Professional Documents
Culture Documents
61
Q.1 When Ni nuclei are bombarded with deuterons in an accelerator, 61 Cu (half life 3.5 hr) is produced. The
copper atoms are made at a rate of 6.93 108 s1 when the accelerator is running. Find the maximum number
of 61
Cu that can be produced in the accelerator. n2 = 0.693 :
(A) 5.0 1010 (B) 1.26 1013 (C) 3.5 108 (D) 1.4 108
Solution : (B)
Q.2 A radioactive material decays by simultaneous emission of two particles with respective half lives 1620 and
810 years. The time (in years) after which one-fourth of the material remains is :
(A) 1080 (B) 2430 (C) 3240 (D) 4860
Solution : (A)
Q.3 The ratio of de-Broglie wavelength of molecules of hydrogen and helium moving at rms speed in two gas jars
kept separately at temperature 27 C and 127 C , respectively, is :
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2 3 8
(A) (B) 2 : 3 (C) (D)
3 4 3
Solution : (D)
Q.4 Probability of decay of a particular nucleus of substance Z in next 1 hour is 3 . Then probability of decay of a
nucleus of same substance :
1 1 5
(A) In next hours is (B) In next 2 hours is
2 3 9
1 1
(C) In next 3 hours is (D) In next 1.5 hour is
3 3
Solution : (B)
Q.5 Hydrogen atom in ground state absorb a photon of energy 12.75 eV. How many spectral lines are observed in
emission spectrum :
(A) 3 (B) 6 (C) 10 (D) 1
Solution : (B)
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Q.6 A free particle with initial kinetic energy E and de-broglie wavelength λ enters a region in which it has
potential energy V. What is the particle’s new de Broglie wavelength?
Solution : (D)
Q.7 In a hypothetical system a particle of mass m and charge – 3q is moving around a very heavy particle having
change q. Assume that Bohr’ model is applicable to this system, then velocity of mass m in first orbit is :
3q 2 3q 2 3q 3q
(A) (B) (C) (D)
2ε 0 h 4ε 0 h 2πε 0 h 4πε 0 h
Solution : (A)
Q.8 A point source of light is used in a photoelectric effect. If the source is moved farther from the emitting metal,
the stopping potential :
(A) will increase (B) will decrease
(C) will remain constant (D) will either increase or decrease.
Solution : (C)
Only intensity will decrease
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No change in frequency
0
Q.9 The wavelength of L line in x-ray spectrum of 78 Pt is 1.32 A . The wavelength of L line in x-ray spectrum
0
of another unknown element is 4.17 A . If screening constant for L line is 7.4, then atomic number of the
unknown element is :
(A) 78 (B) 47 (C) 40 (D) 35
Solution : (B)
Q.10 A stream of particles is incident on a sample of hydrogen gas. What should be minimum kinetic energy of
- particles to ionize the hydrogen atoms [(mass of - particle) = 4 (mass of hydrogen atoms)]
(A) 17 eV (B) 34 eV (C) 51 eV (D) 68 eV
Solution : (D)
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Q.11 In a characteristic X-ray spectra of some atom superimposed on continuous X-ray spectra :
Solution : (C)
Fact Based
Q.12 Fastest electrons ejected from a surface by incident light of wavelength 330 nm are bent into circle of radius 1
m as they pass through magnetic field of 2.5 106 T . Find the work function of the surface.
(A) 4.3eV (B) 2.2eV (C) 2.5eV (D) 3.2eV
Solution : (D)
Q.14 One mole of ideal monoatomic gas at initial state a with pressure P0 and volume V0 is taken to a final state ‘d’
V0
with pressure e3 P0 and volume through the path a b c d (figure) a b and c d are adiabatic
e
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paths were as b c is isothermal with temperature T0 . Find the work done by the gas in the process b c .
(Given : n e 1 )
5 3
(A) 2 RT0 (B) RT0 (C) 4 RT0 (D) RT0
3 2
Solution : (A)
Q.15 In the diagram shown Qiaf = 80cal and Wiaf = 50cal . If W = - 30 cal for the curved path fi, value of Q for
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(A) 60 cal (B) 30 cal (C) – 30 cal (D) – 60 cal
Solution : (D)
Q.16 The distribution of relative intensity I λ of blackbody radiation from a solid object versus the wavelength λ
is shown in the figure. If the Wien displacement law constant is 2.9 103 mK , what is the approximate
temperature of the object?
dp
Q.17 Figure shows the adiabatic curve for 2 moles of an ideal gas. The Bulk modulus i.e. B = at the
dV/V
point P will be :
T0 T0 2RT0
(A) R 1+ (B) 2R 1+ (C) (D) None of these
V0 V0 V0
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Solution : (B)
Q.18 An ideal gas is expanding such that pT 2 = constant. The coefficient of volume expansion of the gas is :
1 2 3 4
(A) (B) (C) (D)
T T T T
Solution : (C)
Q.19 A certain gas is taken to the five states represented by dots in the graph. The plotted lines are isotherms. Order
of the most probable speed vp of the molecules at these five states is :
(A) VPat 3 VPat1 VPat 2 VPat 4 VPat 5 (B) VPat1 VPat 2 VPat 3 VPat 4 VPat 5
(C) VPat 3 VPat 2 VPat 4 VPat1 VPat 5 (D) Insufficient information to predict the result.
