San Rank en Test-Ph5-P2

FIITJEE SANKALP RANK ENHANCEMENT TEST
SERIES
PHYSICS, CHEMISTRY & MATHEMATICS
(PAPER-2)
Time: 3 Hours Maximum Marks: 183
INSTRUCTIONS
A. General
1. Read all instructions carefully. Check total pages and no. of questions of your booklet in each subject.
2. Write your Name, Enrolment number, Examination Centre, Question paper code, Batch code, Examination
session in the boxes provided for STUDENT INFORMATION.
3. Darken the appropriate bubble under each digit of enrolment number, question paper code written by you on
the OMR sheet.
B. Question Paper Format
The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of
three sections.
4. Section – 1 contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE is correct.
5. Section – 2 contains 7 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE THAN ONE are correct.
6. Section – 3 contains 2 paragraphs each describing theory, experiment and data etc. Four questions relate
to two paragraphs with two questions on each paragraph. Each question pertaining to a particular passage
should have ONLY is correct answer among the four given choices (A), (B), (C) and (D).
C. Marking Scheme
7. For each question in Section – 1 you will be awarded 3 marks if you darken only the bubble corresponding to
the correct answer and zero mark if no bubble is darkened. In all other cases, minus one (1) mark will be
awarded.
8. For each question in Section – 2, you will be 4 marks if you darken only the bubble(s) corresponding to all
the correct option(s) is(are) darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
For example, if [A], [C] and [D] are all the correct options for a question, darkening all these three will get
+4 marks; darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get 2 marks, as a
wrong option is also darkened.
9. For each question in Section – 3, you will be awarded 3 marks if you darken only the bubble corresponding
to the correct answer and zero mark if no bubble is darkened. No negative marks will be awarded from
incorrect answer in this section.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
SANKALP RANK ENHANCEMENT TEST SERIES-Paper-2 (Ph-5)-PCM (000000.1)-2
PART I: PHYSICS
SECTION – 1 (Single Correct Type)
This section contains 7 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D). ONLY ONE of these four options is correct.
1. Two mirrors M1 and M2 make an angle  with line AB. A M1

b Surface
point source S is kept at a distance r from the point of
 Sc
intersection of mirrors. A small hemispherical annular r b
mask is kept close to S so that no ray emanating from S A B
 S
directly reaches the screen kept at a distance b from the
hemispherical
source. Interference pattern of rays reflected from M1 and annular mask
M2 is observed on the screen. Find the fringe width of this
interference pattern.  = wavelength of light being emitted
by source.
(b  2r sin2  ) (b  2r cos 2)
(A) (B)
2r sin2 2r sin 2
(b  r cos 2) (b  2r cos 2)
(C) (D)
2r sin2 r sin2
2. A ray of light, travelling parallel to diameter of a sphere enters the sphere

through a hole at point A as shown in the figure. The inner surface of the 9
sphere is made perfectly reflecting. Find the number of reflections
suffered by the ray before coming out of the sphere.
(A) 180 (B) 20
(C) 179 (D) 19
3. ABC is an equilateral metal wire frame of side length 0 kept in uniform A
magnetic field of strength B. The coefficient of linear expansion of the B

metal frame is . If the temperature of the wire frame slowly changes
according to the equation T = T0 sin t and total resistance of circuit is
R, then the charge flown through the wire in first quarter cycle is
3 B 0 T0
2
3 B 20 T0 B C
(A) (B)
8 R 4 R
3 B 0 T0
2
3 B 20 T0
(C) (D)
5 R 2 R
Space for rough work
4. In the circuit, as shown in the figure, if the r.m.s. current is 100  C

2.2 ampere, the power factor of the box is
1/ Henry
1
(A) (B) 1 Box
2
3 1
(C) (D)
2 2 Vrms = 220 volt,  = 100 s1
0
5. Radiation of wavelength (0 being the threshold wavelength) is incident on a photosensitive
3
metallic sphere of radius R. The charge developed on the sphere when electrons cease to be
emitted will be
40Rhc 60Rhc
(A) (B)
e 0 e 0
80Rhc 120Rhc
(C) (D)
e0 e 0
6. In a hypothetical atom, potential energy between electron and proton at distance r is given by
 -ke2 
 3  , where k is constant. Suppose Bohr theory of atomic structure is valid and n is principle
 4r 
quantum number, then total energy E is proportional to
(A) n5 (B) n7
6
(C) n (D) n4
7. Two resistances are measured in Ohm.

