Single Correct Answer Type: Part (A) : Physics

AITS – 22 (Main) Physics
PART (A) : PHYSICS
SINGLE CORRECT ANSWER TYPE

This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and
(D) for its answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Three point like equal masses m1 , m 2 and m3 are connected to the ends of a massless rod of length
L which lies at rest on a smooth horizontal plane (shown figure). At t  0 , an explosion occurs
between m 2 and m3 , and as a result, mass m3 is detached from the rod, and moves with a known
velocity v at an angle of 30o with the y–axis. Assume that the masses m 2 and m3 are unchanged
during the explosion.
What is the velocity of the centre of mass of the system consisting of three masses, after the
expulsion?
v   v 
(A) i  3j (B)  i  3 j
 (C) –v (D) None of these
4 4
1. (D)
As no external force acts, so centre of mass remains at rest.
2. In the pulley system shown, if radii of the bigger and smaller pulley are 2m and 1m, respectively,
and the acceleration of block A is 5ms 2 in the downward direction, the acceleration of block B will
be
5 2
(A) 0 ms 2 (B) 5ms 2 (C) 10 ms 2 (D) ms
2
2. (D)
CENTERS : MUMBAI /DELHI /AKOLA /LUCKNOW /NASHIK /PUNE /NAGPUR /BOKARO /DUBAI # 1
5
Given  A  2  5m s 2    m s2
2
5
Hence, acceleration of B, a B  1    m s 2
2
3. A U–shaped tube contains a liquid of density  and it is rotated about the left dotted line as shown in
the figure. Find the difference in the levels of the liquid column.
2 L2 2 L2 22 L2 2 22 L2
(A) (B) (C) (D)
2 2g 2g g g
3. (B)
dF  dmx2
And  dp  A   Adx  x2
p2 L
2
 dp    dx
p1 0
2 L2
Or, P2  P1 
2
2 L2
 gH 
2
2 2
L
H
2g
4. Two rings having masses M and 2M, respectively, having the same radius are placed coaxially as
shown in the figure.
If the mass distribution on both the rings is non–uniform, then the gravitational potential at point P is
GM  1 2 
(A)    
R  2 5
GM  2 
(B)  1
R  2 
(C) Zero
(D) Cannot be determined from the given information
4. (A)
As all the points on the periphery of either ring are at the same distance from point P, the potential at
point P due to the whole ring can be calculated as V    GM  /  R 2  x2  where x is the axial
distance from the centre of the ring. This expression is independent of the fact whether the
distribution of mass is uniform or non–uniform.
GM G  2M GM  1 2 
So, at P, V       
2R 5R R  2 5
5. Read the given statements and decide which is/are correct on the basis of kinetic theory of gases
(I) Energy of one molecule at absolute temperature is zero.
(II) The rms speeds of different gases are same at same temperature.
(III) For one gram of all ideal gases kinetic energy is same at same temperature.
(IV) For one mole of all ideal gases’ mean kinetic energy is same at same temperature.
(A) All are correct (B) I and IV are correct
(C) IV is correct (D) None of these
5. (C)
If the gas is not ideal then its molecule will possess potential energy. Hence statement (I) is wrong.
 1 
Rms speed of different gases at same temperature depends on its molecular weight  v rms  .
 M
Hence statement (II) is also wrong.
 1 
Kinetic energy of one gram gas depends on the molecular weight  E gm   . Hence statement (III)
 M
is also wrong.
 3 
But K.E. of one mole of ideal gas does not depend on the molecular weight  E  RT  . Hence (IV)
 2 
is correct.
6. The given figure shows an isochore, an isotherm, an adiabatic and two isobars of two gases on a
work done versus heat supplied curve. The initial states of both gases are the same and the scales for
the two axes are same.
Which of the following statements is incorrect?

(A) Straight line 1 corresponds to an isochoric process.
(B) Straight line 2 corresponds to an isobaric process for diatomic gas.
(C) Straight line 4 corresponds to an isothermal process.
(D) Straight line 5 corresponds to an isothermal process.
6. (D)
From the first law of thermodynamics
Q  W  U
For an isobaric process
f 2
W  RT, Q  CP T    RT
 2 
W 2

Q f 2
Where f is the number of degrees of freedom.
For an isochoric process,
W
W  0, 0
Q
The straight line 1 corresponds to an isochoric process. For monatomic gas f  3 and for diatomic
gas f  5 .
W 2
 (for monatomic gas)
Q 5
2
 (for diatomic gas)
7
Straight line 2 corresponds to isobaric process for diatomic gas and straight line 3 corresponds to
isobaric process for monatomic gas.
For isotherm W = Q, tan 4  1 straight line 4 corresponds to isothermal process because W = Q only
if T  0 i.e., U  0 .
For an adiabatic process Q = 0, the straight line 5 corresponds to it.
7. A metre stick swinging in vertical plane about a fixed horizontal axis passing through its one end
undergoes small oscillation of frequency f 0 . If the bottom half of the stick were cut off, then its new
frequency of small oscillation would become
(A) f 0 (B) 2 f0 (C) 2f0 (D) 2 2 f 0

7. (B)
1 mg
f0 
2 I
Where  is the distance between point of suspension and centre of mass of the body. Thus, for the
stick of length L and mass m,
L
mg
1 4 1 12g
f 0'  2
  2 f0
2 m  L / 2 2 L
2 12
8. A sonometer wire, 100 cm in length has fundamental frequency of 330 Hz. The velocity of
propagation of transverse waves along the wire is
(A) 330 m/s (B) 660 m/s (C) 115 m/s (D) 990 m/s
8. (B)
For fundamental mode
  2   100 cm or   200 cm
As n  330 Hz , hence
200
V  n  330   600 m s
100
9. Find the electric field vector at P (a, a, a) due to three infinitely long lines of charges along the x–, y–
and z–axes, respectively. The charge density, i.e., charge per unit length of each wire is  .
       
