08-04-2023 - Outgoing SR - Phase-Iii - Jee Main Model GTM-33 - QP Final

OUT GOING SR(MPC) Date: 08-04-2023
Time: 3 Hrs GTM-33 Max. Marks: 300
08-04-2023_OUTGOING SR _PHASE-III_JEE MAIN MODEL GTM-33_QP FINAL
PHYSICS Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
1. A vernier calipers has 1 mm marks on the main scale. It has 20 equal divisions on the
vernier scale
which match with 16 main scale divisions. For this vernier calipers, the least count is.
A) 0.02 mm B) 0.05 mm C) 0.1 mm D) 0.2 mm
2. A simple pendulum has a time period of 3.0 s. If the point of suspension of the pendulum
starts moving vertically upward with a velocity v  Kt where K  4.4ms -2 , the new time
period will be
(Take g  10ms -1 )
9 5
A) s B) s C) 2.5 s D) 4.4 s
4 3
3. A nucleus of mass number 220, initially at rest, emits an   particle . If the Q value of the
reaction is 5.5 MeV, the energy of the emitted   particle will.
A) 4.8 MeV B) 5.4 MeV C) 6.0 MeV D) 6.8 MeV
Narayana IIT Academy 07-04-2023_OUTGOING SR _PHASE-III_JEE MAIN MODEL GTM-32_QP FINAL
4. The potential energy function for the force between two atoms in a diatomic molecule is
a b
approximately given by U  x   12
 6 , where a and b are constants and x is the distance
x x
between the atoms. If the dissociation energy of the molecule is D  U  x   U at equilibrium  .
Then D is.
b2 b2 b2 b2
A) B) C) D)
4a 6a 2a 12a
5. Two rods of same length L and cross-sectional area A are joined in series. Thermal
conductivity of rods are in the ratio 2 : 1. The ends are maintained at temperatures
TA and TB respectively, where
TA  TB ; and the sides are thermally insulated. Which of the following graph best
dT
represents? temperature gradient   against distance x in steady state is?
 dx 
6. A body projected at t = 0 with a velocity 10ms 1 at an angle of 600 with the horizontal. The
radius of curvature of its trajectory at t = 1s is R. Neglecting air resistance and taking
acceleration due to gravity g  10ms 2 , the value of R is.
A) 5.1 m B) 2.5 m C) 2.8 m D) 10.3 m
7. An ideal gas expands such that PT 2 = constant. Coefficient of volume expansion and
1 dP 
pressure expansion of the gas are V and  P respectively   P  
 . Then,
V

 P dT  P
3
A)  B) 1 C) 2 D) 2/3
2
SR.IIT_*CO-SC Page. No. 2

8. A body falls freely towards the earth from a height 2R, above the surface of the earth,
where initially
it was at rest. If R is the radius of the earth, then its velocity on reaching the surface of
the earth is:
4 2 4
A) gR B) gR C) gR D) 2 gR
3 3 3
9. Young’s double slit experiment is performed inside a liquid. The 35th bright fringe in
liquid lies where 28th dark fringe lies in vacuum. The refractive index of the liquid is.
A) 14/13 B) 14/11 C) 35/22 D) 11/7
10. A message signal of frequency 20 kHz and peak voltage of 10 volts is used to modulate
a carrier signal of frequency 1.5 MHz and peak voltage of 40 volts. The side band
frequencies produced are.
A) 1480 kHz and 1520 kHz B) 5880 kHz and 6020 kHz
C) 1495 kHz and 1505 kHz D) 355 kHz and 395 kHz
11. A transistor connected in common emitter configuration, the collector supply is 8V and
the voltage
drop across a resistor of 800 in the collector circuit is 0.5V. If the current gain factor
   0.96 , then the base current is.
A) 26 A B) 20 A C) 13 A D) 62  A
12. 400g of ice at 253 K is mixed with 0.05 kg of steam at 1000 C . Latent heat of
vaporization of steam  540 cal/g . Latent heat of fusion of ice 80 cal/g. Specific heat of ice
= 0.5 cal/g 0C . The resultant
temperature of the mixture is.
A) 273 K B) 300 K C) 330 K D) 373 K
13. A parallel plate capacitor of capacitance C is connected to a battery and is charged to a
potential difference V. another capacitor of capacitance 2C is similarly charged to a
potential difference 2V. the charging battery is then disconnected and the capacitor are
connected in parallel to each other in such a way that the positive terminal of one is
connected to the negative terminal of the other. The final energy of the configuration is.

