RE VIEW TES T- 1 1 / 8

PAPER-1
Class : XII & XIII
Time : 3 hour Max. Marks : 219
INSTRUCTIONS

Please ensure that the Question Paper you have received contains all the QUESTIONS and
Pages. If you found some mistake like missing questions or pages then contact immediately to the
Invigilator.
1. The question paper contains 63 questions and 19 pages. All of them are compulsory.
PART-A
(i) Q.1 to Q.48 have only one correct alternative and carry 3 marks each.
There is NEGATIVE marking and 1 mark will be deducted for each wrong answer.
(ii) Q.49 to Q.63 have one or more than one is/are correct alternative and carry 5 marks each.
There is NO NEGATIVE marking. Marks will be awarded only if all the correct alternatives are selected.

2. Indicate the correct answer(s) for each question by filling appropriate bubble(s) in your OMR sheet.

3. Use only HB pencil for darkening the bubble(s).

4. Use of Calculator, Log Table, Slide Rule and Mobile is not allowed.

5. For example if only 'B' choice is correct then, the correct method for filling the bubble is
A B C D

For example if only 'B & D' choices are correct then, the correct method for filling the bubbles is
A B C D

The answer of the question in any other manner (such as putting , cross , or partial shading etc.)
will be treated as wrong.

USEFUL DATA
Atomic Mass: Al = 27, Mg = 24, Cu = 63.5, Mn = 55, Cl = 35.5, O = 16, H = 1, P = 31, Ag = 108, N = 14,
Li = 7, I = 127, Cr = 52, K=39, S = 32, Na = 23, C = 12, Br = 80, Fe = 56, Ca = 40, Zn = 65.4, Ba = 137,
Co = 59, Hg = 200, Pb = 207, He = 4, F=19, Ar = 40.
Radius of nucleus =10–14 m; h = 6.626 ×10–34 Js; me = 9.1 ×10–31 kg, RH = 109637 cm–1.
Take g = 10 m/s2 where ever required.
 Select the correct alternative. (Only one is correct) [48 × 3 = 144]
There is NEGATIVE marking. 1 mark will be deducted for each wrong answer.

Q.1 The circuit below is made up using identical light bulbs. The light bulbs of maximum brightness of the
following will be

(A) A (B) C (C) D (D) E

Q.2 In the diagram shown, all the wires have resistance R. The equivalent resistance between the upper and
lower dots shown in the diagram is

(A) R/8 (B) R (C) 2R/5 (D) 3R/8

Q.3 A plastic circular disc of radius R is placed on a thin oil film, spread over a flat horizontal surface. The
torque required to spin the disc about its central vertical axis with a constant angular velocity is proportional
to
(A) R2 (B) R3 (C) R4 (D) R6
Q.4 The surface tension of water is 75 dyne/cm. Find the minimum vertical force
required to pull a thin wire ring up (refer figure) if it is initially resting on a horizontal
water surface. The circumference of the ring is 20 cm and its weight is 0.1 N
(A) 0.125 N (B) 0.225 N
(C) 0.115 N (D) 0.130 N

Q.5 A particle is moving along the locus: y = kx (k > 0) with a constant speed 'v'. At t = 0, it is at the origin
and about to enter the first quadrant of x-y axes. At some later time t > 0, v x = vy. At this moment,
[ay – ax] =
(A) v2/k2 (B) zero (C) –v2/k2 (D) none

Q.6 A radioactive sample decays by -emission. In first two seconds 'n' -particles are emitted and in next
2 seconds, '0.25n' -particles are emitted. The half life of radioactive nuclei is
(A) 2 sec (B) 4 sec (C) 1 sec (D) none

Q.7 The difference between the longest wavelength line of the Balmer series and shortest wavelength line of
the Lyman series for a hydrogen like atom (Atomic number Z) equal to . The value of the Rydberg
constant for the given atom is
5 1 5 Z2 31 1
(A) (B) (C) (D) none
31 ·Z 2 36  5 ·Z 2

