloves should be replaced regularly and if there is any sign of damage to the glove material.
Always ensure that gloves are free from defects and that they are stored and used correctly.
The performance or effectiveness of the glove may be reduced by physical/chemical damage
and poor maintenance.
Barrier creams may help to protect the exposed areas of the skin but should not be applied once
exposure has occurred.

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Hardtop XP Comp A

SECTION 8: Exposure controls/personal protection


Wear suitable gloves tested to EN374.
May be used, gloves(breakthrough time) 4 - 8 hours: butyl rubber, neoprene Not
recommended, gloves(breakthrough time) < 1 hour: PVC, Viton®, PE
Recommended, gloves(breakthrough time) > 8 hours: Teflon, 4H, polyvinyl alcohol (PVA),
nitrile rubber

For right choice of glove materials, with focus on chemical resistance and time of penetration,
seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this product is
the most appropriate and takes into account the particular conditions of use, as included in the
user's risk assessment.
Body protection : Personnel should wear antistatic clothing made of natural fibres or of high-
temperature-resistant synthetic fibres.
Other skin : Appropriate footwear and any additional skin protection measures should be selected based
protection on the task being performed and the risks involved and should be approved by a specialist
before handling this product.
Respiratory protection : If workers are exposed to concentrations above the exposure limit, they must use a
respirator according to EN 140. Use respiratory mask with charcoal and dust filter when
spraying this product, according to EN 14387(as filter combination A2-P2). In confined
spaces, use compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Environmental exposure : Do not allow to enter drains or watercourses.
controls

SECTION 9: Physical and chemical properties


9.1 Information on basic physical and chemical
properties Appearance
Physical state : Liquid.
Colour : Various colours.
Odour : Characteristic.
Odour threshold : Not applicable.
pH : Not applicable.
Melting point/freezing point : Not applicable.
Initial boiling point and : Lowest known value: 126°C (258.8°F) (n-butyl acetate). Weighted average: 140.26°C
boiling range (284.5°F)
Flash point : Closed cup: 30°C
Evaporation rate : Highest known value: 1 (n-butyl acetate) Weighted average: 0.78compared with butyl
acetate
Flammability (solid, gas) : Not applicable.
Upper/lower flammability or : 0.8 - 9.8%
explosive limits
Vapour pressure : Highest known value: 1.5 kPa (11.3 mm Hg) (at 20°C) (n-butyl acetate).
Weighted average: 1.04 kPa (7.8 mm Hg) (at 20°C)
Vapour density : Highest known value: 4 (Air = 1) (n-butyl acetate). Weighted average: 3.79 (Air = 1)
: 1.2 to 1.453 g/cm³
Density
: Insoluble in the following materials: cold water and hot water.
Solubility(ies)
: Not available.
Partition coefficient: n-
octanol/ water
: Lowest known value: 280 to 470°C (536 to 878°F) (hydrocarbons, C9, aromatic).
Auto-ignition temperature
Decomposition temperature : Not available.
Viscosity : Kinematic (40°C): >0.205 cm2/s (>20.5 mm2/s)
Explosive properties : Not available.

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Hardtop XP Comp A

SECTION 9: Physical and chemical properties


Oxidising properties : Not available.

9.2 Other information


No additional information.

SECTION 10: Stability and reactivity


10.1 Reactivity : No specific test data related to reactivity available for this product or its ingredients.
10.2 Chemical stability : Stable under recommended storage and handling conditions (see Section 7).
10.3 Possibility of : Under normal conditions of storage and use, hazardous reactions will not occur.
hazardous reactions
10.4 Conditions to avoid : When exposed to high temperatures may produce hazardous decomposition products.
10.5 Incompatible materials : Keep away from the following materials to prevent strong exothermic reactions: oxidising
agents, strong alkalis, strong acids.
10.6 Hazardous : Decomposition products may include the following materials: carbon monoxide, carbon
decomposition products dioxide, smoke, oxides of nitrogen.

