You are on page 1of 42

BAKLIWAL TUTORIALS

COMP 2021 PART TEST - 9 PHYSICS

SINGLE CORRECT TYPE

61
Q.1 When Ni nuclei are bombarded with deuterons in an accelerator, 61 Cu (half life 3.5 hr) is produced. The
copper atoms are made at a rate of 6.93 108 s1 when the accelerator is running. Find the maximum number

of 61
Cu that can be produced in the accelerator.  n2 = 0.693  :

(A) 5.0 1010 (B) 1.26 1013 (C) 3.5 108 (D) 1.4 108
Solution : (B)

Q.2 A radioactive material decays by simultaneous emission of two particles with respective half lives 1620 and
810 years. The time (in years) after which one-fourth of the material remains is :
(A) 1080 (B) 2430 (C) 3240 (D) 4860
Solution : (A)

Q.3 The ratio of de-Broglie wavelength of molecules of hydrogen and helium moving at rms speed in two gas jars
 
kept separately at temperature 27 C and 127 C , respectively, is :

1
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
2 3 8
(A) (B) 2 : 3 (C) (D)
3 4 3
Solution : (D)

Q.4 Probability of decay of a particular nucleus of substance Z in next 1 hour is 3 . Then probability of decay of a
nucleus of same substance :
1 1 5
(A) In next hours is (B) In next 2 hours is
2 3 9
1 1
(C) In next 3 hours is (D) In next 1.5 hour is
3 3
Solution : (B)

Q.5 Hydrogen atom in ground state absorb a photon of energy 12.75 eV. How many spectral lines are observed in
emission spectrum :
(A) 3 (B) 6 (C) 10 (D) 1
Solution : (B)

2
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Q.6 A free particle with initial kinetic energy E and de-broglie wavelength λ enters a region in which it has
potential energy V. What is the particle’s new de Broglie wavelength?

(A) λ 1  E/V  (B) λ 1  E/V  (C) λ 1  E/V  (D) λ 1  V/E 


1/2 1 1/2

Solution : (D)

Q.7 In a hypothetical system a particle of mass m and charge – 3q is moving around a very heavy particle having
change q. Assume that Bohr’ model is applicable to this system, then velocity of mass m in first orbit is :

3q 2 3q 2 3q 3q
(A) (B) (C) (D)
2ε 0 h 4ε 0 h 2πε 0 h 4πε 0 h
Solution : (A)

Q.8 A point source of light is used in a photoelectric effect. If the source is moved farther from the emitting metal,
the stopping potential :
(A) will increase (B) will decrease
(C) will remain constant (D) will either increase or decrease.
Solution : (C)
Only intensity will decrease

3
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
No change in frequency

0
Q.9 The wavelength of L line in x-ray spectrum of 78 Pt is 1.32 A . The wavelength of L line in x-ray spectrum
0
of another unknown element is 4.17 A . If screening constant for L line is 7.4, then atomic number of the

unknown element is :
(A) 78 (B) 47 (C) 40 (D) 35
Solution : (B)

Q.10 A stream of  particles is incident on a sample of hydrogen gas. What should be minimum kinetic energy of
 - particles to ionize the hydrogen atoms [(mass of  - particle) = 4 (mass of hydrogen atoms)]
(A) 17 eV (B) 34 eV (C) 51 eV (D) 68 eV
Solution : (D)

4
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Q.11 In a characteristic X-ray spectra of some atom superimposed on continuous X-ray spectra :

(A) P represents K α line

(B) Q represents K β line

(C) Q and P represents K α and K β lines respectively

(D) Relative positions of K α and K β depend on the particular atom.

Solution : (C)
Fact Based

Q.12 Fastest electrons ejected from a surface by incident light of wavelength 330 nm are bent into circle of radius 1

m as they pass through magnetic field of 2.5 106 T . Find the work function of the surface.
(A)   4.3eV (B)   2.2eV (C)   2.5eV (D)   3.2eV
Solution : (D)

Q.13 Which of the following is a FALSE statement?


