You are on page 1of 15

MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE

IIT – JEE: 2022 CRASH COURSE (MAIN) DATE: 31/01/22


TIME: 1 Hr. TOPIC: HEAT & THERMODYNAMICS MARKS: 100
JEE Main Practice
MODERN Test - 14
PHYSICS
ALLEN
ALLEN
SINGLE CORRECT ANSWER TYPE
This section contains: (Maximum
SECTION-I 20 multiple choice
Marks: 80) questions. Each question ख�डhas 4 options (A),
–I : (अिधकतम अ ंक: 80)(B), (C) and
(D) for SECTION-I
its answer, :
out (Maximum
of which ONLYMarks: 80)ONE option 3.
This
This section
section contains
contains 20
20 questions.
questions. Each question
Each question hashas इसcan खंड म�be20correct.
�� ह�। ��येक �� म� सही उ�र के िलए 4 िवक�प ह�।
Marking
44 options scheme: +4 for correct answer, 0 if not attempted and –1केin वलallएकother
िवक�प cases.
options for for correct answer. answer. Multiple-Choice
Multiple-Choice बहिवक�पीय �� (MCQs) सही है। ��येक ��
Questions (MCQs) Only one option
Questions (MCQs) option isis correct.
correct. ForFor के िलए, अंक िन�नानसु ार िदए जाएंगे:
1. When stopping potential is applied in an experiment on photoelectric effect, no photocurrent is
each question,
each question, marks
marks will
will be awarded
be awarded as follows:
as follows: पणू � अंक           :    +4 यिद सही उ�र चनु ा गया है।
Full observed.
Marks           This
:   +4 means
If correctthatanswer is selected.
Full Marks 
(A) The       photoelectrons
 :   +4 If correct answer is selected. श�ू य अंकby   the
     : emitter
  0 यिद कोई भी िवक�प नह� चनु ा गया है।
Zero Marks         :    0 If none ofare the emitted
option isbut are reabsorbed
selected.
Zero Marks 
Negative       photoelectrons
(B)Marks 
The  : :   –10 IfIf none
wrongofoptionthedispersed
are option is selected.
is selected. ऋणा�मक
from the sides of theअंकapparatus.
Voltage   :    –1 यिद गलतresistance
across िवक�प चनु ा(V गया) है। versus
R
Negative (C)Marks 
The photoelectrons
:  –1 If wrong
1. Truth table for function X is given by:
are accumulated
option is selected. near the collector plate.
frequency graph of LCR circuit is shown. The
(D) The emission of photoelectrons is stopped
1. During a rainy day, rain is falling vertically 1. bandwidth
िकसी वषा� वाले of circuit
िदन वषा�is:
 2 m/s वेग से ऊ�वा�धर नीचे क�
down with a velocity 2 m/s. A boy at rest
2. A positron is emitted by radioactive nucleus of protonओर िगर रही है90.
number । िवराम
Theम� product
खड़ा एक लड़का nucleusसीधी सड़क
will haveके
starts his motion with a constant acceleration
proton number 2 अनिु दश अपनी गित  2 m/s2  िनयत �वरण से �ार�भ
of 2 m/s
(A) A B along
X a straight(B)road.A FindX the rate at
B
(A) 89
which the angle of the axis0 of0 the 1 umbrella करता है । छाते क� अ� के कोण को ऊ�वा�धर से िकस दर
(B) 900 0 0
with vertical should be changed so that the
(C) 910 1 0 पर प�रवित�त करना होगा तािक वषा� सदैव, छाते क� अ� के
rain always appears to fall 0 1 1to the axis
parallel
(D) 88 समा�तर िगरती �तीत हो? 
of the1 umbrella.
0 1 1 0 0
3. The rest 1 11mass 1 of a deuteron1 is21equivalent 0 to an energy of 1876 1 2 to 939 MeV,
(A) (B) (A) 600 HzMeV,
(A)
that of a proton
(B)
and
(C) that 1 oft a neutron to 940 1MeV.
2
(D) A B t XA deuteron may disintegrate
2 1 tot a proton and a neutron
2 1 t 2 if it
A B X
(A) Capture 1 an X–ray photon of 1 energy 3 MeV 1– 1
(C) 0 0 2 0 (D) 0 0 12 (C) 300 32Hz
(B) (D)
(B) Emits2 tan X–ray photon 1of energy 2t 3 MeV 2 t– 1 2t 2
(C) 200 3 Hz
2. (C) Captures
0 1 1ofan2 X–ray
A resistance photon
Ω is connected 0 1of energy
0 one2gap
across MeV 2.
एक 2Ω �ितरोध मीटर-ि�ज के एक अ�तराल पर जड़ु ा है
(D) Emits an X–ray photon of energy 2 MeV –
of a 1 metre-bridge
0 0 and unknown1 0 1 resistance, (D) 300 2 Hz
तथा अ�ात �ितरोध जो 2Ω से अिधक है, अ�य अ�तराल
greater than 2 Ω , is connected across the other
1 0 500.0 mm is 4. Instead
4. Agap.thin1When 1 1 metal disc of1 radius
circular these resistances are interchanged, set rotating है।ofजबangular
पर जड़ु ाabout �ितरोध momentum,
aये central आपस
axis म�normal a tophysicist
बदल िदये जाते ह�, तो
its plane.
th
assume that energy of n orbit is quantized as भीin
2. UponStudent raising
the balance x, y and its ztemperature
point measure 20gradually,
shifts bylength the radius increases
cm,of neglecting
a ground संतलु न toिब�द
E0
507.5
ु 20 mm.िव�थािपत
cm The percentage
हो जाता है
। change
िकसी
the
anyrotational
using end 50m longkinetic
correction, theenergy
measuring tape
unknown will be
ofresistance
least count
is Eअ��य संशोधन   (E0  > 0) and n is positive integer.
n 2 को नग�य मान�, तो अ�ात �ितरोध है -
(A) 1.5%
0.3cm,
(A)3% 3Ωmeter(B) scale 4Ωof LC(C)0.1cm 5Ω and(D) foot6Ωscale Which
(A) 3Ωof following (B) 4Ωis correct (C) 5?Ω{Consider (D) 6H-like
Ω
(B)
of LC 0.02cm respectively. If specified length atom}
(C)&–1.5%
Enthusiast Leader Course Phase-I to VIII / Score-I / Paper-2 1001CJA102121100
of06042022
E + H /(D) ground
–3% is 17.5m, then lowest relative error is (A) The angular momentum of  e ∝ Page n . 1/36
Space for Rough Work / रफ काय के िलए जगह
reported by student: (B) Radius of e–orbit ∝ n2.
(A) x (B) y (C) Speed of e– ∝ n.
(C) z (D) both x and y (D) Angular speed of e– ∝ n.
Enthusiast & Leader Course / Score-I 1001CJA102121101
CEnglish
Centers
ENTERS :Mumbai
MUMBAI/Delhi
/ :10042022 /DELHI/Akola
/AKOLA/Lucknow
/LSpace
UCKNOW / /Nashik
NASHIK
for Rough /PUNE/Nagpur
Work/Pune /NAGPUR// Bokaro
BOKARO // Dubai
DUBAI
Page # 11
1/16
ALLEN
5. A Rod of cross section area (A) uniform and 6. Consider the following two cases regarding β decay
length ℓ is carrying a constant current i and (a) The decay of nucleus with emission of electron only
a  voltmeter is connected. Rod is stretched by (b) The decay of nucleus with emission of electron and
applying external force F on either side. Graph another nearly massless and neutral particle
of voltmeter reading v/s  strain in Rod will be Consider below curves for energy spectrum of β
(assume the strain developed is small) emission
Choose the correct option:

