You are on page 1of 18

Available online at www.sciencedirect.

com

Precambrian Research 162 (2008) 385–402

Proterozoic polyphase metamorphism in the Chhotanagpur Gneissic


Complex (India), and implication for trans-continental
Gondwanaland correlation
A.K. Maji a , S. Goon a , A. Bhattacharya b , B. Mishra b,∗ ,
S. Mahato c , Heinz-J. Bernhardt d
a Department of Geology, Durgapur Government College, Durgapur 713 214, West Bengal, India
b Department of Geology and Geophysics, Indian Institute of Technology, Kharagpur 721 302, West Bengal, India
c Department of Geological Sciences, Jadavpur University, Kolkata 700 032, India
d Institut fur Mineralogie, Ruhr Universitat, Universitätsstraße 150, D-44780, Bochum, Germany

Received 25 November 2006; received in revised form 30 September 2007; accepted 16 October 2007

Abstract
In recent attempts to reconstruct the Early Cambrian architecture of Gondwanaland, the Prydz Bay Pan African suture separating Archean and
Proterozoic terrains in Antarctica is suspected to extend inwards into Eastern India, presumably through the Chhotanagpur Gneissic Complex
(CGC). However, the lack of thermo-chronologic information in the CGC impedes the proposed Gondwanaland reconstruction. In the Bero-Saltora
area, located in the eastern fringe of the CGC, three deformation events were identified (D1 , D2 and D3 ) in granulite facies gneisses that were
intruded by anorthosites (post-D1 , pre-D2 ) and expansive granites (post-D2 , pre-D3 ). The prograde pre/syn-D1 granulite facies metamorphism
in the enclave suite (750–850 ◦ C and 4–6 kbar) is suggested to be >1.4 Ga (EPMA monazite age) or even older. The D2 and D3 deformation
events (1.1–1.4 Ga EPMA monazite age) occurred at amphibolite facies conditions, manifested by the stabilization of hornblende and/or biotite in
almost all lithologies. The post-D3 stage was marked by the stabilization of prograde garnet + quartz at upper amphibolite facies (650 ± 50 ◦ C and
4.5 ± 0.5 kbar) conditions replacing syn-D2–3 hornblende/biotite + plagioclase assemblages in anorthosites, foliated granites and granulite enclaves,
and the re-stabilization of a two-pyroxene + plagioclase assemblage at the expense of hornblende in mafic granulites. EPMA dating of monazites
in post-D3 garnets in sheared granites yielded ∼0.9–1.0 Ga. The reconstructed thermo-chronology of events is the first record of Meso- and
Neoproterozoic (Grenvillian) polyphase prograde metamorphism in the CGC. The lack of Early Paleozoic ages in the gneissic complex rules out
the suspected continuation of the Early Cambrian Prydz Bay suture within the CGC. The suture arguably should lie to the east of the CGC.
© 2007 Elsevier B.V. All rights reserved.

Keywords: Chhotanagpur Gneissic Complex; Poly-metamorphism; Mesoproterozoic; Pan African suture; Gondwanaland

1. Introduction the Shillong-Meghalaya Gneissic Complex (Chatterjee et al.,


2007) suggests that the trans-continental Early Paleozoic suture
In recent reconstructions of the Early Cambrian architecture may indeed have vestigial parts in northeastern India. Therefore,
of East Gondwanaland, the Pan African (550–500 Ma) Prydz the suture should be traceable southwards within eastern India.
Bay suture in Antarctica is suggested to continue inwards into the Thermo-chronological data from the Central Indian Tectonic
eastern Indian Precambrian Shield (Boger et al., 2001; Powell Zone, CITZ (Roy et al., 2006; Bhowmik et al., 2005; Yedekar
and Pisarevsky, 2002; Harley, 2003; Fitzsimons, 2003; Fig. 1a). et al., 1990, and references therein), located to the west of
The location of the suture within the eastern Indian Precambrian the Chhotanagpur Gneissic Complex (CGC), rules out any
complexes cannot be constrained because of the lack of adequate possibility of Pan African high-grade metamorphism in this
thermo-chronologic coverage in the complexes. Recent work in area. Assuming the East Gondwanaland configuration is correct
(Fig. 1a), the Pan African suture with possible continuation in
the Shillong-Meghalaya Plateau, NE India (Chatterjee et al.,
∗ Corresponding author. 2007) must be traceable within the expansive foliated granite
E-mail address: bmgg@iitkgp.ac.in (B. Mishra). hosted podiform granulite–amphibolite gneiss enclaves of

0301-9268/$ – see front matter © 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.precamres.2007.10.002
386 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

Fig. 1. (a) A reconstruction of the major provinces in Australo-Antarctica showing the palaeomagnetism data-corrected location of India at ∼750 Ma and ∼500 Ma
(after Fitzsimons, 2003; Fig. 11) The Meso- and Neoproterozoic crystalline complexes of northern and eastern India (modified after Saha, 1994) are superposed on
the Australo-Antarctica map at 500 Ma; Aravalli-Delhi Fold Belt (1), Central Indian Tectonic Zone (2), Chhotanagpur Gneissic Complex (3), Eastern Ghats Granulite
Belt (4), Shillong-Meghalya Gneissic Complex (5). The Ganges-Brahmaputra alluvium and the Rajmahal volcanic suite (not shown) separate the Shillong-Meghalya
Gneissic Complex from the crystalline complexes 1–4. The short dashes are the dominant structural trends in the complexes. The broken line northwest of Kolkata and
extending across the Chhotanagpur Gneissic Complex (CGC) is the suspected extension of the Pan-African Prydz Bay suture within India proposed by Fitzsimons
(2003). (b) Generalized geological map of the CGC, modified after Mahadevan (2002). The location of 0.96 Ga Pb-isochron age of Vinogradav et al. (1964) in
monazite–columbite–samarskite-bearing pegmatite in the Bihar Mica Belt is shown. The metamorphic grades indicated in the legend are not exclusive, but are
dominant in the zones indicated. The box in the south-eastern fringe of the CGC shows the location of the Bero-Saltora area. The North Singhbhum Mobile Belt is
separated from the Archean Singhbhum Craton in the south and the Proterozoic CGC to the north by regional shear zones (bold lines with filled triangles).
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 387

Fig. 1. (Continued ).

the CGC (Fig. 1b). However, if the Pan African tectonism is by the segregation of granulite facies mineral assemblages
determined to be lacking in the CGC, the southward extension (Table 1) in quartzofeldspathic, mafic and pelitic lithologies of
of the projected suture, south of the Assam-Meghalaya Plateau, the enclave suite (Fig. 3a). S1 is isoclinally folded (Fig. 3a) with
must then be located to the east of the CGC. development of a penetrative foliation (S2 , D2 ), defined by the
Pan African dates from the CGC are lacking, except for the preferred alignment of hornblende in mafic granulite, biotite
500 Ma date (K–Ar mineral age) obtained from K-rich alkali in quartzofeldspathic gneisses, and biotite–sillimanite aggre-
syenite porphyry and granite aplite (Ghose et al., 1973; Ghose, gates in metapelites (Table 1). The S1 –S2 composite is refolded
1983), and the whole rock—biotite: K-feldspar Rb–Sr isochron (D3 ) into a set of east–west closing asymmetric, upright non-
date of 481 ± 18 Ma in a migmatite from the Hazaribagh belt cylindrical shear related folds. Between Saltora and Santuri, the
(Pandey et al., 1986). The significance of the Cambrian dates D2 and D3 folds (Fig. 3b) are coaxial, and in zones of high
arguably corresponding to a thermal event (cf. Ray Barman D3 strain, a sheath-like geometry for the D3 folds is observed
et al., 1994) is unknown. The aim of this study, based on (Fig. 3c).
the granite-enclave suite in the Bero-Saltora area, is to evolve The expansive granites are characterized by a steep north-
a thermo-chronologic history of the southeastern part of the dipping monophase fabric (Figs. 2f and 3d) defined by quartz
CGC. The exercise is likely to constrain the location of the lenticles (mono-crystalline and straight-walled in the mylonitic
Early Cambrian Prydz Bay suture within the eastern Indian varieties with aspect ratio >8; Fig. 4a), and the preferred align-
Precambrian. ment of biotite that wrap around clasts of former magmatic
feldspar grains and hornblende, and garnet. In the weakly
2. Geological background deformed granites, quartz grains show chess board extinction
(Fig. 4b). The monophase fabric (Fig. 2f) axial planar to D3
The Bero-Saltora area (Fig. 2) is dominated by an east–west folds in granulite facies gneisses of the enclave suite (Fig. 2)
trending centrally bulged anorthosite pluton and variably was correlated with D3 top-to-the-south shearing, with a pro-
deformed granites that intrude into granulite to amphibolite nounced strike-slip component manifested by moderate plunge
facies migmatitic quartzofeldspathic and metapelitic gneisses. of stretching lineation. Since chess board twinning in quartz
Mafic granulites and calc-silicate granulites occurring as bands occurs at T ≥ 650 ◦ C (Kruhl, 1996, 1998; Kruhl and Huntemann,
and distended lenses constitute minor proportions of the intruded 1991; Masberg et al., 1992), the D3 shearing seemingly occurred
gneisses, herein referred to as the enclave suite. The mineral par- at upper amphibolite facies conditions.
ageneses in lithologies relevant to the study are summarized in The interior of the anorthosite pluton is dominated by
Table 1. The enclave suite is characterized by three deformation coarse-grained cumulus-textured massive anorthosites devoid
events (D1 , D2 and D3 ). The earliest fabric (S1 , D1 ) is defined of tectonic foliations (definition after Paterson et al., 1989,
388 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