3 25 9
A) Zero B) CV 2 C) CV 2 D) CV 2
2 6 2
14. A rigid diatomic ideal gas undergoes an adiabatic process at room temperature. The
relation between temperature and volume for this process is TV x  constant , then x is.
A) 5/3 B) 3/5 C) 2/5 D) 2/3
15. An electromagnetic wave with frequency  and wavelength  travels in the +y direction.
Its magnetic field is along +x axis. The vector equation for the associated electric field
(of amplitude E0 ) is :-
 2    2  
A) E  E0 cos  t  yx B) E   E0 cos  t  y x
     
 2    2  
C) E   E0 cos  t  yz D) E  E0 cos  t  yz
     
16. Figures gives a system of logic gates. From the study of truth table, it can be found that
to produce a high output (1) at R. we must have.
A) X = 0, Y = 1 B) X = 1, Y = 1 C) X = 1, Y = 0 D) Not possible.
17. Given below are two statements:

Statement-I: The reactance of an ac circuit is zero. It is possible that the circuit contains
a capacitor and an inductor.
Statement-II: In ac circuit, the average power delivered by the source never becomes
zero.
In the light of the above statements, choose the correct answer from the options given
below:
A) Both statement I and statement II are true.
B) Both statement I and statement II are false.
C) Statement I is true but statement II is false.
D) Statement I is false but statement II is true.

18. A thin spherical conducting shell of radius R has a charge q. Another charge Q is placed
at the centre of the shell. The electronic potential at a point P at a distance R/2 from the
centre of the shell is.
2
A)
2Q
B)
2Q

2q
C)
2Q

q
D)
q  Q
4 0 R 4 0 R 4 0 R 4 0 R 4 0 R 4 0 R
19. The kinetic energy of the most energetic photoelectrons emitted from a metal surface is
doubled when the wavelength of the incident radiation is reduced from 1 to 2 . The work
function of the metal is.
hc 2hc 2hc 2hc
A)  22  1  B)  21  2  C)  1  2  D)  1  2 
12 12 12 12
20. A hydrogen atom emits photon corresponding to an electron transition from n = 5 to n =
1. The recoil speed of hydrogen atom in nearly equal to
A) 104 m / s B) 2 102 m / s C) 4 m / s D) 8 102 m / s
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A conductor of mass m =5 kg and length l = 4m placed on horizontal surface and a

uniform Magnetic field B =2 Tesla exists parallel to the horizontal surface but
perpendicular to the Conductor. Suddenly, a certain amount of charge is passed through
it, then it is found to jump to Height h = 5m. Then, find the amount of charge that passes
through the conductor ( in Coulomb). (take g  10 m/s 2 )
22. The fractional reduction of the acceleration due to gravity due to an increase in elevation
of 10 km near the earth’s surface is x  103 . Find x to the nearest integer (Radius of the
earth is 6400km).
23. When an object is placed at a distance of 25 cm from a mirror, the magnification is m1 .
The object is moved 15 cm further away with respect to the earlier position, and the
magnification becomes m 2 If m1 / m 2  4 , the focal length (in cm) of the mirror is.
24. A battery of emf 10V and internal resistance 3 is connected to resistor. If the current in
the circuit is 0.5A, what is the resistance (in ohms) of the resistor?

25. A 5kg stone of relative density 3 is resting at the bed of a lake. It is raised through a
height of 5m in the lake very slowly. If g  10 m/s 2 , then work done by the person in
x
raising the stone is J .Then the value of x is _____.
3
26. The self-induced emf of a coil is 20 volts, when the current in it is charged at uniform
rate from 10A to 25A in 2s, the change in the energy of the inductance is: (in J).
27. A potentiometer wire of length 10 m and resistance 20 is connected in series with a
25V battery and an external resistance 30 . A cell of emf E in secondary circuit is
x
balanced by 250 cm long potentiometer wire. The value of E (in volt) is , the value of
10
x is_________.
28. Two boys A and B of masses 60kg and 40kg respectively are at the ends of a 4m long
boat of mass 100kg which is on water in lake and the system is at rest. If the boys meet
at the centre of the boat then the displacement of centre of mass of the boat in meter is
y  10 1 . The value of y is (neglect friction between water and boat)
29. An  particle moves along a circle of radius 1.25 cm inside a uniform magnetic field of
intensity 0.1 T. its de Broglie wavelength in Pico – metre is (Nearest integer).
30. A convex length of focal length 20 cm is placed in front of convex mirror with principal
axis Coinciding each other the distance between the lens and mirror is 10 cm. A point
object is placed On principal axis at a distance of 60 cm from the convex lens. The
image formed by combination Coincides the object itself. The focal length of the convex
mirror is _____cm.