(A) The difference in entropy between two states of a system is independent of the path between the two
states.
(B) Entropy is a quantitative measure of disorder.
(C) The total entropy change in one cycle of a Carnot engine is zero.
(D) The entropy of an isolated system can decrease.
Solution : (D)

Q.14 One mole of ideal monoatomic gas at initial state a with pressure P0 and volume V0 is taken to a final state ‘d’
V0
with pressure e3 P0 and volume through the path a  b  c  d (figure) a  b and c  d are adiabatic
e

5
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
paths were as b  c is isothermal with temperature T0 . Find the work done by the gas in the process b  c .

(Given : n  e   1 )

5 3
(A) 2 RT0 (B) RT0 (C) 4 RT0 (D) RT0
3 2
Solution : (A)

Q.15 In the diagram shown Qiaf = 80cal and Wiaf = 50cal . If W = - 30 cal for the curved path fi, value of Q for

path fi, will be -

6
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
(A) 60 cal (B) 30 cal (C) – 30 cal (D) – 60 cal
Solution : (D)

Q.16 The distribution of relative intensity I  λ  of blackbody radiation from a solid object versus the wavelength λ

is shown in the figure. If the Wien displacement law constant is 2.9 103 mK , what is the approximate
temperature of the object?

(A) 10 K (B) 50 K (C) 250 K (D) 1500 K


Solution : (D)
λmT = constant

 dp 
Q.17 Figure shows the adiabatic curve for 2 moles of an ideal gas. The Bulk modulus  i.e. B =  at the
 dV/V 
point P will be :

 T0   T0  2RT0
(A) R 1+  (B) 2R  1+  (C) (D) None of these
 V0   V0  V0

7
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Solution : (B)

Q.18 An ideal gas is expanding such that pT 2 = constant. The coefficient of volume expansion of the gas is :
1 2 3 4
(A) (B) (C) (D)
T T T T
Solution : (C)

Q.19 A certain gas is taken to the five states represented by dots in the graph. The plotted lines are isotherms. Order
of the most probable speed vp of the molecules at these five states is :

(A) VPat 3  VPat1  VPat 2  VPat 4  VPat 5 (B) VPat1  VPat 2  VPat 3  VPat 4  VPat 5

(C) VPat 3  VPat 2  VPat 4  VPat1  VPat 5 (D) Insufficient information to predict the result.

8
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Solution : (A)

Q.20 The co-efficient of thermal expansion of a rod is temperature dependent and is given by the formula   aT ,

where a is a constant and T in  C . If the length of the rod is at temperature 0  C , then the temperature at

which the length will be 2 is : [Heat : made]

n2 n4 1 2
(A) (B) (C) (D)
 a  
Solution : (B)

NUMERICAL TYPE
Q.21 Suppose radiation from a black body is allowed to fall on a photosensitive material after passing it through a
filter which selects the wavelength having maximum intensity to pass. The work-function of the material is 1

1.24eV . Find the minimum temperature  in103 K  of the black-body which will cause the emission of

 3


photo-electrons.  Given Weins con tan t b  3 10 m K & hc 12400 eV A
 
Solution : (03.00)

Q.22 92 U238 changes to 85 At 210 by a series of  and  decays. Find number of  - decays undergone (in integer).
Solution : (07.00)

9
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.23 An ideal gas undergoes a cyclic process ABCDEA. Pressure vs volume graph for this process is given as
shown. Find work done by gas in  kJ 

Solution : (03.00)

Q.24 Bacteria can be knocked out in the presence of radiation from green kryptonite, which has a very long half-
life. If 150 g of it can knock out the bacteria in just 1.5 minutes, how long can the bacteria withstand the
radiation if there is 4.5 kg of slab of green kryptonite? Assume that kryptonite obeys radioactive decay law.
2
Express your answer in power of 10 minutes.
Solution : (05.00)

10
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

1 1
Q.25 A radioactive sample contains two radio nucleoids A and B having decay constant λ hr and 2λ hr .
Initially 25% of total decay comes from A. How long (in hr) will it take before 75% of total decay comes from
A. [Take λ = n 3 ]
Solution : (02.00)

Q.26 A body cools in 7 minutes from 600C to 400C. What will be its temperature after the next 7 minutes in °C. The
temperature of surroundings is 100C.
Solution : (28.00)

Q.27 If the temperature of a hot body is raised by 5%, then the heat energy radiated would increase by what
percentage -
Solution : (21.55)

Q.28 In the P – V diagram shown. The gas does 5 J of work in isothermal process ab and 4 J in adiabatic process
bc. What will be the change in internal energy of the gas in straight path c to a?