Fig. 2. Structural–lithological map of the Bero-Saltora area. The “composite gneisses” include quartzofeldspathic gneiss, metapelite gneiss and mafic granulite. The
width of calc-silicate gneiss bands is exaggerated for clarity. The geological map is different from those proposed (Roy, 1977; Dastidar et al., 1997) for the area, e.g. the
foliated granites, often apophytic within the enclave suite are identified as a distinct lithologic unit, the anorthosite pluton (shown to terminate near Santuri; Roy, 1977)
extends further to the west, albeit in a decomposed state, and is considerably thinned. Stereographic projection of planar and linear structures in the Bero-Saltora area:
(a–e) Quartzofeldspathic gneisses (enclave suite); (f–g) Foliated granites; (h) Anorthosite suite (marginal part). The broken line in (c)–(f) is the girdle corresponding
to ␲S3 maximum. (a) Contoured ␲S1 (n = 31) girdle showing the calculated β-axis at 21◦ → 290◦ N. (b) Contoured ␲S2 (n = 143) girdle; the corresponding β-axis
is 11◦ → 272◦ N. (c) Contoured ␲S3 (n = 30) girdle; the mean orientation of S3 corresponding to the maximum is 67◦ /273◦ N. (d) Orientations of F2 fold axes in
quartzofeldspathic gneisses (mean direction 13◦ → 278◦ N; n = 31). The orientation of the girdle containing the F2 fold axis is 62◦ /271◦ N. (e) Orientations of F3 fold
axes in quartzofeldspathic gneisses (mean direction 25◦ → 283◦ N; n = 15). The orientation of the girdle containing the F3 fold axis is 65◦ /270◦ N. (f) Contoured ␲S3
(n = 235) point maximum for which the corresponding average plane (broken line) has an orientation of 55◦ /265◦ N. (g) Dispersal of stretching lineations in foliated
granites (n = 29). The orientation of the average plane containing the lineations is 51◦ /258◦ N. (h) Contoured ␲S2 girdle in anorthosites. The corresponding β-axis
(49◦ → 309◦ N) compares favorably with the measured plunges (filled squares) of F3 folds. Plots of ␲S3 (open triangles, n = 23) describe a point maximum, the mean
direction of which is 51◦ /263◦ N.

1998). However, magmatic foliation is discernible in pluton- inantly magmatic-textured anorthosites in the pluton interior,
interior anorthosite dykes in which tiling (Fig. 4c; cf. Den the anorthosites at the pluton margin are finer-grained, min-
Tex, 1969; Paterson et al., 1989; Nicolas and Ildefonse, eralogically banded (Figs. 3e and 5a) and characterized by a
1996) among end-to-end touching euhedral plagioclase grains bi-modal size population of recrystallized plagioclase grains
(Fig. 4c; cf. Vernon, 2004) is evident. Compared to the dom- (Fig. 4d). In anorthosites from the pluton interior, plastic strain

Table 1
Mineral parageneses in rocks relevant to this study from the Bero-Saltora area
Deformation event (age in Ga)

D1 (>1.4 Ga) D2 (>1.1–1.2 Ga) D3 (0.9–1.0 Ga) Post-D3 (0.9–1.0 Ga)

Metamorphic stage M1 M2 M3 M4
Migmatitic quartzofeldspathic gneiss (+Qtz + Kfs + Pl + Ilm) Grt1 ± Opx ± Bt1 /Hbl1 Bt2 /Hbl2 Bt3 /Hbl3 Grt4 + Qtz
Mafic granulite (+Pl + Ilm ± Qtz) Opx > Cpx + Hbl1 Hbl2 Hbl3 Grt4 + Qtz, Opx4 + Cpx4 + Pl4
Anorthosite (+Pl + Opx ± Cpx + Ilm) – Hbl2 Bt3 (Hbl3 ) ± Qtz Grt4
Foliated granite (+Qtz + Kfs + Pl + Hbl + Grt0 ) – – Bt Grt4

Subscripts 1–4 refer to the metamorphic stages during which the minerals were formed. Subscript ‘0’ refers to magmatic phase. Minerals shown in bold in the first
column are observed in the rock in addition to those stable during the metamorphic stages.
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 389

Fig. 3. Field photographs of quartzofeldspathic gneisses (a–c), foliated granite (d), and anorthosite (e). (a) Early F2 isoclinal folds on S1 gneissic layering, defined
by mafic granulite layers (coin diameter is 2.5 cm). (b) Co-axial nature of D2 and D3 folds on S1 gneissic layering (scale is 14 cm long). (c) Closed form fold, having
sheath like appearance on plan view. (d) Mylonitic fabric (S3 ) defined by layers of coalescent aggregates of deformed K-feldspar augen in biotite-rich mosaic. (e)
Southerly overturned tight F3 folds on S2 tectonic fabric (length of the pencil is ∼7 cm). Note the penetrative S3 fabric in the banded anorthosite is largely obscured
by intense recrystallization.

in plagioclase is limited to weak strain wavy extinction, mildly nal strain and sub-grain formation. Within the pluton, the
bent twin lamellae and locally developed grain boundary bulges intensity of solid state deformation demonstrably decreases
(Fig. 4c). By contrast, in banded anorthosites at the pluton mar- inwards from the margin because of either waning of stress
gin, the finer sized population of plagioclase grains is a mosaic inwards within the pluton or the absence of weak-to-shear
of internally strained grains that share high-energy bound- minerals.
aries; triple junctions and sub-grains are rare (Fig. 4d). The The girdle distribution of the poles to the earliest tectonic
coarser-sized plagioclase grains are circular/elliptical shaped fabric in banded anorthosites is identical with that of the S2
clasts of former magmatic grains showing high degree of inter- fabric in the gneisses of the enclave suite (Fig. 2). Also, the
390 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

Fig. 4. Microtextural relations in foliated granites (a and b) and anorthosites (c and d). (a) Straight-walled polycrystalline quartz lenticles with transverse fractures
wrap around an internally strained K-feldspar clast showing core–mantle structure. (b) Chess-board extinction in deformed quartz grain in weakly foliated granite.
(c) End to end touching nature of euhedral plagioclase grains showing tiling in anorthosites from the pluton interior. Some of the plagioclase grains are bent and show
bulge nucleation along their margins. (d) Poly-sized aggregates of plagioclase in anorthosites from the pluton margin. The larger grains (clasts of former magmatic
plagioclase) show strong internal strain and sub-grain formation. The smaller-sized recrystallized grains are also internally strained and share high energy boundaries.

poles to the later tectonic fabric in banded anorthosites and of India (GSI), Kolkata (India) and in the Zentrale Elektonen
S3 foliation in the enclave suite describe a common maximum Mikrosonde, Ruhr-Universität Bochum, Germany. Analyses
(Fig. 2). The close correspondence between the mesoscopic in GSI were performed with a CAMECA SX 100 model. The
structures in banded anorthosites and gneisses of the enclave accelerating voltage was 15 kV, beam current 15 nA, beam
suite suggests that the rock suites shared the D2 and D3 defor- size 1 ␮m. Natural standards were used for calibrations of all
mation events, and by implication, the emplacement of the elements, except Mn and Ti for which synthetic standards from
anorthosite pluton was pre-D2 . Also, as with the high-grade BRGM were used. At the Ruhr Universität Bochum, analyses
gneisses in the enclave suite, the two tectonic foliations in were carried out by a CAMECA SX50 equipment, with the same
banded anorthosites are defined by shape preferred aggregates of above mentioned analytical conditions. Analytical conditions
hornblende and biotite, to the exclusion of the D1 granulite facies and reduction of analytical data are discussed in Willner et al.
mineral assemblages (Table 1). By implication, the anorthosite (2000).
pluton was a post-D1 emplacement into the high-grade Quantitative microprobe analyses of monazites for dating
gneisses. by the Th–U–total Pb isochron method (Suzuki et al., 1991)
were carried out at the University of Bochum with a Cameca
3. Petrography SX50 Electron probe Micro analyzer. 20 kV acceleration volt-
age, 100 nA beam current, and beam diameter of 6 ␮m were the
Compositions of minerals (Table 2; mineral abbreviations operating conditions during analyses. Each spot was analyzed
after Kretz, 1983) were obtained by Electron Probe MicroAna- for Th, Y, Pb, P and U; REE’s were taken to be Ce as differ-
lyzer in the Central Petrological Laboratory, Geological Survey ence to a total of 100. The procedure outlined in Armstrong
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 391

Fig. 5. Photomicrographs showing multiple tectonic fabrics defined by shape-preferred mineral aggregates in (a) banded anorthosite and (b) hornblende-rich
mafic granulite. In the banded anorthosite (a), the earliest tectonic fabric (coeval with S2 ) is defined by the shape preferred aggregates of hornblende, whereas
the later fabric (coeval with S3 ) axial planar to folds on S2 is prominent at the fold hinge. Note the small patch of cumulus-textured anorthosite (circled)
within the banded anorthosite does not show the intense recrystallization in plagioclase grains in banded anorthosite. In the mafic granulite (b), the S2 fabric
defined by coarse hornblende grains are replaced by finer aggregates of hornblende along spaced cleavages. Note the small angle obliquity between the two
fabrics.