Q.8 A rigid uniform triangular frame ABC of mass m is hanging from a rigid long horizontal rod PQ. The
frame is constrained to move along horizontal without friction. A bead of mass m is released from B that
moves along BC. Displacement of frame when bead reaches C is
l l
(A) (B)
2 4

3l
(C) (D) none
2
Q.9 Three boys are running on a equi triangular track with same speed 5 m/
s. At start, they were at the three corners with velocity along indicated
directions. The velocity of approach of any one of them towards another,
at t = 10 s equals
(A) 7.5 m/s (B) 10 m/s
(C) 5 m/s (D) 0 m/s

Q.10 Time constant of the given circuit is . If the battery is replaced by an ac source having voltage
V = V0 cos t, power factor of the circuit will be
1
(A)  (B) (C) 1  () 2 (D) None
1  ( ) 2

Comprehension: (Q.11 to Q.13)

A calorimeter of mass m contains an equal mass of water in it. The temperature of the water and calorimeter
is t2. A block of ice of mass m and temperature t3 < 0° C is gently dropped into the calorimeter. Let C1,
C2 and C3 be the specific heats of calorimeter, water and ice respectively and L be the latent heat of
fusion of ice.

Q.11 The whole mixture in the calorimeter becomes ice if

(A) C1t2 + C2t2 + L + C3t3 > 0 (B) C1t2 + C2t2 + L + C3t3 < 0
(C) C1t2 + C2t2 – L + C3t3 > 0 (D) C1t2 + C2t2 – L – C3t3 < 0

Q.12 The whole mixture in the calorimeter becomes water if

(A) (C1 + C2)t2 – C3t3 + L > 0 (B) (C1 + C2)t2 + C3t3 + L > 0
(C) (C1 + C2)t2 – C3t3 – L > 0 (D) (C1 + C2)t2 + C3t3 – L > 0

Q.13 Water equivalent of calorimeter is:

mC1 mC 2
(A) mC1 (B) C (C) C (D) none
2 1
 Comprehension: (Q.14 to Q.16)
The fact that a changing magnetic flux produces an electric field
is basic to the operation of many high energy particle accelerators.
Since the principle was first successfully applied to the
acceleration of electrons (or  particles) in a device called the
betatron, this method of acceleration is often given that name.
The general idea involved is shown in figure.
An electromagnet is used to produce a changing flux through a circular loop defined by the doughnut-
shaped vacuum chamber. We see that there will be an electric field E along the circular length of the
doughnut, i.e. circling the magnet poles, given by
d
2aE =
dt
Where a is the radius of the doughnut. Any charged particle inside the vacuum chamber will experience
a force qE and will accelerate. Ordinarily, the charged particle would shoot out of the vacuum chamber
and becomes lost.However, if the magnetic field at the position of the doughnut is just proper to satisfy
the relation Centripetal force = magnetic force
mv 2
or = qvB
a
then the charge will travel in a circle within the doughnut. By proper shaping of the magnet pole pieces,
this relation can be satisfied. As a result, the charge will move at high speed along the loop within the
doughnut. Each time it goes around the loop, it has, in effect, fallen through a potential difference equal to
d
the induced emf, namely  = . Its energy after n trips around the loop will be q (n)
dt
Q.14 Working of betatron is not based upon which of the following theories
(A) changing magnetic flux induces electric field
(B) charged particles at rest can be accelerated only by electric fields
(C) magnetic fields can apply a force on moving charges which is perpendicular to both magnetic field
and motion of the particle
(D) beta particles are emitted in radioactive decay process.
Q.15 Variable magnetic flux
(A) can change sinusoidally
(B) should either increase or decrease all the time
(C) must becomes zero when induced field is maximum
(D) none of these

Q.16 Magnetic field which keeps the particles in circular path must
(A) remain a constant every where
(B) increase gradually which is proportional to K.E. of the particle
(C) increase gradually which is proportional to speed of the particle
(D) none of these
Q.17 500 ml of sample of AgNO3 is treated with 49.8 gm of pure KI in excess. The resulting ppt. was filtered
off and filterate including washing made upto 2 L. 20 ml of this filterate required 10 ml of M/10 KIO3 in
presence of HCl till all iodine converts into ICl. The molarity of AgNO3 solution used is
(A) 0.2 (B) 0.1 (C) 0.05 (D) none of these

Q.18 Which starting material should be used to produce the compound shown below?