R1 = 3  1%
R2 = 6  2%
When they are connected in parallel, the percentage error in equivalent resistance is
14
(A) % (B) 1%
3
4
(C) 2% (D) %
3
SECTION – 2 (One or More Than One Type)

and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct.
8. Hydrogen atoms absorbs radiation of wavelength 0 and consequently emit radiations of 6

different wavelengths of which three wavelengths are shorter than 0.
(A) The final excited state of the atoms is n = 4
(B) The initial state of the atoms may be n = 2
(C) The initial state of the atoms may be n = 3
(D) There are three transitions belonging to Lyman series.
9. X ray from a tube with a target A of atomic number Z shows strong K lines for target A and weak
K lines for impurities. The wavelength of K lines is z for target A and 1 and 2 for two impurities.
z  1
 4 and z  .
1 2 4
Screening constant of K lines to be unity. Select the correct statement(s)
(A) The atomic number of first impurity is 2z – 1.
(B) The atomic number of first impurity is 2z + 1.
(z  1)
(C) The atomic number of second impurity is .
2
z
(D) The atomic number of second impurity is  1 .
2
10. A resistor R is connected in series with an inductor coil having some unknown resistance. The
system is subjected to an A.C. supply of peak value V0. If peak voltage dropped across the
resistor R and the inductor coil are V1 and V2 respectively. Then
V2
(A) Average power dissipated in the resistor R is 1 .
2R
(B) Average power dissipated in the resistance of coil is

V02  V12  V22.

4R
V 2  V12  V22
(C) Average power dissipated in series combination is 0 .
4R
(D) Resistance of the coil is

V 2
0  V12  V22 R .
2V12
11. In a YDSE set up the separation between the slits is 3  103 m. The distance between the slits
and the screen is 1.5 m. Light of wavelength in the visible range (4000Å – 8000Å) is allowed to
fall on the slits. The wave length in the visible region that will be present on the screen at a
distance of 1.5  103 m from central maxima is
(A) 4285.7Å (B) 5000 Å
(C) 6000 Å (D) 7500Å
12. Carefully analyse the diagram and choose the correct option(s)
(A) Spherical (B) Spherical

wavefront wavefront
Focus Focus
Lens Lens
Plane Plane
wavefront wavefront
(C) Spherical (D) Spherical
wavefront wavefront
Focus Focus
Lens Lens
Plane Plane
wavefront wavefront
13. Which of the following statement(s) is/are correct.

(A) A plane mirror cannot form real image of real object.
(B) A ray of light gets reflected successively from two mirrors which are mutually perpendicular,
net angular deviation suffered by the ray does not depend upon angle of incidence of first
mirror.
(C) When a glass prism is completely submerged in water then its dispersive power increases.
(D) Refractive index of a material does not depend upon wavelength of light.
14. Read the following statements

(A) 12300 has only 3 significant digits
(B) 1.2300 × 104 has only 5 significant digits
(C) 0.012300 × 106 has only 3 significant digits
(D) Trailing zeroes are not significant
SECTION – 3 (Paragraph Type)

This section contains 2 questions. Based on each paragraph, there will be TWO questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
Paragraph for Question Nos. 15 and 16
A square loop, consisting of an inductor L and a

capacitor C is placed between two long parallel
wires each carrying time varying current of L
magnitude I = I0sin(t) in opposite directions as
shown in the figure. Based on the above I = I0 sin (t) C
I = I0 sin (t)
informations answer the following questions.
a a a
15. The magnetic flux due to the magnetic field produced by the long parallel wires through the
square loop is
 I a n(2) sin( t)  I a n(2) sin( t)
(A) 0 0 (B) 0 0
2 
 I a n(3) sin( t)  I a n(3) sin( t)
(C) 0 0 (D) 0 0
2 
16. The function of current through the square loop is

 0I0 an2    0I0 an2  
(A) cos  t   (B) cos  t  
 1   2  1   2
  L   2  L  
  C    C 
 0I0 an2    0I0 an3  
(C) cos  t   (D) cos  t  
 1   2  1   2
  L    L 
 C   C 
Paragraph for Question Nos. 17 to 18

Two coherent point light sources frequency are placed at x = -d/2 and x = d/2. These sources are
2 2 2 2
surrounded by a spherical screen having equation x + y + z = R (where R >> d). The sources emit
monochromatic light of wavelength  ( = d/3).
Waves from both the sources reach screen and superimpose. When waves reaching any point on the
screen have a constant path difference of n (where  is wavelength of light and n is some integer), the
superposition of these waves is constructive in nature (i.e. maximum intensity) n may be called as order
of maximum.
17. The number of maximas on the screen

(A) 7 (B) 12
(C) 6 (D) none of these
18. As screen is a bounded one therefore the length of maxima is finite which of the following data
are correct about shape and length of second order maxima
2R 5 2R 5
(A) hyperbola, (B) circle,
3 3
2R 2R
(C) hyperbola, (D) circle,
3 3
PART II: CHEMISTRY

SECTION – 1(Single correct type)
This section contains SEVEN questions. Each question has FOUR options (A), (B), (C) and (D). ONLY
ONE of these four options is correct.
1. 1.3245 g of a monobasic acid when dissolved in 100 g of water lowers the freezing point by
0.2046oC. 0.2 g of the same acid when dissolved and titrated required 15.1 ml of N alkali.
10
-1
(Assuming molarity = molality), the pH of acid solution is: (Kf of water 1.86 K kg mol )
(A) 1 (B) 2
(C) 3 (D) 4
2. Which of the following complex is optically inactive ?