(1995) was used for correcting the matrix effects from the raw 3.1. M1 metamorphic stage (pre/syn-S1 )
analytical data. The chemical age for each spot analysis was cal-
culated using the decay equation (Montel et al., 1996) and the The metamorphic stage in mafic granulites is represented by
least-square fit model of York (1966) using the MINCALC v. the assemblage plagioclase + orthopyroxene + clinopyroxene +
5 software. Linear background corrections were employed for ilmenite ± hornblende. Plagioclase, hornblende and ilmenite
the analytical conditions. Since the curvature of the background commonly hosted within pyroxenes (Fig. 6a) suggest the
under the Pb peak is a significant analytical consideration (Dahl pyroxenes to be metamorphic in origin. In migmatitic quart-
et al., 2005a,b), the linear background correction employed here zofeldspathic gneisses, the M1 metamorphic assemblage is
may have led to somewhat younger computed dates. In view of defined by almandine-grossular-rich garnet (Alm67–71 Prp05–20
this, the chemical dates may be associated with errors likely to Grs6–24 Sps3–4 ) ± orthopyroxene (Mg/(Mg + Fe) = 0.44–0.47)
be larger than those computed using proper background correc- bearing leucocratic layers (Pl: 45–49 An mol%) and biotite
tions. ± hornblende-rich melanocratic layers. Ilmenite, magnetite,
392
Table 2
Summary of mineral–chemical data in rocks used in this study (analytical details provided in Supplementary data file)
Sample No. Grt Opx Cpx Hbl Ol Bt Sep Pl

Alm Grs Prp Sps Mg/Mg + Fe++ Mg/Mg + Fe++ Mg/Mg + Fe++ , AlVI Mg/Mg + Fe++ Mg/Mg + Fe++ Xmei a Ca/Ca + Na

Mafic granulite
BA54 61 23 11 6 (M4 ) 0.43 (M1 ) 0.61 (M1 ) 0.39, 0.44 (M2 /M3 ) – – – 0.46–0.47 (M1 )
CS68 – – – – 0.48–0.49 (M1 ) 0.69–0.70 (M1 ) 0.46, 0.46 (M2 /M3 ) – – – 0.42–0.44 (M1 )
0.50 (M4 ) 0.66 (M4 ) 0.44 (nr-Hbl)
BA43B 57–60 21–23 12–13 7 (M4 ) – 0.62 (M1 ) 0.51, 0.42 (M2 /M3 ) – – – 0.47 (nr-Hbl) 0.48 (incl. Grt)
Quartzofeldspathic gneiss
CS40 71 6 20 3 (M1 ) 0.44–0.47 (M1 ) – 0.47, 0.52–0.56 (M2 /M3 ) – 0.44–0.53 (M1 ) 0.45–0.49 (M1 )

A.K. Maji et al. / Precambrian Research 162 (2008) 385–402


64 21 13 2 (M4 ) 0.51–0.54 (M2 /M3 ) – 0.46 (nr-Hbl)
CS100A 70 21 5 4 (M1 ) – – 0.20, 0.34 (M2 ) – 0.21 (M1 ) 0.30 (nr-Hbl)
67 25 5 2 (M4 ) 0.27, 0.37 (M3 ) 0.26 (M2 )
BAR33A 69 23 5 3 (M1 c) – – 0.27, 0.40 (M1 ) – – 0.35 (nr-M1 Hbl)
67 24 6 3 (M1 r) 0.26, 0.57 (M2 /M3 ) 0.34 (nr-M2 Hbl)
65 27 5 3 (M4 )
Calc-silicate gneiss
1/2D 1 96 1 2 (M1 ) – 0.66 (M1 ) – – – 0.74 (M1 ) –
5/2Db 55 38 3 4 (M1 ) – – – – – 0.63 (M1 ) 0.90 (rcyst)
Metapelite
4/1D 65 3 30 2 (M1 ) – – – – 0.61 (M2 /M3 ) – 0.31 (mtx)
5/4D 75 3 21 1 (M1 ) – – – – – – 0.24 (nr-Grt)
Monzonite gneiss
CS60A 67 22 9 2 (M4 ) 0.36–0.37 (M0 ) – 0.31–0.34, 0.28–0.35 (M3 ) – – – 0.35–0.37 (nr-Grt)
CS53 68–70 22–23 1–2 6–7 (M4 ) 0.10 (M0 ) 0.16 (M0 ) 0.16, 0.35 (M3 ) 0.03 (M0 ) – – 0.19 (nr-Grt)
Anorthosite
BA26 62 20 14 4 (M4 ) 0.50 (M0 ) 0.61 (M0 ) 0.49–0.61, 0.44–0.59 (M2 ) – – – 0.51(M0 ), 0.73 (nr-Grt)
CS88 63 28 7 2 (M4 ) 0.40 (M0 ) 0.30, 0.46 (M2 ) – – – 0.75 (nr-Hbl)
CS15 52 31 8 9 (M4 ) – – 0.32, 0.57 (M2 ) – – – 0.55 (M0 ), 0.79 (nr-Grt)
CS486A 68 17 11 4 (M4 ) 0.45 (M0 ) 0.61 (M0 ) 0.29, 0.50 (M2 ) – 0.36 (M3 ) 0.53 (M0 ), 0.44 (nr-Hbl)
BA36 61 21 16 3 (M4 ) 0.50 (M0 ) – 0.55, 0.59 (M3 ) – – – 0.54 (M0 ), 0.71 (nr-Grt)
Foliated granite
CS54 71 23 2 4 (M4 ) – – 0.11, 0.39 (M3 ) – 0.14 (M3 ) – 0.24 (nr-Hbl)
CS486B 68 18 10 4 (M4 ) – – – – 0.36 (M3 ) – 0.54 (incl-Grt)

Abbreviations—c: core; incl-X: included in mineral ‘X’; M0 : magmatic mineral; M1 , M2 , M3 , M4 : related to M1 , M2 , M3 and M4 metamorphic stages respectively, mtx: occur in the matrix; nr-X: close to mineral
‘X’; r: rim; rcyst: recrystallized mineral grain.
a X
mei after Oterdoom and Gunter (1983).
b From Sen and Bhattacharya (1993).
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 393

Fig. 6. Textural relations in mafic granulites. (a) Plane polarized light (PPL) image showing coronal garnet around M1 orthopyroxene in hornblende poor varieties.
Note the occurrence of hornblende, plagioclase and ilmenite inclusions in orthopyroxene. (b) PPL image showing garnet porphyroblasts in hornblende-rich mafic
granulites overgrowing shape preferred aggregates of S3 hornblende. The garnets frequently include hornblende (not in picture) and are intergrown with quartz and
ilmenite. (c) PPL and (d) BSE images showing vermicular intergrowths of orthopyroxene, clinopyroxene and plagioclase along the margin of a coarse hornblende
grain in hornblende-rich mafic granulites. Ilmenite, a common accessory phase in the intergrowths, may have formed along with pyroxene–plagioclase or may have
exsolved from hornblende. In (c), coarse orthopyroxene grains are included in the amphiboles.

