Instrumental Analysis Chemistry

Bill Xuan Vikng

4.6) A 10.0-mL solution of 0. 050 0 M AgNO3 was titrated with 0.025 0 M NaBr in the cell
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S.C.E. titration solution Ag(s)
Find the cell voltage for 0.1, 10.0, 20.0, and 30.0 mL of titrant.
4.7) A solution prepared by mixing 25.0 mL of 0.200 M KI with 25.0 mL of 0.200 M
NaC1 was titrated with 0.100 M in the following cell: •
S.C.E. II titration solution I Ag(s)
Call the solubility products of AgI and AgC1 kI and ko respectively. The answers to
parts (a) and (b) should be expressions containing these constants.
(a) Calculate when 25.0 mL of titrant have been added.
(b) Calculate when 75.0 mL of titrant have been added.
(c) Write an expression showing how the cell voltage depends on [Ag+]
4.8) Knowing that the standard potential of an electrode Cd/Ce vs. SHE, has the
value 0.404V, what happens to this potential if the electrode is plunged into an
aqueous solution of 0.01M CdSO4?
4.9) Calculate the molar concentration for the underlined component in the following cell
if the cell potential is measured at +0.294 V
Ag I AgC1 (sat'd) I NaC1 (0.1 M) II KI (x M)1I2(s)IPt.
10) The concentration of NO 3 - in a water sample is determined by a one - point
fit standard addition using an NO3- ion-selective electrode. A 25.00-mL
na,
s
placed in a beaker, and a potential of +0.102 V is measured. A 1.00- aliquot oisf
a 200.0 ppm standard solution of NO is added, after which the potential is found
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to be +0.089 V. Report the concentration of NO3- in parts per million.