O
? 
3
Zn  H 2O

(A) (B) (C) (D)

Q.19 The hybridization of the complex [CrCl2(NO2)2 (NH3)2]– is

(A) sp3d2 (B) d2sp3 (C) sp3d (D) Can't be predicated

Q.20 Give the correct order of initials T (true) or F (false) for following statements.
(I) If electron has magnetic number +1, then it cannot be present in s-orbital.
(II) In given orbital diagram, both the Pauli's Exclusion Principle and Hund's rule
are violated
(III) For the reaction A2(g) + B2(g) l C2(g), the forward reaction at constant temperature is favoured by
introducing an inert gas at constant pressure
(IV) Electrodialysis process is used for purification of lyophobic colloids.
(A) TTFF (B) FFTF (C) TFFT (D) FFTT

Q.21 Which of the following produce chiral molecule after treatment with Lindlar's catalyst?

(A) (B) (C) (D)

Q.22 Match the reactions of metals with HNO3 (in List I) with the products (in List II).
List I List II
(a) Mg + very dil. HNO3 (i) NO
(b) Zn + dil. HNO3 (ii) H2
(c) Sn + very dil. HNO3 (iii) N2O
(d) Pb + dil. HNO3 (iv) NH4NO 3
a b c d
(A) (ii) (iv) (iii) (i)
(B) (ii) (iii) (iv) (i)
(C) (i) (iii) (ii) (iv)
(D) (iii) (i) (iv) (ii)

Q.23 Which of the following statement(s) is/are incorrect:

Statement 1 : If two gases have same value of Vander Waal's constant "b" but different "a", then gas
with higher value of "a" will occupy higher volume
Statement 2 : Pt | H2(g) | H+ (aq) || Ag+ (aq) | Ag
º
If E cell = 0.80 V, then Standard Gibb's energy formation of Ag+ is 77.2 J/mol in a given cell
Statement 3 : A sol is prepared by addition of KBr solution in AgNO3 solution (excess). The
charge likely to develop on dispersed phase particle is positive
(A) Statement 1 (B) Statement 2 (C) Statement 1,2 (D) All
Q.24 Predict major organic product from the following reaction:

(A) (B)

(C) (D)

Q.25 When NH4Cl is not used together with NH4OH in group - III reagent which of the following cation will
not be precipitated
(A) Fe2+ (B) Cr3+ (C) Zn2+ (D) Ba2+

Q.26 The maximum & minimum melting point of first transition and second transition series elements respectively
are obtained with
(A) Cr & Zn (B) Cr & Hg (C) Cr & Cd (D) Mo & Cd
 Comprehension (Q.27 to Q.29)
Cannizaro reaction
This reaction is given by aldehyde having no  - hydrogens in the presence of conc. NaOH/ or KOH/.
O O
|| ||
KOH
H  C  H  H  C  O  + CH3OH

Mechanism of the reaction is
O O
|| ||
CH 3 – O  + H – C – O – H +
CH 3OH H – C – O 

Q.27 Which of following will not undergo Cannizaro reaction

(A) (B) (C) (D) Cl3C–CHO

O
|| H2
Q.28 Ph – C  Cl  (A) HCHO
  (C) + (D)
Pd  BaSO4  , KOH
Product (C) & (D) are
(A) Ph–CO2H, Ph–OH (B) Ph – CO 2– , HCO 2– (C) Ph–CH2OH, H – CO 2– (D) Ph – CO 2– , CH3OH