zircon and apatite occur as accessory phases. Biotite, pla- 5Wo + 3Mei = 3Grs + 2Qtz + CO2 . It is, however, unclear if the
gioclase, K-feldspar and ilmenite commonly hosted within coronal garnets formed during M1 . This will necessitate the
garnet suggest the model prograde reactions for melt gener- delicate coronas to have escaped the penetrative S2 and S3
ation during M1 , e.g. Bt + Qtz + Pl + Ilm = Grt ± Opx + melt, fabric forming events.
Hbl + Qtz + Pl = Grt + melt.
Clinopyroxene–scapolite (Ca/Ca + Na + K ∼ 0.80; cf. 3.2. M2 (syn-S2 ) and M3 (syn-S3 ) metamorphic stages
Sen and Bhattacharya, 1993)—plagioclase (An90 )–K-
feldspar–calcite–quartz in calc-silicate gneisses, and almandine- The M2 and M3 metamorphic stages are marked by the
rich garnet (Alm65–75 Prp21–30 Grs∼3 Sps1–2 )–sillimanite–K- widespread stabilization of biotite in quartzofeldspathic
feldspar–quartz–green spinel (hercynite-rich; ZnO ∼5 wt gneisses, biotite ± sillimanite in metapelites, and hornblende
%)–ilmenite in metapelites constitute the M1 metamorphic (ferrotschermakite; Mg/(Mg + Fe) = 0.39–0.51) in mafic gran-
stage. In the calc-silicate gneisses, beads of almandine-gros- ulites at the expense of M1 minerals (Fig. 5b), e.g.
sular-rich garnet forming partial coronas along clinopy- garnet in felsic and pelitic lithologies, and orthopyroxene–
roxene–scapolite interfaces may have formed via the model clinopyroxene–plagioclase assemblages in mafic lithologies.
reaction, 3Mei + 3Hd = 2Grs + Alm + Cal + 3Qtz. In rare Bi-phase aggregates of hornblende (±biotite) and plagioclase
wollastonite-bearing calc-silicate gneisses, coronal garnets, vir- define the S2 foliation in banded anorthosites, but aggregates
tually grossular in composition and associated with or without of shape preferred alignment biotite grains are the S3 defining
calcite and quartz (cf. Sen and Bhattacharya, 1993), at the inter- mineral in foliated granites and banded anorthosites (Fig. 5a).
face between wollastonite and scapolite are likely to have formed In foliated granites, the S3 biotite grains (and quartz lenticles)
via the CASH reactions, 6Wo + 3Mei + = 3Grs + 3Qtz + Cal, typically wrap around pre-S3 garnet porphyroblasts, hornblende
394 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

and feldspar clasts. The widespread stabilization of hornblende 3.3. M4 metamorphic stage (post-S3 )
and biotite in different lithologies may be attributed to the fol-
lowing model reactions, e.g. Opx + Cpx + Pl + H2 O = Hbl + Qtz The metamorphic stage is marked by the post-S3 growth of
(in mafic granulites), Grt + Kfs + H2 O = Bt + Pl + Qtz + H2 O (in garnet (+quartz) in the form of double layered corona, discrete
felsic lithologies), and 3Grt + Kfs + H2 O = 2Bt + Sil + 2Qtz (in porphyroblasts, and overgrowths on pre-S3 porphyroblasts. In
metapelites). mafic granulites, characterized by the low abundance of horn-

Fig. 7. BSE images of M4 metamorphic stage garnet. (a–c) Garnet–quartz double layered corona mantling orthopyroxene in contact with plagioclase in monzonite
gneiss. In (a), quartz in sub-equal proportion to garnet occurs as thin inner collar; in (b–c), quartz in the coronitic overgrowths occurs in lower modal proportion and
along the outer rim of coronal garnet. (d and e) Garnet beads along the interface of hornblende and plagioclase in anorthosites from the pluton interior. Corroded and
embayed relicts of former magmatic orthopyroxene grains occur in the core of the hornblende + quartz intergrowths. Quartz is absent in the plagioclase matrix. (f)
Post-S3 M4 metamorphic garnet rims (with profuse quartz inclusions) on inclusion-poor pre-S3 garnet core in foliated granites. Inclusion trails of quartz, ilmenite
and biotite grains in M4 garnet rims are continuous with the external S3 foliation that warps around the garnet porphyroblasts.
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 395

blende, coronal garnets (Alm57–61 Prp11–13 Grs21–23 Sps6–7 ) with the monzonite gneisses may be traced to the participation of
inner collar of quartz occur at the interface between orthopyrox- fayalite olivine (Mg/(Mg + Fe) ∼ 0.03) and iron oxide phases as
ene (Mg/(Mg + Fe) ∼0.43) and plagioclase (∼An47 ) in mafic possible reactants for garnet production in Fe richer monzonite
granulites (Fig. 6a). The textural relations may be explained by gneisses, e.g. 3Fa/Fo (in Ol) + 3An (in Pl) = Grs + 2Prp/Alm (in
the model reaction for garnet formation, 3Fs/En (in Opx) + 3An Grt), and 3Fe2 O3 or 2Fe3 O4 + 3An (in Pl)+ 3Qtz = Grs + 2Alm
(in Pl) = Grs + 2Prp/Alm (in Grt) + 3Qtz. (in Grt) + 3/2 or 1 O2 .
The coronitic garnet–quartz intergrowths are unlikely to In cumulus-textured anorthosites, coronal garnets (Alm61–68
remain unmodified by the intense D2 and D3 deformations, Prp7–16 Grs17–28 Sps2–4 ) occur at the interface between
and hence are inferred to be post-tectonic to S2 /S3 fabrics. plagioclase (An71–73 near garnet; An51–55 in matrix) and
Similar garnet (Alm67–70 Prp1–9 Grs22–23 Sps2–7 )–quartz coro- hornblende–quartz aggregates that, in turn, replace for-
nal overgrowths around orthopyroxene (Mg/(Mg + Fe) = 0.10) mer magmatic orthopyroxene (Mg/(Mg + Fe) ∼ 0.45–50)
in contact with plagioclase (∼An36 ) are evident in Fe-rich and subordinate modal amounts of clinopyroxene,
monzonite gneisses (Fig. 7a–c). Compared to mafic granulites Mg/(Mg + Fe) ∼ 0.40–0.61 (Fig. 7d and e). Quartz is typically
(Fig. 6a), the area proportion of garnet/quartz is overwhelm- absent neighboring coronitic garnets. The textural relations
ingly higher in Fe-rich monzonite gneisses (Fig. 7a–c). The are consistent with the following sequence of reactions, Opx +
higher area proportion of coronal garnet relative to quartz in Cpx + Pl + H2 O = Hbl + Qtz, and Hbl + Qtz + Pl = Grt + H2 O.

Fig. 8. Two stage garnet growth (Grt–M1 and Grt–M4 ) in quartzofeldspathic gneisses. (a) Thin section scale (width = 3.5 cm) PPL image showing S1 quartz + K-
feldspar-rich leucocratic layers (with profuse M1 garnet porphyroblasts) interlayered with hornblende–plagioclase-rich melanocratic layers. Hornblende at the hinge of
folded melanocratic layers is re-oriented along S3 . (b) Close up view (box in a) shows M1 garnet (core with few coarse quartz inclusions) mantled by M4 overgrowths
studded with numerous quartz inclusions at the contact with hornblende. (c) X-ray images of Mg, Fe, Ca and Mn of the zoned garnet in b. (d) Compositional
variations in garnet across M1 core and M4 overgrowth along two lines m–p and m–q (shown in the Fe scan in c) are superposed. mXFe = Fe/Mg + Fe + Mn + Ca);
mXFe’ = Fe/Fe + Mg).
396 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