+ +
(A) Cis[CoCl2(en)2] (B) Trans[CoCl2(en)2]
2– –
(C) Cis[PtCl2(NH3)2(Py)2] (D) [Co(EDTA)]
3. Which of the following complex is not matched with its property?

(A) [PtCl4]2– - square planar (B) [PdCl4]2– - diamagnetic
4–
(C) [Fe(CN)6] - high spin complex (D) [FeF6]4– - Effective atomic number = 36
4. If a current of 10 mA be passed through AgNO3 solution using platinum electrode for one minute
to produce 0.638 mg silver, the current efficiency would be
(A) 60% (B) 80%
(C) 95% (D) 100%
5. Calomel when heated with liquid ammonia gives a black coloured precipitate. Black colour ppt. is
due to:
(A) Hg (B) Hg(NH2)Cl
(C) Hg + Hg(NH2)Cl (D) Hg + Hg2(NH2)2
6. The incorrect statement among the following is

(A) N2O is a neutral oxide.
(B) NO2(g) is paramagnetic and dimerises in the liquid state.
(C) ClO2(g) is paramagnetic and dimerises on cooling.
(D) I2Cl6 is a planar molecule in the solid state.
7. Which of the following precipitate is soluble in yellow ammonium sulphide ?

(A) HgS (B) PbS
(C) SnS (D) CuS
SECTION – 2 (One or More than one correct type)

This section contains SEVEN questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four option(s) is(are) correct.
8. Among the following statements which is/are correct

(A) Calamine and Siderite are carbonate ores.
(B) Argenite and Cuprites are oxide ores.
(C) Malachite and Azurites are ores of Cu.
(D) Carnallite and Sylvite are chloride ores.
9. Which of the following formulae is/are valid for potash alum? ( eq is equivalent conductance at
infinite dilution)
1 3
(A)

eq.  alum   eq.  K    eq.  Al3   eq. SO 42 
4 4
 
(B) m  alum   8eq.  alum 
1 1 1
(C)

eq.  alum   eq.  K    m  Al3   m SO 42 
4 3 4
1   3  1 
(D) eq.  alum   m  K   m  Al   m  SO 4 
 3 2
2 2 4
10 All metal sulphides reacts with sod. Nitroprusside to give purple coloured solution of
sod.thionitroprusside.
Na2 S  Na2 Fe  CN5 NO   
 Na 4 Fe  CN 5 NOS  
A  B 
Identify the correct statement(s) regarding the complexes (A) and (B):
(A) Oxidation state of Fe in both the complexes A and B is +2
(B) The above reaction is a redox reaction
(C) IUPAC name of ‘A’ is sod.pentacyanonitrosoferrate(III)
(D) IUPAC name of ‘B’ is sod.pentacyanothionitrosoferrate(II)
11. Boiling point of a solution containing 6.6625 g of a complex (CrCl3.6H2O) in 100 g of water is
o -1 -1
found to be 100.52 C if Kb and Kf of water are 0.52 K kg mol and 1.86 K kg mol respectively,
select the correct statement (s) out of the following: (At. Wt. Cr = 52, Cl = 35.5)
o
(A) freezing point of the solution is – 1.86 C
o
(B) V. P. of the solution at 100 C will be 0.98 atm
(C) 1 mole of this complex reacts completely with 3 moles of AgNO3 solution to form a white
precipitate soluble in liquid ammonia
(D) complex is capable of showing stereo isomerisation
12. Which of the following reaction is/are correct ?

(A) 3HgCl2  2PH3  Hg3P2  6HCl
(B) P4  8SOCl2  4PCl3  4SO2  2S2 Cl2
(C) PCl5  H2O  POCl3  2HCl

(D) 3NaN3  Na3N  4N2
13. The reaction in which N2(g) is produced is/are

 
(A) Ba(N3 )2   (B) (NH4 )2 Cr2O7  
 800C
(C) NH4 Cl(aq)  NaNO 2 (g)   (D) NaNO3 
14. In which of the following reaction(s) one or more than one product is acidic in nature:
(A) NCl3  3H2O .........  ......... (B) CaNCN  3H2O  ........  ......
(C) KNO3  s   K  s  .......  ....... (D) 2NH3  NaOCl ........  ........  .......

