Yashpatil TG~ @bohring_bot

Sec: JR_*CO-SC(MODEL-B) Date: 18-11-2023

Time: 3 Hrs CTM-22 Max. Marks: 300

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: + 4 for correct answ er, 0 if not attempted and -1 if not correct.

1. Hydrostatic pressure ‘P’ varies with displacement ‘x’ as p 

A
B

log Bx 2  C where 
A,B and C are constants. The dimensional formula for ‘A is

A)  M 1 L1T 2  B)  MLT 2  C)  ML2T 2  D)  ML3T 2 

B
2. The work done ‘w’ by a body varies with displacement ‘x’ as Ax  . The
C  x 
2

dimensional formula for ‘B’ is

A)  ML2T 2  B)  ML4T 2  C)  MLT 2  D)  ML2T 4 

3. The velocity of a body is expressed V  G a M b R c where G is gravitational constant. M

is mass, R is radius. The values of exponents a, b and c are
1 1 1 1 1 1 1
A) , , B) 1,1,1 C) , , D) 1,1,
2 2 2 2 2 2 2
4. If energy E, velocity v and time T are taken as fundamental quantities, the dimensional
formula for surface tension is

A)  Ev 2T 2  B)  E 2 vT 2  C)  Ev 2T 1  D)  E 2 v 2T 1 

 Yashpatil TG~ @bohring_bot 18-11-23_JR.IIT_* CO-SC(MODEL-B)_JEE-MAIN_CTM-22_Q’P

5. There are two vernier calipers both of which have 1 cm divided into 10 equal divisions
on the main scale. The vernier scale of one of the calipers  C1  has 10 equal divisions

that correspond to 9 main scale divisions. The vernier scale of the other caliper  C2 

has 10 equal divisions that correspond to 11 main scale divisions. The readings of the
two calipers are shown in the figure. The measured values (in cm) by calipers
C1 and C2 respectively, are

A) 2.87 and 2.87 B) 2.87 and 2.83 C) 2.85 and 2.82 D) 2.87 and 2.86
6. The diameter of a cylinder is measured using a vernier calipers with no zero error. It is
found that the zero of the vernier scale lies between 5.10 cm and 5.15 cm of the main
scale. The vernier scale has 50 division equivalent to 2.45 cm. The 24th division of the
vernier scale exactly coincides with one of the main scale divisions. The diameter of
the cylinder is
A) 5.112 cm B) 5.124 cm C) 5.136 cm D) 5.148 cm
  aZ / k
7. In the relation, P  e p is pressure, Z is distance, k is Boltzmann's constant and

 is the temperature. The dimensional formula of  will be
A)  M 0 L2T 0  B)  ML2T  C)  ML0T 1  D)  M 0 L2T 1 

8. Match List I with List II

LIST-I LIST-II

a) Torque i)  ML2T 2 

b) Stress ii)  ML2T 2 

c) Pressure gradient iii)  ML1T 1 

d) Coefficient of viscosity iv)  ML1T 2 

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Choose the correct answer from the options given below

A) a-iv,b-ii,c-iii,d-i B) a-ii,b-i,c-iv,d-iii
C) a-ii,b-iv,c-i,d-iii D) a-iii,b-iv,c-i,d-ii
9. The speed of a wave produced in water is given v   a g b  c . Where  , g and  are
wavelength of wave, acceleration due to gravity and density of water respectively. The
values of a, b and c respectively, are
1 1 1 1
A) , ,0 B) ,0, C) 1, 1,0 D) 1,1, 0
2 2 2 2
 a 
10.  P   V  b   RT represents the equation of state of some gases. where p is the
 V2 
pressure, V is the volume, T is the temperature and a, b, R are the constants. The
physical quantity, which has dimensional formula as that of b2 / a, will be
A) bulk modulus B) compressibility
C) modulus of rigidity D) energy density
11. Two rods A and B of identical dimensions are at temperature 30°C. If A is heated upto
180°C and B upto T°C, then new lengths are the same. If the ratio of the coefficients
of linear expansion of A and B is 4 :3, then the value of T is
A) 2300 C B) 2700 C C) 2000 C D) 2500 C
12. A pendulum clock loses 12 s a day if the temperature is 40°C and gains 4 s a day if the
temperature is 20°C. The temperature at which the clock will show correct time, and
the coefficient of linear expansion a of the metal of the pendulum shaft are,
respectively
A) 250 C ,   1.85  105 / 0 C B) 600 C ,   1.85  104 / 0 C
C) 300 C ,   1.85 103 / 0 C D) 550 C ,   1.85 102 / 0 C
13. Two rods, one of aluminium and the other made of steel, having initial length l1 and l2

are connected together to form a single rod of length l1  l2 . The coefficients of linear

expansion for aluminium and steel are  a and  s respectively. If the length of each

rod increases by the same amount when their temperature are raised by t 0C , then find
l1
the ratio
l1  l2