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Solution : (A)
Q.20 The co-efficient of thermal expansion of a rod is temperature dependent and is given by the formula aT ,
where a is a constant and T in C . If the length of the rod is at temperature 0 C , then the temperature at
n2 n4 1 2
(A) (B) (C) (D)
a
Solution : (B)
NUMERICAL TYPE
Q.21 Suppose radiation from a black body is allowed to fall on a photosensitive material after passing it through a
filter which selects the wavelength having maximum intensity to pass. The work-function of the material is 1
1.24eV . Find the minimum temperature in103 K of the black-body which will cause the emission of
3
photo-electrons. Given Weins con tan t b 3 10 m K & hc 12400 eV A
Solution : (03.00)
Q.22 92 U238 changes to 85 At 210 by a series of and decays. Find number of - decays undergone (in integer).
Solution : (07.00)
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Q.23 An ideal gas undergoes a cyclic process ABCDEA. Pressure vs volume graph for this process is given as
shown. Find work done by gas in kJ
Solution : (03.00)
Q.24 Bacteria can be knocked out in the presence of radiation from green kryptonite, which has a very long half-
life. If 150 g of it can knock out the bacteria in just 1.5 minutes, how long can the bacteria withstand the
radiation if there is 4.5 kg of slab of green kryptonite? Assume that kryptonite obeys radioactive decay law.
2
Express your answer in power of 10 minutes.
Solution : (05.00)
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1 1
Q.25 A radioactive sample contains two radio nucleoids A and B having decay constant λ hr and 2λ hr .
Initially 25% of total decay comes from A. How long (in hr) will it take before 75% of total decay comes from
A. [Take λ = n 3 ]
Solution : (02.00)
Q.26 A body cools in 7 minutes from 600C to 400C. What will be its temperature after the next 7 minutes in °C. The
temperature of surroundings is 100C.
Solution : (28.00)
Q.27 If the temperature of a hot body is raised by 5%, then the heat energy radiated would increase by what
percentage -
Solution : (21.55)
Q.28 In the P – V diagram shown. The gas does 5 J of work in isothermal process ab and 4 J in adiabatic process
bc. What will be the change in internal energy of the gas in straight path c to a?
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Solution : (04.00)
Q.29 Two ideal monoatomic & diatomic gases are mixed with one another to form an ideal gas mixture. The
11
equation of the adiabatic process of the mixture is PVγ constant , where γ = . If n1 and n2 are the
7
number of moles of the monoatomic & diatomic gases in the mixture respectively, find the ratio n1/n2.
Solution : (03.00)
Q.30 A black body radiates heat energy at the rate of 2 105 joule/sec/m2 at a temperature 127 C . The
temperature of the black body, at which the rate of heat radiation is 32 105 joule/sec/m2 is in C -
Solution : (527.00)
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(A) (B) (C) (D)
2 4 3
Solution: (C)
x dx
Q.2 The expression 0
n
, where [x] and {x} are integral and fractional parts of x and n N is equal
x dx
0
to
1 1
(A) (B) (C) n (D) n 1
n 1 n
Solution: (D)
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2
, then the value of integral f ' x 1 ln x dx 1 is
f x x f x
e
2
Q.3 If x
1
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2012 2
d
x
Q.4 The value of the integral cos t 2 dt dx is
2012
dx 0
(A) 2012 (B) 4024 (C) 0 (D) 2012
Solution: (C)
1 x2
x
dx 1 1
f x is
1/ x
Q.5 If ln c , then lim
x 2
1
3
4 f x
2
2 f x 2 f x x 0
3n
n
Q.6 lim
n
r 2 n 1 r n
2 2
is equal to
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2 3 2 3
(A) ln (B) ln (C) ln (D) ln
3 2 3 2
Solution: (B)
2012
Let x 2 f x t and x 4 f x t 2 2 . Then the value of x . f x . f ' x x dx is
2 1 4 1 3
Q.9
t t 2012
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x x x
Q.10 Let f x ..... then the value of the integral
1 x 1 x 1 2 x 1 9 x 1 10 x
5
1
f x 1 10 x dx is
5
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Q.11 Let f n e x x n1dx, n N , x Q . Then the value of f 5 is
0
log x d2 y
Q.12 If y , then 2
x dx
3 2 log x 2 log x 3 2 log x 3 2 3log x
(A) (B) (C) (D)
x3 x3 x4 x4
Solution: (B)
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dy
Q.13 If 3sin xy 4cos xy 5 , then equals
dx
y y x x
(A) (B) (C) (D)
x x y y
Solution: (B)
1
Q.14 Let g(x) be the inverse of the function f(x), and f ' x then g’(x) equals
1 x3
1 1
(A) (B) (C) 1 g 3 (D) 1 f 3
1 g 3 1 f 3
Solution: (C)
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Q.15 Let f(x) is a polynomial satisfying f x . f y f x f y f xy – 2 x, y and f(2) = 1025,
1 1 1 dy bc
Q.16 If y then find at e a .