11
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Solution : (04.00)

Q.29 Two ideal monoatomic & diatomic gases are mixed with one another to form an ideal gas mixture. The
11
equation of the adiabatic process of the mixture is PVγ  constant , where γ = . If n1 and n2 are the
7
number of moles of the monoatomic & diatomic gases in the mixture respectively, find the ratio n1/n2.

Solution : (03.00)

Q.30 A black body radiates heat energy at the rate of 2 105 joule/sec/m2 at a temperature 127 C . The

temperature of the black body, at which the rate of heat radiation is 32 105 joule/sec/m2 is  in C  -

Solution : (527.00)

12
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

COMP 2021 PART TEST – 9 MATHS


SINGLE CORRECT TYPE
 /2 cot x
Q.1 The value of 0
cot x  tan x
dx is equal to

  
(A)  (B) (C) (D)
2 4 3
Solution: (C)

  x  dx
Q.2 The expression 0
n
, where [x] and {x} are integral and fractional parts of x and n  N is equal
  x dx
0

to
1 1
(A) (B) (C) n (D) n  1
n 1 n
Solution: (D)

1
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

 
2
, then the value of integral  f '  x  1  ln x  dx  1 is
f  x x f  x
e
2
Q.3 If x
1

(A) 3 ln 3 (B) 2 ln 2 (C) ln 2 (D) ln 3


Solution: (B)

2
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
 
2012 2
d 
x
Q.4 The value of the integral     cos t 2  dt dx is
2012 
 dx 0 

(A) 2012 (B) 4024 (C) 0 (D) 2012
Solution: (C)

1  x2 
x
dx 1 1
 f  x   is
1/ x
Q.5 If    ln    c , then lim
x 2
 1
3
4  f  x 
2
2 f  x 2  f  x  x 0

(A) 3 (B) e (C) e2 (D) 1


Solution: (D)

3n
n
Q.6 lim
n 

r  2 n 1 r  n
2 2
is equal to

3
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
2 3 2 3
(A) ln (B) ln (C) ln (D) ln
3 2 3 2
Solution: (B)

Q.7 Let a, b, c be non-zero real numbers such that

 1  cos x  ax  bx  c  dx   1  cos8 x  ax 2  bx  c  dx then the equation ax2+bx +c = 0 has


1 2
8 2
0 0

(A) No root in (0, 2) (B) At least one root in (0, 2)


(C) Two roots in (0, 2) (D) None of these
Solution: (B)

 tan  sin  log   dx is


2
Q.8 The value of x2  1  x
2

(A) cot 4 (B) tan 4 (C) 0 (D) sin 4


Solution: (C)

2012
Let x 2   f  x    t  and x 4   f  x    t 2  2 . Then the value of   x . f  x  . f '  x   x  dx is
2 1 4 1 3
Q.9
t t 2012

(A) 4012 (B) 2012 (C) – 4024 (D) -2012


Solution: (C)

4
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

 x x x 
Q.10 Let f  x      .....   then the value of the integral
 1  x  1  x 1  2 x  1  9 x 1  10 x  
5
1
 f  x   1  10 x  dx is
5

(A) 20 (B) 9 (C) 10 (D) 40


Solution: (C)

5
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS


Q.11 Let f  n    e x x n1dx, n  N , x  Q  . Then the value of f  5  is
0

(A) 20 (B) 5 (C) 24 (D) 120


Solution: (C)

log x d2 y
Q.12 If y  , then 2 
x dx
3  2 log x 2 log x  3 2 log x  3 2  3log x
(A) (B) (C) (D)
x3 x3 x4 x4

