AMINES

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01.Amongst the following, the most basic compound is:
(a) Benzylamine (b) Aniline
(c) Acetanilide (d) p-nitroaniline
02. The compound that is most reactive towards
electrophilic nitration is:
(a) Benzene (b) Nitrobenzene
(c) Benzoic acid (d) Toluene
03. Carbylamine test is performed in alcoholic KOH by
heating a mixture of:
(a) Trihalogenated methane and a primary amine
(b) An alkyl halide and a primary amine
(c) An alkyl cyanide and a primary amine
(d) Chloroform and silver powder
04.Acetamide is treated separately with the following
reagents. Which one of these would give methylamine?
(a) Sodalime (b) PCl5
(c) NaOH + Br2 (d) Hot conc. H2SO4
05.
06. Which of the following reacts with NaNO2 + HCl at
273 – 278 K to give alcohol/phenol?
(a) CH3NH2 (b) C6H5NH2
(c) C6H5CH2NHCH3 (d) (CH3)2NH
07. Hinsberg reagent is:
(a) C6H5NO (b) C6H5N2Cl
(c) C6H5SO2Cl (d) C6H5SO3H
08. When acetamide is treated with NaOBr, the product
formed is:
(a) CH3OH (b) CH3NH2
(c) CH3CN (d) CH3COBr
09. Which of the following compounds cannot by
identified by carbylamine test?
(a) CHCl3 (b) C6H5 – NH – C6H5
(c) C6H5NH2 (d) CH3CH2NH2
10. Among the following compound C3H7NH2, NH3,
CH3NH2, C2H5NH2 and C6H5NH2 the least basic compound
is:
(a) C6H5NH2 (b) C2H5NH2
(c) CH3NH2 (d) NH3
11. Which of the following gives primary amine on
reduction?
(a) CH3CH2NO2 (b) CH3CH2 – O – N = O
(c) C6H5N = NC6H5 (d) CH3CH2NC.
12. Reaction of aniline with benzaldehyde is a ………
reaction?
(a) Addition (b) Condensation
(c) Polymerization (d) Substitution
13. The reagent that reacts with nitromethane to form
methylhydroxylamine is:
(a) Zn/NaOH (b) Sn/HCl
(c) Zn/NH4Cl (d) Zn/HCl
14. Which amine of the following will not give
carbylamine reaction?
(a) Ethylamine (b) Dimethylamine
(c) Methylamine (d) Phenylamine
15. Which of the following reagent can be used to convert
benzenediazonium chloride into benzene?
(a) H3PO2 (b) LiAlH4
(c) Br2 – H2O (d) CH3OH
16.
17. Which of the following reacts with Hinsberg reagent
(Benzene sulphonyl chloride) to form a product,
soluble in KOH?
(a) Primary amine (b) Secondary amine
(c) Tertiary amine (d) Quaternary amine
18.Aniline on reaction with acetyl chloride gives:
(a) Phenol (b) Acetamide
(c) Acetanilide (d) Benzene
19. On heating benzyl amine with chloroform and
ethanolic KOH, the product obtained is:
(a) Benzyl alcohol (b) Benzaldehyde
(c) Benzonitrile (d) Benzyl isocyanide
20. Towards electrophilic substitution, the most reactive
will be:
(a) Nitrobenzene
(b) Aniline
(c) Aniline hydrochloric
(d) n-acetylaniline
21. Pyridine is less basic than triethylamine because:
(a) Pyridine has aromatic character
(b) Nitrogen in pyridine is sp2 hybridized
(c) Pyridine is a cyclic system
(d) In pyridine, lone pair of nitrogen is delocalized
22.
23. A compound ‘A’ when treated with HNO3 (in the
presence of H2SO4) gives compound ‘B’, which is then
reduced with Sn and HCl to aniline? The compound
‘A’ is:
(a) Acetamide (b) Ethane
(c) Benzene (d) Toluene
24.
25.
26.
27.
28. Butanenitrile may be prepared by heating:
(a) Propyl alcohol with KCN
(b) Butyl alcohol with KCN
(c) Butyl chloride with KCN
(d) Propyl chloride with KCN
29. Ethyl chloride on heating with AgCN forms a
compounds X. The functional isomer of X will be:
(a) C2H5NH2 (b) C2H5NC
(c) C2H5CN (d) None of these
30.
31. Compound A on reduction gives B, which on further
reaction with CHCl3 and alcoholic KOH gives
compounds C, which on further hydrolysis gives
aniline. The compound A is:
(a) Nitrosobenzene (b) Methylamine
(c) Nitromethane (d) Nitrobenzene
32.
33. Ethyl isocyanide on hydrolysis in acidic medium generates:
(a) Ethylamine salt and methanoic acid
(b) Propanoic acid and ammonium salt
(c) Ethanoic acid and ammonium salt
(d) Methylamine salt and ethanoic acid
34.
35. Which of the following statements relating to aniline
is not true?
(a) Aniline on Schotten-Baumann reaction gives
benzanilide
(b) Aniline cannot be prepared by the reduction of
benzonitrile with LiAlH4
(c) On heating with concentrated H2SO4 at 180oC,
aniline gives sulphanilic acid
(d) Aniline liberates nitrogen on treatment with ice
cold nitrous acid
36.
37.
38.
39.
40.
41. The correct sequence of reagents used for conversion
of aniline into benzylamine is
(a) NaNO2/HCl, CuCN, Sn/HCl
(b) NaNO2/HCl, CuCN, H3O+
(c) NaNO2/HCl, Cu+/H3PO2 , CH3NH2
(d) None
42. Among the following, the strongest base is:
(a) C6H5NH2
(b) p-NO2 – C6H4NH2
(c) m-NO2 – C6H4NH2
(d) C6H5CH2NH2
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58. Which of the following statement about primary
amines in false?
(a) Alkylamines are stronger base than NH3
(b) Alkylamines are stronger base than arylamines
(c) Alkylamines are react with nitrous acid to
producte alcohols
(d) Arylaminis react with nitrous acid to produce
phenols
59. Method by which Aniline cannot be prepared is?
(a) Reduction of nitrobenzene with H2/pd in ethanol
(b) Hydrolysis of phenylcyanide with acidic solution
(c) Degradation of benzamide with bromine in
alkaline solution
(d) Potassium salt of phthalimide treated with
chlorobenzene followed by hydrolysis with
aqueous NaOH solution
60. Which one of the following nitro compounds does not
react with nitrous acid ?
 ANSWERS

01. 1 11. 1 21. 4 31. 4 41. 1 51. 1

02. 4 12. 2 22. 3 32. 2 42. 4 52. 3
03. 1 13. 3 23. 3 33. 1 43. 1 53. 3
04. 3 14. 2 24. 2 34. 1 44. 2 54. 4
05. 2 15. 1 25. 3 35. 4 45. 2 55. 3
06. 1 16. 3 26. 4 36. 1 46. 2 56. 2
07. 3 17. 1 27. 3 37. 4 47. 3 57. 4
08. 2 18. 3 28. 4 38. 1 48. 1 58. 4
09. 2 19. 4 29. 3 39. 2 49. 1 59. 4
10. 1 20. 2 30. 2 40. 2 50. 2 60. 3