BAKLIWAL TUTORIALS

COMP 2024 BTEST-14 (ADV) CHEMISTRY PAPER

SINGLE CORRECT TYPE

Q.1 The three thermodynamic states P, Q and R of a system are connected by the path shown in the
figure given below. The entropy change in the processes P → Q, Q → R and P → R along the paths
indicated are ΔSPQ , ΔSQR and ΔSPR respectively. If the process P → Q is adiabatic and irreversible,
while P → R is adiabatic and reversible, then the correct relation is:

(A) ΔSQR > 0 (B) ΔSPR > 0 (C) ΔSQR < 0 (D) ΔSPQ < 0
Solution : (C)
P → Q − Adiabatic irreversible ⇒ ΔSPQ > 0.
P → R − Adiabatic reversible ⇒ ΔSPR = 0.
Since entropy is state function hence
ΔSPQ + ΔSQR = ΔSPR
⇒ ΔSQR < 0.
Q.2

(A) (B)

1
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS

(C) (D)
Solution : (D)

Q.3

Best yield for the above conversion can be obtained by :

2
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS

Solution : (C)

Q.4

Product (A) in above sequence of reaction is:

(A) (B)

(C) (D)
Solution : (B)
Sterically hindered ketonic group cannot react with glycol.

3
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
MULTIPLE CORRECT TYPE

Q.5

Which of the following statements is/are correct about the above reaction?
(A) Product shows geometrical isomerism.
(B) Product shows colour due to extended conjugation.
(C) Electophile attack at para position due to large size.
(D) Electron withdrawing group in phenol increases rate of reaction.
Solution : (ABC)
Electron withdrawing group in phenol decreases rate of reaction.

Q.6 Select correct about "Hypophosphorous" acid.

(A) Monobasic acid in water (B) OH − acceptor in water
(C) Reducing in nature (D) Three H attached to P
Solution : (AC)

Q.7

4
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
An organic compound on reaction with O3 followed by Zn and H2 O gives P. The organic compound
can be?

Solution : (ABC)

INTEGER TYPE

Q.8 1-chlorobutane undergoes chlorination in presence of light. Total number of possible dichloro
products are:
Solution : (6)
(i) CH3 CH2 CH2 CHCl2
(ii)/(iii) CH3 CH2 CHClCH2 Cl
(iv)/(v) CH3 CHClCH2 CH2 Cl
(vi) CH2 ClCH2 CH2 CH2 Cl
Q.9 How many reactions give product as indicated? (ignore balancing)
Δ
(1) H3 PO3 ⟶ P4 O6 + H2 O
(2) Cu + conc. H2 SO4 → CuSO4 + H2
(3) S + Conc ⋅ HNO3 → H2 SO4 + NO2 + H2 O

5
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
Pt/Rh
(4) NH3 + O2 ⟶ NO + H2 O
Δ
△
(5) NH4 NO2 ⟶ N2 O + H2 O
(6) P4 + Conc. NaOH ⟶ PH3 + NaH2 PO2
Solution : (3)
(3), (4) and (6) are correct
(1) H3 PO4 + PH3
(2) CuSO4 + SO2 + H2 O
Δ
(5) NH4 NO2 ⟶ N2 + 2H2 O
Q.10 Consider following complexes:
[Cr(H2 O)3 Cl2 (NH3 )], [Fe(C2 O4 )3 ]3− , [Zn(gly)2 ], [Co(H2 O)3 (NH3 )3 ], [Pt(en)Br3 Cl], [Co(gly)3 ]
How many of these show either geometrical or optical isomerism but not both?
Solution : (5)
[Cr(H2 O)3 Cl2 (NH3 )] show only geometrical isomerism
[Fe(C2 O4 )3 ]3− shows only optical isomerism
[Zn(gly)2 ] shows only optical isomerism
[NiCl3 Br3 ]4− shows only geometrical isomerism
[Pt (en) Br3 Cl] shows only geometrical isomerism
[Co(gly)3 ] shows both isomerism
Q.11 The internal energy (U) of an ideal (10.7 mole) gas is plotted against volume for a cyclic process
ABCDA, as shown in the figure.

