Comp2023 Common Btest-3 Chemistry

BAKLIWAL TUTORIALS
COMP2023 COMMON BTEST-3 CHEMISTRY

SINGLE CORRECT
Q.1 A nuclear explosion has taken place leading to increase in concentration of C in nearby areas. C
concentration is in nearby areas and in areas far away. If the age of the fossil is determined to
be and at the places respectively then
(A) The age of fossil will increase at the place where explosion has taken place and − = ln
(B) The age of fossil will decrease at the place where explosion has taken place and − = ln
(C) The age of fossil will be determined to be the same

(D) =
Solution: (A)
Q.2 A liquid mixture having composition corresponding to point in the figure shown in subjected to
distillation at constant pressure. Which of the following statement is correct about the process
1
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

BAKLIWAL TUTORIALS
(A) The composition of distillate differs from the mixture

(B) The boiling point goes on changing
(C) The mixture has highest vapour pressure than for any other composition
(D) Composition of an azeotrope alters on changing the external pressure
Solution: (D)
A liquid mixture having composition corresponding to point in the figure shown in subjected to
distillation at constant pressure, composition of an azeotrope alters on changing the external pressure
Q.3 XeO is obtained when

(A) Xe reacts with O directly.
(B) XeF is hydrolyzed and disproportionated to give XeO .
(C) XeF is hydrolyzed in alkaline medium(barium hydroxide) followed by treatment with conc.
H SO at low temperature.
(D) XeF is hydrolyzed in neutral medium followed by reaction with O .
Solution: (C)
Q.4 Which of the following compound can not show geometrical isomerism?
Solution: (A)
Q.5 The activity per ml of a solution of radioactive substance is x. How much water be added to 200ml
of this solution so that the acitivity falls to x/20 per ml after 4 half-lives ?
(A) 100mi (B) 150ml (C) 80ml (D) 50ml.
Solution: (D)
2

BAKLIWAL TUTORIALS
Q.6 Select the correct option related to stability of following structures.
Solution: (C)
Q.7 Consider the reaction,
A, B and C all are optically active compound. If optical rotation per unit concentration of A, B and C
are 60∘, −72∘ , 42∘ and initial concentration of A is 2M, then select correct statements(s).
(A) Solution will be optically active and dextro after very long time
(B) Solution will be optically active and laevo after very long time
(C) Half life of reaction is 15 min
(D) After 100% conversion of A in to B and C angle of rotation of solution will be 36∘
Solution: (B)
Solution will be optically active and levo after very long time
After 75% conversion of in to B and C angle of rotation of solution will be 36∘
Q.8
3

BAKLIWAL TUTORIALS
The products X and Y are
Solution: (B)
Q.9 50 litre of a solution containing 10 mole of Ag is mixed with 50 litre of a 2 × 10 Mol HBr
solution. [Ag ] in resultant solution is: [Given: K (AgBr) = 5 × 10 ]
(A) 10 M (B) 10 M (C) 10 M (D) None of these
Solution: (C)
Q.10 Decomposition of H O is a first order reaction. A solution of H O labelled as "16.8 V" was left
open due to this, some H O decomposed. To determine the new volume strength after 2.303 hours.
20 mL of this solution was diluted to 100 mL. 25 mL of this diluted solution was titrated against
37.5 mL of 0.02 M KMnO solution under acidic conditions [Given: STP is 1 atm and 273 K].
The rate constant (in hr ) for decomposition of H O is:

(A) 0.15 (B) 0.30 (C) 0.60 (D) 1.3
Solution: (C)
4

BAKLIWAL TUTORIALS
Q.11 Among the following which compound does not yield xenon gas on hydrolysis?
(A) XeF (B) XeF (C) XeF (D) None of these
Solution: (C)
Q.12 The correct Lewis acid order for boron halides is:
(A) BF > BCl > BBr > BI (B) BCl > BF > BBr > BI
C) BI > BBr > BCl > BF (D) BBr > BCl > BI > BF
Solution: (C)
5

BAKLIWAL TUTORIALS
Q.13 The O − O bond length in O , O [AsF ] and K[O ] is:
(A) O [ ] < O < K[O ] (B) O [AsF ] < K[O ] < O
(C) O < O [AsF ] < K[O ] (D) [ ]< < [ ]
Solution: (A)
Band length order: 0⊕ < 0 < 0
Q.14 The rate of a reaction doubles when its temperature changes from 300 K to 310 K. Activation energy
of such a reaction will be : ( = 8.314 JK mol and log 2 = 0.301)
(A) 53.6 kJ mol (B) 48.6 kJ mol (C) 58.5 kJ mol (D) 60.5 kJ mol
Solution: (A)
Q.15 Select reaction giving incorrect products-
 