(A)
30 a
i  j k  (B)
20 a

i  j k 
 i  j  k 2   
(C)
2 2  0a
  (D) 
 0 a
i  j k 
9. (B)
Let us consider the electric field due to wire (3) only.

E3  Eu


2 0  a 2  a 2 12
i cos 45 o
 jcos 45o 

 1  

2 2 0a 2
i j  
  

4 0a
 
i j
Similarly, electric field due to wires (1) and (2)

       
E1 
4 0a

j  k and E 2  4 0a
ik  
       
E net  E1  E 2  E3 
20a
i  j k  
10. One plate of a capacitor is fixed, and the other is connected to a spring as shown figure. Area of both
the plates is A. In steady state (equilibrium), separation between the plates is 0.8d (spring was
unstretched, and the distance between the plates was d when the capacitor was uncharged). The force
constant of the spring is approximately
125  0AE 2 20 AE 2 6 0E 2 0 AE3

(A) (B) (C) (D)
32 d3 d3 Ad 2 2d 3
10. (A)
F  Kx
Q2
 K  0.2d 
2A0
2
 0 A 
 0.8d E 
Or    0.2 Kd
2A 0
Or K  3.9  0 AE 2 / d 3
Or K  40 AE 2 / d 3
11. What resistor should be connected in parallel with the 20  resistor in branch ADC in the circuit
shown in figure. so that potential difference between B and D may be zero?
(A) 20  (B) 10 (C) 5 (D) 5

11. (A)
 20R  /  20  R  
20
or R  20 
5 10
12. Two wires AO and OC carry equal currents i as shown in figure. One end of both the wires extends
to infinity. Angle AOC is  .
The magnitude of magnetic field at point P on the bisector of these two wires at a distance r from
point O is
 
 1  cos 
0 i  0 i   i 2 0 i   
(A) cot   (B) cot   (C) 0  (D)  
2 r 2 4 r 2 2 r  4 r  2 
sin  
2
12. (C)

x  r sin
2
   i     
 BP  2  0    sin  90o    sin 90o 
 4   x    2 
 
 1  cos 
0 i  2
2 r sin 
2
13. Loop A of radius r << R moves toward loop B with a constant velocity V in such a way that their
planes are always parallel. What is the distance between the two loops (x) when the induced emf in
loop A is maximum?
R R  1 
(A) R (B) (C) (D) R  1  
2 2  2
13. (C)
0iR 2
A  r 2
2 32
2  R  x 2

d
 EA  
dt
 0i 2 2 5 2
 R r  3 2   R 2  x 2  2x
2
dE A
E A is maximum when 0
dx
d x
 0
dx  R  x 2 5 2
2
5x 2 52 32
Or R 2
 x2 
2
 R  x 2  2x  0

2 2 2
Or, R  x  5x  0
R
Or, x 
2
14. If a direct current of value a ampere is superimposed on an alternative current I = b sin t flowing
through a wire, what is the effective value of the resulting current in the circuit?
12 12 12
 1  2 12  a2   1 
(A)  a 2  b 2  2
(B)  a  b  (C)   b 2  (D)  a 2  b 2 
 2  2   2 
14. (D)
As current at any instant in the circuit will be
I  Idc  Iac  a  bsin t
12
 T I 2 dt  12
So, Ieff

 0T 
1 T 2 
    a  bsin t  dt 
 dt  T 0

 0 
12
1 T 
i.e., Ieff     a 2  2absin t  b 2 sin 2 t  dt 
T 0 
1 T 1 T 1
but as  sin t dt  0 and  sin 2 t dt 
T 0 T 0 2
12
 1 
So, Ieff  a 2  b 2 
 2 
15. A cube of side 2 m is placed in front of a concave mirror of focal length 1 m with its face A at a
distance of 3 m and face B at a distance of 5 m from the mirror. The distance between the images of
faces A and B and heights of images of A and B are, respectively,
(A) 1 m, 0.5 m, 0.25 m (B) 0.5 m, 1 m, 0.25 m
(C) 0.5 m, 0.25 m, 1 m (D) 0.25 m, 1 m, 0.5 m
15. (D)
For A:
u  3m, v1  ?, f  1m
1 1 1 1 1 1 2
     1  
u1 f u 1 3 3 3
3
Or v1  
2
For B:
1 1 1
 