CHEMISTRY MAX.MARKS: 100

SECTION – I
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31.
Then the correct structure of P and Q and respectively are (use 1 equivalent of Br2)

32.
33. The correct combination is
C) CH 2Cl2  CHCl3  CCl4 (density order)
34. (i) H  COOH  Ph  COOH  CH 3  COOH (acidic nature)

(ii) CF3  COOH  CCl3  COOH  NO2  CH 2  COOH (acidic nature)
iii) N – methylmethanamine > methanamine > N , N – dimethylmethanamine (Basic
nature in aqueous phase)

iv) N , N – diethylethanamine > N – ethylethanamine > Ethanamine (Basic nature in

aqueous phase)
Then the correct option is
A) i , ii , iv B) ii , iii , iv C) i , ii , iii D) i , ii , iii , iv
35. Which of the following is not an essential aminoacid ?
A) Tryptophan B) Histidine C) Proline D) Threonine
36. Which of the following is a condensation polymer ?
A) Polystyrene B) Polyvinylchloride C) Dacron D) NEOPRENE
373 K
37. HCOOH 
conc H 2 SO4
 A  B , then identify the incorrect statement regarding ‘B’ ? (B has
carbon)
A) It act as a  - acceptor ligand in coordination compounds
B) It acts as a reducing agent
C) It is almost water insoluble gas
D) It is failed to reduce an aqueous PdCl2 solution to metallic Pd
38. The number of S = O bonds present in sulphurous acid, peroxodisulphuric acid and
pyrosulphuric acid , respectively are :
A) 2 , 3 and 4 B) 1 , 4 and 3 C) 2 , 4 and 3 D) 1 , 4 and 4
39. Which one of the following reaction is correct ?
1
A) F2  3H 2O  2 H 3O   2 F   O2 , G = + 795 kJ mol 
2
1
B I 2  H 2O  2 H   2 I   O2 , G = - 105 kJ mol 1
2
2
C) SiO2  6 HF   SiF6   2 H   2 H 2O
800 C
D) 2 BeO  CCl4   Be2C  2Cl2  O2
40. Which one of the following compounds involve disproportionation reaction with water ?
A) XeF2 B) XeF4 C) XeF6 D) XeO2 F2

41.
Then ‘Q’ in the reaction is
4) Reaction does not takes place
42. Which one of the following is a square planar complex ?

2 2 2
A)  NiCl4  B)  Ni  CO 4  C) Cu  NH 3 4  D)  Zn  NH 3 4 
43.
44. Which one of the following can undergo calcinations ?

I) Fe2 O3 . xH 2O II) Calamine III) Dolomite IV) Malachite
A) only II B) only I C) only III and IV D) I , II , III and IV
45. Which of the following options regarding defects in a crystal is correct ?
A) Schottky defect is a dislocation defect
B) Impurity defect in metals will always increases the density of metal
C) As temperature increases, orderly arrangement of the crystal will decrease.
D) LiCl crystals appear pink due to metal excess defect in which excess cations will be
present in interstitial voids.

46. A liquid solution is formed by mixing 10 moles of aniline with 20 moles of phenol at a
temperature T. If vapour pressure of phenol and aniline is 90 and 87 mm of Hg
respectively at the temperature T, then identify what could be the possible value of
vapour pressure of the solution?
A) 88 mm B) 80 mm C) 93 mm D) 90 mm
47. Which of the following options is incorrect ?
A) pH at half equivalent point of a weak acid (H.A.) with strong base is equal to pK b of
its conjugate base.
B) An aqueous solution of sodium acetate will be basic due to anionic hydrolysis.
C) pK a for H 3O  at 298 K is – 1.74.
D) on dilution of a solution of a weak acid, degree of ionization will increase but  H  
will decrease.
48. MnO4  8 H   5e   Mn 2   4 H 2O , If H  concentration is decreased from 1 M to 10 4 M at
25C , whereas concentration of Mn 2 and MnO4 remains 1 M, then :
A) the potential decrease by 0.38 V with decrease in oxidising power