This section contains TWO paragraphs. Based on each paragraph, there are TWO questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct.
A white compound (A) on strong heating decomposes to produce two products (B) and (C). (B) on
reaction with white phosphorus produces (D) which is a strong dehydrating agent. (D) on reaction with
perchloric acid converts it to its anhydride.
15. The compound (A) is

(A) NH4NO2 (B) NH4ClO4
(C) (NH4)2Cr2O7 (D) NH4NO3
16. The no. of moles of H2O needed to hydrolyse 1 mole of D is

(A) 10 (B) 4
(C) 6 (D) 2
Benzene and toluene form an ideal solution. The vapour pressure of pure benzene and toluene are 0.12
bar and 0.04 bar, respectively at 300 K. A liquid mixture composed of 1 mole, each of benzene and
toluene.
17. What is the vapour pressure of the solution composed of 1 mole each of benzene and toluene at
300 K?
(A) 0.16 bar (B) 0.08 bar
(C) 0.10 bar (D) 0.09 bar
18. What is mole fraction of benzene in first trace of vapour formed

(A) 0.50 (B) 0.67
(C) 0.75 (D) 0.89
PART III: MATHEMATICS

SECTION – 1 (Single correct type)
and (D). ONLY ONE of these four options is correct.
1. 5 different games are to be distributed among 4 children randomly. The probability that each child
get atleast one game is
1 15
(A) (B)
4 64
21
(C) (D) none of these
64
     
2. If a, b, c , are three nonzero vectors, no two of which are collinear, a  2b is collinear with c
     
and b  3c is collinear with a , then | a  2b  6c | will be equal to
(A) Zero (B) 1
3. A plane passing through (1, 1, 1) cuts positive direction of co-ordinate axes at A, B and C the
volume of tetrahedron OABC satisfies
9 9
(A) V  (B) V 
2 2
9
(C) V = (D) none of these
2
 3 1 
 
4. Let A =  2 2  , B =  1 1 and C = ABAT, then ATC3A is equal to
 
 1 3 0 1
 
 2 2 
 3 1  1 0
(A)   (B)  3 
 2 2  1
 1 0   2 
 3
1 1 3
(C)  2 
 (D)  
 0 1
0 3 
d 1
5. Let f(x) = (2x  )3 + 2x  cosx. The value of f (x) is
dx x 
(A) 32 + 2 (B) 2

1 1
(C) 2
(D)
3  2 3
6. Area bounded by the curves y = [x2/64 + 2], y = x – 1, and x = 0 above x – axis is: ([.] GIF)
(A) 2 (B) 3
x3 x4 x

7. If x  4 x  5 x   = 0, where , ,  are in A.P. , is
x5 x6 x
(A) an identity in x (B) an equation whose all roots are real
(C) an equation with only one real root (D) None of these
SECTION – 1 (One or more than one type)
and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct.
8. K subsets of a set A  {1, 2, 3, …, n} are chosen at random with replacement. The probability that
their intersection is
n n
 1 3
(A) empty is   for K = 2 (B) empty is   for K = 2
2 4
n n 1
7 7
(C) empty is   for K = 3 (D) singleton is n   for K = 3
8 8
   
9. Let a, b and c are three mutually perpendicular unit vectors and a unit vector r satisfying the
            
equation  b  c    r  a    c  a    r  b    a  b    r  c   0 , then r is
1    1    
(A) abc (B)  2a  3b  c 
3 14
1     
(C) 2a  3b  c  (D) 
1  a  b  c 
14 3
10. The nature of the intersection of the set of planes :

2x  4y + 2z = 5,
5x  y  z = 8 and
x+yz=7
is / are that
(A) they form a triangular prism
x y z
(B) each of the plane is parallel to the line  
1 2 3
(C) they intersect at a unique point
x y z
(D) they pass through the line   .
1 2 3
11. The volume of the parallelopiped whose coterminous edges are represented by the vectors
      
2b  c, 3c  a and 4a  b where a  2 1  sin   i  cos j  sin2k ,
 
  2    2    4  
b  sin     i  cos    3  j  sin  2  3  k ,
 3     
  2   2    4  
c  sin    i  cos    j  sin  2  k is 18 cubic units, then the values of  , in the
 3   3   3 
 