v2 1 5
1 1 4 5
Or  1   or v2   m
v2 5 5 4
3  5
Now, v1  v 2   
2  4
3 5 1
     m  0.25m
2 4 4
 v
Again, 1   1
O u
v  3  1 
Or 1   1 O       1m
u  2  3 
 v
Again, 2   2
O u
 5  1 
Or  2       2  0.5 m
 4  5 
16. In YDSE, D = 1 m, d = 1 mm, and   5000 nm . The distance of 100th maxima from the central
maxima is
1 3 1
(A) m (B) m (C) m (D) Does not exist
2 2 3
16. (C)
For 100th maximum,
d sin   100
100  500  109 5 104 1
 sin   3
 3
 0.5 
110 10 2
1
 y  D tan   1 tan 30 
3
17. In a series of photoelectric emission experiments on a certain metal surface, possible relationships
between the following quantities were investigated: threshold frequency f 0 frequency of incident
light f, light intensity P, photocurrent I, maximum kinetic energy of photoelectrons Tmax . Two of
these quantities, when plotted as a graph of v against x give a straight line through the origin.
Which of the following correctly identifies x and y with the photoelectric quantities?
x y
(A) I f0
(B) f f0
(C) P I
(D) P Tmax
17. (C)
The rate of emission of photoelectrons (i.e., photocurrent) depends linearly on the rate of incident
photons.
18. In figure E1 to E 6 represent some of the energy levels of an electron in the hydrogen atom.
Which one of the following transitions produces a photon of wavelength in the ultraviolet region of
the electromagnetic spectrum?
(A) E 2  E1 (B) E3  E 2 (C) E 4  E 3 (D) E 6  E 4
18. (A)
The wavelength of the hydrogen spectrum could be arranged in a formula or series named after its
discoverer. For ultraviolet spectrum the series is called Lyman series, for visible spectrum the
Blamer series, and for infrared region we have the Paschen series.
The ultraviolet series is obtained when the energy of the atom falls from higher states to the energy
level corresponding to n  1 . Thus, ultraviolet radiation can only be possible with transition from E 2
to E1 out of the given transitions.
19. Two particles A and B are placed as shown in figure. The particle A, on the top of tower, is projected
horizontally with a velocity u and particle B is projected along the surface towards the tower,
simultaneously. If both particles meet each other, then the speed of projection of particle B is [ignore
any friction]
g g g
(A) d u (B) d (C) d u (D) u
2H 2H 2H
19. (A)
Time taken by particles to collide
2H
t
g
2H 2H
Then, u V d
g g
g g
 uVd or vd u
2H 2H
20. In the arrangement shown in figure. there is no friction between the block of mass 2m and ground,
but there is friction between the blocks of masses m and 2m. The block of mass m is stationary with
respect to block of mass 2m. The value of coefficient of friction between m and 2m is
1 1 1 1
(A) (B) (C) (D)
2 2 4 3
20. (C)
f  mA ………… (i)
mg  T  mA …………… (ii)
T  f  2mA ………….. (iii)
From Eqs. (ii) and (iii),
f  mg 4
If friction is static, f  mg
1
 
4
NUMERICAL VALUE TYPE

This section contains 10 questions. Attempt any 5 questions out of 10. Each question is
numerical value type. For each question, enter the correct numerical value (in decimal notation
(e.g. 6.25, 7.00, 7, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. Two circular coils X and Y, having equal number of turns and carrying currents in the same sense,
subtend same solid angle at point O. If the smaller coil X is midway between O and Y and if we
represent the magnetic induction due to bigger coil Y at O as B y and that due to smaller coil X at O
as Bx , then find the ratio Bx By .
21. (2)
2
0 2I  2r  0 2Ir 2
By  , Bx 
4  2r 2  2d 2  3 2 4  r 2  d 2  3 2
      
B
Solve to get x  2
By
22. A 5 m potentiometer wire having 3 resistance per meter is connected to a storage cell of steady
emf 2V and internal resistance 1 . A primary cell is balanced against 3.5 m of it. When a resistance
of 32 n  is put in series with the storage cell, the null point shifts to the center of the last wire,
i.e., 4.5 m What is ‘n’?
22. (7)
This means you will not get the balancing point.
1 1 1 7 21
i  , EP   3 
2  15 8 8 2 16
21 9 7
 i  3  or i  A
16 2 72
7 2 32
 or R  
72 16  R 7
23. A copper rod and an aluminium rod of equal diameter M are joined end to end in good thermal
contact. The temperature of the free end of the copper rod is held constant at 100o C and that of the
far end of the aluminum rod is held at 0o C . If the copper rod is 0.150 m long, then the length (in cm)
k 3
of the aluminum rod so that the temperature at the junction is 50.0o C must be  Al  
 k Cu 5 
23. (9)
When the temperature of the junction stabilizes, the energy transfer rate must be the same for each
rod, or PCu  PAl . The cross–sectional areas of the rods are equal, and if the temperature of the
junction is 50.0o C , the temperature difference is T  50.0o C for each rod. Thus,
 T   T 
PCu  k Cu A    k Al A    PAl
 L Cu   L Al 
Which gives
 k Al   238 W m.0 C 
LAl    LCu   o  15.0 cm 
 k Cu   397 W m. C 
 9.00 cm
24. An ambulance sounding a horn of frequency 264 Hz is moving towards a vertical wall with a
velocity of 5 ms–1. If the speed of the sound is 330 ms–1, how many beats per second will be heard by
an observer standing a few meters behind the ambulance?
24. (8)
The observer will hear a sound of the source moving away from him and another sound after
reflection from the wall. The apparent frequencies of these sounds are
 v   v 
f1    f , f2   f
 vu   vu 
Number of beats  f 2  f1
 v v  2uvf 2uf
  f  2 2
 8
 vu vu  v u v
25. Two forces of magnitude F are acting on a uniform disc kept on a horizontal rough surface as shown
in the figure. Friction force by the horizontal surface disc is nF. Find the value of n.
25. (0)
Let f be the friction force acting on the disc in the backward direction. Then 2F  f  ma and
 F  f  r  I
1 2a
 F  f  r mr
2 r
 solving the above equations, we get f  0 .
26. A ring of radius r made of wire of density  is rotated about a stationary vertical axis passing
through its centre and perpendicular to the plane of the ring as shown in the figure. Determine the
angular velocity (in rad/s) of ring at which the ring breaks. The wire breaks at tensile stress  .
Ignore gravity. Take    4 and r  1m .
26. (2)

2T sin  dm2 r
2
   2 2
2T     A  r 
 2 
T
   r 22
A
1 
   2 rad s
r 
27. A child of mass 4 kg jumps from cart B to cart A and then immediately back to cart B. The mass of
each cart is 20 kg and they are initially at rest. In both the cases the child jumps at 6 m/s relative to
the cart. If the cart moves along the same line with negligible friction with the final velocities of VB
and VA , respectively, find the ratio of 6v B and 5v A .
27. (1)
All the velocities shown in diagrams are w.r.t. ground. After first jump.
20v1  4v 2 and v1  v 2  6  given 