1 x a b x c b 1 x b c x a c 1 xb a x c a dx
(A) 0 (B) 1 (C) 2 (D) 3
Solution: (A)
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2
dx
Q.17 The value of x 1 x
1
4
is equal to
1 17 1 17 17 1 32
(A) log (B) log (C) log (D) log
4 32 4 2 2 4 17
Solution: (D)
Q.18 The area of figure bounded by the curves y a x a 1 and y b – x b 1 and the straight line x = 1
is
1 1 1 1
(A) a 1 1 (B) (log a ) a 1 (log b) 1
log a log b b b
1 1
(C) a 1 b 1 (D) (log a ) a 1 (log b) b 1
log a log b
Solution: (A)
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2 2
(A) 2sq.unit (B) 2 2sq.unit (C) sq.unit (D) sq.unit
2 4
Solution: (C)
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NUMERICAL TYPE
18
Q.21 If sin x cos x dx k and [.] denotes the greatest integer function, then k is _________.
0
Solution: (09.00)
x 2 sin 2 x sin cos x
Q.22 If 2 dx A , then A is _____________.
0
2x
Solution: (08.00)
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x sin 1 x 3
1/2
Q.23 If I 0 1 x2
dx A
12
, then 2A is _________.
Solution: (01.00)
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Q.24 If the right hand derivative of h(x) = {x} ({.} is fractional part of x) exists at x = 1 then it is equal
to_______.
Solution: (01.00)
Solution: (01.00)
Q.26 If f(x) = f(1 – x) and f(x) is differentiable at every real value of x then the value of
1 1 3
f ' f ' f ' is ______.
2 4 4
Solution: (00.00)
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Solution: (01.00)
10
Q.28 The area of f x dx , where f x min x x , x x , where [ ] is G.I.F., is
10
Solution: (05.00)
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k
Q.29 If the area bounded by y x2 and x y 2 is sq. units, then k is __________.
15
Solution: (05.00)
Q.30 For which of the following positive value of m, the area of the region bounded by the curve
9
y x x 2 line y = mx equals ?
2
Solution: (04.00)
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COMP2021 PART TEST -9 CHEMISTRY PAPER
SINGLE CORRECT TYPE
Q.1 The catalyst decrease the Ea from 100 kJ mol–1 to 80 kJ mol–1. At what temperature the rate of
reaction in the absence of catalyst at 500 K will be equal to rate reaction in presence of catalyst
(A) 400 K (B) 200 K (C) 625 K (D) None of the above
Solution: (A)
rate k A B
3/2
Q.4 Which of the following statement is true for all the alkali metals?
(A) Their nitrates decompose on heating to give the corresponding nitrites and oxygen.
(B) Their chlorides are deliquescent and crystallise as hydrates.
(C) They react with water to form hydroxide and hydrogen gas.
(D) They readily react with halogens to form ionic halides, M X
Solution: (C)
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Q.5 Which of the following statements is not true about the dilute solutions of alkali metals in liquid
ammonia?
(A) They are deep blue coloured solution
(B) They are highly conducting in nature
(C) They are diamagnetic in nature.
(D) Ammoniated cation and solvated electron are formed in the solution.
Solution: (C)
Q.6 Which of the following statements are true about the alkali metals?
(1) All alkali-metal chloride salts impart a characteristic colour to the Bunsen flame.
(2) The correct order of increasing thermal stability of the carbonates of alkali metals is
Li2CO3 Na2CO3 K2CO3 Rb2CO3 Cs2CO3
(3) Among the alkali metals, cesium is the most reactive.
(4) The reducing character of the alkali metal hydrides follow the order:
LiH NaH KH RbH CsH
(A) (1), (2) and (3) (B) (1), (3) and (4) (C) (2), (3) and (4) (D) (1), (2), (3) and (4)
Solution: (A)
Q.7 S1: Plaster of paris is a hemihydrated of calcium sulphate obtained by heating the gypsum above
393K.