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s a s a
A) B) C) D)
a s  a  as   a  as 
14. The coefficient of linear expansion for a certain metal varies with temperature as
 (T) If L0 is the initial length of the metal and the temperature of metal is changed
from T0 toT T0  T  , then

 T  dT B) L  L0 1    T  dT 
T
A) L  L0 
T
T0  T0

C) L  L0 1    T  dT 
T
D) L  L0
 T0

15. A piece of metal floats in mercury. The coefficients of volume expansion of the metal
and mercury are  1 and  2 respectively. If the temperatures of both mercury and the
metal are increased by T , the fraction of the volume of the metal submerged in
mercury changes by the factor of
1   2 T 1   2 T
A) B) 1   2 T C) 1   1T D)
1   1T 1   1T
16. The coefficient of linear expansion of glass is alpha  g per °C and the cubical

expansion of mercury  m per °C. The volume of the bulb of a mercury thermometer at

00 C isV0 and cross section of the capillary is A0 . What is the length of mercury
column in capillary at T°C, if the mercury just fills the bulb at 0°C

V0T   m  3 g  V0T   m  3 g 
A) B)
A0 1  2 g T  A0 1  2 g T 

V0T  m  2 g  V0T   m  2 g 
C) D)
A0 1  3 g T  A0 1  3 g T 

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17. Two elastic rods are joined between fixed supports as shown in the figure. Condition
for no change in the lengths of individual rods with the increase of temperature
(1 , 2  linear expansion coefficient, A1 , A2  areas of cross-section of rods, Y1 , Y2 
Young's modulii ) is

A1 1Y1 A1 L11Y1 A1 L2 2Y2 A1  2Y2

A)  B)  C)  D) 
A2  2Y2 A2 L2 2Y2 A2 L11Y1 A2 1Y1
18. The densities of wood and benzene at 0°C are 880 kg/m³ and 900 kg/m³, respectively.
The coefficients of volume expansion of wood is 1.2 ×103 / 0 C and of benzene
1.5 103 / 0 C . The temperature at which a piece of this wood would just sink in
benzene at the same temperature is
A) 530 C B) 630 C C) 730 C D) 830 C
19. A bimetallic strip is formed out of two identical strips- one of copper and the other of
brass. The coefficients of linear expansion of the two metals are  C and  B . On
heating, the temperature of the strip goes up by T and the strip bends to form an arc
of radius of curvature R. Then, R is
a) Proportional to T b) inversely proportional to T
c) proportional to  B   C d ) inversely proportional to  B   C

A) b and d are correct B) a and d are correct

C) b and c are correct D) a and c are correct
20. At what temperature a gold ring of diameter 6.230 cm be heated, so that it can be fitted
on a wooden bangle of diameter 6.241 cm? Both the diameters have been measured at
room temperature (27°C).
(Given, coefficient of linear thermal expansion of gold   1.4 105 K 1 )

A) 125.70 C B) 91.7 0 C C) 425.7 0 C D) 152.70 C

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SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answ er any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: + 4 for correct answ er, -1 in all other cases.

21. A clock with a metallic pendulum at 15°C runs faster by 5 s each day and at 30°C, runs
slow by 10 s. Find the coefficient of linear expansion of the metal. (nearly in
105 / 0 C )
22. A steel rod of length 1 m and cross-sectional area 10 m is heated from 0°C to 200°C
without being allowed to extend or bend. The compressive tension produced in the rod
is ....  10 4 N . (Given Young's modulus of steel  2  1011 Nm 2 , coefficient of linear
expansion  105 K 1 )
23. The area of cross-section of a railway track is 0.01 m². The temperature variation is
10°C. Coefficient of linear expansion of material of track is 10 5 / 0 C. The energy
stored per meter in the track is____ J/m. (Young's modulus of material of track is 1011 Nm 2 )
24. The system shown in figure consists of three springs and two rods as shown. The
temperature of the rods is increased by  T. The springs are initially relaxed. There is
no friction. The coefficient of linear expansion of the rods is equal to  . The energy
81 2 2
kL   T  . Find x
2
stored in spring S1 is
x

25. The temperature compensated pendulum is designed to compensate for the change in
length due to temperature rise. Fig shows one such pendulum. It consists of an
isosceles triangular frame as shown in figure. The pendulum is supported at midpoint
of side AB and it remains horizontal. The ratio l1 / l2 so that the length of the

