BAKLIWAL TUTORIALS

COMP2024 BTEST-4 CHEMISTRY

SINGLE CORRECT

Q.1 S1 : Bohr model is applicable for He2+ ion.

ℎ
S2 : As per Bohr model , linear momentum of an e- is integral multiple of 2𝜋.
1
S3 : Specific charge ratio of proton to alpha particle is 2.
e
S4 ∶ m ratio of cathode ray experiment, depends on the nature of the gas.

(A) T T F T (B) T T T T (C) F F T F (D) F F F F

Solution: (D)

Q.2 Heating of a solution does not change

(A) the %V/V of the solution (B) the molarity of the solution
(C) the molality of the solution (D) the density of the solution

Solution: (C)

MOLALTTY 
 independent of volume.
Q.3 The energy of an electron in the first Bohr orbit is −13.6 eV. The energy of Be3+ in the first excited
state is
(A) −30.6 eV (B) −40.8 eV (C) −54.4 eV (D) +40.8 eV

Solution: (C)

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Q.4 As an electron jumps from the fourth orbit to the second orbit in Be3+ ion, its
(A) K.E. decreases (B) speed decreases
(C) frequency of revolution decreases (D) P.E. decreases

Solution: (D)

Q.5 Which of the following is incorrect for Rutherford’s  – particle scattering experiment -
(A) Most of the space in the atom is empty
(B) The radius of the atom is about 10−10 m while that of nucleus is 10−15 m
(C) Electrons move in a circular path of fixed energy called orbits
(D) Electrons and the nucleus are held together by electrostatic forces of attraction.

Solution: (C)

Q.6 5 moles of A, 6 moles of B and excess amount of C are mixed to produce a final product D, according
to the reactions:

A+2B →E

E+C→B+D

What is the maximum moles of D. which can be produced assuming that the products formed can
also be reused in the reactions?
(A) 3 moles (B) 4.5 moles (C) 5 moles (D) 6 moles

Solution: (C)

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Q.7 Of the following sets which one does not contain isoelectronic species?
(A) BO3− 2− −
3 , CO3 , NO3 (B) SO2− 2− −
3 , CO3 , NO3

(C) CN − , N2 , C22− (D) PO3− 2− −

4 , SO4 , ClO4

Solution: (B)

Q.8 A particle X moving with a certain velocity has a debroglie wave length of 1 A∘ . If particle Y has a
mass of 25% that of X and velocity 75% that of X, debroglies wave length of 𝑌 will be :-
(A) 3 A∘ (B) 5.33 A∘ (C) 6.88 A∘ (D) 48 A∘

Solution: (B)

Q.9 Last line of Lyman series for H-atom has wavelength 𝜆1 Å, 2nd line of Balmer series has wavelength
𝜆2 Å then
16 9 16 3 4 1 16 3
(A) 𝜆 = 𝜆 (B) 𝜆 = 𝜆 (C) 𝜆 = 𝜆 (D) 𝜆 = 𝜆
1 2 2 1 1 2 1 2

Solution: (B)

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𝑥
Q.10 An electron in an atom jumps in such a way that kinetic energy changes from 𝑥 to 4. The change in

potential energy will be:

3 3 3 3
(A) + 2 𝑥 (B) − 8 𝑥 (C) + 4 𝑥 (D) − 4 𝑥

Solution: (A)

Q.11 The ionization energy of hydrogen atom in the ground state is 𝑥 kJ. The energy required for an
electron to jump from 2nd orbit to 3rd orbit in Be3+ is
5𝑥 20 x
(A) (B) 5 x (C) 7.2 x (D)
36 9

Solution: (A)

6.62
Q.12 An electron having velocity 2 × 106 m/s has uncertainity in kinetic energy is × 10−21 J, then
𝜋

calculate the uncertainity in position (in Angstrom, Å) of the electron.

[Given: h = 6.62 × 10−34 J − sec]

(A) 1000 (B) 200 (C) 250 (D) 500

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Solution: (D)

Q.13 The graph between |ψ|2 and 𝑟(radical distance) is shown below. This represents:

(A) 2𝑠 orbital (B) 2𝑝 orbital (C) 3s orbital (D) 1s orbital

Solution: (A)

It is clear from the graph it has one node and starting from maximum i.e. 2 s orbital.

Q.14 Two electrons occupying the same orbital are distinguished by

(A) Principal quantum number (B) Magnetic quantum number
(C) Azimuthal quantum number (D) Spin quantum number

Solution: (D)

Q.15 The graphical representation of energy of e− and atomic number is :-

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Solution: (D)

Q.16 The number of d-electrons in Fe2+ (𝑍 = 26) is not equal to the number of electrons in which one of
the following ?
A) p-electrons in Cl(Z = 17) (B) d-electrons in Fe(Z = 26)
(C) p-electrons in Ne(𝑍 = 10) (D) s-electrons in Mg(𝑍 = 12)

Solution: (A)

Q.17 Which is the correct order of increasing energy of the listed orbitals in the atom of titanium?

(At. no. 𝑍 = 22 )

(A) 3s 3p 3d 4s (B) 3s 3p 4s 3d (C) 3s 4s 3p 3d (D) 4s 3s 3p 3d

Solution: (B)

Q.18 A balloon filled with H2 is pricked with a sharp point and quickly dropped in a tank of C2 H2 gas
under identical conditions. After a while the balloon will have : (assume non reacting mixture)
(A) Enlarged (B) Remained unchanged in size
(C) Shrunk (D) None of these

Solution: (C)

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Q.19 Which gas can be easily liquefied?

given 'a' for NH3 = 4.17, CO2 = 3.59, SO2 = 6.71, Cl2 = 6.49
(A) NH3 (B) Cl2 (C) SO2 (D) CO2

Solution: (C)

Q.20 A certain mass of a gas occupies a volume of 2 litres at STP. Keeping the pressure constant at what
temperature would the gas occupy a volume of 4 litres-
(A) 546∘ C (B) 273∘ C (C) 100∘ C (D) 50∘ C

Solution: (B)

INTEGER TYPE

Q.21 The figure shows a sample of H-atoms having electron revolving in higher orbit ' 𝑛 '.

If this electron makes transition from this orbit 'n' to ground state, Number of paschen lines emitted
are
Solution: (3)

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Q.22 A volume of 10 ml of gaseous C4 HX exactly requires 55 ml O2 for complete combustion. The value
of ' x ' is
Solution: (6)

Q.23 The work function 𝜙 of some metals is listed below. The number of metals which will show
photoelectric effect when light of 300 nm wavelength falls on the metal is :-

Metal Li Na K Mg Cu Ag Fe Pt W
 (eV) 2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

Solution: (4)

Q.24 The eyes of certain member of the reptile family pass single visual signal to the brain when the visual
receptors are struck by photons of wavelength 662 nm. If a total energy of 3.0 × 10−14 J is required
to trip the signal, the minimum number of photons that must strike the receptor is 10𝑥 . find 𝑥(ℎ =
6.62 × 10−34 J × s)
Solution: (5)

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Q.25 Most probable speed of a gas at 150 K is equal to the root mean square speed of O2 gas at 400 K.
Molecular mass of the gas in g/mol is:

Solution: (8)

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