interval  0,  , is/are
 2
 2
(A) (B)
9 9
 4
(C) (D)
3 9
a b c 
12. If the matrix A  b c a  where a, b, c are positive real number such that abc = 1 and ATA = I.
c a b 
Then find the value of a3 + b3 + c3
x2  4 sin2x
(A) lim 2 (B) lim
x 2 x  3x  2 x 0 log 1  x 
e
x x
cos  sin
x 2 2
(C) lim (D) 4 lim
x  0 1  x   1 x0 cos x
13. Let A, B, C be nn real matrices and product is pair wise commutative also ABC = On, if  =
det(A3 + B3 + C3). det (A + B + C) then
(A)  > 0 (B)  < 0
(C)  = 0 (D)   (-, ) – {0}
3/2
2 2 2
  dy 2 
d2 y
14. If (x – a) + (y – b) = c , then c 2  1     is dependent on
dx   dx  
(A) a (B) b
(C) c (D) none of these
This section contains 2 questions. Based on each paragraph, there will be TWO questions. Each
question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is correct
A ray of light is coming along the line L = 0 and strikes the plane mirror kept along the plane P = 0 at B.
A(2, 1, 6) is a point on the line L = 0 whose image about P = 0 is A. It is given that L = 0 is
x  2 y 1 z  6
  and P = 0 is x + y – 2z = 3.
3 4 5
15. Co-ordinates of A are

(A) (6, 5, 2) (B) (6, 5, – 2)
(C) (6, – 5, – 2) (D) none of these
16. If L1 = 0 is the reflected ray, then its equation is

x  10 y  5 z  2 x  10 y  15 z  14
(A)   (B)  
4 4 3 3 5 5
x  10 y  15 z  14
(C)   (D) none of these
4 5 3
B and C are the only two people who will enter the Lady Gaga Jingle contest. Only one entry is allowed
per contestant and the judge will declare the one winner as soon as he receives a suitably inane entry,
which may be never. B writes inane jingles rapidly but poorly. He has probability 0.7 of submitting his
entry first. If C has not already won the contest, B’s entry will be declared the winner with probability 0.3.
C writes slowly, but he has a gift for this sort of thing. If B has not already won the contest by the time of
C’s entry, C will be declared the winner with probability 0.6.
17. What is the probability that B will win?

(A) 0.24 (B) 0.142
(C) 0.18 (D) 0.246
18. Given that B wins, what is the probability that C’s entry arrived first?
(A) 0.146 (B) 0.124
(C) 0.28 (D) 0.236
FIITJEE SANKALP RANK ENHANCEMENT TEST

SERIES
PHYSICS, CHEMISTRY & MATHEMATICS
(PAPER-1)
ANSWERS
PHYSICS (PART-I)
1. A 2. D 3. D 4. A
5. C 6. C 7. D 8. A, B, D
9. A, C 10. A, B, C, D 11. A, B, C, D 12. A, D
13. A, B, C 14. A, B 15. B 16. A
17. A 18. B
CHEMISTRY (PART-II)
1. B 2. B 3. C 4. C
5. C 6. C 7. C 8. A, C, D
9. A, B 10. A, D 11. A, B, C 12. A, B, C
13. A, B, C, D 14. A, C 15. D 16. C
17. B 18. C
MATHEMATICS (PART-III)
1. B 2. A 3. B 4. D
5. D 6. C 7. A 8. B, C
9. A, D 10. A, B 11. C 12. A, D
13. A, C 14. D 15. B 16. C
17. D 18. A
HINTS AND SOLUTION
PHYSICS (PART-I)
1. A
All light rays hitting the screen will be appearing to be S1
r sin 
coming from S1 and S2
2
 D = b + 2r sin   r sin 
90
d = 4r sin cos  r
D 
fringe width = 90
d
S2
2. D
Path traced by rays will be a regular polygon with
angle 18°. Side of polygon will substend angle 9
(180° – 18°) at centre. 9
(180°– 18°) n = 360 k where n, k are integers
9n = 20 k
20
n .k
9
Minimum value of n is 20.
No. of reflections suffered by ray before coming
out of sphere is (20 – 1) = 19.
3. D
d BdA
dq = 
R R
4. A
5. C
6. C
dU mr 2
F=  
dr r
1
r  V  n3
n2
6
En
7. D
36
R   2
36
1 1 1
 
R R1 R 2
dR dR1 dR 2
  2  2
R2 R1 R2
R
% error =  100%
R
 R1 1 R 2 1 
= R  100    100  %
R
 1 R1 R 2 R 2 
 1 1 4
= 2 1  2   % = %
 3 6  3
8. A, B, D
n(n  1) n=4
6  n4
2 3
If the initial state were n = 3, in the emission spectrum, no 2
wavelengths shorter than 0 would have occurred. This is possible if
initial state were n = 2
 (A), (B) and (D)
1
9. A, C
Moseley’s law :
1
 2
(z  1)
 z (z1  1)2