(A)
(A) Curve I is for case (a) and curve II is for
case (b)
(B) Curve I is for both cases
(C) Curve II is for both cases
(B) (D) Curve I for is case (b) and curve II is for
case (a)
7. A metallic ring of radius r and resistance R is
held fixed with its axis along a uniform
magnetic field in space whose magnitude  is
varying with time as B0sin(ωt). Neglect gravity,
(C) then
(A) Current in ring oscillates with angular
frequency ω
(B) The net force on ring is non-zero
(C) Force per unit length on ring will be
(D) proportional to B03
(D) Joule heating loss proportional to r2

Enthusiast & Leader Course / Score-I 1001CJA102121101


Page 2/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 2
ALLEN
8. A compound microscope of tube length 200mm, 11. A simple pendulum swings with angular
magnifying power 400 has objective of focal amplitude θo in vertical plane. The tension in
the swing when it is vertically lowest position
length 10mm. The focal length of eye-piece will be
is twice the tension in it’s extreme position then
(under normal adjustment) cos θo is equal to
250
(A) mm (A) 1/3 (B) 1/2 (C) 2/3 (D) 3/4
19
200 12. A tank accelerates upward with acceleration
(B) mm a = 1 m/sec2 contains water. A block of mass 1 kg
19
500 and density 0.8 gm/cm3 is held stationary inside
(C) mm the tank with help of the string as shown in figure.
19
The tension in string is
(D) 150 mm
19
9. In YDSE, light of wave length 500nm and
distance between slit and screen is 1.5m, the
interference pattern on screen disappear when
separation between the slits is 4mm. The
angular resolution of the observer eye is (in
degrees)
(A) T= 2.20N (B) T= 2.75N
o o
(A) 0.0225 (B) 0.225 (C) T = 3N (D) T = 2.4N
π π
0.00225 o 2.25o 13. For the situation shown in figure, water flows
(C) (D) on the surface of a fixed plate. The velocity of
π π
10. Figure shows zener diode (Breakdown of 40v), water a function of distance ‘y’ is given as 
y y 2
connected to 50v DC supply with load u α 2 . Determine the magnitude
h h
resistance RL  = 4kΩ. The output voltage across
of shear stress that the water applies at the base
RL is
of plate. Coefficient of viscosity is η