Solve to get v1  m s , v 2  5 m s
When child arrives on A:
 20  4  v3  4v 2  v3  5 / 6 m s
After the second jump:
v 4  v A  6, 24v3  20v A  4v 4
11 25
Solve to get v A  m s , v4  ms
6 6
When child arrives on B:
24v B  4v 4  20v1
 25  55
 24vB  4    20 1  v B  m s
 6  36
6v B 6  55  6
Now  1
5v A 36  5 11
28. A block of mass m = 0.14 kg is moving with velocity v 0 towards a mass less unstretched spring of
force constant K  10 Nm 1 . Coefficient of friction between the block and the ground is   1 2 .
Find the maximum value of compression in the spring (in cm), so that after pressing the spring the
block does not return back but stops there permanently.
28. (7)
Let compression in the spring be x.
f  kx  1 2   0.14  10  10x
 x  0.07 m  7 cm
29. A point object is placed at a distance of 25 cm from a convex lens. Its focal is 22 cm. A glass slab of
refractive index 1.5 is inserted between the lens and the object, then the image is formed at infinity.
Find the thickness of the glass slab (in cm),
29. (9)
When object is placed at the focus of the lens, i.e., at 22 cm from the lens, image will be formed at
infinity. Shift in the position of object;
 1
25  22   1   t
 

 1 
3  1   t  t 
 31.5  9 cm
 1.5  0.5
30. The half–life of a radioactive nuclide is 20 h. It is found that the fraction (1/x) of original activity
remains after 40 hours? What is the value of x?
30. (4)
t 40 hours
We have  2
t1 2 20 hours
A0 A0 A0
Thus, A  t t1 2
 
2 22 4
So one fourth of the original activity will remain after 40 hours.
AITS – 22 (Main) Chemistry
PART (B) : CHEMISTRY

31. 40 ml of CH 3COOH solution is mixed with V ml of 0.4 M – NaOH solution. If the pH of resulting
solution at equivalence point is 9.0, the initial concentration of CH 3COOH solution is [ K a of
CH 3COOH  2  10 5 , log 2  0.30
(A) 0.2 M (B) 0.1 M (C) 0.4 M (D) 0.8 M
31. (C)
At equivalence point only CH 3COONa salt is present
1
pH  7   pK a  log C 
2
1
9  7  4.7  log C   C  0.2M
2
It initial conc. of CH 3COOH is ‘x’ M. Then
40x  0.4V ………… (i)
0.4V  0.2  V  40  ………… (ii)
V  40ml
x  0.4M
r  
32. The solid A  B crystallize in rock–salt structure. If  A
r    
2  1 , the only INCORRECT
 B 
information is–
(A) Anions are in contact with each other
(B) Cations are in contact with each other
(C) Edge length of unit cell, a  2 2  rB
(D) The packing fraction is about 0.79
32. (B)
r  
 
If the given radius ratio  A   2  1 , this implies that cations are present in octahedral voids
r 
 B 
made by anions. B forms fcc lattice and A  are present in their octahedral voids.

Now we can say

* Anions are in contact with each other
* Cations are NOT in contact with each other
* By face diagonal we can say.
2a  4rB
 a  2 2rB
Total volume occupied by all ions

4 4 
 4  rA3   rB3 
3 3 
6 16 

  rA3   rB3 
3
 3 
5 2  6 
16

5 2  6 rB3 
Packing fraction  3
16 2rB3


3 2
 
5 2  6  0.79
33. In a Carnot’s cycle, we use a monoactomic gas. The volume V is:–
(A) 1.5m 3 (B) 2.4 m3 (C) 2 m3 (D) 1.8m 3

33. (C)
P1  1  P2  2
P3  4  P2  2 
P3  4  P4  V
P1  1  P4  V 
Solving, we get V  2
34. Half life of a first order reaction:

A  aq.  2B  aq. is 40 min at 27o C and 20 min at 37o C . The activation energy of reaction is
 ln 2  0.7, R  2.0 cal mol 1
K 1 
(A) 19530cal / mol (B) 13020cal / mol
(C) 26040cal / mol (D) 6510cal / mol
34. (B)
ln 2
Rate constant R 300  min 1
40
ln 2
Rate constant R 300  min 1
20
R 310 E a  1 1  Ea  1 1 
ln     
R 300 R  T1 T2  R  300 310 

 40  E  10 
ln    a  
 20  R  310  300 
E a   ln 2  2  310  30  cal / mol

 13020cal / mol.
35. The wave function of an atomic orbital of H–like atom is–

x
1 Z
 nm  .   .r.e  Zr 2a0 .cos 
32  a 0 
The only INCORRECT information about the orbital is–
5
(A) Value of ‘x’ is
2
(B) Orbital is 2p z
(C) Most probable distance of electron from the centre of nucleus is 4a 0 , in case of H–atom
(D) There is no node (neither radial nor angular) in this orbital
35. (D)
 1  1 5 2 
 2 2 2
 2
4 r   r   4r    .re
 32  a 0 
1r 2a 0
.cos  

52
1 1 
   r 4 e  r a 0 .cos 2 
8  a0 
For most probable distance,


d 4r 2  2r   0
dr
 1
4r 3 .e  r a 0 .  r 4    .e  r a0  0
 a0 
 r 
r 3.e  r a0 .  4    0
 a0 
r  4a 0
36. Back bonding does not affect bond length in which of the following case?
(A) BF3 (B) B  OH 3 (C) H3Si  NCO (D) None of these
36. (D)
Due to back bonding bond length always decreases.
37. In the oxidation of C 2 O 42  ion by MnO4 ion in acidic medium, moles of H  ions needed per mole of
C 2 O 42  ion is–
(A) 16 (B) 8 (C) 3.2 (D) 6.4
37. (C)
5C 2 O 42   2MnO 4  16H   10CO 2  Mn 2   8H 2 O
16
Ans.  3.2
5
38. Rutherford’s planetary model of atom was rejected because:–

(A) This would suggest that atom was mostly empty.