CHO H
Q.29 | conc
  (A)  (B)
. NaOH

 O
CHO
||
Product (B) is CH 2  O  C
(A) H2C=CH–CO2H (B) (C) | | (D) H2C=C=O
CH 2  O  C
||
O
Comprehension (Q.30 to Q.32)
Read the following short write up and answer subsequent questions based on (A) to (J) observations
Q.30 Compound A & B is respectively
(A) FeCl2; FeCl3 (B) CuCl2 · 2H2O; [CuCl4]–2
(C) CrCl3; K2CrO4 (D) NiCl2; NiCl3

Q.31 Gas J is also produce by

(i) Heating NH4NO3 (ii) Heating NH4NO2
(iii) Heating NH4Cl (iv) Reaction of NH4Cl & Ca(OH)2
(A) (i) & (iii) (B) (i) & (ii) (C) (i) & (iv) (D) (iii) & (iv)

Q.32 Select the incorrect reaction

(A) C in solid state + KBr + conc. H2SO4  Red gas
(B) C in solid state + KCl + conc. H2SO4  Red gas
(C) C in solid state + FeCl3 + conc. H2SO4  Red gas
(D) C in solid state + HgCl2 + conc. H2SO4  Red gas
 1 1 1
Q.33 L et f (x) = 3  x 5  3x 2 3x 3  1 . Then the equation f (x) = 0 has
2 x 2  1 3x 5  1 7 x 8  1
(A) no real root (B) atmost one real root
(C) atleast 2 real roots (D) exactly one real root in (0,1) and no other real root.
Q.34 For any complex number w = a + bi, where a, b  R.
If w = cos 40° + i sin40°, then | w + 2w2 + 3w3 + ..... + 9w9 | –1 equals
1 2 1 9
(A) sin 40 (B) sin 20 (C) cos 40 (D) cosec 20
9 9 9 2
Q.35 The latus rectum of a conic section is the width of the function through the focus. The positive difference
between the lengths of the latus rectum of 3y = x 2 + 4x – 9 and x2 + 4y2 – 6x + 16y = 24 is
1 3 5
(A) (B) 2 (C) (D)
2 2 2
  n n  n  1 n  1  
n

Lim       ......    equals
Q.36 n    n 
  n   n  
1 e 1 e
(A) (B) (C) (D)
e 1 1 e 1 e e 1
  
Q.37 For some non zero vector V , if the sum of V and the vector obtained from V by rotating it by an angle

2 equals to the vector obtained from V by rotating it by  then the value of , is
  2 2
(A) 2n ± (B) n ± (C) 2n ± (D) n ±
3 3 3 3
where n is an integer.

Let  k  represents the combination of n things taken k at a time.

n
Q.38
 
100   99   98   97   3  2 
The value of  98  +  97  +  96  +  95  + ...... +  1  +  0  equals
           
(A) 15050 (B) 101000 (C) 151500 (D) 166650
Q.39 A 3 digit palindrome is a 3 digit number (not starting with zero) which reads the same backwards as
forwards. For example 171. The sum of all even 3 digit palindromes, is
(A) 22380 (B) 25700 (C) 22000 (D) 22400

Q.40 Find the range of the function, f (x) = cot–1x + sec–1x + cosec–1x.
  3    3   5 3 
(A)  ,  (B)  ,    , 
2 2  2 4   4 2 
    3     3 
(C)  ,     ,  (D)  ,     , 
2   2  2   2 
dy dy
Q.41 Suppose A = of x2 + y2 = 4 at ( 2 , 2 ), B = of sin y + sin x = sin x · sin y at (, ) and
dx dx
dy
C= of 2exy + ex ey – ex – ey = exy + 1 at (1, 1), then (A + B + C) has the value equal to
dx
(A) – 1 (B) e (C) – 3 (D) 0