The temperature of the gas at B and C are 500 K and 300 K, respectively. The heat absorbed by the
gas (in kcal) in this cyclic process is:
Solution : (3)
q = q AB + q BC + q CD + q DA
2 V0 V0
= nRTB ⋅ ln + n ⋅ Cv,m ⋅ (TC − TB ) + nRTc ℓn + n ⋅ Cv,m (TA − TD )
V0 2 V0
= nR𝑙n2(TB − TC ) = 10.7 × 2 × 0.7 × 200 = 3k cal

6
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
Q.12 Total numbers of triangular faces in mer [Ma3 b3 ] complex which have either two a atom or two b
atoms -
Solution : (8)

Q.13

M
If the molecular weight of product (P) is M, then the value of 27 is:

Solution : (4)

7
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
NUMERICAL TYPE

PARAGRAPH : 1 FOR Q.NO. 14 & 15

Standard Gibb's energy of reaction (Δr G∘ ) at a certain temperature can be computed as Δr G∘ =
Δr H ∘ − T ⋅ Δr S ∘ and the change in the value of Δr H ∘ and Δr S ∘ for a reaction with temperature can be
computed as follows:
Consider the following reaction: CO(g) + 2H2 (g) ⇌ CH3 OH(g)
Given: Δf H ∘ (CH3 OH, g) = −201 kJ/mol; Δf H ∘ (CO, g) = −114 kJ/mol
S ∘ (CH3 OH, g) = 240 J/K/mol; S ∘ (H2 , g) = 29 JK −1 mol−1
S ∘ (CO, g) = 198 J/mol/K; ∘ (H )
Cp,m 2 = 28.8 J/mol/K
∘ ∘ (CH
Cp,m (CO) = 29.4 J/mol/K; Cp,m 3 OH) = 44 J/mol/K
320
and ln (300) = 0.07, all data at 300 K

Q.14 Calculate Δr S ∘ at 320 K is x then find |x| Where |x| is nearest integer value
Solution : (19)
∘ ∘ ∘
Δr S ∘ = SCH 3 OH
− SCO − 2SH 2
= −16 J/Kmol
∘ ∘ (CH ∘
Δr H = Δr H 3 OH) − Δr H (CO) = −87 kJ/mol
∘ ∘
Δr S320 − Δr S300 = Δr CP ln T2 /T1
Where Δr Cp∘ = 44 − 29.4 − 2 × 28.8 = −43 J/K/mol
∘
320
Δr S320 = −16 + (−43)ln = −19.01
300
Q.15 Calculate Δr Hf∘ at 320 K is x then find |x| where |x| is nearest integer
Solution : (88)
(−43) × 20
∘
Δr H320 ∘
= Δr H300 + Δr CP∘ [T2 − T1 ] = −87 + = −87.86 kJ/mol
1000

PARAGRAPH : 1 FOR Q.NO. 16 & 17

Compound having unpaired electron is paramagnetic in nature and having no unpaired electron is
diamagnetic in nature.

Q.16 Find the number of paramagnetic compound(s) with octahedral anion.

K 2 [CoF6 ]: O2 [AsF6 ]: K 2 [CoCl4 ]: K 3 [Co(CN)6 ]:
K 3 [CoF6 ]: [Ni(NH3 )6 ]SO4 : [Pt(NH3 )6 ][Fe(CN)6 ]: Na2 [Fe(CN)5 NO]
Solution : (03)

8
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com
 BAKLIWAL TUTORIALS
Paramagnetic octahedral compound
K 2 [CoF6 ]
K 3 [CoF6 ]
[Ni(NH3 )6 ]SO4
Q.17 Which of the following statements are true?
(A) MnCl2−
4 ion has tetrahedral geometry and is paramagnetic

(B) [Mn(CN)6 ]2− ion has octahedral geometry and is diamagnetic

(C) [Cu(CN)4 ]3− has square planar geometry and is diamagnetic
(D) [Ni(Ph3 P)2 Br3 ] has trigonal bipyramidal geometry and is paramagnetic
(E) [Ni(PPh3 )2 Cl2 ] − tetrahedral and paramagnetic
(F) [Ni(CO)4 ] - tetrahedral and diamagnetic
(G) [Ni(CN)4 ]2− square planar and diamagnetic
(H) [Ni(CO)4 ] - square planar and diamagnetic
Solution : (05)
A, D, E, F, G are correct
MnCl2−
4 :

Mn2+ : 3d5 configuration

: sp3 hybridized and Paramagnetic
[Mn(CN)6 ]2− :
Mn+4 (3d3 ) : Octahedral and Paramagnetic
[Cu(CN)4 ]3− has Square planar geometry and is diamagnetic due to d10 configuration.
[Ni(pph3 )2 Cl2 ]:
Ni2+ : 3d8
- tetrahedral and Paramagnetic
Ni(CO)4
Ni: 3d8 4s2
With CO as ligand, it gets converted to 3d10
Hybridisation sp3
Tetrahedral and diamagnetic
[Ni(CN)4 ]2− :
Ni2+ : 3d8
With CN− as ligand, it forms low spin complex
Hybridistation = dsp2
Square planar and diamagnetic

9
Bakliwal Tutorials |Camp| FC Rd| PaudRoad|Wanowrie|Aundh|VimanNagar|Deccan|SataraRd|Pimple Saudagar|PCMC|www.bakliwaltutorialsiit.com