Liquid Solutions For JEE Adv-2023

-2016
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023
The vapour pressure of two miscible liquids A and B are 300 and
500 mm of Hg respectively. In a flask 10 moles of A is mixed with
12 moles of B. However, as soon as B is added, A starts -2001
polymerising into a completely insoluble solid. The
polymerisation follows first-order kinetics. After 100 min, 0.525
mole of a solute is dissolved which arrests the polymerisation
completely. The final vapour pressure of the solution is 400 mm
of Hg. Estimate the rate constant of the polymerisation reaction.
Assume negligible volume change on mixing and polymerisation
and ideal behaviour for the final solution.
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023

Just sufficient moles of HgI2 are added to a solution of potassium iodide

containing 2 moles of it. The Van’t Hoff factor for this solution would be;

A. 8/3 -2015
B. 3/8
C. 3/5
D. 5/3

C
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023
10 moles of each A and B are mixed to obtain an ideal solution in
a closed container at 300K. If PoA =200 Torr and PoB = 800 Torr .
Find vapour pressure of solution when half of the mixture has
been vaporised.
A. 500 Torr -2010
B. 400 Torr
C. 1000 Torr
D. 300 Torr

B
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023

2 moles of chlorobenzene and 3 moles of water are placed in a container

at 90oC. If PoH2O = 600 Torr and PoC6H5Cl= 400 Torr at 90oC then find
vapour pressure of solution.
-2014
A. 520 Torr
B. 600 Torr
C. 1000 Torr
D. 800 Torr

C
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023

For a solution formed by mixing a nonvolatile solute ‘B’ to a volatile

solvent ‘A’ ,the
relative lowering in vapour pressure is given by ?
-2009
A. 𝚫H.𝚫Tb/RTb2
B. 𝚫H.Tb2/R .𝚫Tb
C. 𝚫H.Tb2/M.R .𝚫Tb2
D. 𝚫H.𝚫Tb2/M.RTb2

A
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023
PtCl4·6H2O can exist as a hydrated complex. 1.0 molal aqueous solution
has depression in freezing point of 3.72°C. Assume 100% ionization and
Kf of water = 1.86°C mol−1 kg. The complex is
-2012
A. [Pt(H2O)6]Cl4
B. [Pt(H2O)4Cl2]Cl2 ·2H2O
C. [Pt(H2O)3Cl3]Cl · 3H2O
D. [Pt(H2O)2Cl4] · 4H2O

C
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023
-2008

B
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023

-2005
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023
-2017

BD
Liquid Solutions For JEE Adv-2023
Liquid Solutions For JEE Adv-2023-Integer

-2020

.2
Liquid Solutions For JEE Adv-2023