B) the potential increase by 0.38 V with increase in oxidising power
C) the potential decreases by 0.25 V with decreases in oxidising power
D) the potential decreases by 0.38 V without affecting oxidising power
49. The kinetic energy of an electron in second Bohr orbit of a hydrogen atom is [ a0 is Bohr
radius] :
h2 h2 h2 h2
A) B) C) D)
4 2 ma02 16 2 ma02 32 2 ma02 64 2 ma02
50. For the process H 2O  l , T 0 K , P bar   H 2O  g , T 0 K , P bar  Identify the option which is not
correct
A) G = 0 if P represents vapour pressure of H 2O at T 0 K .
B) G < 0 if P represents vapour pressure of H 2O at temperature greater than T 0 K .
C) G > 0 if p is greater than vapour pressure of H 2O at T 0 K .
D) If reaction is at equilibrium at T 0 K and P bar then G > 0 at temperature less than
T 0K .
SECTION-II
51. An aqueous solution contains 0.10 M H 2 S and 0.20 MHCI . If the equilibrium constants
for the
formation of HS  from H 2 S is 1.0 107 and that of S 2 from HS  ions is 1.2 1013 then
concentration of S 2 ions in aqueous solution is x 10 20 then the value of x is
_________ .
52. The neutralization occurs when 10 mL of 0.1 M acid ‘A’ is allowed to react with 30 mL
of 0.05 M base M (OH )2 . The basicity of the acid ‘A’ is
53. Amongst SF4 , XeF4 , CF4 and H 2O , the number of species with two lone pairs of electrons
54. Consider the following equations :
2 Fe2  H 2O2  x A  y B (in basic medium)
2 MnO4   6 H   5 H 2O2  x 'C  y ' D  z ' E (in acidic medium)
The sum of the stoichiometric coefficients x, y, x ' , y ' and z ' for products A , B ,
C, D and E , respectively, is
55. The activation energy of one of the reactions in a biochemical process is 532611 J mo 11 .
When the
temperature falls from 310 K to 300 K, the change in rate constant observed is
k300  x 103 k310 . The value of x is __________ [  Given ln10  2.3 , R = 8.3 J k 1mol 1 ]
56. When 200 mL of 0.2 M acetic acid is shaken with 0.6 g of wood charcoal, the final
concentration of acetic acid after adsorption is 0.1 M. The mass of acetic acid adsorbed
per gram of carbon is
57. Number of electrons present in 4 f orbital of Ho3 ion is ---------- (Given Atomic No.of
Ho = 67)

2
58. Considering that  0  P , the magnetic moment (in BM) of  Ru( H 2O)6  would be
59. An element with molar mass 2.7 102 kg mol 1 forms a cubic unit cell with edge length
405 pm. If its density is 2.7  103 kg m 3 , the radius of the element is approximately --------
1012 m (to the nearest integer)
60. Assume a cell with the following reaction
Cu ( S )  2 Ag  (110 3 M )  Cu 2  (0.250 M )  2 Ag ( S ) Ecell
0
 2.97 V
Ecell for the above reaction is --------V.(Nearest integer) [Given : log 2.5 = 0.3979, T =
298 K]
MATHEMATICS MAX.MARKS: 100
SECTION – I
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. Given two real sets A  a1 , a 2 , a 3 ,......, a 2n  and B  b1 , b 2 ,......, b n  . If f :A  B is a function
such that every element of B has a preimage and f  a1   f  a2   f  a3   .......  f  a2n  then
the number of such mappings are.
A) 2nC n
B) 2nC n1
C) 2n  1C n1
D) 2n  1C
n
2n
2 n
62. If  a x  1  x  x 
r 0
r
r
, then the value of a2  3a3  6a4  10a5  ....... is.
n n
A)  n  1 B)  n  1 C) n  n  1 D) n  n  1
2 2
r n
63. If f  x   tan x  tan 2 x tan 2x and g  n    f  2 r  , then g (2013)  tan  22014  is equal to.
r 0
A) 0 B) tan 1 C) –tan 1 D) tan1  tan 2 1.tan 2
64. If the two expressions 99 x 2  19 x  9 and 55 x 2  ax  b have a common factor, then the
value of fractional part of  a  b  is ;  a, b  R  .
A) 2/9 B) 3/9 C) 4/9 D) 5/9
3b  a 2a  b  a
65. If the minimum value of    ,  a  0, b  0  , is equal to m for     , then
3a  b a  2b
  b  
the possible value of m and  is;
1 5 2 1 5 2
A)   and m  2 2  2 B)   and m  2 2  2
7 7
5 2 1 5 2 1
C)   and m  2 2  2 D)   and m  2 2  2
7 7

