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IIT – JEE: 2020 TW TEST (ADV) DATE: 19/08/18

TIME: 1 Hr. TOPIC: ATOMIC STRUCTURE & MOLE CONCEPT MARKS: 80

SECTION-I (SINGLE ANSWER CORRECT TYPE)

This section contains 05 Multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONLY ONE is correct. (+4, –1)

21. The number of molecules present in a drop of water with volume 0.06 cm 3 having density 1 gm/cm3
is approximately.
(A) 1021 (B) (C) (D)

22. A sentence contains 35 alphabets and written in a line. One page contain 35 lines. The mass of
carbon needed to write this page if one alphabet contains carbon atom is approximately.
(A) (B) (C) (D)

23. Mole fraction of methanol is 0.4 in methanol-ethanol solution. What is molality of the solution?
(A) 14.5 (B) 37.1 (C) 20.83 (D) 7.25

24. 5 gm each of H2 and Cl2 reacts together to form maximum HCl of mass
(A) 5 gm HCl (B) 5.14 gm HCl (C) 10gm HCl (D) 25gm HCl

25. If 0.5 mole of BaCl2 is mixed with 0.2 mole of Na 3PO4 solution. The maximum mole Ba3(PO4)2 that
can be formed is
(A) 0.7 (B) 0.5 (C) 0.3 (D) 0.1

SECTION-II (MULTIPLE ANSWER(S) CORRECT TYPE)

This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO incorrect
option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C) and (D) are all the correct options for a question, darkening all these three will
result in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will
result in –2 marks, as a wrong option is also darkened.

26. 4.4 gm of CO2 contains:

(A) 1 mole of CO2 (B) 0.1 mole of CO2
(C) molecules of CO2 (D) 0.1 gm-mole of CO2

27. 1021 molecules are removed from 440 mg of CO2. It becomes

(A) 366 mg (B) 8.3 milli mole (C) 200 mg (D) 4.1 milli mole

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28. A certain compound has the molecular formula X4O6 having 57.2%.X thus:
(A) ‘X’ can be non metal (B) ‘X’ is an electro positive metal
(C) Atomic mass of X is 32 (D) ‘X’ may contains six valence electrons

29. In diammonium hydrogen phosphate percentage as .

(A) N = 21.21 % (B) P = 23.48 % (C) H = 6.81 % (D) O = 48.48 %

30. If the wave number of 1st line of Balmer series of H-atom is ‘x’ then:

(A) Wave number of 1st line of lyman series of the ion will be

(B) Wave number of 1st line of lyman series of the ion will be

(C) The wave length of 2nd line of lyman series of H-atom is

(D) The wave length of 2nd line of lyman series of H-atom is

31. Radius of 3rd orbit of ion is ‘x’ cm then de-broglie wavelength of electrons in the 1 st orbit of
hydrogen is

(A) (B) (C) (D)

SECTION-III (COMPREHENSIONS TYPE)

This section contains 04 questions. Based on each paragraph, there are TWO questions. Each question has 4
choices (A), (B), (C) and (D) for its answer, out which ONLY ONE is correct. (+4, –1)

Paragraph for Questions No. 32 & 33

The French physicist Louis de Broglie in 1924 postulated that matter, like radiation, should exhibit a
dual behavior. He proposed the following relationship between the wavelength of a material
particle, its linear momentum p and Planck constant h.

The de Broglie relation implies that the wavelength of a particle should decrease as its velocity
increases. It also implies that for a given velocity heavier particles should have shorter wavelength
than lighter particles. The waves associated with particles in motion are called matter waves or de
Broglie waves. These waves differ from the electromagnetic waves as they
(i) have lower velocities
(ii) have no electrical and magnetic fields and
(iii) are not emitted by the particle under consideration.
The experiment confirmation of the de Broglies relation was obtained when Davisson and Germer,
1927, observed that a beam of electrons is diffracted by a nickel crystal. As diffraction is a
characteristic property of waves, hence the beam of electron behaves as a wave, as proposed by de
Broglie

32. If proton, electron and -particle are moving with same kinetic energy then the order of their de-
Broglie’s wavelength.
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 (A) (B) (C) (D)

33. Using Bohr’s theory, the transition, so that the electrons de-Broglie wavelength becomes 3 times of
its original value in ion will be
(A) (B) (C) (D)

Paragraph for Questions No. 34 & 35

DEFINITION VALID FOR SINGLE ELECTRON SYSTEM:
Ground state: Lowest energy state of any atom or ion is called ground state of the atom. It is n=1.
Excited state: States of atom other than the ground state are called excited states.
Ionisation energy (IE): Minimum energy required to move an electron from ground state to
is called ionisation energy of the atom or ion.
Ionisation Potential (I.P): Potential difference through which a free electron must be accelerated
from rest, such that its kinetic energy becomes equal to ionisation energy of the atom is called
ionisation potential of the atom.
Excitation Energy: Energy required to move an electron from ground state of the atom to any other
state of the atom is called excitation energy of that state.
Excitation Potential: Potential difference through which an electron must be accelerated from rest
to so that its kinetic energy become equal to excitation energy of state is called excitation potential of
that state.
Binding Energy ‘or’ Separation Energy: Energy required to move an electron from any state to
is called binding energy of that state.
The wavelength of the photon emitted upon an electronic transition from to orbit in a H-like
species is given by the formula:

Now answer the following questions:

34. If the binding energy of II excited state of a H-like species is 13.6eV, then:
(A) The atomic number Z of given H-like species is 2.
(B) A photon of energy 30eV can ionize an electron from I excited state of given H-like species.
(C) Upon de-excitation from n=4 to n=2 in given H-like species, the emitted photon has wave

number (R = Rydberg’s constant)

(D) Ionisation potential of given H-like species is 122.4 V.

35. If the wavelength of Photon emitted from an electron jump n = 4 to n = 2 in a H-like species is
1216Å then the species is:
(A) H-atom (B) He+ ion (C) ion (D) ion

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 SECTION-IV (INTEGER ANSWER TYPE)
This section contains 05 questions. The answer to each question is a NUMERICAL VALUE. For each
question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the second
decimal place; e.g. 6.25, 7.00, 0.33, 30.27, 127.30) (+4, –1)

36. The Calculated spin only magnetic moment of 41Nb is found to be 5.916. Total number of unpaired
electrons are:

37. The maximum number of electrons that can have principal quantum number, n = 3, and spin

quantum number , is:

38. In an orbital maximum number of possible electrons with the quantum numbers l = 3 and s = –1/2
is/are

39. In a sample of excited hydrogen atoms electron make transition from n = 2 to n =1. Emitted photon
strike on a metal of work function . Calculate the wavelength (Å) associated with
ejected electron having maximum kinetic energy.

40. The decomposition of a certain mass of CaCO 3 gave 11.2 dm3 of CO2 gas at STP. The mass (in g) of
KOH required to react with CO2 obtained above to form potassium bicarbonate ,KHCO3, is fourteen
times x, where x is _______.

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 MUMBAI / AKOLA / DELHI / KOLKATA / LUCKNOW / NASHIK / GOA / BOKARO / PUNE / NAGPUR
IIT – JEE: 2020 TW TEST (ADV) DATE: 19/08/18
TOPIC: ATOMIC STRUCTURE & MOLE CONCEPT

ANSWER KEY

21. (B) 22. (D) 23. (A) 24. (B) 25. (D)

26. (BCD) 27. (AB) 28. (ACD) 29. (ABCD) 30. (AC)

31. (A) 32. (C) 33. (A) 34. (D) 35. (B)

36. (5) 37. (9) 38. (1) 39. (5) 40. (2)

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