1 (z  1)2
z1 – 1 = (z – 1) 2
z1 = 2z – 1
2
 z 1  z2  1 
   .
2 4  z  1 
10. A, B, C, D
11. A, B, C, D
Here the position y on the screen will correspond to maxima.
n D
y
d
30,000
 when n = 1, 2, 3, 4, …………..
n
12. A, D
Converging lens directs a parallel beam of light to its focus.
13. A, B, C
14. A, B
15. B
16. A
0 2i L C
15-16. d  B  adx  adx
4 x
a  an2 i
   0 i | nx |2a a
 0 i0 sin t
2  ~
dy 0  0 an2
emf =   cos t  K cos t
dt 
  an2 dx
where K = 0 0
 L
1
Z  x L  x C  L  I = I0 sin (t) C
I = I0 sin (t)
C
x
e K  
i  cos  t   eL
Z  1   2
 L  C 
  eL  eC
 0  0 an2    
i  cos  t   i
 1   2
  L 
C 
eC

17. A
As explained in figure the no of maximums are 7.
18. B
R2 = Rsin and (3 cos = 2)= R5/3
2R 5
Length =
3
CHEMISTRY (PART-II)
1. B
Meq. of alkali = Meq. of acid
1 0.2
 15.1   1000
10 M
On, solving M = 132.45 g mol-1
1.3245  1000
Now, molality of acid soln (m) =  0.1
132.45  100
 Tf  i  K f  m
0.2046 = i ×1.86 × 0.1
i = 1.1 = 1 + 
  = 0.1
HA 


 H

 A
Now, C 0 0
C  C C C
[H+] = C = 0.1 × 0.1 = 10-2
pH = 2
2. B
Trans[CoCl2(en)2]+ is optically inactive.
3. C
–
CN being strong field ligand form low spin complex.
4. C
+
Ag (aq) + 1e  Ag(s)
Number of faraday = No. of moles of Ag
10  103  1 60  108
Weight of Ag would be deposited =  0.67 mg
96500
0.638
Current efficiency   100%  95%
0.67
5. C
Hg2Cl2  NH3  Hg  Hg NH2  Cl
 Calomel 
Black ppt.
Hence, (C) is the correct answer.
6. C
ClO2(g) does not dimerise on cooling.
7. C
SnS is soluble in yellow ammonium sulphide.
8. A, C, D
Calamine  ZnCO3 , Siderite  FeCO3 , Argentite  Ag2S , Cuprite  Cu2O , Sylvite KCl
Malachite  CuCO3. Cu(OH)2 , Azurite  Cu(OH)2. 2CuCO3 , Carnallite  KCl. MgCl2. 6H2O
9. A, B
Its n factor is 8
m  alum   eq.

 alum   n factor
2m  K    2m  Al3   4m  SO 42   m  alum 

2eq.  K    2  3eq.  Al3   4  2eq. SO 42   8eq.  alum 
1  3 
eq.  K    eq.  Al3   eq.

 SO 42    eq.

 alum 
4 4
10. A, D
In both the complexes iron is present in +2 oxidation state. So, the reaction can not be redox.
Hence, (A) and (D) is the correct answer.
11. A, B, C
6.6625  1000
m=  0.25
266.5  100
Tb = i × Kb × m  0.52 = i × 0.52 × 0.25  i = 4
Tf = 4 ×1.86 × 0.25 = 1.86o
i = 4 means, one mole of complex gives 4 moles of ions on dissociation. Hence the formula of the
complex is [Cr(H2O)6]Cl3
Hence, (A), (B) and (C) are the correct answer.
12. A, B, C

2NaN3  2Na  3N2
13. A, B, C, D

Ba(N3 )2   Ba  2N2

(NH4 )2 Cr2O7   N2  4H2 O  Cr2 O3

NH4 Cl(aq)  NaNO2 (g)   N2  2H2 O  NaCl
800 C
4NaNO3  2Na 2O  5O2  2N2
14. A, C
(A) NCl3  3H2O  NH3  3HOCl


acidic
(B) CaNCN  3H2O 

 CaCO3  2NH3
(C) KNO3  s   K  s  
 K 2 O  NO 2

Acidic
(D) 2NH3  NaOCl 

N2H4  NaCl  H2O
15. D

NH4NO3   N2 O H2O
(B) (C)
10N2O  P4  P4 O10  10N2

(D)
P4 O10  12HClO4   6 Cl2 O7  4H3PO4

16. C
P4O10 reacts with 6 moles of H2O as it possesses six P–O–P bonds.
P4 O10  6H2O  4 H3PO 4
Solution for the comprehension 17 to18