dy  6 
66. If y  y  x  is a solution of  x  1  xy  1; y  0   1 then y   is equal to
dx  5 
A) 7 B) 3 C) 5 D) -5
67. Let A be the 2  2 matrices given by A   aij  where aij  0,1, 2,3, 4 such
tha a11  a12  a21  a22  4 , the number of matrices A such that A is either symmetric or
skew symmetric or both and det (A) is divisible by 2 is.
A) 7 B) 4 C) 5 D) 6
68. The equation of a plane passing through the line of intersection of the planes
2
x  2 y  3 z  2 and x  y  z  3 and at a distance from the point (3,1,-1) is.
3
A) 5 x  11y  z  17 B) 2 x  y  3 2  1 C) x  y  z  3 D) x  2 y  1  2
      
69. Let a  i  j  k , b  i  j  k , a  c  b   a and a.c  1 then which of the following is true?
 8 1  8 1
A)  a b c   and    B)  a b c    and   
3 3 3 3
 8 2  8 2
C)  a b c    and    D)  a b c    and  
3 3 3 3
x
2
70. Let f  x    e1t  dt and g  x   f  h  x   where h (x) is defined for all x  R . If g '  2   e4
2
and h '  2   1 then absolute value of sum of all possible values of h (2) is.
A) 2 B) 3 C) 4 D) 0
71. Let the given function is differentiable at x = 1.

n
  x
   px  2 
2
 ax  x  1  cot
lim  4 
f  x    n  x
n
, x   0,1  1, 2  . Then the value of a  p is.
  cot   1
 4 

 0 x 1
A) 4 B) 6 C) 8 D) 10
72. The number of integral points inside the triangle made by the line 3x  4 y  12  0 with the
coordinate axes which are equidistant from at least two sides is (an integral point is a
point both of whose coordinates are integers).
A) 1 B) 2 C) 3 D) 4
73. Two parallel towers A and B of different heights are at some distance on same level
ground. If angle of elevation of a point P at 20m height on tower B from a point Q at
10m height on tower A is θ and is equal to half the angle of elevation of point R at 50m
height on A from point P on B. then θ is.
A) 300 B) 450 C) 150 D) 600

5 5
2
74. If   xr  10  5 and   xr  10  25 , then standard deviation of observations
r 1 r 1
2 x1  7, 2 x2  7, 2 x3  7, 2 x4  7 and 2 x5  7 is equal to.
A) 8 B) 16 C) 4 D) 2
 15 
75. The number of integral values of x satisfying the equation sgn   
2 
 1  2 x is :
 1  x  
(where [.] is greatest integer function, {.} is fractional part function and sgn (x) is
signum function)
A) 5 B) 7 C) 15 D) 16
e
 x 1  x x
x
76. The value of lim 2

is equal to
x 0
 x 2  x  1
 
A) 1 B) 1/8 C) 3/2 D) ¼
77. If e1 and e 2 are the roots of the equation x 2  ax  2  0 , where e1 and e 2 are the
eccentricities of an ellipse and hyperbola, respectively, then the value of a belongs to.
A)  3,   B)  2,   C) 1,   D)  ,1  1, 2 
78. The number of permutations of 1,2,3,4,5,6,7,8 and 9 taken all at a time such that digit 1
appearing somewhere to the left of 2, 3 appearing somewhere to the left of 4, and 5
somewhere to the left of 6 is (e.g. 815723946 would be one such permutation)
A) 9.7! B) 8! C) 5! 4! D) 8! 4!
79. The area bounded by the curve y  xe  x , xy  0 and x  c where c is the x – coordinate of
the curve’s Inflection point, is.( in square units)
A) 1  3e 2 B) 1  2e 2 C) 1  e2 D) e 2
 2
1  r 15 
80. The value of  cot    is.
r 1 2 8
3
A) Tan 1 1 B) Tan 1 2 C) Tan 1 4 D) Tan 1
2