However, in hornblende-rich mafic granulites, post-S3 gar-


nets invariably occur as porphyroblasts overgrowing S2 /S3
hornblende-defined fabrics (Fig. 6b), and typically contain
inclusions of hornblende, plagioclase, and ilmenite, but never
pyroxenes. In quartzofeldspathic gneisses (Fig. 8) from the
enclave suite and foliated granites (Fig. 7f), garnet with quartz
vermicule either overgrows S3 biotite/hornblende as discrete
spongy porphyroblasts or as mantles around pre-S3 garnet
nuclei. In the quartzofeldspathic gneisses (say BAR-33A,
Fig. 8), the composition of post-S3 garnet (overgrowths or dis-
crete grains) can be approximated as Alm65 Prp5 Grs27 Sps3 ; by
contrast, the interior of pre-S3 nuclei of garnet has a com-
position around Alm69 Prp6 Grs23 Sps2 (Fig. 8). A perusal of
Fig. 8 shows that post-S3 garnets become progressively richer
in grossular and poorer in almandine, pyrope and spessar-
tine compared to the pre-S3 garnet nuclei. The warping S3
external foliation around pre-S3 garnet in foliated granites is Fig. 9. P–T conditions for M1 (pre-S2 ) and M4 (post-S3 ) metamorphic stages in
the Bero-Saltora area obtained from mineralogical thermo-barometry. The P–T
continuous with inclusion trails in the post-S3 garnet mantles boxes for the garnet forming M4 metamorphic stage are designated as Mg, Mz, A
(Fig. 7f). Barring coronal garnet + quartz in hornblende-poor and Q for mafic granulite, monzonite gneiss, anorthosite and quartzofeldspathic
mafic granulites and monzonite gneisses, in all other lithologic gneiss respectively. The possible prograde P–T paths for the M1 and M4 meta-
varieties, garnets formed through reactions involving biotite morphic stages are respectively shown by black (broken) and continuous gray
and/or hornblende. The following prograde reaction is suggested lines with arrows. The P–T locations of mineral thermo-barometric reactions
(numbered) for the M1 metamorphic stage are as follows: Opx–Grt thermome-
for the formation of garnet from biotite in felsic granulites, ters 1–3 (Sen and Bhattacharya, 1984; Harley, 1984; Lee and Ganguly, 1988);
Bt + Pl + Qtz + H2 O = Grt + Kfs + H2 O. Opx–Grt–Pl–Qtz barometers 4–8 (Newton and Perkins, 1982; Bohlen et al.,
In metapelites, quartz-rich spongy margins on M1 por- 1983; Powell and Holland, 1988; Moecher et al., 1988; Eckert et al., 1991);
phyroblasts overgrowing the warping schistosity defined Al-in-Opx equilibrium 9 (Aranovich and Berman, 1997).
by Bt + Sil + Spl are attributed to the following dehydra-
tion reactions, 2Bt + 3Spl + 9Qtz = 3Grt + 2Kfs + 2H2 O, and/or, Mn (having fastest diffusivity) suggest that the frozen-in com-
2Bt + Sil + 2Qtz = 3Grt + Kfs + H2 O. position was unlikely to have been homogenized by post-S1
Apart from the prolific development of M4 garnet in all metamorphic re-equilibration (Fig. 8). The thermometric for-
lithologies, the other textural feature that assumes importance mulations of Sen and Bhattacharya (1984), Harley (1984) and
is the vermicular orthopyroxene + clinopyroxene + plagioclase Lee and Ganguly (1988) for Mg–Fe exchange in Grt–Opx pairs
intergrowths along the margins of coarse hornblende grains in and Aranovich and Berman (1997) for Al solubility between
mafic granulites (Fig. 6c and d). The minerals in the vermicular Opx and Grt were applied to estimate temperatures. For pressure
intergrowths are not internally strained and therefore, post-date determination, the Opx–Grt–Pl–Qtz barometric formulations
the penetrative S2 /S3 shear fabric. of Newton and Perkins (1982), Bohlen et al. (1983), Powell
and Holland (1988), Moecher et al. (1988) and Eckert et al.
4. Metamorphic P–T conditions (1991) were used. Based on the thermo-barometric formula-
tions, the preferred estimate of M1 metamorphic conditions
4.1. M1 metamorphic stage is suggested to be 750–850 ◦ C and 4–6 kbar. The maximum
temperature (∼830 ◦ C) for Saltora granulites estimated by Sen
Metamorphic P–T conditions for the pre/syn-S1 gran- and Bhattacharya (1993) compares favorably with the estimated
ulite facies M1 stage are difficult to constrain because of T for the M1 stage (Fig. 9). The low-pressure, high-temperature
overprinting effects during later metamorphic events. The conditions during the M1 metamorphic stage is supported by
M1 P–T conditions summarized in Fig. 9 arguably were wollastonite–scapolite assemblages in calc-silicate gneisses (cf.
at a temperature comparable to or higher than the experi- Harley and Buick, 1992) and the Zn, Fe-rich spinel, sillimanite
mentally determined P–T loci of the fluid-absent garnet ± and quartz inclusions hosted in M1 garnet in metapelites (cf.
orthopyroxene producing melting reactions, e.g. biotite (mg# Dasgupta et al., 1995). The absence of M1 garnet in mafic
44) + plagioclase + quartz = orthopyroxene + melt (Vielzeuf and granulites indicates that the peak-M1 pressure was unlikely to
Montel, 1994) and biotite (mg# 23) + plagioclase + ilmenite + be high.
quartz = orthopyroxene + garnet + melt (Patiño Douce and
Beard, 1996). P–T conditions were estimated from core com- 4.2. M4 metamorphic stage
positions of incongruently produced garnet and orthopyroxene
(non-touching grains) in leucosomes from quartzofeldspathic Metamorphic P–T conditions (Fig. 9) correlatable with
gneisses. The large size (>1500 ␮m diameter) of garnet porphy- the widespread stabilization of garnet + quartz were esti-
roblasts (and maximum length of orthopyroxene ∼500 ␮m) and mated from (a) hornblende–plagioclase–garnet ± quartz
the preserved chemical zonations for Ca, Mg, Fe and especially assemblage in anorthosites, mafic granulites and quart-
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 397

zofeldspathic gneisses using the hornblende-plagioclase


thermometer of Holland and Blundy (1994) and low dP/dT
reactions (for which the P–T locations were determined using
the THERMOCALC program after Holland and Powell,
1998), and (b) orthopyroxene–garnet–plagioclase–quartz
reactions in monzonite gneisses. For the hornblende–
plagioclase–garnet ± quartz assemblages, good conver-
gence of the P–T loci for the vapor-free reactions, e.g.
Prp + Grs + Ts + Ab = Tr + Prg + An and its Fe-end member
reaction, and Grs + Alm + Ts + Ab = Tr + Fe-Act + Prg + An
(all quartz-free) were obtained within the T range retrieved
from the thermometer of Holland and Blundy (1994). The
retrieved pressure obtained from the intersection of the three
quartz-free reactions was bracketed within ±2 kbar by the two
quartz-bearing reactions, i.e. Prp + Grs + Ts + Qtz = Tr + An and
Prg + An + Qtz = Prp + Grs + Ts + Ab. In all assemblages, the
Tr-bearing reaction (Qtz in high-P side) was located at higher
pressure compared to the Ts-bearing reaction (Qtz in the low-P
side). This ensured that in lithologies such as anorthosites, and Fig. 10. Activity-corrected petrogenetic grid at X(H2 O) = 0.1 in the NCMASH
hornblende-rich mafic granulites in which the participation of system computed using the analytical data for the hornblende-rich garnet-
quartz in the garnet-forming reaction is doubtful (i.e. activity of bearing mafic granulite (BA 54). The P–T locations of the reactions were
SiO2 < 1), the two reactions limited the maximum and minimum computed using the THERMOCALC program (version 3.21) after Holland
and Powell (1998). The shaded box is the average P–T condition for garnet
M4 pressures respectively. In spite of the wide variations in formation in hornblende-rich mafic granulites. The model [Di, En] reaction
mineralogical compositions in the different lithologies, the (pargasite + anorthite + quartz = albite + pyrope + grossular + H2 O) is deemed to
estimated P–T conditions overlap to a large extent (Fig. 9). correspond closest with the stabilization of M4 garnet from M2 /M3 horn-
The preferred P–T conditions from the overlapping P–T boxes blende + plagioclase assemblage.
appear to be 650 ± 50 ◦ C and 4.5 ± 0.5 kbar.
Fig. 10 is a NCMASH activity-corrected petrogenetic
4.3. Synthesis of metamorphic P–T conditions grid for a hornblende-rich garnet-bearing mafic granulite
(BA 54) showing the topology of stable reactions involv-
Manna and Sen (1974) and Sen and Bhattacharya (1993) ing En, Di, Prg, Ab, An, Grs, Prp, Qtz and H2 O. X(H2 O)
attributed the growth of coronal garnet in the Saltora gran- was taken to be equal to 0.1 to ensure that the invariant
ulites to cooling from a thermal peak of ∼830 ◦ C at ∼7.5 kbar points relevant to possible garnet-forming reactions corre-
to 680 ± 20 ◦ C at 6.8 kbar. On the other hand, Bhattacharya spond closely to the preferred M4 P–T condition (shaded box)
and Mukherjee (1987) suggest that garnets in mafic gran- retrieved from garnet–hornblende–plagioclase–quartz equilib-
ulites were prograde in nature. The contention of Sen and rium in hornblende-rich mafic granulites. The activities of the
Bhattacharya (1993) is untenable because of the following rea- phases were linearized at the P–T for garnet formation. In petro-
sons. First, Sen and Bhattacharya (1993) failed to recognize genetic grids constructed over a large range of P–T conditions,
that M4 garnet in anorthosites, migmatitic quartzofeldspathic the activities are not necessarily constant and deviate from the
gneisses and hornblende-rich mafic granulites formed at the P–T value at which the activities were linearized. The close cor-
expense of M2 and M3 biotite and/or hornblende. Similarly, in respondence between the P–T loci of the reactions and the P–T
post-D1 , pre-D2 anorthosites and post-D2 , pre-D3 foliated gran- value at which the reactions were linearized ensured that the
ites, M4 garnets formed at the expense of biotite–plagioclase activities of the phase components were well-constrained and
and hornblende–plagioclase assemblages. By implication, gar- consequently the reaction topology in the neighborhood of the
net formation was prograde in nature. Second, textural evidence P–T box in Fig. 10 was reasonable.
favoring pre-S1 garnet in mafic granulites is lacking. The only The reactions relevant to stabilization of garnet from
point of concern could be the occurrence of coronal garnet at hornblende-bearing assemblages and excluding the reactions
orthopyroxene–plagioclase interfaces in hornblende-poor mafic with En and Di as co-product of garnet, are the [En, Di] and
granulites and monzonite gneisses. If the coronal garnets were [En, Qtz] reactions, e.g.
pre/syn-D1 features, and therefore corresponded to the M1
stage, it would be difficult to explain as to how the deli- [En, Di]6Prg + 9An + 9Qtz
cate corona remained unmodified by the intense D2 and D3 = 6Ab + 8Prp + 7Grs + 6H2 O
deformation events, and why the S2 /S3 fabrics do not wrap
around the coronitic garnets. Finally, the prograde nature of and
M4 metamorphism is supported by post-S3 re-stabilization of 2-
[En, Qtz]6Prg + 9Di + 18An
pyroxene + plagioclase vermicular intergrowths at the expense
of hornblende in hornblende-rich mafic granulites. = 6Ab + 11Prp + 13Grs + 6H2 O
398 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