(A) XeF6  BF3   XeF5   BF4 

(B) XeF6  MF  M   XeF7 
(D) XeF6  2H 2O  XeO2 F2  4HF
Solution: (C)
6

BAKLIWAL TUTORIALS
Q.16 The correct order of dipole moment for the following molecules is
(A) IV > I > III > II (B) I > IV > III > II
(C) III > I > II > IV (D) II > III > IV > I
Solution: (B)
Q.17
Solution: (B)
2 reaction ⟶ Inversion product.
Q.18 Select incorrect statement regarding uses of noble gases-
(A) Xenon and krypton are used in light bulbs designed for special purposes
(B) Argon is used in handling air sensitive substances
(C) Radon is used as cryogenic agent
(D) Neon bulbs are used in botanical gardens and in green houses
Solution: (C)
Q.19
7

BAKLIWAL TUTORIALS
(1R, 3S)-Cis-1-Bromo-3–methylcyclohexane.
The product formed in the reaction is
(A) (1R, 3S)-Cis-3-methyl cyclohexanol
(B) (1 S, 3S)-Cis-3- methyl cyclohexanol
(C) (1 S, 3S) − Trans-3-methyl cyclohexanol
(D) (1 , 3 ) − Trans-3-methyl cyclohexanol
Solution: (C)
Q.20 The decreasing reactivity of the sites ( − ) in the following compounds in S 1 reaction is.
(A) > > > (B) > > > (C) > > > (D) > > >
Solution: (C)
INTEGER TYPE
Q.21 What is pOH of an aqueous solution with [H ] = 10 M and K = 2 × 10 ? Report your answer
after dividing by 2 and round it off to the nearest whole number.
Solution: (5)
Q.22 How many reactions are not representing the correct major product ?
Solution: (2)
8

BAKLIWAL TUTORIALS
Q.23 Among the 6, how many cyclic isomers of molecular formula C H Br can form 1-
methylcyclohexan-1-ol on reaction with H O/ acetone/Ag+ ?
Solution: (5)
Q.24 If no. of  -bonds in XeO3F2  x
oxidation state of Xe in XeO2 F4  y
No. of lone pairs on central atom in XeO2 F2  z
What is value of y   x  z 
Solution: (4)
x3
y 8
z 1
8   3  1  4
Q.25 Observe the following compound and write the number of hydrogen atom involved in
hyperconjugation.
Solution: (9)
Q.26 Identify total number of stereoisomers for the following compound?
Solution: (8)
Q.27 The number of Cl = O bonds in perchloric acid is
Solution: (3)
9

BAKLIWAL TUTORIALS
Per chloric acid ⇒ HCIO
Total Cl = O bonds = 3
Q.28 The P at which an acid indicator with K acid (indicator) = 10 changes colour when the Conc. of
the indicator is 10 M.
Solution: (5)
Q.29 The rate of a first order reaction is 0.04 mollitre sec at 10 minutes and 0.03 mol litre sec at
22 minutes after initiation. The half-life of the reaction (in minutes) is (given data ln (4/3) = 0.287)
Solution: (29)
Q.30 7.8 g pure liquid benzene (Vapour pressure 300 torr) and 18.5 g pure toluene (Vapour pressure =
900 torr) are mixed to form an ideal solution. The vapour pressure of solution (torr)/100 is_____.
Solution: (7)
7.8
n = = 0.1
78
18.4
n = = 0.2
92
⇒X = and X =
P = (300) + (900) = 700 torr
10

BAKLIWAL TUTORIALS
700 torr
= 7 torr
100
11

Comp2023 Common Btest-3 Chemistry

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Comp2023 Common Btest-3 Chemistry

Uploaded by

Copyright:

Available Formats

BAKLIWAL TUTORIALS

COMP2023 COMMON BTEST-3 CHEMISTRY

(C) The age of fossil will be determined to be the same

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

(A) The composition of distillate differs from the mixture

Q.3 XeO is obtained when

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Q.7 Consider the reaction,

After 75% conversion of in to B and C angle of rotation of solution will be 36∘

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

The products X and Y are

The rate constant (in hr ) for decomposition of H O is:

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Band length order: 0⊕ < 0 < 0

Q.15 Select reaction giving incorrect products-

(D) XeF6  2H 2O  XeO2 F2  4HF

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Q.18 Select incorrect statement regarding uses of noble gases-

(B) Argon is used in handling air sensitive substances

(C) Radon is used as cryogenic agent

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Q.24 If no. of  -bonds in XeO3F2  x

oxidation state of Xe in XeO2 F4  y

No. of lone pairs on central atom in XeO2 F2  z

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

P = (300) + (900) = 700 torr

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

Print to PDF without this message by purchasing novaPDF (http://www.novapdf.com/)

You might also like