SECTION-II
x  3 y 1 z  5 x 1 y  2 z  5
81. The value of ‘k’ so that the lines   and   are coplanar,
3 1 5 1 k 5
is.
 2 9 
82. If square matrix A   and An  B  nC where B and C are two square matrices
1 4 
then trace of 2B + C is equal to (where matrices B and C are independent of n)

b
dx
83. The value of  1 x 2 n 1
, where n  N and a and b are local maximum and
a  1  x 4 n 2
x
minimum point of g  x     t  2016 7  t  2014 110  t  2016 5 dt respectively is.
0
84. From the point of intersection (P) of lines given by x 2  y 2  2 x  2 y  0 , points A, B, C, D

are taken on the lines at a distance of 2 2 units to form a quadrilateral whose area is A1
and the area of the quadrilateral formed by joining the circumcentres of PAB , PBC ,
A1
PCD & PAD is A2 , then equals.
A2
85. A plane passing through (1, 1, 1) and parallel to the lines L1 , L2 having direction ratios (1,
0, -1) (1, -1, 0). If v is the volume of tetrahedron formed by origin and the points where
the plane intersect the coordinate axes then value of 2v is equal to.
18
th  1 
86. The 13 term in the expansion of  9 x   , x  0 is a 5 – digited number N, when all
 3 x
the five digits in this number N are permutated in all possible ways and numbers so
obtained are arranged in increasing order of their magnitude. Then the rank of the
number N is.
3
87. The number of points where the function f  x   min e x , ,1  e  x  is not differentiable
 2 
are.

88. A tank with rectangular base and rectangular sides, open at the top is to be constructed
so that its depth is 2m and volume is 8 m3 . If building of tank costs Rs. 70 per sq. ,meter
for the base and Rs. 45 per square meter for sides, then the cost of least expensive tank
(in rupees) is k, then sum of the digits of k is _____.
1 1 1 1
89 If the sequence an  is defined by a1  , an 1  an2  an and S =   ....  ,
2 a1  1 a2  1 a100  1
then [ S ] (where [.] denotes the greatest integer function) is.

90. Let z and  be two complex numbers. If Re  z   z  2 , Re      2 and arg  z     ,
3
Then Im  z    =



08-04-2023 - Outgoing SR - Phase-Iii - Jee Main Model GTM-33 - QP Final

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OUT GOING SR(MPC) Date: 08-04-2023

Time: 3 Hrs GTM-33 Max. Marks: 300

08-04-2023_OUTGOING SR _PHASE-III_JEE MAIN MODEL GTM-33_QP FINAL

SR.IIT_*CO-SC Page. No. 2

SR.IIT_*CO-SC Page. No. 3

17. Given below are two statements:

SR.IIT_*CO-SC Page. No. 4

21. A conductor of mass m =5 kg and length l = 4m placed on horizontal surface and a

SR.IIT_*CO-SC Page. No. 5

SR.IIT_*CO-SC Page. No. 6

CHEMISTRY MAX.MARKS: 100

SR.IIT_*CO-SC Page. No. 7

33. The correct combination is

C) CH 2Cl2  CHCl3  CCl4 (density order)

34. (i) H  COOH  Ph  COOH  CH 3  COOH (acidic nature)

SR.IIT_*CO-SC Page. No. 8

iv) N , N – diethylethanamine > N – ethylethanamine > Ethanamine (Basic nature in

SR.IIT_*CO-SC Page. No. 9

Then ‘Q’ in the reaction is

4) Reaction does not takes place

42. Which one of the following is a square planar complex ?

44. Which one of the following can undergo calcinations ?

SR.IIT_*CO-SC Page. No. 10

D) on dilution of a solution of a weak acid, degree of ionization will increase but  H  

25C , whereas concentration of Mn 2 and MnO4 remains 1 M, then :

A) the potential decrease by 0.38 V with decrease in oxidising power

2 MnO4   6 H   5 H 2O2  x 'C  y ' D  z ' E (in acidic medium)

SR.IIT_*CO-SC Page. No. 12

A) 0 B) tan 1 C) –tan 1 D) tan1  tan 2 1.tan 2

SR.IIT_*CO-SC Page. No. 13

71. Let the given function is differentiable at x = 1.

SR.IIT_*CO-SC Page. No. 14

2 x1  7, 2 x2  7, 2 x3  7, 2 x4  7 and 2 x5  7 is equal to.

76. The value of lim 2

SR.IIT_*CO-SC Page. No. 15

then trace of 2B + C is equal to (where matrices B and C are independent of n)

84. From the point of intersection (P) of lines given by x 2  y 2  2 x  2 y  0 , points A, B, C, D

SR.IIT_*CO-SC Page. No. 16

then [ S ] (where [.] denotes the greatest integer function) is.

SR.IIT_*CO-SC Page. No. 17

SR.IIT_*CO-SC Page. No. 18

SR.IIT_*CO-SC Page. No. 19

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