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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based

PHYSICS

1. When a proton and an α-particle accelerate under the same potential difference, the ratio of their

de-Broglie wavelengths is m . Find the value of m.

2. If radius of first Bohr orbital of H-atom is 0.6 nm then find the radius of third Bohr orbital of He+
atom.

3. If a particle of mass 100 g is projected at an angle 45° with the horizontal having a speed of 20
m/sec. Then find the angular momentum of the particle at t = 2 sec. about point of projection.

4. The time taken by a block to move down on a rough incline surface is n times the time taken by
the block on a smooth surface of same inclination ( θ = 45°). Find the value of coefficient of kinetic
friction of the surface.

5. A charge q = 2 ×10–2 C is taken from a point P (1, 2, 0) to the point S (0, 0, 0) in the presence of an
uniform electric field of magnitude E = 20 N/C along the +ve x-axis. Find the work done by
electrostatic force.

6. There are two types of radioactive material A and B in a sample. Molecular weight of A is
32 gm/mole and of B is 16 gm/mole. Half-life of A is one day and of B is half day. If initial amount
of both A and B is 320 gm each. Find the total number of atoms present in the sample after
2 days.

7. What is the modulation index, if given that Amax = 14 and Amin = 6 ?

8. A constant force is acting on a block for 20 seconds. After removing the force, block covers 50 m
distance in next 10 seconds. What will be the acceleration of block during first 20 seconds.

2
 B
9. Equation of a circle is given by x2 + y2 = a2. If another equation is given by (x − At)2 +  y −  =a2
 t 
then find the dimensions of A and B. (x and y are in meter and t in sec.)

10. A particle is moving in a circle whose centre is at origin. Its velocity at x = 2 m is −4j . If the speed
of the particle is constant, then find its velocity and acceleration at x = –2 m.

11. A current carrying circular loop has four turns and magnetic field at the centre of this loop is
32 T. Now, same loop rewound and makes it loop of one turn. Find magnetic field at the centre of
this new loop.

12. A square loop of area 25 cm2 and resistance 10 Ω is pulled with constant velocity from a region of
a uniform magnetic field 40 T perpendicular to it. If time taken to pull out the loop out of the
magnetic field is one second, then find the value of work done by external agent.

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based

13. Statement – 1 : Electro Magnetic Wave does not get deflected when passed through electric field
and magnetic field.
µ0
Statement – 2 : EO = BO .
∈o
(1) Statement-1 is true and Statement-2 is true
(2) Statement-1 is false and Statement-2 is false
(3) Statement-1 is true and Statement-2 is false
(4) Statement-1 is false and Statement-2 is true

14. What will be the truth table for the given arrangement?
A

α+5
15. At 300 K, RMS speed of an ideal gas molecule is times the average speed of gas molecule,
α
then value of α is equal to (take π = 22/7)

16. In a potentiometer, when a shunt of 5Ω is connected parallel to the non-ideal battery, the null
point is at 200 cm. If a shunt of 15Ω is used, then the null point is at 300 cm. Find the value of
internal resistance of the battery.

17. Time period of a satellite revolving in an orbit of radius R is 24 hours. If the radius is decreased to
1/4th time of the initial radius of the orbit, then the new time period is:

18. A man pulls a block as shown: Pull


Consider the following statements:
1. Work done by the gravity on block is positive.
2. Work done by the gravity on block is negative.
3. If man pulls block with constant speed, then tension in the string
equals to weight of the block. m
4. None of these

19. A force F = – 40x acts on a particle of mass 1 kg, where x is the position of the particle. If maximum
speed of the particle is 4 m/s during its entire motion, find amplitude of the motion (All parameters
are in SI units).
1 2 3 4
(1) m (2) m (3) m (4) m
10 10 10 10

20. RMS current in circuit (a) is Ia while current in circuit (b) is Ib then:
4Ω 3Ω 5Ω

4Ω

~ ~
220 V, 50 Hz 220 V, 50 Hz
(a) (b)