Q.42 A piece of cheese is located at (12, 10) in a coordinate plane. A mouse is at (4, – 2) and is running up the
line y = – 5x + 18. At the point (a, b), the mouse starts getting farther from the cheese rather than closer
to it. The value of (a + b) is
(A) 6 (B) 10 (C) 18 (D) 14

Comprehension: (Q.43 to Q.45)

From a point 'P' three normals are drawn to the parabola y2 = 4x such that two of them make angles with
the abscissa axis, the product of whose tangents is 2. Suppose the locus of the point 'P' is a conic 'C'.
Now a circle S = 0 is described on the chord of the conic 'C' as diameter passing through the point (1, 0)
and with gradient unity. Suppose (a, b) are the coordinates of the centre of this circle. If L1 and L2 are the
two asymptotes of the hyperbola with length of its transverse axis 2a and conjugate axis 2b (principal
axes of the hyperbola along the coordinate axes) then answer the following questions.
Q.43 Locus of P is a
(A) circle (B) parabola (C) ellipse (D) hyperbola
Q.44 Radius of the circle S = 0 is
(A) 4 (B) 5 (C) 17 (D) 23
Q.45 The angle   (0, /2) between the two asymptotes of the hyperbola lies in the interval
(A) (0, 15°) (B) (30°, 45°) (C) (45°, 60°) (D) (60°, 75°)

Comprehension: (Q.46 to Q.48)

While finding the Sine of a certain angle x, an absent minded professor failed to notice that his calculator
was not in the correct angular mode. However he was lucky to get the right answer. The two least
positive values of x for which the Sine of x degrees is the same as the Sine of x radians were found by
m p mn
him as and where m, n, p and q are positive integers. Suppose be denoted by the
n q pq
quantity 'L'. Now answer the following questions.
Q.46 The value of (m + n + p + q) is equal to
(A) 720 (B) 900 (C) 1080 (D) 1260

BC
Q.47 If x is measured in radians and Lim  Ax 2  Bx  Cx  = L, the the value of equals (A,B,CR)
x    A
1
(A) 4 (B) 2 (C) (D) none
2

Q.48 Assume that f is differentiable for all x. The sign of f ' is as follows:
f ' (x) > 0 on (– , – 4)
f ' (x) < 0 on (– 4, 6)
f ' (x) > 0 on (6, )
Let g (x) = f (10 – 2x). The value of g ' (L) is
(A) positive (B) negative
(C) zero (D) the function g is not differentiable at x = 5
 Select the correct alternative(s). (One or more than one is/are correct) [15 × 5 = 75]
There is NO NEGATIVE marking.
Q.49 Monoatomic, diatomic and triatomic gases whose initial volume and pressure are same, each is compressed
till their pressure becomes twice the initial pressure then.
(A) If the compression is isothermal then their final volumes will be same
(B) If the compression is adiabatic, then their final volume will be different
(C) If the compression is adiabatic, then triatomic gas will have maximum final volume
(D) If the compression is adiabatic then monoatomic gas will have maximum final volume

Q.50 Coherent light consisting of two wavelengths 1 = 4500 Å & 2 = 6000 Å is sent through both slits of a
Young's double slit apparatus
(A) Central maxima for both wavelengths will coincide
(B) The third order bright fringe of 1 will coincide with the fourth order bright fringe of 2
(C) The third order bright fringe of 2 will coincide with fourth order bright fringe of 1
(D) The fringes of wavelength 1 will be wider than the fringes of wavelength 2

Q.51 In Young’s double slit experiment, phase difference between the waves at a point on screen having
intensity less than the average intensity on screen may be
(A) /4 (B) 2/3 (C)  (D) 7/8
Q.52 A point source of light S is placed on the axis of a lens of focal length 20 cm as shown. A screen is placed
normal to the axis of lens at a distance x from it. Treat all rays as paraxial.