(A) 25v (B) 50v


3αη 2αη 4αη αη
(C) 40v (D) 10v (A) (B) (C) (D) h
h h h
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 3/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 3
ALLEN
14. In the ideal atwood machine arrangement 17. 3 identical blocks shown in figure. If A and C
shown in figure, the change in kinetic energy are moving together at 12m/sec and B is at rest
(in Joules) of system during 3rd second of their
when A hits B as shown, collision is perfectly
motion starting from rest is
inelastic. The friction coefficient between A
and C is same as that between B and C and is
equal to 0.2. Finally C is on  top of B and all
blocks are moving together with same speed.
What is the length of each block if ground is
perfectly smooth ?

(A) 450J (B) 800J (C) 250J (D) 200J


15. Two steel wires of same length but radii r and  
2r respectively connected together end to end (A) 4m
and tide to a wall as shown in figure. The force
stretches the combination by 10mm. The (B) 5m
displacement of mid point A is: (C) 6m
(D) 8m
18. The angular velocity of a body moving in
(A) 5mm (B) 4mm
circular path is shown in graph below. What is
(C) 8mm (D) 10mm the average angular velocity for the entire
16. Two boys each of mass 50kg are at the ends of motion?
uniform 4m long platform of mass 95 kg
moving 2m/sec on a smooth surface. The boy at
the rear end has a ball of mass 5kg also which
he rolls towards the front end at 4m/sec relative
to himself. How far has the platform moved by
the time the ball is caught by boy at other end ?
(A) 150cm (A) 8 rad/sec
(B) 190cm (B) 9 rad/sec
(C) 200cm (C) 20 rad/sec
(D) 500cm (D) 10 rad/sec
Enthusiast & Leader Course / Score-I 1001CJA102121101
Page 4/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 4
ALLEN
19. A block of mass 2kg is sitting on a vertical SECTION-II : (Maximum Marks: 20)
spring and compressing it by 4cm. Another This section contains 10 questions Candidates have
block of mass 1 kg in dropped on it from a to attempt any 5 questions out of 10. If more than 5
height of 45cm. The block stick together after questions are attempted, then only first 5 attempted
questions will be evaluated.
collision. What is the maximum compression of The answer to each question is a Numerical Value
the spring? Type questions.
For each question, enter the correct integer value (in
decimal notation, the answer should be rounded off
to the nearest Integer).
Answer to each question will be evaluated according
to the following marking scheme:
Full Marks          :   +4 If correct answer is selected.
Zero Marks        :   0 If none of the option is selected.
Negative Marks  :   –1 If wrong option is selected.
1. Air of density ρ is blown on a soap film of surface
tensiom T by a pipe of radius r with it's opening
right next to film. The film is deformed and a
(A) 10cm (B) 12cm bubble detaches from the film when shape of
(C) 14cm (D) 20cm deformed surface is hemisphere. Given that the
dynamic pressure on the film due to air blown at
20. Two beads of mass m and 2 m are connected
speed v as 2ρv2, the speed at which the bubble is
by massless rod of length R and threaded on to
XT
a smooth circular wire of radius R. When the formed is  , calculate value of x.
ρr
wire rotates uniformly about a vertical
diameter, the beads do not slide on it and rod 2. An electric field E 2x i y3 j  N/C is passing
remains vertical as shown. What must be the through Box shown in figure
angular velocity ω  of the wire,  if radius a Cube of side : 2 meter
5 ϕ1  : flux through surface ABCD and
circular wire R m ?
3
ϕ2  : flux through surface BCFG
Calculate the value of   ϕ2 ϕ1  (in Nm2C–1) 

(A) 5 rad/sec (B) 6 rad/sec


(C) 4 rad/sec (D) 10 rad/sec
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 5/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 5
ALLEN
3. A solenoid of 500 turns/meter is carrying a 8. All the surface are frictionless then acceleration
current of 5A. It's core is made up of iron with of the block B is 2g/n. Find n.
relative permeability of 10000. The magnetic field
inside core is Xπ (in T). Calculate value of X.
4. A satellite observed the Balmer alpha
emission line of H-like ion (atomic no. 36)
from distant galaxy. Take value of Rydberg’s
constant R = 1.1 × 107 , calculate wavelength
of line up to nearest integer (in Å)
9. Figure shows the VT diagram for helium gas in
5. A time varying voltage V = 3t2 is applied across cyclic process. Find the ratio of maximum and
an ideal inductor of L = 2H. The potential energy minimum pressure.
at time t = 1 sec in magnetic field is increasing at
rate of X J/s. Calculate value of 2X.
(Initial current in inductor is zero)
6. A flexible drive belt runs over a frictionless
flywheel (see fig.). The mass per unit length of
the drive belt is 1kg/m, and the tension in the
drive belt is 10N. The speed of the drive belt is
2m/s. The whole system is located on a
horizontal plane. Find the normal force (in N)
10. A block of mass m is connected with ideal
exerted by the belt on the flywheel.
pulley and a massless spring of spring constant
K as shown in figure. A block is slightly
displacement from its equilibrium position. If
m
the time period of oscillation is μπ , then
K
find the value of µ.
7. Between two isotherm we have a cycle as shown.
Find the work done by the gas during the cycle (in J)
[Take  T1 = 127oC, T2 = 16oC, n = 1 mole]