In both reactions, plagioclase forms along with garnet, and estimate for the age of M1 metamorphic stage. Chatterjee (2006,
quartz is absent. These features are in agreement with the textural personal communication) retrieved the magmatic age of the
observations; however, the molar ratio of pyrope + almandine: Saltora anorthosite to be 1.55 Ga using isotope dilution ther-
grossular in the reactions is higher than the measured values of mal ionization mass spectrometry technique in zircons from
the ratio in garnets from mafic granulites. Both reactions are anorthosites; the lower intercept of the U–Pb discordia is at
characterized by high dP/dT slope indicating that garnet was ∼0.95 Ga. Since the anorthosite pluton is a post-D1 intrusive,
stabilized by an increase in temperature, assuming the P–T path the age of M1 granulite facies metamorphism (and charnock-
to be orthogonal to the P–T loci of the reactions. ite emplacement?) should arguably be older than 1.5 Ga. In
other words, the <1.5 Ga dates retrieved from monazites in
5. Chronology of polyphase metamorphism metapelites correspond to younger metamorphic events. At the
other extreme, the 0.9–1.0 Ga age population obtained from
The textural relations and petrogenetic considerations monazites hosted in post-S3 garnet overgrowths in foliated
suggest that the M1 (750–850 ◦ C and 4–6 kbar) and M4 granites coincides with the lower intercept age of 0.95 Ga (cf.
(650 ± 50 ◦ C and 4.5 ± 0.5 kbar) metamorphic stages represent Chatterjee, 2006, personal communication). This age popula-
episodes of prograde metamorphism, separated by M2 and M3 tion is likely to correspond with the prograde M4 metamorphic
retrograde stages. In order to ascertain the ages of the polyphase stage.
metamorphic events, monazites were analyzed in four samples, By implication, the 1.1–1.4 Ga age population in garnet-
e.g. two garnet-bearing metapelites (BA 90B and CS 39B), and hosted monazites in metapelites and bracketed by the >1.5 Ga
two garnet-bearing foliated granites (CS 515 and CS 549). The M1 metamorphic stage and the 0.9–1.0 Ga M4 metamorphic
analyzed monazites were grouped into two textural types, i.e. stage is likely to correspond with the D2 and/or the D3 amphi-
those hosted within garnet porphyroblasts, and the ones occur- bolite facies ductile deformation events. The age cluster is also
ring as discrete grains in the recrystallized matrix (Fig. 11). In reflected by monazites in foliated granites. Since the foliated
two metapelite samples, garnets that host monazites were pre-D1 granites were emplaced post-dating D2 , the 1.1–1.4 Ga EPMA
porphyroblasts (M1 metamorphic stage), whereas garnets that monazite age in the granites is best explained if the pre-S3 gar-
hosted monazites in foliated granites have pre-D3 cores with nets were entrained from the precursor enclave suite which on
post-D3 (M4 ) overgrowths. melting at deeper levels produced the post-D2 granites. In other
Chemical ages obtained from spot analysis in monazites in words, the pre-S3 garnet nuclei in foliated granites were not
metapelites fit into several age clusters (Figs. 11 and 12). The incongruently produced phases on melting.
dominant number of spot analyses yielded monazite ages in the In contrast to the monazite chemical ages discussed above,
range 1.1–1.2 Ga. Few spots more centrally located within mon- the youngest chemical ages (660–830 Ma) retrieved along
azites yielded older ages, ∼1.3–1.4 Ga. However, the margins the margins of monazite grains constitute a minor popula-
of the monazite grains yield younger ages between 830 and 660 tion of the analyzed spots in one metapelite sample (BA
Ma, out of which the dominant age population is between 800 90B; Figs. 11 and 12). The ages are rare in foliated granites.
and 830 Ma (Fig. 12). These post-Grenvillian rim ages (Fig. 11a and c) are diffi-
Monazites in post-D2 foliated granites fit into two groups, cult to explain. The chemical ages may correspond with a
e.g. monazites within pre-S3 garnets, and post-S3 garnet over- subsequent regional scale tectonic event that does not man-
growths. Spot analysis in monazites hosted in pre-S3 garnets ifest itself in the mesoscopic or microscopic scale in the
yielded dates between 0.9 and 1.2 Ga. A majority of these dates samples examined. Alternatively, the age cluster may repre-
cluster between 0.9 and 1.0 Ga, as do the EPMA dates from sent local re-setting of older ages by fluid-driven processes of
monazites hosted in post-S3 garnet overgrowths. The Grenvillian dissolution-recrystallization operating at temperatures below the
age (∼0.9–1.0 Ga) obtained from the foliated granites is iden- Pb diffusional closure temperature. A more definitive assess-
tical with the Pb–Pb (zircon) emplacement age of granites (cf. ment of the age should await a more detailed scrutiny of monazite
Vinogradov et al., 1964; Fig. 1b). The youngest dates ∼0.8 Ga chemical ages in a larger set of samples.
occur sporadically in the marginal parts of monazite.
Available evidence (Copeland et al., 1988; Smith and 6. Tectonic implications
Barreiro, 1990; Suzuki and Adachi, 1994) indicates Pb loss in
monazites occurs at temperatures >600 ◦ C. Dahl (1997) and The thermo-chronologic data emphasize the existence of
Cherniak et al. (2004) postulate higher closure temperatures mid-Proterozoic polyphase high-grade metamorphism in the
∼700 ◦ C and >900 ◦ C, respectively, for diffusive Pb loss in CGC, but precludes Pan African ductile deformation and
monazite. Since temperatures comparable to 600–700 ◦ C were associated high grade metamorphism. In the Proterozoic
attained during M1 and M4 metamorphic stages, the EPMA North Singhbhum Mobile Belt to the south, age data on
monazite ages need to be examined carefully. For example, the greenschist–amphibolite facies metamorphic events experi-
oldest monazite age population (>1.1–1.4 Ga) may be corre- enced by metabasic and metapelitic schists and phyllites are
lated with the earliest metamorphic event (M1 ), or the chemical sketchy. However, available chronologic data suggest two
age may correspond with partially or complete re-set ages of age populations for tectono-thermal events, e.g. at ∼1.2 and
M1 metamorphism during subsequent metamorphic events. In ∼1.5–1.6 Ga (EPMA dates from garnet-hosted monazites in
the latter case, the 1.1–1.4 Ga age should provide the minimum metapelites, Mahato et al., 2008; whole rock Sm–Nd, Roy et
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 399

Fig. 11. BSE images of representative texturally constrained monazite (Mnz) grains analyzed in metapelite sample BA 90B (a–d), and foliated granite samples CS
515 (e) and CS 549 (f–h). Bars indicate scale in ␮m, and numbers indicate EPMA ages (in Ma) obtained from analyzed spots. In the metapelite samples, the textural
set up of the monazite grains to the left (a and c) are shown to the right (b and d). (a and b) Monazite grain in the recrystallized matrix. (c and d) Monazite grain
hosted within quartz which in turn is hosted in a M1 garnet porphyroblast. (e) and (f) are monazite grains within the recrystallized quartzofeldspathic mineral mosaic
in foliated granites. (g) Monazite grain at the rim of garnet. The inclusions in the overgrowth are continuous with the linear aggregate of ilmenite defining the S3
fabric in the granite. (h) Garnet-hosted monazite grain centrally located within pre-S3 garnet.
400 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

Fig. 12. Plots of PbO against ThO∗2 in monazite grains in metapelites (a and b) and in foliated granites (c and d) from the Bero-Saltora area. The lines correspond
to reference isochrons indicated in the figures. Core and rim indicate interiors and margins of monazite grains. Porphyroblast and matrix refer to monazites hosted
within and outside garnets, respectively. ‘n’ indicates the number of analyzed spot used in the regression analysis.