SECTION 11: Toxicological information


11.1 Information on toxicological effects
There are no data available on the mixture itself. The mixture has been assessed following the conventional method of the CLP
Regulation (EC) No 1272/2008 and is classified for toxicological properties accordingly. See Sections 2 and 3 for details.

Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in adverse
health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central
nervous system. Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact
with the mixture may cause removal of natural fat from the skin, resulting in non- allergic contact dermatitis and absorption
through the skin. Ingestion may cause nausea, diarrhea and vomiting.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
xylene LC50 Inhalation Vapour Rat 20 mg/l 4 hours
LD50 Oral Rat 4300 mg/kg -
TDLo Dermal Rabbit 4300 mg/kg -
n-butyl acetate LC50 Inhalation Vapour Rat >21.1 mg/l 4 hours
LD50 Dermal Rabbit >17600 mg/kg -
LD50 Oral Rat 13100 mg/kg -
ethylbenzene LC50 Inhalation Vapour Rat - Male 17.8 mg/l 4 hours
LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
n-butyl methacrylate LD50 Oral Rat 16 g/kg -
Acute toxicity estimates
Route ATE value
Dermal 9546.07 mg/kg
Inhalation (vapours) 126.25 mg/l
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
xylene Eyes - Mild irritant Rabbit - 87 milligrams -
Skin - Mild irritant Rat - 8 hours 60 -
microliters
n-butyl methacrylate Skin - Mild irritant Rabbit - 500 -
microliters
Eyes - Mild irritant Mammal - - - -
species
unspecified

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 11: Toxicological information


Sensitisation
Product/ingredient name Route of Species Result
exposure
2-Propenoic acid, 2-methyl-, 2- skin Mammal - species Sensitising
(dimethylamino)ethyl ester, unspecified
polymer with butyl
2-propenoate, comps. with
polyethylene glycol
hydrogen maleate
C9-11-alkyl ethers
n-butyl methacrylate skin Mammal - species Sensitising
unspecified
bis(1,2,2,6,6-pentamethyl- skin Mammal - species Sensitising
4-piperidyl) sebacate unspecified
Mutagenicity
No known significant effects or critical hazards.
Carcinogenicity
No known significant effects or critical hazards.
Reproductive toxicity
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.
Specific target organ toxicity (single exposure)
Product/ingredient name Category Route of Target organs
exposure
xylene Category 3 Not applicable. Respiratory tract
irritation Narcotic
n-butyl acetate hydrocarbons, Category 3 Not applicable. effects Narcotic
C9, aromatic Category 3 Not applicable. effects
Category 3 Not applicable. Respiratory tract
irritation
n-butyl methacrylate Category 3 Not applicable. Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of Target organs
exposure
ethylbenzene Category 2 Not determined hearing organs
Aspiration hazard
Product/ingredient name Result
xylene ASPIRATION HAZARD - Category 1
ethylbenzene ASPIRATION HAZARD - Category 1
hydrocarbons, C9, aromatic ASPIRATION HAZARD - Category 1
Other information : None identified.

SECTION 12: Ecological information


12.1 Toxicity
There are no data available on the mixture itself. Do
not allow to enter drains or watercourses.

The mixture has been assessed following the summation method of the CLP Regulation (EC) No 1272/2008 and is classified for
eco-toxicological properties accordingly. See Sections 2 and 3 for details.

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 12: Ecological information


Product/ingredient name Result Species Exposure
ethylbenzene hydrocarbons, Acute EC50 7.2 mg/l Algae 48 hours
Acute EC50 2.93 mg/l Daphnia 48 hours
Acute LC50 4.2 mg/l Fish 96 hours
C9, aromatic Acute EC50 <10 mg/l Daphnia 48 hours
Acute IC50 <10 mg/l Algae 72 hours
Acute LC50 <10 mg/l Fish 96 hours
n-butyl methacrylate Chronic NOEC 2.6 mg/l Fresh water Daphnia - Daphnia magna - 21 days
Neonate
This material is harmful to aquatic life with long lasting effects.