 
Enthusiast & Leader Course / Score-I 1001CJA102121101
Page 6/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 6
ALLEN
ALLEN
SECTION-I : (Maximum Marks: 80) 5. Which of the following statement about hydrogen
This section contains :20(Maximum
SECTION-I questions.Marks:
Each question
80) has are correct
5. Which of the following statement about hydrogen
4 options for correct answer. Multiple-Choice (a) Hydrogen has three isotopes of which tritium is
This section(MCQs)
Questions containsOnly 20 questions.
one option Each is question has
correct. For are correct
     radioactive in nature
4 options
each question,formarks correct
will beanswer.
awarded as Multiple-Choice
follows: (a) Hydrogen has three isotopes of which tritium is
Questions (b) Hydrogen never acts as a cation in ionic salt
Full Marks           :   +4 If correct answer iscorrect.
(MCQs) Only one option is selected.For      radioactive in nature
(c) Hydrogen ion, H+, does not exist free in solution
each question, marks will be awarded as follows:
Zero Marks         :    0 If none of the option is selected. (b) Hydrogen never acts as a cation in ionic salt
Full Marks           : : –1
 +4IfIfwrong
correctoption
answer is selected. (d) Hydrogen does not act as an oxidising agent
Negative Marks  is selected. (c) Hydrogen ion, H+, does not exist free in solution
Zero Marks         : rd  0 If none of2+the option is selected. (A) (a) and (d)
(d) Hydrogen does not act as an oxidising agent
1. Radius
Negative Marks of : 3 –1orbit of Li option
If wrong ion isisxselected.
cm then de
Broglie wavelength of electrons in the first (B)
(A) (c)(a) and (d)
1. Radius of 3rd orbit of Li2+ ion is x cm then de
orbit is (in cm) (C)
(B) (a), (b) and
(c) and (d) (c)
Broglie wavelength of electrons in the first
orbit6isπx(in cm) 2πx 2πx 8πx
(A) (B) (C) (D) (D)
(C) (b), (c) and (d)
(a), (b) (c)
9 3 3
2πx 2πx 8πx 6. The (b),
pollutants
2. (A)
An 6aqueous
πx (B)solution (C)
of 6.33 g (D)
oxalic 3acid (D) (c) andwhich
(d) come directly in the air
9 from sources are called primary pollutants.
dihydrate is made up to 250 mL. The volume of 6. The pollutants which come directly in the air
2. An Naqueous
0.1 solution toofcompletely
NaOH required 6.3 g oxalic acid
neutralize Primary pollutants are sometimes converted
dihydrate is made up tois 250 mL. The volume of from sources are called primary pollutants.
10 ml of this solution into secondary pollutants. Which of the
0.1 N NaOH required to completely neutralize Primary pollutants are sometimes converted
following belongs to secondary air pollutants?
(A)
10 ml40ofmL
this solution is (B) 20 mL into secondary pollutants. Which of the
(A) CO belongs to secondary air pollutants?
following
(C)
(A) 10
40 mL (D)
(B) 420mLmL
3. What10will (B)
(A) Hydrocarbon
CO
(C) mLbe the heat of(D) formation
4 mL of methane,
if the heat of combustion of carbon is ‘–x’ kJ, (C)
(B) Peroxyacetyl
Hydrocarbon nitrate
3. What will be the heat of formation of methane,
heat of formation if water is ‘–y’ kJ and heat of (D)
if the heat of combustion of carbon is ‘–x’ kJ, (C) NO
Peroxyacetyl nitrate
combustion of methane is ‘–z’ kJ
heat of formation if water is ‘–y’ kJ and heat of 7. Which
(D) NOof the statements about solutions of
(A) (– x – yof+ z)
combustion methane is ‘–z’ kJ electrolytes is not correct?
7. Which of the statements about solutions of
(B) (–– xz –– xy + 2y)
(A) z) kJ (A) Conductivity
electrolytes is not of solution depends upon size
correct?
(B) (–– xz –– x2y+–2y)
(C) z) kJ of ions.
(A) Conductivity of solution depends upon size
(D) ((–– xx –– 2y
(C) 2y –+ z)
z) kJ (B) Conductivity
of ions. depends upon viscosity of
The solution.
4. (D) pH
(– xof– 0.1
2y +molar
z) solution of the acid HQ is 3. (B) Conductivity depends upon viscosity of
The value of the ionisation constant Ka of the (C) Conductivity
solution. does not depend upon solvation
4. The
acid pH
is of 0.1 molar solution of the acid HQ is 3. of ions present in solution.
The value of the ionisation constant Ka of the (C) Conductivity does not depend upon solvation
acid 3is × 10–1
(A) (B) 1 × 10–3 (D) of
Conductivity of solution.
ions present in solution increases with
temperature.
(A) 13 × 10––51
(C) (B) 1 × 10––73
(D) (D) Conductivity of solution increases with
Enthusiast & Leader Course / Score-I
(C) 1 × 10 –5
(D) 1 × 10–7 temperature. 1001CJA102121101
English / 10042022 Space for Rough Work Page 7/16
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 7/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 7
ALLEN
8. Which of the following process is not 12. Given compounds are related as
responsible for the presence of electric charge
on the sol particles? (I)   (II)   
(A) Electron capture by sol particles
(B) Adsorption of ionic species from solution (A) Identical (B) Diastereomer
(C) Formation of Helmholtz electrical double (C) Enantiomer (D) Constitutional isomer
layer 13. Which of the following reactions results in the
(D) Absorption of ionic species from solution formation of a pair of diastereomers ?
 