Benzene and toluene form a ideal binary mixture which follow Raoult’s law.
17. (B)
o
PBenzene  0.12
o
PToluene  0.04
PT  X APAo  XBPBo
= 0.5 × 0.12 + 0.5 × 0.04
= 0.06 + 0.02
PT = 0.08
18. (C)
PAo X A
YA 
PT
0.12  0.5
  0.75
0.08
MATHEMATICS (PART-III)
1. B
Total ways of distribution = 45
5
n(S) = 4
5 4 5 4 5 4
Total ways of distribution so that each child get atleast one game = 4 – C1 3 + C2 2 – C3
= 1024 – 4  243 + 6  32 – 4 = 240
n(E) = 240
n  E  240 15
required probability =  5  .
n S  4 64
2. A
        
a  2b  c and b  3c   a , where a, b and c are non collinear vectors
   
 a  6c  c  2a
 
 a 1  2      6  c
1  
    and  = –6 as a and c are non–collinear.
2
     
 | a  2b  6c |  | 6c  6c | | 0 | 0
3. B
x y z
Let the equation of the plane be   1
a b c
1 1 1
   1
a b c
1
 volume of tetrahedron OABC = v =  abc 
6
3
Now (abc)1/3  3
1 1 1
 
a b c
9
 abc  27  v  .
2
4. D
AAT = ATA = I  AT = A–1
C = ABA–1
A–1C = BA–1
T 3 –1 2 –1 2 –1 3
Now A C A = A (C.C )A = A C(C A) = BA (C)(CA) = B
1 3
=  .
0 1
5. D
d 1
We know f(x) 
dx  f 1 (y)
 
1
 [f 1 (y)]  .
f (x)

For, (2x  )3 + 2x  cosx =   x =
2
d 1 1 1
 f (x) = 2
= .
dx x 0 3(2x  )  2  sin x x   3
2
6. C
y = [x2/64 + 2], y = x – 1 and x = 0 above x-axis is
y
(0, 3)
B
C
(-8, 0) O A (3, 0) (8, 0) x
y=x-1
so required area of trapezium (OABCO)

1
= 1  3  2  = 4.
2
Alternate
-8 < x < 8  y = 2
A=22
= 4 sq. units.
7. A
x3 x4 x
Since x4 x5 x = 0
x5 x6 x
 R  R3 
R2  R2 –  1 .
 2 
x3 x4 x
 
 0  0  =0
 2 
x5 x6 x
But ,  ,  are in A.P. .

=
2
x3 x4 x
 0 0 0 =0 xR
x5 x6 x
 An identity in x .
8. B, C
For K = 2, each element has four possibility and three out of four are favorable for the event.
n
3
Hence required probability =   .
4
n
7
For K = 3, Probability that intersection is empty is  
8
n 1
n 7
For K = 3, Probability that intersection is singleton =  
8 8
9. A, D
  
 b  c    r  a    b  c   a  r   b  c   r  a
           
Now,  b  c    r  a    c  a    r  b    a  b    r  c   0
                     
  b  c   a   c  a   b   a  b   c  r  b  c   r  a   c  a   r  b   a  b   r  c = 0
              
 b  r  c  r  a  c  r  a  r  b  a  r  b  r  c  0
     
 br  cr  ar  
   
also, r  xa  yb  zc
   
 r   a  b  c 
2 1
r  1  3 2  1    
3
 1    
 r  a  b  c .
3
10. A, B
Eliminating z from first and second and then from second and third, we get
4x  2y = 7, 4x  2y = 1, which leads to 0x + 0y = 6
Similarly, eliminating y, we get
6x  2z = 9, 6x  2z = 15, which leads to 0x + 0z = 6.
No, finite values of x, y and z satisfy all, but the obtained equations are limiting form of
x y x z
  6,   6 , as k tends to infinity.
k k k k
So, three planes intersect at an infinite distance.
Let first two planes intersect in a line whose direction cosines are proportional to  , m, n then
2  4m  2n  0 and 5   m  n  0 , from which we get
 m n x y z
  . So, lines of intersection of any two of the planes are parallel to the line   .
1 2 3 1 2 3
Since no two of the planes are parallel, so they form a triangular prism.
11. C
     
Volume = 2b  c,3c  a,4a  b   18
 2  3
24 a b c   18  a b c  
2
1  sin   cos  sin 2

  2    2    4 
Now, abc   sin     cos     sin  2  
   3   3   3 
 2   2   4 
sin     cos    3  sin  2  3 
 3     
Applying R1  R1  R2  R3 we get after simplification ,

abc   3 cos3  3
  2
1  2 4  2 4 
 cos 3    3  , ,   , , .
2 3 3 3 9 9 9
12. A, D
Here, AT = A
 ATA = A2 = I (given)
a b c
We know, b c a    a3  b3  c 3  3abc 
c a b
2 2 2
 A  1   a 3  b3  c 3  3abc   1   a 3  b3  c 3  3   1  abc  1
a3  b3  c 3 1/ 3 3 3 3
  a b c  abc
3
 a3 + b3 + c3  3
 a3 + b3 + c3 – 3  –1
 a3 + b3 + c3 – 3 = 1
 a3 + b3 + c3 = 4
13. A, C
A 3  B3  C3  A 3  B3  C3  3ABC