(1) Ia > Ib (2) Ia < Ib (3) Ia = Ib (4) none of the above

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based

CHEMISTRY
1. Which of the following is sulphide ore
(1) Siderite (2) Calamine
(3) Malachite (4) Sphalerite


2. LiNO3 →?
(1) Li2O (2) NO2 (3) O2 (4) NO

3. Number of acidic oxide among the following


N2O3, NO2, N2O, NO, CO, Cl2O7, SO2, SO3

4. If bohr radius of H-atom in ground state is 0.6 Å, find out bohr's radius of He+ ion in 3rd orbit
(1) 2.7 Å (2) 0.9 Å (3) 5.4 Å (4) 1.8 Å

5. In which of the given molecules, dehydrohalogenation forms maximum number of isomers


(excluding rearrangement)

Br
(1) (2) Br

Br
(3) (4)
Br

6. Which of the following complexes has zero spin only magnetic moment?
(1) [FeF6]3– (2) [CoF6]3– (3) [Co(C2O4)3]3– (4) [Fe(H2O)6]3+

7. If propanamide is reacted with Br2/KOH it gives


(1) Ethyl nitrile (2) Propanamine
(3) ethyl amine (4) Propane nitrile

8. Which of the following diseases can be cured by equanil drug


(1) Pain (2) Stomach
(3) Depression (4) Hyperacidity

9. Compare the bond order of the following molecules


O22− , NO, CO

(1) O22− > NO > CO (2) O22− > CO > NO

(3) CO > NO > O22− (4) NO > CO > O22−

10. What is the colour of CrO5


(1) Yellow (2) Green (3) Blue (4) Orange

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based
11. Statement I: Ionisation enthalpy difference from B to Al is more than of Al to Ga
Statement II: Ga has completely filled d-orbital
Choose the correct option from the following
(1) Both statement-I and statement-II are correct
(2) statement-I is correct and statement-II are correct
(3) statement-I is correct and statement-II are incorrect
(4) Both statement-I and II are incorrect

12. Which of the following relation is correct


(1) ∆G = ∆H – T ∆S: at constant T & P
(2) ∆U = ∆H + nRT (For n moles of ideal gas)
(3) P∆V = (∆n)RT
(4) none of these

13. Match the correct column

Column - I Column - II
(a) Thermosetting (p) Neoprene
(b) Thermoplastic (q) Polyester
(c) Elastomer (r) Polytyrene
(d) Fibre (s) Urea formaldehyde resin

(1) a-p, b-r, c-q, d-s (2) a-s, b-r, c-p, d-q
(3) a-s, b-q, c-p, d-r (4) a-p, b-s, c-r, d-q

14. Denticity of Fehling reagent?

KCN MeMgBr(excess)
15. 
EtO−H/H O+
→ (A) 
H O+
→B
3 3
Cl
OH OH OH
CH3
C C CH3
(1) (2)
H
OHCH3
Cl Cl
O OH O
CH3
C CH3 C—CH3
(3) (4)
CH3
Cl Cl

απ
16. At 300 K, the ratio of Vrms and Vavg of oxygen molecule is
α+5
The value of α will be:
(1) 1 (2) 2 (3) 3 (4) 4

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based
17. BOD value of drinking water ranges between?
(1) 3 - 5 (2) 10 - 13 (3) 14 - 17 (4) 20 - 22

18. A 1 : 1 (by mole) mixture of A and B is passed to a container. Molar mass of A is 16 g, and molar
mass of b is 32 g. And the half life of A is 1 day and half life of B is ½ day. Then find the average
molar mass of the remained mixture after 2 days.