9. Among following which are amphoteric oxide? (A)
HBr
  →
Mn2O7, CrO3, Cr2O3, CrO, V2O5, V2O4
(A) V2O5, Cr2O3 HBr
(B)          →
(B) Mn2O7, CrO3
(C) CrO, V2O5
HBr
(D) V2O5, V2O4 (C)    →
ROOR UV
10. Which of the following reactions does not
1.BH 3 THF
occur in Bessemer converter in the extraction (D)      →
2 H 2 O2 OH H 2 O
of copper from chalcopyrites?
14. In which of the following reaction saytzeff
(A) 2CuF eS 2 O 2 → C u 2S 2F eS SO 2
alkene is major product ?
(B) FeO + SiO2 → FeSiO3
HO
(C) 2F eS 3O 2 → F eO 2SO 2 (A)      →
Δ
(D) Cu2S + 2Cu2O → 6Cu + SO2 
(B) EtO
11. Which of the following orders is true regarding    →
Δ
the acidic nature of phenol ?
t BuOK
(A) phenol > o-cresol < o-nitrophenol (C)      →
Δ
(B) o-nitrophenol < o-cresol < phenol
(C) phenol > o-cresol > o-nitrophenol CH 3 OK
(D)    →
(D) phenol < o-cresol < o-nitrophenol Δ

Enthusiast & Leader Course / Score-I 1001CJA102121101


Page 8/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 8
ALLEN
15. In the given reaction 18. If structure of D-Glucose is
  A
+ B (A and B are cross Cannizaro product) A
and B are
(A) HCOO– + Me   CH2OH

(B) CH3OH + Me   coo


(C) HCOO– + Me   coo
then the structure of L-Glucose is
(D) CH3OH + Me   CH2OH  

Br 2
16.   →   A; A can be
CCl4 (A) (B)

(A) (B)

(C) (D)