al., 2006). The older age coincides with the U–Pb age obtained north–south direction in its present geographical configuration,
from uraninites (Rao et al., 1979) in the southern shear zone. or should describe north and south closing folds in response to
The youngest ages yet recorded in the mobile belt is ∼1.0 Ga the southward migration of the Indian block from north latitude
arguably correlatable with uranium mineralization by the K–Ar and its glancing juxtaposition with the Australo-Antarctic block.
method (cf. Misra and Johnson, 2005). Clearly, the lack of Cam- The lack of north–south trending fabrics and north/south clos-
brian dates from the North Singhbum Mobile Belt and the CGC ing folds post-dating the Grenvillian fabric in the CGC precludes
suggests that Pan African tectonism was not a regional feature the likely continuation of the Pan African suture (Sheraton et al.,
in the Eastern Indian Precambrian crystalline complexes. 1984, 1993; Harley and Fitzsimons, 1995; Kinny et al., 1993;
The east–west trending north-dipping tectonic fabric (S3 ) in Boger et al., 2001; reviewed in Harley, 2003) within the CGC.
Bero-Saltora, associated with Grenvillian prograde amphibolite- Apparently, the proposed westward extension of the Australo-
to-granulite facies metamorphism and ductile shearing with Antarctic suture within eastern India with possible vestiges in
reverse sense movement on the shear plane assumes impor- the Shillong-Meghalaya Plateau (Chatterjee et al., 2007) should
tance. This tectonic grain, popularly known as “the Satpura lie to the east of the Bero-Saltora area.
trend”, is a regional feature within the CGC (eastern India)
and the Central Indian Tectonic domain (central India). If the Acknowledgements
proposed trend of the Australo-Antarctic Pan African collision
zone within India is correct, the Pan African suture in East- Financial support for the work was provided by the CSIR
ern India is expected to be at high angle to the penetrative grant in aid [No: 24(0268)/04/EMR-II] to AKM and the DST
east–west “Satpura trend” in consonance with the palaeomag- funded project (ESS/23/VES/125/2001) to AB and BM. The
netic data at 500 Ma (Fig. 1a). If the proposed Pan African work was completed during the tenure of SG and SM as Research
suture passed within the CGC, the Grenvillian tectonic fabric Fellows in the Department of Geology and Geophysics, IIT
within the CGC is expected to be oriented in an approximately Kharagpur in the DST funded project. A part of the work was
A.K. Maji et al. / Precambrian Research 162 (2008) 385–402 401

adopted from the doctoral dissertation of SG submitted to the Dahl, P.C., Terry, M.P., Jercinovic, M.J., Williams, M.L., Hamilton, M.A.,
Indian Institute of Technology, Kharagpur in 2006. Sabyasachi Foland, K.A., Clement, S.M., Freiberg, L.M., 2005b. Electron probe (Ultra-
chron) microchronometry of metamorphic monazite: Unraveling the timing
Som (GSI, Kolkata) provided valuable assistance in obtaining
of polyphase thermotectonism in the easternmost Wyoming Craton (Black
the BSE images. Dr. R. Kleinschrodt (University of Koln) is Hills, South Dakota). Amer. Miner. 90, 1712–1728.
thanked for assisting in X-ray imaging (Fig. 8) using the JEOL Dasgupta, S., Sengupta, P., Ehl, P., Raith, M., Bardhan, S., 1995. Reaction
microprobe machine; the compositional data for the zoned gar- textures in a suite of spinel granulites from the Eastern Ghats Belt, India:
net in the figure was determined using the CAMECA electron evidence for polymetamorphism and a partial petrogenetic grid in the system
probe microanalyzer at the University of Bonn. In this connec- KFMASH, and the role of ZnO and Fe2 O3 . J. Petrol. 36, 435–461.
Dastidar, S., Samanta, S., Chaudhuri, A.K., 1997. Multiple deformations around
tion, AB acknowledges the financial support provided by the Saltora–Murlu in the western part of Bengal anorthosite. J. Geol. Soc. India
Alexander von Humboldt Stiftung (Germany). Prof. M. Raith 50, 201–208.
(University of Bonn) provided hospitality during the stay and Den Tex, E., 1969. Origin of ultramafic rocks, their tectonic setting and history:
access to the Cameca EPMA for the analytical work. S. Das A contribution to the discussion of the paper “The origin of ultramafic and
(Ex-research Scholar) in the Department of Geology and Geo- ultrabasic rocks” by P.J. Wyllie. Tectonophysics 7, 457–488.
Eckert Jr., J.O., Newton, R.C., Kleppa, O.J., 1991. The H of reaction and
physics, IIT Kharagpur is thanked for his help during the course recalibration of garnet–pyroxene–plagioclase–quartz geobarometers in the
of the work. The authors are grateful to Ingo Braun and an anony- CMAS system by solution calorimetry. Amer. Miner. 76, 148–160.
mous journal reviewer for their thoughtful comments on the Fitzsimons, I.C.W., 2003. Proterozoic basement provinces of southern and south-
manuscript. Their suggestions helped to improve the style and western Australia, and their correlation with Antarctica. In: Yoshida, M.,
presentation of the manuscript. Windely, B.F., Dasgupta, S. (Eds.), Proterozoic East Gondwana: supercon-
tinent assembly and breakup., 206. Geol. Soc. Lond., pp. 93–130 (Spec.
Pub.).
Appendix A. Supplementary data Ghose, N.C., 1983. Geology, tectonics and the evolution of the Chhotanagpur
Granite–Gneiss Complex, Eastern India. In: Roy, S.S. (Ed.), Structure and
Supplementary data associated with this article can be found, Tectonics of Precambrian Rocks of India. Hindustan Publishing Corporation,
Delhi, pp. 211–247.
in the online version, at doi:10.1016/j.precamres.2007.10.002.
Ghose, N.C., Shmakin, B.M., Smirnov, V.N., 1973. Some geochronological
observations on the Precambrians of Chhotanagpur, Bihar, India. Geol. Mag.
References 110, 477–482.
Harley, S.L., 1984. An experimental study of the partitioning of Fe and Mg
Aranovich, L.Y., Berman, R.G., 1997. A new garnet–orthopyroxene thermome- between garnet and orthopyroxene. Contrib. Miner. Petrol. 86, 359–373.
ter based on reversed Al2 O3 solubility in FeO–Al2 O3 –SiO2 orthopyroxene. Harley, S.L., 2003. Archaean-Cambrian crustal development of East Antarc-
Amer. Miner. 82, 345–353. tica: metamorphic characteristics and tectonic implications. In: Yoshida, M.,
Armstrong, J.T., 1995. CITZAF: a package of correction programs for the quan- Windley, B.F., Dasgupta, S. (Eds.), Proterozoic East Gondwana: supercon-
titative electron microbeam X-ray analysis of thick polished materials, thin tinent assembly and breakup., 206. Geol. Soc. Lond., pp. 203–230 (Spec.
films, and particles. Microbeam Anal. 4, 177–200. Pub.).
Bhattacharya, P.K., Mukherjee, S., 1987. Granulites in and around the Bengal Harley, S.L., Buick, I.S., 1992. Wollastonite–scapolite assemblages as indi-
anorthosite, eastern India; genesis of coronal garnet, and evolution of the cators of granulite pressure–temperature histories: the Rauer Group, East
granulite–anorthosite complex. Geol. Mag. 124, 21–32. Antarctica. J. Petrol. 33, 693–728.
Bhowmik, S.K., Basu Sarbadhikari, A., Spiering, B., Raith, M.M., 2005. Harley, S.L., Fitzsimons, I.C.W., 1995. High-grade metamorphism in the Prydz
Mesoproterozoic reworking of Palaeoproterozoic ultrahigh-temperature Bay region, East Antarctica: terranes, events and regional correlations. In:
granulites in the Central Indian Tectonic Zone and its implications. J. Petrol. Yoshida, M., Santosh, M. (Eds.), India and Antarctica During the Precam-
46, 1085–1119. brian, 34. Geol. Soc. India Mem., pp. 73–100.
Boger, S.D., Wilson, C.J.L., Fanning, C.M., 2001. Early Paleozoic tectonism Holland, T.J.B., Blundy, J., 1994. Non-ideal interactions in calcic amphiboles
within the East Antarctic craton: The final suture between east and west and their bearing on amphibole plagioclase thermometry. Contrib. Miner.
Gondwana? Geology 29, 463–466. Petrol. 116, 433–447.
Bohlen, S.R., Wall, V.J., Boettcher, A.L., 1983. Experimental investigation Holland, T.J.B., Powell, R., 1998. An internally consistent thermodynamic
and application of garnet granulite equilibria. Contrib. Miner. Petrol. 83, dataset for phases of petrological interest. J. Met. Geol. 16, 309–343.
52–61. Kinny, P.D., Black, L.P., Sheraton, J.W., 1993. Zircon ages and the distribution
Chatterjee, N., Mazumdar, A.K., Bhattacharya, A., Saikia, R.R., 2007. Meso- of Archaean and Proterozoic rocks in the Rauer Islands. Antarctic Sci. 5,
proterozoic granulites of the Shillong–Meghalaya Plateau: evidence of 193–206.
westward continuation of the Prydz Bay Pan-African suture into North- Kretz, R., 1983. Symbols for rock-forming minerals. Amer. Miner. 68, 277–279.
eastern India. Precamb. Res. 152, 1–26. Kruhl, J.H., 1996. Prism- and basal-plane parallel subgrain boundaries in quartz:
Cherniak, D.J., Watson, E.B., Grove, M., Harrison, P.M., 2004. Pb diffusion in a microstructural geothermobarometer. J. Met. Geol. 14, 581–589.
monazite: a combined RBS/SIMS study. Goechim. Cosmochim. Acta 68, Kruhl, J.H., 1998. Prism- and basal-plane parallel subgrain boundaries in
829–840. quartz: a microstructural geothermobarometer – Reply. J. Met. Geol. 16,
Copeland, P., Parrish, R.R., Harrison, T.M., 1988. Identification of inherited 142–146.
radiogenic Pb in monazite and its implications for U–Pb systematics. Nature Kruhl, J.H., Huntemann, T., 1991. The structural state of the former lower conti-
333, 760–763. nental crust in Calabria (S. Italy). Int. J. Earth Sci. (Geologische Rundschau)
Dahl, P.S., 1997. A crystal-chemical basis for Pb retention and fission- 80, 289–302.
track annealing systematics in U-bearing minerals, with implications for Lee, H.Y., Ganguly, J., 1988. Equilibrium compositions of coexisting
geochronology. Earth Planet. Sci. Lett. 150, 277–290. garnet and orthopyroxene: experimental determinations in the system
Dahl, P.C., Hamilton, M.A., Jercinovic, M.J., Terry, M.P., Williams, M.L., Frei, FeO–MgO–Al2 O3 –SiO2 , and applications. J. Petrol. 29, 93–113.
R., 2005a. Comparative isotopic and chemical geochronometry of monazite, Mahadevan, T.M., 2002. Geology of Bihar and Jharkhand, first edition. Geolog-
with implications for U–Th–Pb dating by electron microprobe: An example ical Society of India Publication, Bangalore, pp. 257–321.
from metamorphic rocks of the eastern Wyoming Craton (U.S.A.). Amer. Mahato, S., Goon, S., Bhattacharya, A., Mishra, S., Bernhardt, H.J., 2008.
Miner. 90, 619–638. Thermo-tectonic evolution of the North Singhbhum Mobile Belt; A
402 A.K. Maji et al. / Precambrian Research 162 (2008) 385–402