2
pendulum remains same at all temperatures is P . Then P is
a1

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26. A string secured at its ends is stretched with a force of tension F. The mass of the string
and the force of gravity can be neglected. A point weight with a mass mis attached to
the middle of the string. The time period of small oscillations of the weight

ml
2 .The value of x is
xF
(Neglect any change in the magnitude of tension of the string during oscillations

27. One end of a spring of force constant k is fixed to a vertical wall and the other to a
body of mass m resting on a smooth horizontal surface. There is another wall at a
distance x0 from the body. The spring is then compressed by 2x0 and released. The

x m
time of oscillation of body is . Find x  y
y k

28. A simple pendulum has time period 2s. The point of suspension is now moved upward

 
according to relation y  6t  3.75t 2 m, where t is in second and y is the vertical

displacement in upward direction. The new time period (in s) of simple pendulum will


be g  10ms 2 

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29. Two separate air bubbles  r1  0.002 cm, r2  0.004cm  formed of same liquid

T  0.07 N / m come together to form a double bubble. The radius of curvature of the

internal film surface common to both the bubbles is   103  cm . Find x

8
x 
30. The pressure inside soap bubble is 1.01 and 1.02 atmosphere respectively. The ratio of
x
their volume is . Then x  y is
y

CHEMISTRY Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: + 4 for correct answ er, 0 if not attempted and -1 if not correct.

31. Decreasing order of  I effect of the triad   NO2 ,  N H 3 , CN  is:-



 
 
(A)  N H 3   NO2  CN (B)  N H 3  CN   NO2
 
(C) CN   NO2   N H 3 (D)  NO2  CN   N H 3
32. The correct order of stability of given carbanions will be:-
  
CH 3  C H 2 CH 2  C H HC  C

(I) (II) (III)

(A) I > II > III (B) III > II > I (C) I > III > II (D) II > III
33. Most stable carbocation is:-

(A) (B) (C) (D)

34. Which resonating structure of vinyl chloride is least stable:-
   
(A) CH 2  CH  C l : (B) C H 2  CH  C l
 


(C) C H 2  CH  Cl (D) All have equal stability

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35. In which of the following compounds carbon-chloride bond distance is minimum:-

(A) CH 3  Cl (B) C6 H 5  CH 2  Cl
(C) CH 2  CH  Cl (D) CH 2  CH  CH 2  Cl
36. Consider the following carbocations

The relative stabilities of these carbocations are such that:-

(A) d < b < c < a (B) b < d < c < a (C) d < b < a < c (D) b < d < a < c
37. Which of the following is most stable carbocations:-


(A) (B) (C) (D) CH 2  CH  C H 2
38. Which is incorrect stability order:-
   
(A) CH 2  CH  C H 2  CH 3  C H  CH 3 (B) CH 2  C H  CH 3  C H 2
   
(C) CH 3  CH 2  C H 2  CH 3  C H  CH 3 (D) CH 3  C H 2  CH 3O  C H 2
39. Mesomeric effect is due to:-
(A) Delocalization of  es (B) Delocalization of   e 
(C) Migration of H-atom (D) Migration of proton
40. Among the following the aromatic compound is-

(A) (B) (C) (D)

41. Which is aromatic compound among the following

(A) (B) (C) (D) All of these

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42. Select the correct option for stability of following carbanions:

(A) I > II > III (B) II > I > III (C) III > II > I (D) II > III > I
43. Which is Aromatic compound:-

(A) (B)

(C) (D) (B) & (C) Both

44. Which of the following resonating structures of 1-methoxy-1, 3-butadiene is least
stable:-
   
(A) C H 2  CH  CH  CH  O  CH 3 (B) C H 2  C H  C H  CH  O  CH 3
 
(C) C H 2  C H  CH  CH  O  CH 3 (D) C H 2  C H  CH  CH  O  CH 3
45. Four structures are given in options (a) to (d). Examine them and select the aromatic
structures.