(C) (D)
19. SbF5 reacts with XeF4  and XeF6 to form ionic
17. identify B, X and R respectively in the following compounds XeF 3 SbF 6   and  XeF 5 SbF 6
sequence of reactions   then molecular shape of  XeF 3   ion and 
ClCN H3O
C2H5MgBr  → A  →    XeF 5  ion respectively :
Ag
CH3COCH3        → Y (A) Square pyramidal, T-shaped
CuCN 4H
C6H5NH2   P  →  Q  →   (B) Bent-T-shape, distorted octahedral
(A) C2H5COOH, CHI3, C6H5CH2NH2 (C) See-saw, Square pyramidal
(B) C2H5COOH, CH3I, C6H5COOH (D) Square pyramidal, See-saw
(C) C2H5CH2NH2, CH3I, C6H5COOH
(D) C2H5COOH, C2H5I, C6H5CONH2
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 9/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 9
ALLEN
20. Consider the following conversions 2. 99% of a first order reaction was completed in
(i)   O(g) + e– →  O g ,  ΔH 1 32 minutes, and then 99.9% of the reaction will
(ii)  F g e → F g ΔH 2 be completed in how many minutes?
(iii) C l g e → C l g ΔH 3 3. A sample of water has a hardness expressed as
(iv) O g e → O 2g ΔH 4 200 ppm of Ca2+. This sample is passed through
That according to given information the incorrect an ion exchange column and the Ca2+ is
statement is : replaced by H+. What is the pOH of the water
after it has been so treated ? [Atomic mass of
(A) ΔH 3  is more negative than ΔH 1  and ΔH 2
Ca = 40]
(B) ΔH 1   is less negative than ΔH 2 4. (No. of P–O–P bonds in P4O6) + (No. of B–O–B
(C) ΔH 1 , ΔH 2  and ΔH 3  are negative whereas  bonds in borax) – (No. of S–O–S bonds in γ
ΔH 4  is positve form of SO3) = _______
(D) ΔH 1  and  ΔH 3  are negative whereas  ΔH 2 5. How many grams of sucrose (molecular
 and ΔH 4  are positive weight = 342 g mol–1) should be dissolved in
1000 g of water in order to produce a solution
SECTION-II : (Maximum Marks: 20) with a 104.76οC difference between the
This section contains 10 questions Candidates have freezing point and the boiling point
to attempt any 5 questions out of 10. If more than 5 temperature ?
questions are attempted, then only first 5 attempted
questions will be evaluated. (Kf = 1.86 K-kg mol–1, Kb = 0.52 K-kg mol–1)
The answer to each question is a Numerical Value 6. Consider the following compounds
Type questions. (i) IF5      (ii) ICl 4         (iii) XeO 2 F 2    (iv) NH 2      
For each question, enter the correct integer value (in (v) BCl3  (vi) BeCl2    (vii) AsCl 4      (viii) BH 4    
decimal notation, the answer should be rounded off
to the nearest Integer). (ix) NO 2  (x) ClO 2
Answer to each question will be evaluated according Then calculate value of "x + y – z" here, x, y and z
to the following marking scheme: are total number of compounds in given compounds
Full Marks          :   +4 If correct answer is selected. in which central atom used their all three p-orbitals,
Zero Marks        :   0 If none of the option is selected.
Negative Marks  :   –1 If wrong option is selected. only two p-orbitals and only one p-orbital in
hybridisation respectively.
1. Considering the following examples number of
7. How many of the following are addition copolymer ?
complexes which are paramagnetic is
(i) Natural rubber     (ii) Neoprene     (iii) Buna-N   
[Cr(NH3)6]2+, [Co(H2O)6]3+, [Cu(NH3)4]2+, [PtCl4]2–, (iv) Gutta Percha    (v) Nylon-6, 6     (vi) Teflon
[AuCl4]–, [Ni(CN)6]4–, [V(CO)6]2–, [Ag(CN)2]–, (vii) PAN                (viii) Bakelite       (ix) Dacron    
[Fe(CO)5], [NiCl4]2– (x) Bunna-S

Enthusiast & Leader Course / Score-I 1001CJA102121101


Page 10/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 10
ALLEN
8. Find the total number of reactions in which 9. How many of following will react with ammonia
benzaldehyde is obtained as a product. at rate faster than p-chloro nitro benzene ?

i CrO2 Cl2
(i)    →                           
ii H 2 O
(a)       (b)       (c)  
i CrO3 CH 3 CO 2O
(ii)    →   
ii H 2 O

H2 Pd
(iii)      →            
BaSO4 (d)       (e) 

i DIBAL H 70 C
(iv)    →
ii H 2 O

Cu 300 C
(v)     →            
(f)     (g)    

i B 2 H 6 THF
   (vi)   →
ii H 2 O

i LiAlH 4 (h) 
(vii)      →                     
ii H 2 O

i DIBAL H 70 C
 (viii)     →
ii H 2 O

H3O
(ix)     →              

Θ
OH
     (x)     
H 2O

Enthusiast & Leader Course / Score-I 1001CJA102121101


English / 10042022 Space for Rough Work Page 11/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 11
ALLEN
10. Number of compounds which can give iodoform
test are :

(a)    (b)   

(c)   (d)   

(e)    (f) 

(g)     (h)   

(i)      

(j) 