12.2 Persistence and degradability


Not available.
Product/ingredient name Aquatic half-life Photolysis Biodegradability
xylene - - Readily
ethylbenzene - - Readily
hydrocarbons, C9, aromatic - - Not readily
bis(1,2,2,6,6-pentamethyl- 4- - - Not readily
piperidyl) sebacate

12.3 Bioaccumulative potential


Product/ingredient name LogPow BCF Potential
xylene 3.12 8.1 to 25.9 low
n-butyl acetate 2.3 - low
ethylbenzene 3.6 - low
hydrocarbons, C9, aromatic - 10 to 2500 high
n-butyl methacrylate 2.99 - low

12.4 Mobility in soil


Soil/water partition : Not available.
coefficient (KOC)
Mobility : Not available.

12.5 Results of PBT and vPvB assessment


This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Other adverse effects : No known significant effects or critical hazards.

SECTION 13: Disposal considerations


The information in this section contains generic advice and guidance. The list of Identified Uses in Section 1 should be consulted for
any available use-specific information provided in the Exposure Scenario(s).
13.1 Waste treatment methods
Product
Methods of disposal : The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any regional
local authority requirements. Dispose of surplus and non- recyclable products via a licensed
waste disposal contractor. Waste should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with jurisdiction.
Hazardous waste : Yes.

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 13: Disposal considerations


Disposal considerations : Do not allow to enter drains or watercourses.
Dispose of according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer
apply and the appropriate code should be assigned.
For further information, contact your local waste authority.
European waste : 08 01 11* Waste paint and varnish containing organic solvents or other dangerous substances
catalogue (EWC)
Packaging
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible.
Disposal considerations : Using information provided in this safety data sheet, advice should be obtained from the
relevant waste authority on the classification of empty containers.
Empty containers must be scrapped or reconditioned.
Dispose of containers contaminated by the product in accordance with local or national
legal provisions.
Type of packaging European waste catalogue (EWC)
CEPE Paint Guidelines packaging containing residues of or contaminated by hazardous substances
15 01 10*

Special precautions : This material and its container must be disposed of in a safe way. Care should be taken
when handling emptied containers that have not been cleaned or rinsed out. Empty
containers or liners may retain some product residues. Vapour from product residues may
create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or
grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal
of spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information


ADR/RID ADN IMDG IATA
UN1263
14.1 UN number UN1263 UN1263 UN1263

Paint
UN proper shipping name Paint Paint Paint
Transport hazard class(es)
3 3 3 3

14.4 Packing group III III III III


14.5
Environmental hazards
No. Yes. No. No.

Additional information
ADR/RID : ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles
< 450 litre capacity).
Hazard identification number 30
Special provisions 640E
Tunnel code (D/E)
ADN : The product is only regulated as an environmentally hazardous substance when transported in
tank vessels.
IMDG : IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to
receptacles < 450 litre capacity).
Emergency schedules F-E, S-E

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 14: Transport information

14.6 Special precautions : Transport within user’s premises: always transport in closed containers that are upright
for user and secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.

14.7 Transport in bulk : Not applicable.


according to Annex II of
Marpol and the IBC
Code

SECTION 15: Regulatory information


15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture EU Regulation (EC) No. 1907/2006 (REACH)
Annex XIV - List of substances subject to authorisation
Annex XIV
None of the components are listed.
Substances of very high
concern None of the components are
listed.
Annex XVII - : Not applicable.
Restrictions on the
manufacture, placing on
the market and use of
certain dangerous
substances, mixtures
and articles
Other EU regulations
VOC : The provisions of Directive 2004/42/EC on VOC apply to this product. Refer to the
product label and/or technical data sheet for further information.
VOC for Ready-for- : Not available.
Use Mixture
Europe inventory : At least one component is not listed.
Ozone depleting substances (1005/2009/EU)
Not listed.
Prior Informed Consent (PIC) (649/2012/EU)
Not listed.
Seveso Directive
This product may add to the calculation for determining whether a site is within the scope of the Seveso Directive on major
accident hazards.
National regulations
Industrial use : The information contained in this safety data sheet does not constitute the user’s own
assessment of workplace risks, as required by other health and safety legislation. The
provisions of the national health and safety at work regulations apply to the use of this
product at work.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.