(B) Such a nucleus cannot undergo   decay.
(C) The accelerating electron would rapidly lose energy.
(D) It cannot explain atomic spectra.
38. (C)
39. Which of the following information is CORRECT for a Van der waal’s gas?
(A) The pressure exerted by the gas is always higher than ideal gas
(B) The constants ‘a’ and ‘b’ have same dimension.
(C) At a temperature below critical temperature, the gas may have three theoretically real molar
volumes at a given pressure
(D) In moderate range of pressure and at about room temperature, all real gases perfectly obey
Vander waal’s gas equation
39. (C)
The pressure exerted by the Vander Waal’s gas is always lower ideal gas.
Unit of ‘a’ is atm litre2 mol–2 units of ‘b’ in litremol–1.
In moderate range of pressure and at about room temperature all real gases do not perfectly obey
Vander Waals gas equation.
40. The dependence of molar conductance on concentration of electrolyte, may be expressed as

 m   m0  a. C
For all given aqueous solutions, except
(A) HCl  aq. (B) CH 3COOH  aq. (C) NaOH  aq. (D) NaCl  aq.
40. (B)
 m   m0  A C is not applicable for weak electrolyte (like CH 3COOH  aq. )
41.
(A) (B)
(C) (D)
41. (D)
, CN 
42. Benzoin.
EtOH, H 2 O
The reactant is obtained by dry distillation of the calcium salts of the following pairs–
(A) C6 H 5 CH 2  COOH, HCOOH (B) C6 H 5 COOH, HCOOH

(C) C 6 H 4  OH  COOH, HCOOH (D) C 6 H 4  NH 2  COOH, HCOOH
42. (B)
43. In the reaction CH 3CH 2 NH 2  CH 3 MgBr  X , the product is–

(A) CH3 CH 3 (B) CH 3CH 2 CH 3
(C) CH 3CH 2 CH 2 CH 3 (D) CH 4
43. (D)
44. Final product P is

 i  HNO3 H 2SO4
P 
 ii  SnCl2 HCl
 iii  HNO 2
 iv  CuBr
(A) (B)
(C) (D) None of these
44. (A)
45. C* is with in the product–
(A) CO 2 (B)
(C) Both (D) None

45. (A)
46. Identify the product A in the following reaction
(A) CO 2 (B) CH3 CHO (C) CH 3OH (D) None of these

46. (A)
decarboxylation
47. HI  Red P
Glucose Number of mole of organic compound
(1 mole) 
(x)
HIO4
Number of mole of organic compound

(y)
Find the value of (x + y).
(A) 3 (B) 5 (C) 7 (D) 9
47. (C)
48. Which of the following is incorrect about amylopectin?

(A) Amylopectin has C1–C4 glycosidic linkage
(B) Amylopectin has C1–C6 glycosidic linkage
(C) Amylopectin is polymer of   D  glucose
(D) Amylopectin is highly soluble in water
48. (D)
49. Nucleic acid contains five heterocyclic nitrogen containing base. How many of them are aromatic?
(A) 2 (B) 3 (C) 4 (D) 5
49. (D)
50. Correct order of increasing intermolecular forces of polymers

(A) Bune-S < Polythene < Nylon-6,6
(B) Polythene < Buna-S < Nylon-6,6
(C) Nylon-6,6 < Polythene < Buna-S
(D) Polythene < Nylon-6,6 < Buna-S
50. (A)

(e.g. 6.25, 7.00, 7, –0.33, –.30, 30.27, –127.30).
e
51. N   N  ; the number of INCORRECT set of quantum number for incoming electron in the
given process is:–
(i) n  2,   0, m   0, ms  1
2
(ii) n  2,   0, m  1, ms  1
2
(iii) n  1,   1, m  1, ms  1
2
(iv) n  2,   1, m   0, ms  1
2
(v) n  2,   1, m   1, m s  1
2
(vi) n  2,   1, m  1, ms  1
2
(vii) n  2,   2, m  1, ms  1
2
(viii) n  2,   1, m   2, ms  1
2
51. (3.00)
(i) n  2,   0, m   0, ms  1
2
(ii) n  2,   0, m  1, ms  1
2
(iii) n  1,   1, m  1, ms  1
2
(viii) n  2,   1, m   2, ms  1 and
2
(vii) n  2,   2, m  1, ms  1
2
Are incorrect set of quantum numbers for incoming electron in given process.
52. Find the number of CORRECT set of ionization energy order.

(i) Ar > P (ii) P > F (iii) N > O (iv) O > B
(v) P > S (vi) He > Cs (vii) O 2  O (viii) N 2  N 2
52. (6.00)
(i) Ar > P (iii) N > O (iv) O > B (v) P > S
(vi) He > Cs (viii) N 2  N 2
Are correct set of ionization energy.
115
53. The vapour density of a sample of N 2 O 4  g  is at 4.8 atm at 127o C . The value of K p (in atm)
3
of the reaction:
N 2 O 4  g   2NO 2  g  , at 127o C , is –
53. (0.80)
M0 92
 1    1      0.2
M eq 2 115 / 3
2 0.22
K p  4Peq  4  4.8   0.8atm
1  2 1  0.22
54. In the Kjeldahl’s method of estimation nitrogen, total NH3 evolved was allowed to reat with 150 ml
of 0.1 M H2SO4. The solution was found to be acidic and required the addition of50 ml of 0.1 M
Ca(OH)2 for complete neutralisation. The % by mass of nitrogen in the compound if the mass of the
compound taken initially was 1.6 g, is
54. (17.5)
55. Valium is a tranquilizer used for the treatment of stress. What is the degree of unsaturation in
valium?
55. (11)
56. A particular water sample is saturated in CaF2 and has Ca+2 content of 120 ppm. Then the F– content
of water in ppm would be : [Given K sp  CaF2   6.0 109 M 3 ]
56. (26.8 to 26.90)
CaF2  s   Ca 2  aq   2F  aq 
K sp  6.0 109
2
K sp   Ca 2   F 
Given
120 1
 Ca 2   3   3  103 mol L
10 L 40
6.0 109
 F2  
3 103
 F   1.414  103 mol L
 F   1.414  10 3  19  103
 F   26.84 ppm
57. M+ form M3C60 where C603 fulleride (a superconductor) form octahedral holes. If radius of C603 is
500 pm then the minimum possible radius in pm for M+ is (round off to nearest integer)
57. (207)
R
For octahedral structure    0.414
R
 
