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COMP2023 COMMON BTEST-2 CHEMISTRY

SINGLE CORRECT
Q.1 The correct order of acidic strength of oxides of nitrogen is
(A) NO < NO2 < N2 O < N2 O3 < N2 O5 (B) N2 O < NO < N2 O3 < N2 O4 < N2 O5
(C) NO < N2 O < N2 O3 < N2 O5 < N2 O4 (D) NO < N2 O < N2 O5 < N2 O3 < N2 O4

Solution: (B)

Q.2 The osmotic pressure of a solution of benzoic acid dissolved in benzene is less than expected
because:
(A) benzoic acid is an organic solute (B) benzene is a non-polar solvent
(C) benzoic acid dissociates in benzene (D) benzoic acid gets associated in benzene

Solution: (D)

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Q.3 Arrange the given phenol & its derivative in their decreasing order of acidity:

Select the correct answer from the given code:

(A) IV > III > I > II (B) IV > II > III > I
(C) IV > III > II > I (D) IV > I > III > II

Solution: (C)

Q.4 Formic acid is considered as a hybrid of the four structures

Which of the following order is correct for the stability of four contributing structures.

(A) I > II > III > IV (B) I > II > IV > III (C) I > III > II > IV (D) I > IV > III > II

Solution: (A)

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Q.5 Among the following, the strongest base is :-
(A) C6 H5 NH2 (B) p − NO2 − C6 H4 NH2
(C) m − NO2 − C6 H4 NH2 (D) C6 H5 CH2 NH2

Solution: (D)

Q.6 Among the following statements, the incorrect one is :


(A) Calamine and siderite are carbonates
(B) Argentite and cuprite are oxides
(C) Zinc blende and pyrites are sulphides
(D) Malachite and azurite are ores of copper

Solution: (B)

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MULTIPLE CORRECT

Q.7 Which of the following metals are extracted by electrolytic reduction?


(A) Cu (B) Al (C) Mg (D) Ag

Solution: (BC)

Active meals like K, Na, Ca. Mg, Al are extracted through electrolytic reduction (B) Al and (C) mg

Q.8 Which of the following compound is correctly matched with number of hyperconjugating structures
(involving C − H bond):

Solution: (ABC)

Q.9 For the reaction A + 3 B → C, select the correct statement (s)-


d[C] −d[A] 3 d[C] d[B]
(A) = (B) =−
dt dt dt dt

(C) Rate law must be 𝑟 = 𝑘[𝐴][𝐵]3

(D) Units for rate of reaction are independent of order of reaction

Solution: (ABD)

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Q.10 For an SN2 reaction, which of the following statements are true :-
(A) The rate of reaction is independent of the concentration of the nucleophile
(B) The nucleophile attacks the C-atom on the side of the molecule opposite to the group being
displaced
(C) The reaction proceeds with simultaneous bond formation and rupture
(D) None of these

Solution: (BC)

Q.11 The correct statement(s) regarding defects in solid is (are)


(A) Frenkel defect is usually favoured by a very small difference in the sizes of cation and anion.
(B) Frenkel defect is a dislocation defect
(C) Trapping of an electron in the lattice leads to the formation of F-center.
(D) Schottky defects have no effect on the physical properties of solids.

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Solution: (BC)

Q.12 Which of the following reaction produces PH3 :


(A) Ca3 P2 + H2 O → (B) P4 + NaOH →
Δ
(C) PH4 I + KOH → (D) H3 PO2 ⟶

Solution: (ABCD)

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INTEGER TYPE
Q.13 Lithium forms body centred cubic structure. The length of the side of its unit cell is 351 pm. Atomic
radius of the lithium will be x pm. Then the value of x/10 to nearest integer will be.

Solution: (15)

Q.14 Total volume of atoms present in a face-centred cubic unit cell of a metal is (r is atomic radius) is
(a/b)r3. Where a/b is simplified fraction. The value of (a + b) will be

Solution: (19)

Q.15 The total number of acylic isomers including the stereoisomers (geometrical and optical) possible
with the molecular formula C4H7Cl is
Solution: (12)

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Q.16 A 0.01 m aqueous solution of K3[Fe(CN)6] freezes at –0.062°C [Kf for water = 1.86]. Find the
nearest integer number to the percentage dissociation.
Solution: (78)

Q.17 An organic compound undergoes first-order decomposition. The time taken for its decomposition to
1/8 and 1/10 of its initial concentration are t1/8 and t1/10 respectively. What is the value of
[t1/8 ]
× 10 ? (take log10 ⁡2 = 0.3)
t1/10

Solution: (9)

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Q.18 Tautomerism is exhibited by –

Solution: (5)

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