(A) (a) and (d) (B) (b) and (c) (C) (a) and (b) (D) (a) and (c)
46. Which is not aromatic compound:-

(A) (B) (C) (D)

47. Select the correct option for stability of following resonance structures:-

(A) x > y > z (B) z > y > x (C) y > x > z (D) y > z > x

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48. C – C single bond distance would be:-

(a) CH 2  CH  CH  CH 2 (b) CH 3  CH  CH 2
(c) CH 3  CH 3
(A) a < b < c (B) a > b < c (C) a < b > c (D) b < a > c
49. In the following the correct bond order sequence
A) O22  O2  O2  O2 B) O2  O2  O22  O2
C) O2  O2  O2  O22 D) O2  O2  O22  O2
50. When ammonia react with Diborane which of the following reaction do not takes
place?
A) Initially Diborane reacts with ammonia to form diammoniate of Diborane
B2 H 6 .2 NH 3
B) Diammoniate of Diborane formed initially is an ionic compound consisting of

 BH 2  NH 3  
 2
 BH 4 
C) Diammoniate of Diborane is formed by symmetric cleavage of Diborane
D) Diammoniate of Diborane on heating gives inorganic benzene, B3 N 3 H 6

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answ er any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: + 4 for correct answ er, -1 in all other cases.

51. Calculate the number of Benzenoid isomers possible for C6 H 3 ClBrI .

52. How many following are the enantiomers?

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Na2  B4O5  OH 4  .8 H 2O
53. In the compound If the
i) number of B-O-B bonds is X
ii) number of B-B bonds is Y
2
iii) number of sp hybridized B atoms is Z
calculate the value x  y  z
54. How many cyclopentane structures (excluding stereo) are possible for C7 H14 ?
55. Calculate the total number of chrial carbon atoms in:

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56. Total Resonating structure = x , What is the value of x ?

57. Find the total number of Aromatic Compounds:

58. Find the total number of Resonating structure of P.

59. How many  electron are there in the following species:

60. Total number of species which have fractional Bond order amongst the following.
i) O2 ii) CO iii) B2 iv) O2 v) NO

vi) He2 vii) CN  viii) N 2

MATHS Max.Marks:100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
============================================================================
61. If the function f given by f ( x)  x3  3(a  2) x 2  3ax  7 , for some a  R is increasing in
f ( x )  14
(0, 1] and decreasing in [1, 5), then a root of the equation  0 , ( x  1) is
( x  1)2

(a) 6 (b) 5 (c) 7 (d) 7

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1
62. Let f : (1, )  R be defined by f (0)  1 and f ( x)  log e (1  x), x  0 . Then the function
x
(a) decreases in (1, ) (b) decreases in (1, 0) and increases in (0, )
(c) increases in (1, ) (d) increases in (1, 0) and
decreases in (0, )
 55 x, if x  5

63. Let f : R  R be defined as f ( x)   2 x3  3x 2  120 x if 5  x  4 .
 3
2 x  3x  36 x  336 if x4
2

Let A = { x  R : f is increasing}. Then Ais equal to

(a) (, 5)  (4, ) (b) (5, ) (c) (, 5)  (4, ) (d) (5, 4)  (4, )
64. Let   be the largest value of  for which the function f  ( x)  4 x3  36 x 2  36 x  48 is
increasing for all x  R . Then f  (1)  f (1) is equal to

(a) 36 (b) 48 (c) 64 (d) 72

65. Let f ( x)  2 x  tan 1 x and g ( x)  loge ( 1  x 2  x) , x [0,3] . Then

(a) min f '( x)  1  max g '( x)
(b) there exist 0  x1  x2  3 such that f ( x)  g ( x) , x  ( x1, x2 )
(c) max f ( x)  max g ( x)

(d) there exist x  [0,3] such that f '( x )  g '( x )

66. The absolute minimum value of the function f ( x) | x 2  x  1|  [ x 2  x  1] , where [t ]
denotes the GIF, in the interval [1, 2] is
3 1 5 3
(a) (b) (c) (d)
2 4 4 4

67. Let x  2 be a local minima of the function f ( x)  2 x 4  18 x 2  8 x  12 , x  (4, 4) . If M is

local maximum value of the function f in (4, 4) , then M =
33 33 31 31
(a) 18 6  (b) 12 6  (c) 12 6  (d) 18 6 
2 2 2 2

a2 b2
68. The minimum distance from the origin to a point on the curve  1
x2 y2

(a) 2ab (b) 2(a  b) (c) 2a  4b (d) a  b

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sin 2 x
 3e    k
69. If the local maximum value of the function f ( x )    , x   0,  , is , then
 2 sin x   2 e

88
k k
   5  k is equal to
8

e e

(a) e5  e 6  e11 (b) e3  e6  e11 (c) e3  e6  e10 (d) e3  e5  e11

70. Twenty meters of wire is available for fencing off a flower-bed in the form of a circular
sector. Then the maximum area (in sq. m) of the flower-bed is
(a) 30 (b) 12.5 (c) 10 (d) 25
71. The triangle of maximum area that can be inscribed in a given circle of radius ' r ' is
(a) An isosceles triangle with base equal to 2r
2r
(b) An equilateral triangle of height
3