Solution: (B)

6
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

dy
Q.13 If 3sin xy  4cos xy  5 , then equals
dx
y y x x
(A) (B)  (C) (D) 
x x y y
Solution: (B)

1
Q.14 Let g(x) be the inverse of the function f(x), and f '  x   then g’(x) equals
1  x3
1 1
(A) (B) (C) 1  g 3 (D) 1  f 3
1  g 3  1  f 3 
Solution: (C)

7
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Q.15 Let f(x) is a polynomial satisfying f  x  . f  y   f  x   f  y   f  xy  – 2 x, y and f(2) = 1025,

then the value of lim f '  x  is


x 2

(A) 5.28 (B) 5.29 (C) 5.27 (D) 5.210


Solution: (D)

1 1 1 dy bc
Q.16 If y    then find at e a .
1  x a  b  x c b 1  x b c  x a c 1  xb a  x c a dx
(A) 0 (B) 1 (C) 2 (D) 3
Solution: (A)

8
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
2
dx
Q.17 The value of  x 1  x 
1
4
is equal to

1 17 1 17 17 1 32
(A) log (B) log (C) log (D) log
4 32 4 2 2 4 17
Solution: (D)

Q.18 The area of figure bounded by the curves y  a x  a  1 and y  b – x  b  1 and the straight line x = 1

is
1 1 1  1 
(A)  a  1    1 (B) (log a )  a  1  (log b)   1
log a log b  b  b 
1 1
(C)  a  1   b  1 (D) (log a )  a  1  (log b)  b  1
log a log b
Solution: (A)

9
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.19 The area enclosed by the curve y 2  x4  x2 is


2 4 8 16
(A) (B) (C) (D)
3 3 3 3
Solution: (B)

Q.20 The area bounded by the curve y  cos 1  cos x  and y  x   is

2 2
(A)  2sq.unit (B) 2 2sq.unit (C) sq.unit (D) sq.unit
2 4
Solution: (C)

10
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

NUMERICAL TYPE
18
Q.21 If  sin x  cos x dx  k and [.] denotes the greatest integer function, then k is _________.
0

Solution: (09.00)

 
x 2 sin 2 x sin  cos x 

Q.22 If   2  dx  A , then A is _____________.
0
2x   
Solution: (08.00)

11
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

x sin 1 x 3
1/2
Q.23 If I  0 1  x2
dx  A 
12
, then 2A is _________.

Solution: (01.00)

12
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.24 If the right hand derivative of h(x) = {x} ({.} is fractional part of x) exists at x = 1 then it is equal
to_______.
Solution: (01.00)

Q.25 If y  f  x  and y 4 – 4 y  x  0. If f  –8   2 then the value of 28 f '  –8  is _____.

Solution: (01.00)

Q.26 If f(x) = f(1 – x) and f(x) is differentiable at every real value of x then the value of
1 1 3
f '    f '    f '   is ______.
2 4 4
Solution: (00.00)

13
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.27 The area between the curves y  x3 and y  x  x is equal to

Solution: (01.00)

10
Q.28 The area of  f  x  dx , where f  x   min x   x ,  x    x  , where [ ] is G.I.F., is
10

Solution: (05.00)

14
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

k
Q.29 If the area bounded by y  x2 and x  y 2 is sq. units, then k is __________.
15
Solution: (05.00)

Q.30 For which of the following positive value of m, the area of the region bounded by the curve
9
y  x  x 2 line y = mx equals ?
2

Solution: (04.00)

15
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

16
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
COMP2021 PART TEST -9 CHEMISTRY PAPER
SINGLE CORRECT TYPE
Q.1 The catalyst decrease the Ea from 100 kJ mol–1 to 80 kJ mol–1. At what temperature the rate of
reaction in the absence of catalyst at 500 K will be equal to rate reaction in presence of catalyst
(A) 400 K (B) 200 K (C) 625 K (D) None of the above
Solution: (A)

Q.2 The rate law has the form

rate  k  A B 
3/2

can the reaction be elementary process


(A) yes (B) no
(C) may be yes or no (D) cannot b predicted
Solution: (B)

Q.3 Which of the following statements is incorrect?