view from the western part of the belt. Precamb. Res. 162, 102– Roy, A., Kagami, H., Yoshida, M., Roy, A., Bandyopadhyay, B.K., Chattopad-
127. hyay, A., Khan, A.S., Huin, A.K., Pal, T., 2006. Rb–Sr and Sm–Nd dating
Manna, S.S., Sen, S.K., 1974. Origin of garnet in basic granulites around Saltora, of different metamorphic events from the Sausar Mobile Belt, central India:
West Bengal, India. Contrib. Miner. Petrol. 44, 195–218. implications for Proterozoic crustal evolution. J. Asian Earth Sci. 26, 61–76.
Masberg, H.P., Hoffer, E., Hoernes, S., 1992. Microfabrics indicating granulite- Roy, A.K., 1977. Structure and metamorphic evolution of the Bengal anorthosite
facies metamorphism in the low-pressure central Damara Orogen, Namibia. and associated rocks. J. Geol. Soc. India 18, 203–223.
Precamb. Res. 55, 243–257. Saha, A.K., 1994. Crustal Evolution of Singhbhum,North Orissa Eastern India,
Misra, S., Johnson, P.T., 2005. Geochronological constraints on evolution of vol. 27. Geol. Soc. India Mem, 341p.
Singhbhum Mobile Belt and associated basic volcanics of Eastern Indian Sen, S.K., Bhattacharya, A., 1984. An orthopyroxene–garnet thermometer and
Shield. Gond. Res. 8, 129–142. its application to the Madras charnockites. Contrib. Miner. Petrol. 88, 64–71.
Moecher, D.P., Essene, E.J., Anovitz, L.M., 1988. Calculation and applica- Sen, S.K., Bhattacharya, A., 1993. Post-peak pressure–temperature fluid history
tion of clinopyroxene–garnet–plagioclase–quartz geobarometers. Contrib. of the granulites around Saltora, West Bengal. Proc. Nat. Acad. Sci India 63
Miner. Petrol. 100, 92–106. (A) (I), 282–306.
Montel, J.M., Foret, S., Veschambre, M., Nicollet, C., Provost, A., 1996. Electron Sheraton, J.W., Black, L.P., McCulloch, M.T., 1984. Regional geochemical and
microprobe dating of monazite. Chem. Geol. 131, 37–53. isotopic characteristics of high-grade metamorphics of the Prydz Bay area:
Newton, R.C., Perkins III, D., 1982. Thermodynamic calibration of geo- the extent of Proterozoic reworking of Archaean continental crust in East
barometers based on the assemblage garnet–plagioclase–orthopyroxene Antarctica. Precamb. Res. 26, 169–198.
(clinopyroxene)–quartz. Amer. Miner. 67, 203–222. Sheraton, J.W., Tingey, R.J., Black, L.P., Oliver, R.L., 1993. Geology of the
Nicolas, A., Ildefonse, B., 1996. Flow mechanism and viscosity in basaltic Bunger Hills area, Antarctica: implications for Gondwana correlations.
magma chambers. Geophys. Res. Lett. 23, 2013–2016. Antarctic Sci. 5, 85–102.
Oterdoom, H.W., Gunter, W.D., 1983. Activity models for plagioclase and Smith, H.A., Barreiro, B., 1990. Monazite U–Pb dating of staurolite grade
CO3 -scapolite—an analysis of field and laboratory data. Amer. J. Sci. 283, metamorphism in pelitic schists. Contrib. Miner. Petrol. 105, 602–615.
255–282. Suzuki, K., Adachi, M., 1994. Middle Precambrian detrital monazite and zircon
Pandey, B.K., Gupta, J.N., Lall, Y., Mahadevan, T.M., 1986. Rb–Sr isochron and from the Hida gneiss on Oki-Dogo Island, Japan: their origin and impli-
Sm–Nd model ages for soda granites from Singhbhum Shear Zone, Bihar cation for the correlation of the basement of Southwest Japan and Korea.
and their bearing on crustal evolution. Ind. J. Earth Sci. 13, 117–128. Tectonophysics 235, 277–292.
Paterson, S.R., Fowler, T.K., Schmidt, K.L., Yoshinobu, A., Yuan, S., 1998. Suzuki, K., Adachi, M., Tanaka, T., 1991. Middle Precambrian provenance of
Interpreting magmatic fabric patterns in plutons. Lithos 44, 53–82. Jurassic sandstone in the Mino terrane, central Japan: Th–U–total Pb evi-
Paterson, S.R., Vernon, R.H., Tobisch, O.T., 1989. A review of criteria for the dence from an electron micro probe monazite study. Sed. Geol. 75, 141–147.
identification of magmatic and tectonic foliations in granitoids. J. Struct. Vernon, R.H., 2004. A Practical Guide to Rock Microstructure. Cambridge
Geol. 11, 349–363. University Press, Cambridge, 468p.
Patiño Douce, A.E., Beard, J.S., 1996. Effects of P, f(O2 ) and Mg/Fe ratio on Vielzeuf, D., Montel, J.M., 1994. Partial melting of metagreywackes. Part I.
dehydration melting of model metagreywackes. J. Petrol. 37, 999–1024. Fluid absent experiments and phase relationships. Contrib. Miner. Petrol.
Powell, C.Mc.A., Pisarevsky, S.A., 2002. Late Neoproterozoic assembly of East 117, 375–393.
Gondwana. Geology 30, 3–6. Vinogradov, A.P., Tugarinov, A.I., Zhykov, C., Stapnikova, N., Bibikova, E.,
Powell, R., Holland, T.J.B., 1988. An internally consistent thermodynamic Khorre, K., 1964. Geology of the Indian Precambrian. In: Proceedings of
dataset with uncertainties and correlations. Part 3. Applications to geo- the 22nd International Geological Congress 10, pp. 553–567.
barometry, worked examples and a computer program. J. Met. Geol. 6, Willner, A.P., Herve, F., Massonne, H.J., 2000. Mineral chemistry and
173–204. pressure–temperature evolution of two contrasting levels within an accre-
Rao, N.K., Aggarwal, S.K., Rao, G.V.U., 1979. Lead isotopic ratios of uraninites tionary complex in the Chonos Metamorphic Complex, Southern Chile. J.
and the age of uranium mineralisation in Singhbhum Shear Zone, Bihar. J. Petrol. 41, 309–330.
Geol. Soc. India 20, 124–127. Yedekar, D.B., Jain, S.C., Nair, K.K.K., Dutta, K.K., 1990. The central Indian
Ray Barman, T., Bishui, P.K., Mukhopadhyay, K., Ray, J.N., 1994. Rb–Sr collision suture. In: Precambrian of Central India. Geol. Surv. India 28, 1–43
geochronology of the high-grade rocks from Purulia, West Bengal and (Spec. Pub.).
Jamua-Dumka sector, Bihar. Ind. Miner. 48, 45–60. York, D., 1966. Least squares fitting of straight line. Can. J. Phys. 44, 1079–1088.

You might also like