Montreal Protocol (Annexes A, B, C, E)


Not listed.

Stockholm Convention on Persistent Organic Pollutants

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Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)

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Conforms to Regulation (EC) No. 453/2010 (REACH), Annex II, as amended by Regulation (EU) No. 2015/830
Hardtop XP Comp A

SECTION 15: Regulatory information


Not listed.

UNECE Aarhus Protocol on POPs and Heavy Metals


Not listed.

15.2 Chemical safety : Not applicable.


assessment

SECTION 16: Other information


Indicates information that has changed from previously issued version.
Abbreviations and : ATE = Acute Toxicity Estimate
acronyms CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
DMEL = Derived Minimal Effect Level DNEL
= Derived No Effect Level
EUH statement = CLP-specific Hazard statement PBT =
Persistent, Bioaccumulative and Toxic PNEC =
Predicted No Effect Concentration
RRN = REACH Registration Number
vPvB = Very Persistent and Very Bioaccumulative
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Classification Justification
Flam. Liq. 3, H226 On basis of test data
Skin Irrit. 2, H315 Calculation method
Eye Irrit. 2, H319 Calculation method
Skin Sens. 1, H317 Calculation method
Aquatic Chronic 3, H412 Calculation method
Full text of abbreviated H statements
H225 Highly flammable liquid and vapour.
H226 Flammable liquid and vapour.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated
exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Full text of classifications [CLP/GHS]
Acute Tox. 4, H312 ACUTE TOXICITY (dermal) - Category 4
Acute Tox. 4, H332 ACUTE TOXICITY (inhalation) - Category 4
Aquatic Acute 1, H400 SHORT-TERM (ACUTE) AQUATIC HAZARD - Category 1
Aquatic Chronic 1, H410 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 1
Aquatic Chronic 2, H411 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 2
Aquatic Chronic 3, H412 LONG-TERM (CHRONIC) AQUATIC HAZARD - Category 3
Asp. Tox. 1, H304 ASPIRATION HAZARD - Category 1
EUH066 Repeated exposure may cause skin dryness or cracking.
Eye Irrit. 2, H319 SERIOUS EYE DAMAGE/EYE IRRITATION - Category 2
Flam. Liq. 2, H225 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS - Category 3
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION - Category 2

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Hardtop XP Comp A

SECTION 16: Other information


Skin Sens. 1, H317 SKIN SENSITISATION - Category 1
STOT RE 2, H373 SPECIFIC TARGET ORGAN TOXICITY - REPEATED
EXPOSURE - Category 2
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Respiratory tract irritation) - Category 3
STOT SE 3, H336 SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
(Narcotic effects) - Category 3

Date of printing : 07.05.2020


Date of issue/ Date : 07.05.2020
of revision
Date of previous : No previous validation
issue Version : 1
Notice to reader
The information in this document is given to the best of Jotun's knowledge, based on laboratory testing
and practical experience. Jotun's products are considered as semi-finished goods and as such, products
are often used under conditions beyond Jotun's control. Jotun cannot guarantee anything but the quality of
the product itself. Minor product variations may be implemented in order to comply with local requirements.
Jotun reserves the right to change the given data without further notice.

Users should always consult Jotun for specific guidance on the general suitability of this product for their
needs and specific application practices.

If there is any inconsistency between different language issues of this document, the English (United
Kingdom) version will prevail.

