LPP- General Organic Chemistry | FITSEE ‘Single Correct Assign double bond configurations to the following: CHO NC CH,OH ®) Ze (CEE (2) 2,2 Which of the following molecules have non zero dipole moments? (1). Gauche conformation of 1,2-dibromoethane (il) Anti conformation of 1, 2-dibromoethane (lil) Trans-1,4-dibromocyciohexane (IV) Cis-1,4-dibromocyciohexane (V) Tetrabromomethane (VI) 4,1 - Dibromocyciohexane (A) land tt (8) landiv (C) Wand iv (0) 1, Vand VI Geometrical isomerism is possible in ) Oo @) O © Ll ©) CO Which of the following is correct set of physical properties of the geometrical isomers? CH HQ} Hee r and c=C ‘cl WA \ () (ll) Dipole Boiling point Melting point Stability (A) >it I> Met I> () ort tet u>! ot () ion tan ul eu (D) Nel Wet ill iol The following two compounds are: I i (A) identical (B) conformational isomers (C) geometrical isomers. (0) structural isomers Which of the following would exhibit cis — trans isomerism? (A) CH,CH,CH = CH, (8) CICH =CHCI (c) CICH =CCl, (0) CH, =CH-COOH Which of the following compounds will show geometrical isomerism? (A) 2-pentyne (8) 2-pentene (C) 2-methy! propene (0) 2-methyl-2-butene TIEN Tower, C5446 Tana tra eS, Nl TIO? Ph OTIATS RON B5ONSOESTE RII La Fao, Hot! Bung, Wegman uses Pare KPI Sarapar Kas. Grr Nod 301508 Ph9809773875 9471771273422 ‘wo facebook comv/FIITJEENOIDAOFFICIAL, 5 J atvce note 6 | Websites fijeensie.comGeometrical isomers are possible for (A) CHyCHa—E—— CHC (8) CHyCHy—G-—CHsClHy NOH oO (6) CHyCH:—E—cHy (0) HsGa—E-—Cots NOH ‘Among the following compounds, the one which does not show geometrical isomerism is (A) CHWN= NCH, (8) C,H,CH =CHC,H, (C) HsCge—* N—OH (0) HeCa—¢: :N—CH3 CHy Cols CHs How many geometrical isomers are possible for the above compound? (B) 2 (c)3 Multi Correct Select ‘cis’ isomer among the following: jr Br jr Sr “) CL ® CO ) on ©) Ce ir “Br “Br ir For which of the following pairs of compounds are the correct notations(syn, anti, E, Z, cis, trans) given Ph Ph Ph =n and NEN a = “ ‘pn Anti-azobenzene Syn -azobenzene HSC, a and fo ‘Syn-acetaldoxime Anti-acetaldoxime HyQ_CHaCHsCHy CH CHy c=c and C=C yA rN (ce) H CHs BrH,C ‘CH E- isomer wor facebook com FIITIEENOIDAOFFICIAL13. Which of the following compounds will exhibit geometrical isomerism? (A) CH,-CH =CH-COOH (8) Br-CH =CH-Br (©) C.H,-CH =N-OH (0) 0 NZ 14. Which of the following cycloalkanes will show cis-trans isomerism? CH. GHs CHy ° HyS CH, A) 8) (C (0 (A) ®) cH, (0) HC’ 15. _ Which of the following are correctly matched? Compounds Number of geometrical isomers: (A) CH,-CH=CH-CH=CH-Ph 4 (©) CH,-(CH =CH),-CH, 2 (©) H,C=CH-CH=CH, 10 (2) H,C-(CH =CH),-CH, 20 Comprehension ~1 Cis trans isomers are also known as geometrical isomers; observed because of stereoisomerism. Reply the following question: 16. Assign double bond configurations to the following: HgC. COOH nc Me ‘CHZOH HyN—CH, COOH (AV EZ (B)ZE (EE (0) 2,2 17. The stable form of trans -1, 4-dimethylcyclohexane is represented as: oth CH, (A) oe (8) HC " CH, () Hye {THs (0) CH, THIEN Tower C501 36, somal tea Sel, Nola T0107 Ph 150-475 AND GETASTASTA (MINA Lu, For Hotel dng, Womans Masnes Park. KP uma. Greater Noda 201308 Ph 950079247 /9871113448 / 70437022 [er [wrists itierwomaorrciat | |) | ate Nn |B | Webern com[ 18. Among the lowing ‘strucures, select E tomer (arrows Indicate the bond to Be considered}? Bete ee CHy qa) (2) (3) (4) (A) tand2 (8) 1and3 (C) 1and4 (0) 2and 3 Comprehension - 2 Bongkrekic acid is a toxic compound produced by Pseudomonas cocovenenans, and isolated from a mold that rows on bongkrek, a fermented Indonesian coconut dish. COOH COOH 2 | A n S Vee “ | ‘COOH ~——-Bongkrekic acid 5 Label each double bond as E, Z or neither (N) and select the correct options: (A) 19Z,49Z — (B)59Z29E (C)69E,39E — (0) Allarecorrect How many sites of unsaturation are present in bongkrekic acid? (A) 10 (8) 11 (9 (0) 8 Integer Type Find out number of conformation those have cis geometry. CH, Total number of stereoisomer possible for the compound H,C-CH = CH -CH =CH-CH =CH-Ph PATRON Ter. C540 Tanna tra Se, Nd 307307 Ph O1SO-AS oO SDRSHANTE (AMIE La Sor Hote ase Par, RPM, Srp Kavn Ra. Greater Nala 30308 PX 9500773476 /O87PLIMAN/ 7003724022 Towra smtrmnomaornicit [1 [tie ae | B | Weer naanirean show geomelrical Isomensm Ha CH 24, Total number of possible structural isomers of C,H, Br. 25. Theoretical possible geometrical isomer of Matrix Match Type 26. Match the following Column -1 Column ~ I ® THO (P)_| Ring chain isomers TN ond “Non 9 OH TT kw hy (Q)_| Functional isomers HN’ IH Na Ayre wo we S oF “wo Wo Sw ~on H (R) \ EtCN and Me—N et Pr OH and gm io’ \ 7 TIEN oer. C54, mal tra) No 301307 Sur Aana a Grater Ned. S00773476/ 947111344870 meats tet es et eco FITHEENOIDAOPPCTAL re a