Comp2023 Common Btest-5 Chemistry (Mains)

BAKLIWAL TUTORIALS
COMP2023 COMMON BTEST-5 CHEMISTRY PAPER

SINGLE CORRECT TYPE
Q.1 Identify major product of the following reaction
Solution : (A)
Q.2
1
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Solution : (B)
1, 2, 4 indicate sequence of electronic attack.

Q.3
Solution : (A)
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Q.4 Identify the reactant (X) on the given reaction
Solution : (B)
Q.5
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Solution : (C)
Q.6
Find the structure of A.
Solution : (D)
Antiaddition
Trans alkene   Erythro products
Q.7 From the following molar conductivities at infinite dilution:
m for Ba  OH2  457.6 1 cm2 mol1
m for BaCl2  240.6 1 cm2 mol1
m for NH4Cl  129.8 1 cm2 mol1
Then m for NH4OH .
(A) 138 Scm2 / mol1 (B) 238 Scm2 / mol1
(C) 338 Scm2 / mol1 (D) 328 Scm2 / mol1

Solution : (B)
[ ]
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[ ]
Q.8 AgNO3(aq) was added to an aqueous KCl solution gradually and the conductivity of the solution was
measured. The plot of conductance    versus the volume of AgNO3 is
(A) P (B) Q (C) R (D) S

Solution : (D)
In this reaction, ions are replaced by

i. Till all ( ions) gets consumed by will get replaced by ion.
.
Conductance is constant since the conductance o
conductance of .
Initially, conductance do not fall to a large extent. Even the fall/rise will be linear
(either decreasing or increasing).
ii. When all ions are reacted and no reaction occurs there are , and ions are
left in the solution which increases the conductance of solution sharply.
Hence, graph (s) is the most appropriate answer.

Q.9 The rusting of iron takes place as follows :
1
2H  2e  O2  H 2O  l  ; E   1.23V
2
Fe  2e  Fe  s  ;
2 
E   0.44V
Calculate G  For the net process.
(A) 322kJ mol1 (B) 161kJ mol1 (C) 152kJ mol1 (D) 76 kJ mol1
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Solution : (A)
Reactions:
i.
and
ii.
and
Net reaction:
Q.10 10 mole of an ideal gas is heated at constant pressure of one atmosphere from 27 C to 127 C . If
Cv,m  21.686 103 T  JK1.mol1  , then H for the process is :
(A) 3000 J (B) 3350 J (C) 3700 J (D) 30350 J

Solution : (D)
Q.11 If enthalpy of hydrogenation of C6H6 (l) into C6H12 (l) is – 205 kJ / mol and resonance energy C6H6
(l) is – 152 kJ/mol then enthalpy of hydrogenation of is

Assume Hvap of C6H6 (l), C6H8 (l), C6H12 (l) all are equal :
(A) – 535.5 kJ/mol (B) – 238 kJ/mol (C) – 357 kJ/mol (D) – 119 kJ/mol
Solution : (D)
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Q.12 Which of the following will give cis diol?
Solution : (C)
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Q.13 A block of ice at – 10 C is slowly heated and converted into steam at 100 C. Which of the following
curves represents the phenomenon qualitatively?
Solution : (A)
Q.14 Which of the following curves assures that the metal obtained by carbon reduction is in the vapour
state?
Solution : (B)
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Q.15 The process of converting hydrated alumina into anhydrous alumina is called :
(A) Roasting (B) Smelting (C) Dressing (D) Calcination
Solution : (D)
Calcination is a process in which ore is heated generally in the absence of air to expel water for
hydrated oxide or carbon dioxide from a carbonate.
Q.16 Auto reduction process is used in the extraction of :
(A) Cu and Hg (B) Zn and Hg (C) Cu and Al (D) Fe and Pb
Solution : (A)
Auto reduction process is used in the extraction of and .
Q.17 Which of the following is not correctly matched?

