c23 Btts-26 Chemistry (Paper-1)

BAKLIWAL TUTORIALS
COMP2023 BTTS-26 CHEMISTRY (PAPER-1)

SINGLE CORRECT TYPE
Q.1 of a solution of is changed by 0.3 units due to dilution, calculate change in osmotic
pressure if temperature of solution is .( litre atm/K/mole)
(A) (B) (C) (D)
Solution : (A)
Q.2
Solution : (C)
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Q.3 Structure of which of the following species is similar to or based on square anti prismatic geometry?
(A) (B) (C) (D)
Solution : (B)
In crown conformation of S8 molecule, on connecting atoms it look like square
antiprismane geometry
Q.4 Identify correct statements-

(i) If on adding electrolyte in an emulsion the conductivity increases significantly, then it will be oil
in water type emulsion.
(ii) Formation of miscelles take place only above a particular temperature called Kraft temperature.
(iii) Zeolites are widely used in petrochemical industries for cracking of hydrocarbon and
isomerisation.
(iv) In the process of tanning, mutual coagulation takes place.
(A) i, ii, iii only (B) i, iii only (C) i, ii, iii, iv (D) i, iii, iv only
Solution : (C)
Theory Based
Q.5 Which of the following reaction has been written with incorrect major product?
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Solution : (D)
Q.6 Major product of following reaction is :
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Solution : (A)
MULTIPLE CORRECT TYPE
Q.7 Select correct statement(s).

(A) is less acidic as compared to
(B) is more basic than
(C) more easily dimerizes as compared to
(D) is better L.P. acceptor (lewis acid) as compared to
Solution : (ABCD)
(A) is more acidic due to back bonding.
(B) is less basic due to back bonding.
(C) In odd electron is present in hybrid orbital, so it easily undergoes dimerisation.
(D) is better lewis acid as compare to and .
Q.8
Select correct statement(s).

(A) 'A' on hydrolysis produces dibasic acid (B) Solid ' ' shows chemiluminescence.
(C) Gas B can be used as antichlor. (D) Liquid ' ' do not contain S – S bond
Solution : (ABC)
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has open book structure like
Q.9 Which of the following statement(s) is/are correct for given structures –
(A) In naphthalene, the 1,2 and 2, 3 bond distance are 1.36 and respectively.
(B) The non equivalency of bonds in fused aromatic systems, called partial bond fixation.
(C) In phenanthrene 9, 10 bond is readily attacked by many reagents.
(D) The resonance energy of benzene, naphthalene, anthracene and phenanthrene are close to 36, 61,
84 and respectively.
Solution : (ABCD)
Molecular orbital calculation of naphthalene show bond orders of 1.724 and 1.603 respectively
(compare benzene, 1.667). In agreement with these predictions the 1, 2 and 2, 3 bond distance are
1.36 and , respectively. This non equivalency of bonds, called partial bond fixation, is found
in nearly all fused aromatic system. In phenanthrene where the 9,10 bond is a single bond in only one
of five forms, bond fixation becomes extreme and this bond is readily attacked by many reagents.
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Q.10 An oxime of compound (which can substitute – Cl intramolecularly in

alkaline condition) whenever treated with gives a compound (P) which on hydrolysis
produce (Q) and (R). If (Q) is primary amine, then choose the correct option(s)?
(A) (P) and (R) are soluble in hot aq. .
(B) (R) gives brisk effervence of with aqueous .
(C) can give foul smelling compound with .

(D) Q on Hofmann exhaustive methylation gives a product which is soluble in water.
Solution : (ABD)
Q.11 A mixture of liquids and in molar ratio forms a maximum boiling azeotrope. Identify the
incorrect statement(s), if 'A' is more volatile. Molar masses of A & B are 200 and
respectively.
(A) A liquid solution of ' ' and ' ' having mass of will have vapours having mass of
(B) A liquid solution of ' ' and ' ' having mass of will have vapours having mass of
(C) A mixture of ' ' and ' ' in the mass ratio can be separated into azeotropic mixture and
pure 'A'
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BAKLIWAL TUTORIALS
(D) A mixture of ' ' and ' ' in the molar ratio can be separated into zeotropic mixture and
pure 'A'
Solution : (C)
if mass of in liquid Mole ratio of A & B would be 1:2

(Azeotropic composition)
So liquid composition vapour composition
If mass in liquid
(left side of Azeotropic composition)
Mass of in vapour
If mass ratio of in liquid
Mole ratio of in liquid
(right side of Azeotropic composition)
It can be separated into azeotropic mixture and pure B.
If mole ratio of is
(left side of Azeotropic composition)
It can be separated into azeotropic mixture and pure
Q.12 Which of the following is/are correct statements -
(A) Lyophobic sols are usually less solvated than lyophilic sols
(B) If a solution is prepared by dissolving excess of solution in KI solution, the charge likely
to develop on colloidal particle is positive
(C) Gold number determine protective power of a lyophilic sol.
(D) Gel is a liquid dispersed in another liquid.
Solution : (ABC)
(Theory Based)
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NUMERICAL TYPE
Q.13 Write sum of the molecular weight of nitrogen containing major volatile products of given reactions.
(Given atomic weight : )
(i) →
(iii) →
(iii) →
(iv) sulphamic acid →

Solution : (103)
Products of NO M.wt.
(ii)
(iii) (M.wt.
(iv) (M.wt.
Q.14 Which of the following will show positive carbyl amine test?
Solution : (5)
1, 3, 6, 7, 8
It is given by 10 Amine and Aniline.
Q.15
Number of compounds which can show faster rate of nucleophilic substitution of halogens than
compound (A) in the given below compounds.
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Solution : (4)
1, 2, 3, 6
Q.16 Number of compounds that are colourless in their aqueous solution among the following is
Solution : (2)
Blue
White
Green
Green
White
Purple
Orange
Q.17 Find the sum of bond order in all the given species.
Solution : (11)
Q.18 In a compound, oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-
sixth of the tetrahedral voids and cations B occupy one-third of the octahedral voids. The formula of
the compound is , then find the value of .
Solution : (5)
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BAKLIWAL TUTORIALS

COMP2023 BTTS-26 CHEMISTRY (PAPER-1)

Q.4 Identify correct statements-

Q.6 Major product of following reaction is :

MULTIPLE CORRECT TYPE

Q.7 Select correct statement(s).

Select correct statement(s).

Q.10 An oxime of compound (which can substitute – Cl intramolecularly in

(C) can give foul smelling compound with .

if mass of in liquid Mole ratio of A & B would be 1:2

(iv) sulphamic acid →

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