S2: Sodium carbonate is used in water softening.
S3: The order of mobilities of the alkali metal ions in aqueous solutions is
Li Na K Rb CS
(A) TTF (B) TTT (C) FTF (D) FFF
Solution: (C)
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Q.8 Composition of a sample is Fe0.93O1.00 . If Fe is present in +2 & +3 oxidation state in this sample then
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Q.11 A gaseous mixture contains CO2 g and H 2 g in a 2.2 : 1 ratio by mass. The ratio of the number
Q.12 For a first order reaction, the value of rate constant for the reaction
A gas
2B gas C solid
1 P0 1 P0
(A) ln (B) ln
t P0 Pt t 2 P0 Pt
1 2 P0 1 2 P0
(C) ln (D) ln
t 3P0 Pt t 2 P0 Pt
Solution: (B)
Q.13 What is the activation energy for a reaction if its rate doubles when the temperature is raised from
20 C to 35 C ? (R = 8.314 J mol–1 K–1)
(A) 269 kJ mol –1 (B) 34.6 kJ mol –1 (C) 15.1 kJ mol –1 (D) 342 kJ mol –1
Solution: (B)
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Q.14 An aldehyde X (C11H10O), which does not undergo self aldol condensation, gives benzaldehyde
and two moles of Y on ozonolysis. compound Y, on oxidation with silver ion gives oxalic acid. The
compounds X and Y, are respectively :
Solution: (C)
(A) It gives yellow ppt with I 2 / OH (B) It gives silver mirror with Tollen’s reagent
(C) It shows stereoisomerism (D) It does not give yellow ppt with 2,4 DNP
Solution: (A)
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Q.16
(B) P when reacts with NaCNand H 2 SO4 , gives two optically active resolvable product.
Solution: (C)
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Q.17 Match list I (reaction) with II (product) and then select the correct answer from the codes given
below the lists:
List I List II
(Reactions) (Product)
Codes:
P Q R S P Q R S
(A) 1 3 4 2 (B) 4 1 3 2
(C) 4 1 2 3 (D) 3 1 4 2
Solution: (B)
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Q.18 Match list I (reaction) with II (product) and then select the correct answer from the codes given
below thelists:
List I List II
(Reactions) (Product)
Codes:
P Q R S P Q R S
(A) 1 2 3 4 (B) 1 2 4 3
(C) 2 1 3 4 (D) 2 1 4 3
Solution: (D)
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Q.19
Solution: (B)
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Q.20
Solution: (A)
NUMERICAL TYPE
Q.21 How many of the following compounds do not impart characteristic colour to the Bunsen flame:
NaCl , BeCl2 , KOH , BaSO4 , MgCl2 , CsCl , Na2 SO4 , Mg OH 2 , K 2CO3
Solution: (03.00)
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Compounds of Be and Mg do not impart any colour to Bunsen flame.
Q.22 A bottle of 1 litre capacity is labeled as 1 molar Al2 SO4 3 aq . If the bottle is half filled and
density of solution is 1.342 g/mL, then what will be molality of Al 3 aq in this solution.
Solution: (02.00)
Q.23 A sample of copper is used to prepare 100 ml of 0.02 M CuSO 4(aq) solution. 10 ml of this
CuSO4(aq) solutionis mixed with excess of KI to show the following changes.
CuSO 4 + 2KI K 2SO 4 + Cul 2
2Cul2 Cu 2 I 2 + I 2
The liberated iodine is titrated with hypo solution (Na2S2O3) and requires V ml of 0.01 M hypo
solution for itscomplete reduction. The volume (V) of hypo required is :
Solution: (20.00)
N
Q.24 20 ml of H 2O2 after acidification with dil H2SO4 required 30 ml of KMnO4 for complete
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oxidation. The volume strength of H2O2 solution is :
Solution: (00.70)
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Q.25 One litre of a sample of hard water contain 4.44 mg CaCl2 and 1.9 mg of MgCl2. What is the total
hardness in terms of ppm of CaCO3 ?
Solution: (06.00)
Q.26 How many of the following compounds react with NaHCO3 and liberate CO2(g)
1. Salicylic acid 2. Pthalic acid 3. Picric acid 4. Resorcinol
5. Carbolic acid 6. Aspirin 7. Anisol 8. Tarteric acid
Solution: (05.00)
Q.27
The total number of isomeric products (including stereoisomers) formed at the end of the reaction
is:
Solution: (04.00)
Q.28 How many moles of formaldehyde is formed by the complete hydrolysis of following compound
with H3O .
Solution: (04.00)
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Solution: (09.00)
Q.30 The following compound is treated with excess of Br2 / H 2O . Find the total number of positions,
where bromination will occur significantly:
Solution: (07.00)
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