Method Used for refining
(A) Van Arkel Zr and Ti
(B) Zone refining Ge, Si, Ga, In
(C) Liquation Zn and Hg
(D) Mond’s Ni
Solution : (C)
Distillation is used for Zn and Hg.
Q.18 An element whose IUPAC name is ununtrium (Uut), belongs to :
(A) s-block element (B) p-block element (C) d-block element (D) Transition element
Solution : (B)
Ununtrium for atomic number for no.
[ ]
p-block
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Q.19 In which of the following pair, both the species are isoelectronic but the first one is large in size than
the second?
(A) S2 ,O2 (B) Cl ,S2 (C) F , Na  (D) N3 , P3
Solution : (C)
both are isoelectronic. Both have 10 electrons. As ( ) ; size decreases.
Q.20 The hydration energy of Mg 2 ions is lesser than that of :
(A) Al3 (B) Ba 2 (C) Na  (D) None of these

Solution : (A)
Hydration energy of ion  Charge density of ion. The hydration energy of Mg 2 ions is lesser than
that of Al3 .
INTEGER TYPE
Q.21 Consider the following reactions
Identify value of X + Y.
Solution : (8)
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Q.22 How many number of moles of H2 is used for the complete hydrogenation of the given compound in
the presence of a metal catalyst?
Solution : (7)
Q.23 For the reaction : 2Fe3  3I 2Fe2  I3 . The standard reduction potentials in acidic conditions are
0.78 V and 0.54 V respectively for Fe3 Fe2 and I3 I couples. Calculate Keq as 10x . Find x.
 RT 
 Use :2.303 F  0.06at 298K 
Solution : (8)
The given reaction is :
Using the expression :
The electrode reactions are : (at ) [ncell ]
Anode : 3I  I3  2e
Cathode :
Q.24 What is the amount of Al (in mg) deposited on the electrolysis of molten Al2O3 when a current of
9.65 A is passed for 10.0 s.
Solution : (9)
Molten →
Number of Faradays
Reduction of at cathode
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d os d
Q.25 If bond energies of H2, Cl2 and HCl are 104, 58, 103 kcal/mol respectively. Find the magnitude of
 F H 
 11  of HCl  g  …
 
Solution : (2)
Now analyse the given thermochemical equation in two parts :

(i) Bond Breaking [ ] : Endothermic Reaction
;
;
[ ] [as we need mole of each reactant]
[ ]
(ii) Bond Formation: : Exothermic reaction

; (Bond energy of
Now (using Hess's Law)
  H  22
  F   2kcal / mol
 11  11
12

Comp2023 Common Btest-5 Chemistry (Mains)

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BAKLIWAL TUTORIALS

COMP2023 COMMON BTEST-5 CHEMISTRY PAPER

Q.1 Identify major product of the following reaction

1, 2, 4 indicate sequence of electronic attack.

Q.4 Identify the reactant (X) on the given reaction

Find the structure of A.

m for Ba  OH2  457.6 1 cm2 mol1

m for BaCl2  240.6 1 cm2 mol1

m for NH4Cl  129.8 1 cm2 mol1

Then m for NH4OH .

(A) 138 Scm2 / mol1 (B) 238 Scm2 / mol1

(C) 338 Scm2 / mol1 (D) 328 Scm2 / mol1

(A) P (B) Q (C) R (D) S

In this reaction, ions are replaced by

Hence, graph (s) is the most appropriate answer.

(A) 3000 J (B) 3350 J (C) 3700 J (D) 30350 J

(l) is – 152 kJ/mol then enthalpy of hydrogenation of is

Q.12 Which of the following will give cis diol?

Q.17 Which of the following is not correctly matched?

both are isoelectronic. Both have 10 electrons. As ( ) ; size decreases.

Q.20 The hydration energy of Mg 2 ions is lesser than that of :

(A) Al3 (B) Ba 2 (C) Na  (D) None of these

Q.21 Consider the following reactions

The electrode reactions are : (at ) [ncell ]

Anode : 3I  I3  2e

Now analyse the given thermochemical equation in two parts :

(ii) Bond Formation: : Exothermic reaction

Now (using Hess's Law)

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