Enthusiast & Leader Course / Score-I 1001CJA102121101


Page 12/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 12
ALLEN
ALLEN
SECTION-I : (Maximum Marks: 80) 5. If  a ,  b are two vectors such that |a     b| =  –3
This section contains :20(Maximum
questions.Marks:
Each question has then
SECTION-I
4 options for correct answer. Multiple-Choice
80) 5. If  a , [ba are
  b a  two  bvectors
] is such that |a     b| =  –3
This section(MCQs)
Questions containsOnly 20 questions.
one optionEach
is question has
correct. For (A) 1[a   b a  (B)  b]3is (C) 9
then (D) 2
4eachoptions for correct answer. Multiple-Choice
question, marks will be awarded as follows:
Questions 6. Minimum
(A) 1 length(B) 3of tangent
(C)drawn
9 from (D)a 2point Q
Full Marks (MCQs) Only
         :   +4 one option
If correct answerisiscorrect.
selected.For 2 2
on 3x + 4y = 20 to the circle x + y = 1 is
each
Zero question,
Marks     marks willnone
   :    0 If be awarded as follows:
of the option is selected. 6. Minimum length of tangent drawn from a point Q
Full Marks           :   +4 If correct answer
Negative Marks  :  –1 If wrong option is selected. is selected. (A)3x15+ 4y =(B)
on 15 circle
20 to the (C) x02 + y2 = (D)
1 is 3
Zero Marks         :    0 If none of the option is selected.
1. TheMarks 
Negative value of  :  –1 If wrong option is selected. 7. One
(A) side
15 of square
(B) PQRS 15 (C)is on0the line(D)
y = 32x – 17
3π π 5π 3π and other 2 vertices are on parabola y = x2, then
1. The1 value
tan of tan 1 tan tan   +  7. One side of square PQRS is on the line y = 2x – 17
8 8 8 8 minimum area of square is:
37ππ π5π 5π 9π 3π 7π and other 2 vertices are on parabola y = x2, then
11 tantan tan 1 1tan tan tan   +  –
88 tan 88 8 8 tan
8 8 (A) 80 area
minimum (B)of 4square (C) 1280 (D) 16 –5
5 is:
7π 5π 9π 7π
is 1equaltanto tan 1 tan tan 8. If the80variable
(A) (B)line –
4 y5 = kx
(C)+ 1280 (D) 16to –5an
2h is tangent
8 8 8 8
(A)equal
is 0 to (B) 1 (C) 2 (D) irrational ellipse 2x2 + 3y2 = 6, then locus of P(h, k) is a
8. If the variable line y = kx + 2h is tangent to an
conic C whose eccentricity equals
2. The distance
(A) 0 between
(B) 1 the(C)line 
2 (D) irrational ellipse 2x2 + 3y2 = 6, then locus of P(h, k) is a

r 2 i 2 j 3k λ i j 4k  and the conic C–5whose
(A) 7
(B)eccentricity

7 (D)
(C) equals
7
2. The distance between the line  2– 3– 2– 3
plane 
r 2 ri i2 j 5 j3k k λ i 5 isj 4k  and the 5 7 7
9. (A)
Let x 2and (B)
y be real (C) 7
numbers (D)
satisfying
3 2 3the
plane 10r i (B)5 j 10k (C)
(A) 5 is 3
(D)
10 2
equation 4y + 4xy + x + 6 = 0. The complete
9 – 10 3 9. Let x and y be real numbers satisfying the
3 3 set of values2 for x, is
10 10 3 10 equation 4y + 4xy + x + 6 = 0. The complete
3. (A)
If θ ∈ 9 R and(B) – (C) 10
the equation  (D)
3 3 3 : – 2 ≤forx ≤x,3}
(A)of{xvalues
set is
3. sinx
If θ ∈+ Rcosand(θ the
+ x)equation 
+ cos(θ – x) = 2 has
(B) {xx : –x2 ≤ x 2≤ 3}
(A) or x 3
a solution then which of the following is true 
sinx + cos (θ + x) + cos(θ – x) = 2 has
(A) sin2 θ > 3/4which of(B) cos2 θ 1/4 (B) {xx : –x2 ≤ x 2≤ 2}
(C) or x 3
a solution then the following is true 
(C) sin2 θ > 3/4 (D) (C) {xx : –x2 ≤ x ≤22}or x
(D) 3
(A)  1/4 (B) cos2 θ  3/4
1/4
10. The solution
(D) x x set of or x 3 (cot–1x) (tan–1x) +
2 inequality
(C) sinθ2 θ    co 1/4
t 1 x dx
(D) cos2 θ  3/4 π –1 –1 π
10.  cotset
2 solution
The x of
– 3tan x – 3 (cot
inequality  >–01x)is+
2 –1x) (tan
1 2 2 2
4.   θθ  cot 1 x dx   (where [.] denotes the π π
θ→∞  cot2,–1xtan
2 x ∈ (tan
(A) 3) –1x – 3  2
– 3tan  > 0 is
1 2 2
  1 θ2   1 x dx   (where [.] denotes the
1 2
4.
θ→∞
1 (A) x ∈∈ (cot
(B) (tan 3,
2, cot
tan 2)
3)
  1 function)
greatest integer x dx is   
1 2 (C) (– ∞ 3,, tan
(B) x ∈∈ (cot cot2)2)∪ (tan 3, ∞)
(A) 0 integer
greatest (B) function)
1 (C)is  cot
  1 (D) tan 1
(C) x ∈∈ (–– ∞
(D) ∞ , cot
tan 3)
2) ∪∪ (cot
(tan 2, ∞)
3, ∞
(A) 0 (B) 1
Enthusiast & Leader Course / Score-I (C) cot 1 (D) tan 1
English / 10042022 Space for Rough Work
(D) x ∈ (– ∞ , cot 3) ∪ (cot 2, ∞1001CJA102121101
) Page 13/16
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 13/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 13
ALLEN
49
n 16. Let R be a relation defined in the set of real
11. The sum ∑  (– 1)k   99  where  n
r  = 
k 0
2k r n r numbers by a R b ⇔ 1 + ab > 0. Then R is :
 equals  (A) Equivalence relation
  (B) Transitive
98
(A) – 2 (B) 2 98 49 49
(C) – 2 (D) 2 (C) Symmetric 
12. Consider the polynomial equation
(D) Anti-symmetric
x4 – 2x3 + 3x2 – 4x + 1 = 0. Which one of the
following statements describes correctly the 17. In an experiment with 15 observations on x, the
solution set of this equation ?  following results were available 
Σx2 = 2830, Σx = 170
(A) four non real complex zeroes. One observation that was 20, we found to be
(B) four positive zeroes wrong and was replaced by the correct value
(C) two positive and two negative zeroes 30. Then, the corrected variance is :
(D) two real and two non real complex zeroes. (A) 78.00
∞ a b
(B) 188.66
13. 1
If the sum ∑    =   
k 1
k 2 k k k 2 c (C) 177.33
where a, b, c ∈  N and lie in [1, 15] then a + b + c (D) 8.33
equals 
18. If p and q are two statements, then 
(A) 6 (B) 8 (C) 10 (D) 11  (p ^ q) v   (q ⇔ p) is
14. The polynomial function f (x) satisfies the (A) tautology
equation f (x) – f (x – 2) = (2x – 1)2 for all x. If
p and q are the coefficient of x2 and x (B) contradiction
respectively in f (x), then p + q is equal to (C) neither tautology nor contradiction
(A) 0 (B) 5/6 (D) either tautology or contradiction
(C) 4/3 (D) 1 19. If f be a continuous function on [0, 1],
15. A real number x is chosen at random such that differentiable in (0, 1) such that f (1) = 0, then
0 < x < 100. The probability that  their exists some c ∈  (0, 1) such that 
1 a (A) c f′ (c) – f (c) = 0
x x is  where a and b are relatively
3 b
primes and [x] denotes the greatest integer then (B) f′ (c) + c f (c) = 0
(b - a) equals (C) f′ (c) – f (c) = 0
(A) 0 (B) 1 (C) 2 (D) 4 (D) c f′ (c) + f (c) = 0
Enthusiast & Leader Course / Score-I 1001CJA102121101
Page 14/16 Space for Rough Work English / 10042022