R  0.414  R
 0.414  500
R   207 pm
58. If EAN of central metal cation M 2 in a non-chelating complex is 36 and atomic no. of metal M is
26, then the number of monodentate ligand in this complex are :
58. (6)
36 = 26 – 2 + x(2)
x=6
59. Formula of plaster of Paris is CaSO4.xH2O. Here x is

59. (0.50)
It is 2CaSO4.H2O or CaSO4.(1/2)H2O
60. Total number of oxygen atom(s) which act(s) as bridge between any two silicon atoms in a mineral
with composition MM  Si3 O x (M = divalent metal ion and M   tetravalent metal ion).
60. (3)
AITS – 22 (Main) Mathematics
PART (C) : MATHEMATICS

1 0  1 0 
61. If a    and I    , then which one of the following holds for all n  1 , by the principle of
1 1  0 1 
mathematical induction
(A) A n  nA   n  1 I (B) A n  2 n 1 A   n  1 I
(C) A n  nA   n  1 I (D) A n  2 n 1 A   n  1 I
61. (C)
1 0  1 0  1 0 
A2    
1 1  1 1   2 1 
 1 0  1 0  1 0   1 0
A3        An   
 2 1  1 1  3 1  n 1
n 0  n 1 0 
nA    ,  n  1 I  
n n   0 n  1
1 0
nA  n  n  1 I     An
n 1
 1 x 
62. If a  tan 1    b where 0  x  1 then  a, b  
 1 x 
      
(A)  0,   (B)  0,  (C)   ,  (D)  , 
 4  4 4 4 2
62. (B)
0  x 1
  
 0  tan 1 x   0   tan 1 x 
4 4 4
63. The point of intersection of the curves whose parametric equations are x  t 2  1, y  2t and
2
x  2s, y  , is given by
s
(A) 1, 3  (B)  2, 2  (C)  2, 4  (D) 1, 2 
63. (B)
x  t 2  1, y  2t  x  1  y 2 2
x  2s, y  2 s  xy  4
4 y2
For the point of intersection we have 1   y3  4y  16  0  y  2  x  2
y 4
Hence (B) is the correct answer.
64. If 1  x  1  x  x  ......1  x  x

2 2
 ......  x n   a 0  a1 x  a 2 x 2  ....  then a 0  a 2  a 4  a 6  ....
equals
n!  n  1!
(A) n! (B)  n  1! (C) (D)
2 2
64. (D)
Put x  1 and –1 and add
a 0  a1  a 2  .....  1  11  1  11  1  1 .....  n  1
Also, a 0  a1  a 2 ......  0  an integer adding,
2  a 0  a 2  a 4  .....  1 2  3  .....  n  1   n  1!
 a 0  a 2  a 4  ..... 
 n  1!
2
3
65.  
If f  x   ax 2  b , then the function g such that f  g  x    g  f  x   is
12
 b  x1 3  1
(A) g  x     (B) g  x   3
 a   ax 2
 b
12
13  x1 3  b 

(C) g  x   ax  b 2
 (D) g  x    
 a 
65. (D)
3
y   ax 2  b 
ax 2  b  y1 3
12
 y1 3  b 
x  
 a 
12
 x1 3  b 
gx    where x  f  x 
 a 
66.  ~ p   p    p   ~ p   is
(A) A tautology (B) A contradiction
(C) A tautology and a contradiction (D) Neither a tautology nor a contradiction
66. (B)
 2   2 
67. The triangle formed by the lines x cos   ysin   p, x cos      y sin    p,
 3   3 
 2   2 
x cos      y sin      p is
 3   3 
(A) Isosceles (B) Equilateral (C) Right angled (D) Right angled isosceles
67. (B)
x cos   ysin   p represents a straight line for which the length of the perpendicular from the
origin is p and this perpendicular makes an angle  with the +ve direction of x–axis.
Cleary from the figure LMN is an equilateral triangle.
68. If e 2     / 2 , then

(A) coslog   log cos  (B) coslog   log cos 
(C) coslog   log cos  (D) cos   log 
68. (B)
e  2     2
 
  log   log
2 2
So, log  , lies in 1 & 4th quadrant.
st
69. The smallest positive root of the equation sin 1  x   cos x , is

1 7 1 5 1 3
(A)  (B)  (C)  (D) None of these
2 4 2 4 2 4
69. (A)
sin 1  x   0, cos x  0 , squaring sin 1  x   cos x
 