(c) An equilateral triangle having each of its side of length 3r

(d) A right-angle triangle having two of its sides of length 2r and r .
72. Consider a cuboid of sides 2 x, 4 x and 5x and a closed hemisphere of radius ' r ' . If the
sum of their surface areas is a constant k , then the ratio x : r , for which the sum of their
volumes is maximum, is
(a) 2 : 5 (b) 19 : 45 (c) 3 : 8 (d) 19 : 15
73. A wire of length 20 m is to be cut into two pieces. A piece of length 1 is bent to make
a square of area A1 and the other piece of length  2 is made into a circle of area A2 . If
2 A1  3 A2 is minimum then ( 1 ) :  2 is equal to

(a) 6 : 1 (b) 3 : 1 (c) 4 : 1 (d) 1 : 6

74. The number of points on the curve y  54 x5  135 x 4  70 x3  180 x 2  210 x at which the
normal lines are parallel to x  90 y  2  0 is
(a) 2 (b) 4 (c) 0 (d) 3
75. Let x  2 be a root of the equation x 2  px  q  0 and
1  cos( x 2  4 px  q 2  8q  16)
 , x  2p
f ( x)   ( x  2 p) 4 . Then lim  [ f ( x)] , where [.] denotes GIF, is
x 2 p
 x  2p
 0,

(a) 2 (b) 2 (c) – 1 (d) 0

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x2  2x  1
76. Let f : R  R be a function such that f ( x )  . Then
x2  1
(a) f ( x) is many-one in (, 1) (b) f ( x) is one-one in (, )
(c) f ( x) is many-one in (1, ) (d) f ( x) is one-one in [1, ) but not in (, )
77. If P is a 3  3 real matrix such that PT  aP  (a  1) I , where a  1 , then
1
(a) | adj P | 1 (b) | adj P |  (c) P is a singular matrix (d) | adj P | 1
2
78. A box open from top is made from a rectangular sheet of dimension a  b by cutting
squares each of side ' x ' from each of the four corners and folding up the flaps. If the
volume of the box is maximum, then ' x ' is equal to
a  b  a 2  b 2  ab a  b  a 2  b 2  ab
(a) (b)
6 12

a  b  a 2  b 2  ab a  b  a 2  b 2  ab
(c) (d)
6 6

79. A cone is made from a circular sheet of radius 3 by cutting out of a sector and giving
the cut edges of the remaining piece together. The maximum value of attainable for the
cone is
  2
(a) (b) (c) (d) 3 3
3 6 3
80. The height of a right circular cylinder of maximum volume inscribed in a sphere of
radius 3 is
2
(a) 6 (b) 3 (c) 2 3 (d) 3
3
SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answ er any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: + 4 for correct answ er, -1 in all other cases.

81. The lengths of the sides of a triangle are 10  x 2 , 10  x 2 and 20  2 x 2 . If for x  k , the
area of the triangle is maximum, then 3k 2 is ___________

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82. The sum of the maximum and minimum values of the function f ( x ) | 5 x  7 |  [ x 2  2 x ]

in the interval  , 2 , where [t ] is the greatest integer  t is _______

5
4 
4 1
83. The minimum value of  for which the equation    has at least one
sin x 1  sin x

solution in  0,  is _________
 2 

84. A wire of length 36 m is cut into two pieces, one of the pieces is bent to form a square
and the other is bent to form a circle. If the sum of the areas of the two figures is

minimum, and the circumference of the circle is k (meter), then   1 k is equal to
4
  

_________
85. If a rectangle is inscribed in an equilateral triangle of side length 2 2 as shown in the
figure, then the square of the largest area of such a rectangle is ____________

86. If p( x) be a polynomial of degree three that has a local maximum value 8 at x  1 and a
local minimum value 4 at x  2 , then | p(0) | is __________
87. Let  ,  (   ) be the roots of the quadratic equation x 2  x  4  0 . If Pn   n   n ,

P15 P16  P14 P16  P152  P14 P15

n  N , then is ________
P13 P14

88. The number of distinct real rots of the equation 3 x 4  4 x3  12 x 2  4  0 is ____

89. Let the function f ( x)  2 x 2  log e x , x  0 be decreasing in (0, a) and increasing in (a, 4) .
A tangent to the parabola y 2  4ax at a point P on it passes through the point (8a,8a  1)

but does not pass through the point   , 0  . If the equation of the normal at P is
1
 a 
x y
  1 , then    is equal to ______
 

90. If (20)19  2(21)(20)18  3(21) 2 (20)17  ...  20(21)19  k (20)19 , then k is _________

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