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 14
ALLEN
20. If |z|   4, then the maximum value of |iz + 3 – 4i| 4. Tangents drawn from the point P(2, 3) to the circle
is equal to x2 + y2 – 8x + 6y + 1 = 0 touch the circle at the points
(A) 2 A and B. The circumcircle of the ΔPAB  cuts the
(B) 4 x 5 2
y 3 2
director circle of ellipse   = 1
(C) 3 9 b2
orthogonally. Find the value of  b2.
(D) 9
x2 y2
SECTION-II : (Maximum Marks: 20) 5. The value of a for the ellipse  = 1
a2 b2
This section contains 10 questions Candidates have (a > b), if the extremities of the latus-rectum
to attempt any 5 questions out of 10. If more than 5
of the ellipse having positive ordinate lies
questions are attempted, then only first 5 attempted
questions will be evaluated. on the parabola  x2 =  – 2 (y – 2), is    
The answer to each question is a Numerical Value 6. If the point P (a, b) lies on the curve 9y2 = x3
Type questions. such that the normal to the curve at P makes
For each question, enter the correct integer value (in
equal intercepts with the axes. Find the value of
decimal notation, the answer should be rounded off
to the nearest Integer). (a + 3b). 
Answer to each question will be evaluated according 7. Let S be the set of all x such that x4 – 10x2 + 9   0.
to the following marking scheme:
Find the maximum value of f (x) = x3 – 3x on S
Full Marks          :   +4 If correct answer is selected.
Zero Marks        :   0 If none of the option is selected. 8. The lengths of the sides  of a triangle are
Negative Marks  :   –1 If wrong option is selected. log10 12, log10 75 and log10 n, where n ∈  N. Find
1. If y2 = 3cos2x + 2sin2x, then the value of  the number of possible values of n.
d 2y
y4 y3 9. Let P(x) be a polynomial of degree 5 having
dx 2
2. Let the function  f 4 4 → 1 1  be defined P x
extremum at x = – 1, 1 and     2  = 4.
x→0 x3
implicitly by the equation x + 5y – y5 = 0. If M and m are the maximum and minimum value of
Find the area of triangle formed by tangent and
normal to f(x) at x = 0 and the line y = 5. the function y = P' (x) on the set
m
A = {x |x2 + 6  5x} then find  .
3. If the angle between the plane x – 3y + 2z = 1 M
x 1 y 1 z 1 10. Find the number of 4 digit numbers starting
and the line  is θ,
2 1 3
with 1 and having exactly two identical digits.
then the value of cosec θ is 
Enthusiast & Leader Course / Score-I 1001CJA102121101
English / 10042022 Space for Rough Work Page 15/16

Centers : Mumbai /Delhi /Akola /Lucknow / Nashik /Pune /Nagpur / Bokaro / Dubai # 15

You might also like