Use cos x  cos   1  x  
2 
2
sin  ax 2  bx  c 
70. If  is a repeated root of ax  bx  c  0 then lim 2
is
x 
x  
(A) 0 (B) a (C) b (D) c
70. (B)
sin  ax 2  bx  c 
lim 2
x 
x  
2
sin a  x   
 lim 2
a  a
x 
a  x  
71. The values ‘a’ for which the function f  x    a  2  x 3  3ax 2  9ax  1 decreases for all real values
of x, is
(A) a  2 (B) a  2 (C) a  3 (D) 3  a  2
71. (A)
f '  x   0 x  R
  a  2  x 2  2ax  3a  0 x  R
 discriminant < 0 and a  2  0
x 2 y2
72. Tangent drawn to the ellipse 2  2  1 at point ‘P’ meets the coordinate axes at points A and B
a b
respectively. Locus of mid–point of segment AB is
x 2 y2 a 2 b2 a 2 b2 x 2 y2
(A)  2 (B)  2 (C)  4 (D)  4
a 2 b2 x 2 y2 x 2 y2 a 2 b2
72. (C)
Equation of tangent
x cos  y sin 
 1
a b
 A  a sec , 0  and B  0, b cos ec 
Let  h, k  is the mid point of AB.
 2h  a sec , 2k  bcosec
a 2 b2
 Locus is  4
x 2 y2
dy
73. The general solution of the differential equation  y tan x  y 2 sec x is
dx
(A) tan x   c  sec x  y (B) sec y   c  tan y  x
(C) sec x   c  tan x  y (D) tan y   c  sec x  x
73. (C)
dy
We have,  y tan x  y 2 sec x
dx
1 dy 1
  tan x   sec x
y 2 dx y
1 1 dy dV
Putting  V  
y y 2 dx dx
dV
We obtain  tan x.V  sec x which is linear.
dx
I.F.  e 
tan x dx
 elogsec x  sec x
 The solution is
1
V sec x   sec 2 xdx  c  sec x  tan x  c
y
 sec x  y  c  tan x 
3
74. The probability that a man can hit a target is . He tries 5 times. The probability that he will hit the
4
target at least three times is
291 371 471 459
(A) (B) (C) (D)
364 461 502 512
74. (D)
3 1
P  ,q  ,n  5
4 4
3 2 4 5
3 1 3 1 3 459
Required probability  C3      5 C 4  
5
.    5 C5   
4 4 4 4  4  512
75. The area bounded by the curves y  f  x  , the x-axis and the ordinates x  1 and x  b is
 b  1 sin  3b  4  . Then f  x  is
(A)  x  1 cos  3x  4  (B) sin  3x  4 
(C) sin  3x  4   3  x  1 cos  3x  4  (D) None of these
75. (C)
b
Since,  f  x  dx   b  1 sin  3b  4 
1
 Differentiating both sides with respect to b, we get

f  b   3  b  1 .cos  3b  4   sin  3b  4 
 f  x   sin  3x  4   3  x  1 cos  3x  4 
76. The equation of the common tangent to the equal parabolas y2 = 4ax and x2 = 4ay is
(A) x  y  a  0 (B) x  y  a (C) x  y  a (D) x  y
76. (A)
a
Any tangent to y 2  4ax is y  mx  .
m
2 2 a 2 4a 2
It touches x  4ay if x  4a  mx   , i.e. x  4amx   0 has equal roots.
 m m
So, m3  1  0 , i.e. m  1 . Hence, the common tangent is y   x  a .
x y 1 z  2
77. The equation of the plane through the point  1, 2, 0  and parallel to the lines   and
3 0 1
z  2 2y  1 z  1
  is
1 2 1
(A) 2x  3y  6z  4  0 (B) x  2y  3z  5  0
(C) xy  y  3z  1  0 (D) x  2y  3z  3  0
77. (D)
  
Let  a  3i  k be vector parallel to 1st line and b  i  2j  k be vector parallel to 2nd line
i j k
 
a  b  3 0 1  i  0  2   j  3  1  k  6   2i  4j  6k
1 2 1
 Equation of plane is of the form 2x  4y  6z  k  0
 It passes through  1, 2, 0   2  8  k  0  k  6
 Equation is 2x  4y  6z  6, or x  2y  3z  3
d 
8a 2 b 2 c 2
78. If in a ABC , (a + b + c) (a + b – c) (b + c – a) (c + a – b) = , then the triangle is
a 2  b2  c2
(A) equilateral (B) isosceles (C) right angled (D) none of these
78. (C)
a 2 b 2c2
s  s  a  s  b  s  c  
2  a 2  b2  c2 
a 2 b 2c2
2 
2  a 2  b2  c2 
 a 2  b 2  c 2  8R 2
ex  x  1
79. lim 2
equals where {.} is fractional part function and I is an integer
x I
x
1
(A) (B) e – 2 (C) I (D) does not exist
2
79. (B)
e1h  1  h  1
lim 2
 e2.
h 0
1  h 
2 2
80. The shortest distance between

 x  5 
y2
 1 and
x 2  y  5
  1 is
9 1 1 9
(A) 5 2  2 5 (B) 5 2  2 5 (C) 5 5  2 2 (D) 5 5  2 2
80. (B)
2 2
Given
1  5

y2
 1 and
x 2 1  5
  1 are mirror image of each
9 1 1 9
other about y = x.
So, common normal is perpendicular to y = x.
Also, points corresponding to shortest distance are mirror image of each
other about y = x.
Say (h, k) and (k, h) So, d
√10 | = 5√2 − 2√5

(e.g. 6.25, 7.00, 7, –0.33, –.30, 30.27, –127.30).
81. Let z1 and z 2 be the complex roots of the equation 3z 2  3z  b  0 . If the origin, together with the
points represented by z1 and z 2 from an equilateral triangle, then the value of b
81. (1)
z1 , z 2 , 0 will be the vertices of an equilateral triangle if z12  z 22  0 2  z1z 2  0z 2  0z1
2b b
 1   b 1
3 3
82. In a G.P., T2  T5  216 and T4 : T6  1: 4 and all terms are integers, then its first term is
82. (12)
ar 3 1
ar 1  r   216 and 5 
3
ar 4
2
 r  4  r  2, 2
When r  2 then 2a  9   216  a  12
When r  2 , then 2a 1  8   216
216 108
a   , which is not an integer.
14 7
83. The number of solutions of equation x 2  x  6  x  2 , where x is a real number.