(A) The superoxide ion (i.e O2 ) is stable only in presence of larger cations such as K  , Rb , Cs 

(B) Alkali metals are normally kept in kerosene oil.


(C) All the alkali metal hydrides are ionic solids with high melting points.
(D) The concentrated solution of alkali metals in liquid ammonia is paramagnetic in nature.
Solution: (D)

Q.4 Which of the following statement is true for all the alkali metals?
(A) Their nitrates decompose on heating to give the corresponding nitrites and oxygen.
(B) Their chlorides are deliquescent and crystallise as hydrates.
(C) They react with water to form hydroxide and hydrogen gas.
(D) They readily react with halogens to form ionic halides, M  X 
Solution: (C)

1
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.5 Which of the following statements is not true about the dilute solutions of alkali metals in liquid
ammonia?
(A) They are deep blue coloured solution
(B) They are highly conducting in nature
(C) They are diamagnetic in nature.
(D) Ammoniated cation and solvated electron are formed in the solution.
Solution: (C)

Q.6 Which of the following statements are true about the alkali metals?
(1) All alkali-metal chloride salts impart a characteristic colour to the Bunsen flame.
(2) The correct order of increasing thermal stability of the carbonates of alkali metals is
Li2CO3  Na2CO3  K2CO3  Rb2CO3  Cs2CO3
(3) Among the alkali metals, cesium is the most reactive.
(4) The reducing character of the alkali metal hydrides follow the order:
LiH  NaH  KH  RbH  CsH
(A) (1), (2) and (3) (B) (1), (3) and (4) (C) (2), (3) and (4) (D) (1), (2), (3) and (4)
Solution: (A)

Q.7 S1: Plaster of paris is a hemihydrated of calcium sulphate obtained by heating the gypsum above
393K.
S2: Sodium carbonate is used in water softening.
S3: The order of mobilities of the alkali metal ions in aqueous solutions is
Li   Na  K   Rb  CS 
(A) TTF (B) TTT (C) FTF (D) FFF
Solution: (C)

2
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.8 Composition of a sample is Fe0.93O1.00 . If Fe is present in +2 & +3 oxidation state in this sample then

% of Fe present in +3 oxidation state is


(A) 85% (B) 30% (C) 15% (D) 60%
Solution: (C)

Q.9 (i) Br2 +2NaOH  cold  


 NaBr +  X  +H 2 O

(ii) 2Br2 + 6NaOH  hot  


 NaBr +  Y  +H 2O

What is the oxidation number of Br in (X) and (Y) respectively


(A) +1, +7 (B) +1, +5 (C) +4, +5 (D) +3, +5
Solution: (B)

Q.10 In the reaction, xVO + yFe2O3 


 FeO + V2 O5 . What is the value of x and y respectively?

(A) 1, 1 (B) 2, 3 (C) 3, 2 (D) None of these


Solution: (B)

3
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Q.11 A gaseous mixture contains CO2  g  and H 2  g  in a 2.2 : 1 ratio by mass. The ratio of the number

of molecules of CO2  g  and H 2  g  is

(A) 5 : 2 (B) 1 : 10 (C) 10 : 1 (D) 1 : 5


Solution: (B)

Q.12 For a first order reaction, the value of rate constant for the reaction
A gas  
 2B gas   C solid 

(If Po is initial pressure and Pt is pressure of mixture at time t)

1  P0  1  P0 
(A) ln   (B) ln  
t  P0  Pt  t  2 P0  Pt 

1  2 P0  1  2 P0 
(C) ln   (D) ln  
t  3P0  Pt  t  2 P0  Pt 

Solution: (B)

Q.13 What is the activation energy for a reaction if its rate doubles when the temperature is raised from
20 C to 35 C ? (R = 8.314 J mol–1 K–1)
(A) 269 kJ mol –1 (B) 34.6 kJ mol –1 (C) 15.1 kJ mol –1 (D) 342 kJ mol –1
Solution: (B)

4
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.14 An aldehyde X (C11H10O), which does not undergo self aldol condensation, gives benzaldehyde
and two moles of Y on ozonolysis. compound Y, on oxidation with silver ion gives oxalic acid. The
compounds X and Y, are respectively :

Solution: (C)

Q.15 The true statement about the major product of in reaction


with aq. NaOH followed by heating is.