Date of issue/Date of : 07.05.2020 Date of previous : No previous Version 17/


Anne

Hardtop XP Comp A
Exposure Scenario: Use in coatings Industrial use
-
Sector of Use Process Category : Industrial use
Environmental release category(ies) : PROC05 PROC07 PROC08a PROC10
: ERC4

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by
hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures


Control of worker exposure
Frequency and duration of use General - Operational conditions
: Covers daily exposures up to 8 hours
General - Risk management measures : Assumes use at not more than 20°C above ambient temperature. Assumes a good basic standard of occupational hygiene i
: Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Wear suitable coveralls to

Type of activity or process Risk management measures


Preparation of material for application Roller, spreader,
: Provide
flowa good
application
standard of controlled ventilation (10 to 15 air changes per hour).
: Provide extract ventilation to points where emissions occur. Avoid carrying out activities involving exposure for more than 4
or
Provide extract ventilation to points where emissions occur. Wear a respirator conforming to EN140 with type A/P2 filter or b
: Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation at openings. Wear a ful
Spraying - Manual

Control of environmental exposure


Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations. See
treatment of waste for disposal Section 13 for additional waste treatment information.
Conditions and measures related to
external recovery of waste : External recovery and recycling of waste should comply with applicable local and/or national regulations.

Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119488216-32
REACH #: 01-2119485796-17 (from Comp B)

Page:
Anne

Hardtop XP Comp A
Exposure Scenario: Use in coatings Professional use
-
Sector of Use Process Category : Professional use
Environmental release category(ies) : PROC05 PROC08a PROC10 PROC11
: ERC8a ERC8d

Covers the use in coatings (paints, inks, adhesives, etc) including exposures during use (including product transfer and preparation, application by brush, spray by
hand or similar methods) and equipment cleaning.

Operational conditions and risk management measures


Control of worker exposure
Frequency and duration of use General - Operational conditions
: Covers daily exposures up to 8 hours
General - Risk management measures : Assumes use at not more than 20°C above ambient temperature. Assumes a good basic standard of occupational hygiene i
: Wear chemical-resistant gloves (tested to EN374) in combination with specific activity training. Wear suitable coveralls to

Type of activity or process Risk management measures


Preparation of material for application - : Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out Indoor
activities involving exposure for more than 1 hour per day.
or
Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to
EN140 with type A/P2 filter or better.
Preparation of material for application - : Ensure operation is undertaken outdoors. Avoid carrying out activities involving exposure for more
Outdoor than 1 hour per day.
or
Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2 filter or
better.
Equipment cleaning and maintenance : Drain down system prior to equipment break-in or maintenance. Avoid carrying out activities involving
exposure for more than 4 hours per day.
Roller, spreader, flow application - Indoor : Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Avoid carrying out
activities involving exposure for more than 4 hours per day. or
Provide a good standard of controlled ventilation (10 to 15 air changes per hour). Wear a respirator conforming to
EN140 with type A/P2 filter or better.
Roller, spreader, flow application - Outdoor : Ensure operation is undertaken outdoors. Wear a respirator conforming to EN140 with type A/P2
filter or better. Avoid carrying out activities involving exposure for more than 4 hours per day.
Spraying - Manual - Indoor : Minimise exposure by partial enclosure of the operation or equipment and provide extract ventilation
at openings. Wear a full-face respirator conforming to EN136 with Type A/P2 filter or better. Avoid carrying out
activities involving exposure for more than 4 hours per day.
Spraying - Manual - Outdoor : Ensure operation is undertaken outdoors. Wear a full-face respirator conforming to EN136 with Type
A/P2 filter or better. Avoid carrying out activities involving exposure for more than 4 hours per day.

Control of environmental exposure


Organisational measures to prevent/limit : Prevent environmental discharge consistent with regulatory requirements.
release from site
Conditions and measures related to external : External treatment and disposal of waste should comply with applicable local and/or national regulations. See
treatment of waste for disposal Section 13 for additional waste treatment information.
Conditions and measures related to
external recovery of waste : External recovery and recycling of waste should comply with applicable local and/or national regulations.

Additional information
The exposure scenario for the mixture is based on the following substances:
REACH #: 01-2119488216-32
REACH #: 01-2119485796-17 (from Comp B)

Page:

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