=  A  B  C  A 2  B2  C2  AB  BC  CA 
=  A  B  C   A  B   C  A   B  C  [ is complex cube root of unity]
2 2
=  A  B  C   A  B   C  A  B   C 
2 2
thus det(A3 + B3 + C3).det(A + B + C)

det(A + B + C)2.det(A + B + 2C)det A  B  2C  
2 2

=  det  A  B  C   . det A  B  2C  0.
14. D
The parametric equation of the curve is
dx
x = a + c cos  = – c sin
d
dy
y = b + c sin  = c cos
d
dy
 = – cot.
dx
d2 y 1 d2 y
Now,  cos ec 2   c 2   cos ec 3 
dx 2 c sin  dx
3/2
  dy 2 
d2 y
 c 2  1       cos ec 3   cos ec 3   0 .
dx   dx  
15. B
Let A(x2, y2, z2) be image of A(2, 1, 6) about mirror x + y – 2z = 3 then
x 2  2 y 2  1 z 2  6 2  2  1  12  3 
   =4
1 1 2 12  12  22
 (x2, y2, z2)  (6, 5, – 2).
16. C
Equation of reflected ray L1 = 0 is
line joining A(x2, y2, z2) and B(– 10, – 15, – 14)
x  10 y  15 z  14
i.e.  
16 20 12
x  10 y  15 z  14
   .
4 5 3
17. D
18. A
17–18. B1: B submits his entry first

C1: C submits his entry first
Bw: B’s entry wins
Cw: C’s entry wins
Bw 0.21
0.3
0.6 Cw 0.294
B1
0.7 0.7 Bw
0.4 Cw 0.196
Entry
Cw 0.18
0.6
0.3 Bw 0.036
C1
0.4 Cw
0.7 Bw 0.084
17. P(B will win) = 0.21 + 0.036 = 0.246.
18. P(C’s entry arrived first/ B wins)

0.036
=  0.1463 .
0.246

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FIITJEE SANKALP RANK ENHANCEMENT TEST

Time: 3 Hours Maximum Marks: 183

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

1. Two mirrors M1 and M2 make an angle  with line AB. A M1

2. A ray of light, travelling parallel to diameter of a sphere enters the sphere

3. ABC is an equilateral metal wire frame of side length 0 kept in uniform A

magnetic field of strength B. The coefficient of linear expansion of the B

Space for rough work

4. In the circuit, as shown in the figure, if the r.m.s. current is 100  C

7. Two resistances are measured in Ohm.

Space for rough work

SECTION – 2 (One or More Than One Type)

8. Hydrogen atoms absorbs radiation of wavelength 0 and consequently emit radiations of 6

(B) Average power dissipated in the resistance of coil is

(D) Resistance of the coil is

Space for rough work

(A) Spherical (B) Spherical

13. Which of the following statement(s) is/are correct.

14. Read the following statements

Space for rough work

SECTION – 3 (Paragraph Type)

A square loop, consisting of an inductor L and a

16. The function of current through the square loop is

Space for rough work

Paragraph for Question Nos. 17 to 18

17. The number of maximas on the screen

Space for rough work

PART II: CHEMISTRY

2. Which of the following complex is optically inactive ?

3. Which of the following complex is not matched with its property?

6. The incorrect statement among the following is

7. Which of the following precipitate is soluble in yellow ammonium sulphide ?

Space for rough work

SECTION – 2 (One or More than one correct type)

8. Among the following statements which is/are correct

Space for rough work

12. Which of the following reaction is/are correct ?

13. The reaction in which N2(g) is produced is/are

Space for rough work

SECTION – 3 (Paragraph Type)

Paragraph for Question Nos. 15 and 16

15. The compound (A) is

16. The no. of moles of H2O needed to hydrolyse 1 mole of D is

Paragraph for Question Nos. 17 and 18

18. What is mole fraction of benzene in first trace of vapour formed

Space for rough work

PART III: MATHEMATICS

Space for rough work

(A) 32 + 2 (B) 2

x3 x4 x

Space for rough work

SECTION – 1 (One or more than one type)

10. The nature of the intersection of the set of planes :

Space for rough work

Space for rough work

SECTION – 1 (Paragraph Type)

Paragraph for Question Nos. 15 to 16

15. Co-ordinates of A are

16. If L1 = 0 is the reflected ray, then its equation is

Paragraph for Question Nos. 17 to 18

17. What is the probability that B will win?

Space for rough work

FIITJEE SANKALP RANK ENHANCEMENT TEST