(A) As x is increased from zero intensity continuously decreases

(B) As x is increased from zero intensity first increases then decreases
(C) Intensity at centre of screen for x = 90 cm and x = 110 cm is same
(D) Radius of bright circle obtained on screen is equal to 1 cm for x = 200 cm

Q.53 Three equal point changes (Q) are kept at the three corners of an equilateral triangle ABC of side a. P
is a point having equal distance a from A, B and C. If E is the magnitude of electric field and V is the
potential at point P, then

3Q 6Q 3Q 3 6Q
(A) E = (B) E = (C) V = (D) E =
4 0 a 2 4 0 a 2 40 a 4 0 a 2

Q.54 Select the incorrect statement(s):

(A) Entropy for a closed system is always maximized at equilibrium
(B) Bohr model can explain spectrum of the hydrogen atom only
(C) A d-orbital can accommodate maximum 10 electrons only
(D) The efficiency of heat engine operating between 1000 K and 400 K is greater than the engine
operating between 1000 K and 500 K
Q.55 

Above conversion can be achieved by

(A) O3/H2O2 (B) NaIO4/KMnO4(cold)
(C) O3/Zn(H2O) (D) LiAlH4

Q.56 Which one of the following statement(s) is/are false?

(A) Weak ligands like F—, Cl— and OH— usually form low spin complexes.
(B) Strong ligand like CN— and NO 2– , generally form high spin complexes.
(C) [FeF6]3– is high spin complex.
(D) [Ni(CO)4] is high spin complex

Q.57 Select the correct statement(s):

(A) In general G, H, S all have negative values in physical adsorption
(B) When a nuclide undergoes electron capture the mass number remains unchanged and the atomic
number increases by one
(C) Gas A diffuses twice as fast as another gas B. If the vapour density of the gas A is 4, then the gram
molecular mass of the gas B is 32
a 3
(D) Shortest distance between cation & anion in antifluorite structure (A 2B type) is ; where
2
a = edge length of cube

Q.58 Which statement is correct

(A) Higher is the polarisation, higher will be relative solubility in non-polar solvent
(B) Higher is the polarisation, higher will be the intensity of colour
(C) Diamagnetic substances some times become coloured due to HOMO-LUMO transition
(D) Higher is the polarisation in metal oxide, higher will be the basic character
 /2 /2 /2
Q.59 Suppose I1 =  cos( sin
2
x ) dx ; I2 =  cos(2 sin
2
x ) dx and I3 =  cos( sin x ) dx , then
0 0 0
(A) I1 = 0 (B) I2 + I3 = 0 (C) I1 + I2 + I3 = 0 (D) I2 = I3
Q.60 Suppose that the function f has a continuous second derivative for all x and that f (0) = 2, f '(0) = – 3 and
f ''(0) = 0. Let g be a function such that g'(x) = e–2x (3 f (x) + 2 f ' (x) ) for all x and g(0) = 4. Which of
the following is/are correct?
(A) Equation of the line tangent to the graph of g at the point where x = 0 is y = 4.
(B) The function g has a local maxima at x = 0
(C) The function g has local minima at x = 0
(D) The function g has an inflection point at x = 0
Z1
Q.61 Let Z1 and Z2 are two non zero complex numbers such that | Z1 + Z2 | = | Z1 | = | Z2 | then can
Z2
be equal to
(A) 1 +  (B) 1 + 2 (C)  (D) 2
where  is the non real cubs root of unity.
Q.62 A pair of fair dice having six faces numbered from 1 to 6 are thrown once. Suppose two events E and F
are defined as
E: At least one of the dice shows up the face one.
F: Product of the two numbers appearing is divisible by 5.
Then the events E and F are
(A) mutually exclusive (B) such that P(E / F) = P(F / E)
(C) neither independent nor mutually exclusive (D) are equiprobable
n
Q.63 If there are three square matrix A, B, C of same order satisfying the equation A2 = A–1 and let B = A 2
( n  2)
& C = A2 then which of the following statements are true?
(A) det. (B – C) = 0 (B) (B + C)(B – C) = 0
(C) B must be equal to C (D) none