83. (3)
Here x 2  x  6 occurs and x 2  x  6  0
 x  2,3
Given equation x 2  x  6  x  2 ………….. (1)

Case 1:– When x  2 or x  3 . In this case x 2  x  6  0
 x2  x  6  x2  x  6
Now, equation (1) becomes x 2  x  6  x  2  x 2  2x  8  0  x  2, 4
Only x  4 is acceptable  x  2 or x  3 
Case 2:– When 2  x  3. x 2  x  6  0
 x 2  x  6    x 2  x  6
Now, equation (1) becomes
  x2  x  6  x  2
 x 2  4  0  x  2, 2
Since, x  2 is not acceptable in this case.
Case 3:– Clearly, x  2 satisfies equation (1)
But x  3 does not satisfy it
Thus, x  2,2, 4 .
Note: Equality sign may be taken in case 1 and 2 and in that case, case 3 will not be required.
84. If the tangent from a point P to the circle x 2  y 2  1 is perpendicular to the tangent from P to the
circle x 2  y2  3 , then the locus of P is a circle of radius
84. (2)
The equation of a tangent to x 2  y 2  1 is
x cos   ysin   1 …………… (1)
The equation of the tangent to x 2  y2  3 , perpendicular to (1) is
x sin   y cos   3 ………….. (2)
Let the co–ordinates of P be  h, k  , then h cos   k sin   1 & h sin   k cos   3 . Eliminating
(h, k) from these two equation h 2  k 2  4 .
85. The number of numbers pq of the form 4n  1 , where p, q,  1, 2,3,5, 7,9,11 is
85. (18)
In pq either both p and q are of the form 4n  1 or both are of the form 4n  3 . Thus p can be chosen
in 6 ways (any other than 2) and then q can be chosen in 3 ways.
 required number is 18.
2
86.   sin x  cos x  dx , where [.] denotes the greatest integer function, is equal to n  , then the value
0
of n is
86. (2)
2
    
4  2 sin  x     4  1.dx  4.  2
  4  0
2
87. If in a binomial distribution n = 20 and q = 0.75, then its mean is

87. (5)
esin x  sin x  1 1
88. lim 2
is equal to , then K is
x 0 x K
88. (2)
 sin x sin 2 x sin 3 x 

sin x 1     ......   sin x  1
e  sin x  1 1 2 3
lim 2
 lim  2

x 0 x x  0 x
sin 2  1 sin x  1
 lim 2    ......  
x0 x
 2 3  2
1 1 1
89. If S denote the sum to infinity and Sn the sum of n terms of the series 1     ... such that
3 9 27
1
S  Sn  , then the least value of n is
300
89. (6)
1
S  Sn 
300
1
1 n
1 1 3 1 1
  3   1  1  n  
1 1 300 2 3  300
1 1
3 3
1 1 2 1 1
 n    n   3n  450
3 300 3 3 450
 Least value of n = 6
1
90. Let f  x   max tan x, cot x . Then number of roots of the equation f  x   in  0, 2 is
3
90. (0)
If we draw the graph of tan x and cot x,
We observes that range of f  x  is [ 1, 0)  [1,  ) .
1
So, f  x   does not have any root.
3

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AITS – 22 (Main) Physics

PART (A) : PHYSICS

SINGLE CORRECT ANSWER TYPE

Which of the following statements is incorrect?

(A) f 0 (B) 2 f0 (C) 2f0 (D) 2 2 f 0

Similarly, electric field due to wires (1) and (2)

125  0AE 2 20 AE 2 6 0E 2 0 AE3

(A) 20  (B) 10 (C) 5 (D) 5

NUMERICAL VALUE TYPE

20v1  4v 2 and v1  v 2  6  given 

After the second jump:

PART (B) : CHEMISTRY

SINGLE CORRECT ANSWER TYPE

Now we can say

Total volume occupied by all ions

33. In a Carnot’s cycle, we use a monoactomic gas. The volume V is:–

(A) 1.5m 3 (B) 2.4 m3 (C) 2 m3 (D) 1.8m 3

34. Half life of a first order reaction:

E a   ln 2  2  310  30  cal / mol

35. The wave function of an atomic orbital of H–like atom is–

For most probable distance,

38. Rutherford’s planetary model of atom was rejected because:–

(A) This would suggest that atom was mostly empty.

40. The dependence of molar conductance on concentration of electrolyte, may be expressed as

(A) C6 H 5 CH 2  COOH, HCOOH (B) C6 H 5 COOH, HCOOH

43. In the reaction CH 3CH 2 NH 2  CH 3 MgBr  X , the product is–

44. Final product P is

(C) (D) None of these

45. C* is with in the product–

(C) Both (D) None

46. Identify the product A in the following reaction

(A) CO 2 (B) CH3 CHO (C) CH 3OH (D) None of these

Number of mole of organic compound

48. Which of the following is incorrect about amylopectin?

50. Correct order of increasing intermolecular forces of polymers

NUMERICAL VALUE TYPE

52. Find the number of CORRECT set of ionization energy order.

59. Formula of plaster of Paris is CaSO4.xH2O. Here x is

PART (C) : MATHEMATICS

SINGLE CORRECT ANSWER TYPE

64. If 1  x  1  x  x  ......1  x  x

Cleary from the figure LMN is an equilateral triangle.

68. If e 2     / 2 , then

69. The smallest positive root of the equation sin 1  x   cos x , is

 Differentiating both sides with respect to b, we get

80. The shortest distance between

√10 | = 5√2 − 2√5

NUMERICAL VALUE TYPE

83. The number of solutions of equation x 2  x  6  x  2 , where x is a real number.

Given equation x 2  x  6  x  2 ………….. (1)

87. If in a binomial distribution n = 20 and q = 0.75, then its mean is

 sin x sin 2 x sin 3 x 

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