(A) It gives yellow ppt with I 2 / OH  (B) It gives silver mirror with Tollen’s reagent

(C) It shows stereoisomerism (D) It does not give yellow ppt with 2,4 DNP
Solution: (A)

5
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.16

Which is not true about above sequence of reaction.


(A) Product R and S reacts with NaHCO3 solution with effervescence of CO2 gas.

(B) P when reacts with NaCNand H 2 SO4 , gives two optically active resolvable product.

(C) Q is formed by nucleophilic substitution reaction on P.

(D) S is formed by evolution of H 2O and CO2 from R.

Solution: (C)

6
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Q.17 Match list I (reaction) with II (product) and then select the correct answer from the codes given
below the lists:
List I List II
(Reactions) (Product)

Codes:
P Q R S P Q R S
(A) 1 3 4 2 (B) 4 1 3 2
(C) 4 1 2 3 (D) 3 1 4 2

Solution: (B)

7
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.18 Match list I (reaction) with II (product) and then select the correct answer from the codes given
below thelists:
List I List II
(Reactions) (Product)

Codes:
P Q R S P Q R S
(A) 1 2 3 4 (B) 1 2 4 3
(C) 2 1 3 4 (D) 2 1 4 3
Solution: (D)

8
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.19

Compound X in the above reaction is

Solution: (B)

9
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.20

Solution: (A)

NUMERICAL TYPE
Q.21 How many of the following compounds do not impart characteristic colour to the Bunsen flame:
NaCl , BeCl2 , KOH , BaSO4 , MgCl2 , CsCl , Na2 SO4 , Mg  OH 2 , K 2CO3

Solution: (03.00)

10
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS
Compounds of Be and Mg do not impart any colour to Bunsen flame.

Q.22 A bottle of 1 litre capacity is labeled as 1 molar Al2  SO4 3  aq  . If the bottle is half filled and
density of solution is 1.342 g/mL, then what will be molality of Al 3  aq  in this solution.

Solution: (02.00)

Q.23 A sample of copper is used to prepare 100 ml of 0.02 M CuSO 4(aq) solution. 10 ml of this
CuSO4(aq) solutionis mixed with excess of KI to show the following changes.
CuSO 4 + 2KI  K 2SO 4 + Cul 2
2Cul2  Cu 2 I 2 + I 2
The liberated iodine is titrated with hypo solution (Na2S2O3) and requires V ml of 0.01 M hypo
solution for itscomplete reduction. The volume (V) of hypo required is :
Solution: (20.00)

N
Q.24 20 ml of H 2O2 after acidification with dil H2SO4 required 30 ml of KMnO4 for complete
12
oxidation. The volume strength of H2O2 solution is :

Solution: (00.70)

11
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.25 One litre of a sample of hard water contain 4.44 mg CaCl2 and 1.9 mg of MgCl2. What is the total
hardness in terms of ppm of CaCO3 ?

Solution: (06.00)

Q.26 How many of the following compounds react with NaHCO3 and liberate CO2(g)
1. Salicylic acid 2. Pthalic acid 3. Picric acid 4. Resorcinol
5. Carbolic acid 6. Aspirin 7. Anisol 8. Tarteric acid
Solution: (05.00)

Q.27

The total number of isomeric products (including stereoisomers) formed at the end of the reaction
is:
Solution: (04.00)

Q.28 How many moles of formaldehyde is formed by the complete hydrolysis of following compound
with H3O .

Solution: (04.00)

12
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

Q.29 The number of resonating structures for N is

Solution: (09.00)

Q.30 The following compound is treated with excess of Br2 / H 2O . Find the total number of positions,
where bromination will occur significantly:

Solution: (07.00)

13
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
BAKLIWAL TUTORIALS

14
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com

You might also like