19. Match the column

Column - I Column – II
(i) Electro (p) Solvent moves from lower
osmosis concentration to higher
concentration of solution
(ii) Electrophoresis (q) Solvent moves from higher
concentration to lower
concentration of solution
(iii) RO(reverse (r) Dispersion medium moves
osmosis) towards oppositely charged
electrodes across semi-
permeable membrane
(iv) Osmosis (s) colloidal particles moves in
the presence of electric field

(1) i-(s), ii-(r), iii-(p), iv-(q)


(2) i-(r), ii-(s), iii-(p), iv-(q)
(3) i-(q), ii-(p), iii-(r), iv-(s)
(4) i-(r), ii-(s), iii-(q), iv-(p)

20. Find the major product

H3O⊕

OH

(1) (2)

(3) (4)

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based
O
C 1. KOH
2. CH3 —CH2 —Br
21. NH 
3. NaOH(aq)

C
O
COO–Na+
(1) CH3—CH2—NH2 and
COO–Na+
A B
O–Na+
(2) CH3—CH2—NH2 and
COO–Na+
A B
O
O
C
(3) CH3—CH2—C—OH and O
C
O
A B
O
NH2
(4) CH3—CH2—C—OH and
NH2
A B

22. The number of voids in 0.02 moles of a solid which forms HCP lattice is?
[Given: nA = 6 × 1023]
(1) 3.6 × 1022 (2) 3.6 × 1024 (3) 7.2 × 1020 (4) 5.4 × 1026

23. The ratio of de-broglie wavelength of proton to that of α-particle, if they are accelerated through
same potential is given as
(1) 2 2 : 1 (2) 2 : 1 (3) 1 : 2 2 (4) 2:1

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based

MATHEMATICS

1
1. If z ≠ 0 be a complex number such that z − 2, then find maximum value of |z|.
=
z
1
2
tan−1 x
2. Find the integral I = ∫
2
x
dx :

3. Find rank of word 'TOUGH' according to the rule of dictionary :

4. If (cos22x – 2sin4x – sin2x) = λ then find the interval in which λ lies :


(1) [–1, 0] (2) [– 2, 1] (3) [– 2, 0] (4) None of these

5. Find the number of three digit numbers which are divisible by 3 and 4 but not 48 :

1 1
6. If f(1) = 1, f(1) + 2f(2) + …….. + nf(n) = n(n + 1) f(n + 1). ∀ n ∈ N then find + .
f ( 2022 ) f ( 2028 )

2
t6 + 1
7. Find the definite integration ∫t
1
4
+1
dt :

x − 1 2y − 2 z − 3 x−2 y −1 z+2
8. Find the shortest distance between the lines= = and = =
2 3 1 3 2 4

9. A line x + y = 3 cuts a circle having centre (2, 3) and radius 4 at two points A and B. If the tangents
at A and B are drawn which intersect at a point S(α, β). Find the value of 4α – 7β.

10. Let x = 11, 12, …… 40, 41


y = 61, 62, ……… 90, 91

here σ2 variance of ( x ∪ y ) . Then value of σ2 − x − y where :

11. Number of four-digit natural numbers n such that, gcd (n, 52) = 2.

12. R = {(a, b) : 2a + 3b is divisible by 5 and a, b∈N}, then the relation is :


(1) Transitive but not symmetric (2) Equivalence
(3) Symmetric but not transitive (4) Not equivalence

dy
13. A function follows the differential equation xlogex= + y x2 log e x, x ≥ 1, then y(e) is :
dx
e2 e2 − 1 e2 + 1 1
(1) (2) (3) (4)
4 4 4 4

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JEE(Main)-2023 | 29 January 2023 (Shift-2 Evening) | Question Paper | Memory Based

14. The sum of coefficients of odd powers of “x” in the expansion of (1 + x)99 is K. The middle term in
200 200
 1  C99K m
the expansion of  2 +  is α. If = 2 . i . m, n are odd the (, n) is
 2 α n
(1) (50, 101) (2) (49, 101) (3) (51, 101) (4) (50, 99)

15. A → (  AVB ) is equivalent to :


(1) AVB (2) A → B (3) B → A (4)  AΛB

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