LPP - Ionic Equilibrium FIITJEE

Single Correct

1. For pure water:

(A) pH Increases \Mille pOH decreases with rise In temperalt.nl
(B) pH decreases while pOH Increases with rise In temperature
(C) bOlh pH end pOH decreeees with rise In temperature
(D) both pH and pOH Increase with rise In temperature

2. The hydrogen ion concentrallon ol the oceans Is about 2 •10~. What Is the pH? pog 2 = 0.3010)
(A) 8.85 (B) 9.3
(C) 7.85 (0) 8.7

3. The pH ol solution Is 5. To this solution add was added so that Its pH •-becomes 2.0. The Increase in H"
co11ceut,.,Uon Is
(A) 100 tJmes (B) 5 times
(C) 2.5 times (D) 1000 Umes

4. pOH ol 0.002 M HNO, Is:

(A) 11 +log2 (B)11-log2
(C) -3 + log 2 (0) None ol these

5. Numb&< ol equivalents of HCI present In 100 ml ol its soluUon IMlose pH la 4:

(A) 10.. (B) 10_,
(C) 10·• (0) 10..

8. pH ol a strong diprotlc acid (H,A) at concentrations: Q) 10.. M, (II) 10.. N are lffl)eClively )log 2 • 0 .3010)
(A) 3.7 and 4 .0 (B) 4 and 3. 7
(C) 4 and 4 (0) 3.7 and 3.7

7. A 25.0 ml sample of 0 .10 M HCI Is Utrated with 0.10 MNaOH. Whal Is tha pH ol the soluUon 81 the polnla
...tle<e 24.9 and 25. 1 ml ol NaOH hlllle bean added? )log49.9 = 1.698, log 50.1 = 1.699)
(A) 3.70, 10 .70 (B) 3.30. 10.30
(C) 3.70. 10.30 (0) 3.0. 11.0

8. Al eo·c , pure _ . , has (H"J • 10·• M, II 100 ml al 0.2 M HCI Is added to 200 m l of 0.1 M KOH at 90•c !hen
pH or the resulting aoludon will be
(A) 5 (B) 8
(C) 7 (0) None ol these

9. pH or solution made by mixlng 200 ml ol 0 .0657 M NaOH. 140 ml ol 0 .107 M HCI and 160 m l ol H 2O Is
pog 500 = 2.6989 and log 1.84 • 0.2848)
(A) 3.04 (B) 2.43
(C) 2.74 (0) 2 .27

10. When one drop ol a C<lllCMttated HCI Is added to 1 lo( pure water at 25"C, the pH drops suddenly from 7 to
4. When lhe second drop ol the same acid Is added, Iha pH ol the solution fLVlher drops to about
(A) 0 (B) 1.0
(C) 2.0 (0) 3.7

Multi CorNCt

11. Which al the following Slatements ls.tare nol correc:t?

(A) A substance which can provide OH" In aqueous medium Is a base
(B) A substance which can accept a pair ol elec:tron la a base
(C) A substance which can accept a pro1on In aqueous medium la a base
(0) A substance which can donate a pair o( electron Is a base

12. Which among the following sta1ement is/are correct?

(A) pH = -log,o [H,O '] lot dilute aoluUon
(B) pH of H 20 decreases with Increase ol tempareewa
(C) pH + pOH = pl<.,

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13. Which of the rollOY.ing solution will have pH• 13?

(A) 2 g NaOH In 500 mL 10lutlon (B) 100 mL soluUon ol 0.05 M Ca(OH>,
(C) 100 mL solution of 0.1 N Ce(OH), (D) 4 g NaOH In 500 mL soluUon

14. pOH of wale< Is 7 ..0 II 298 K. II water Is heated to 350 K, which d the r01IO<Mng sliO<Jld be lnJe?
(A) pOH wtl decre-
(B) pOH wtl lncreese
(C) pOH wtl remain seven
(D) concentreUon of H' Ions wlll Increase bul that ol OH" wtl decrease

15. 8-manygrema of NaOH must be dil90lved In 1 L of the solution to give ii a pH value of 12?
1
(A) 0.20 g L" ' (B) 0.40 g L"
(C)0.10gL· ' (D)1.2gL· '

C0111f1rehen ■Ion Type

PMaege •1
For dilute S()lutlon,
pH = -log(H,O']
pH or a solution i11 dependent on tempeniture. An_, the lollowlng questions:

16. Foltowtng five soluUon, or KOH were prepa,ed ••

1" ... 0.1 mole in 1 L
-r' -+ 0.2 mole in 2 L
3'" -+ 0.3 mole in 3 L
4•• ➔ 0 .4 mole In 4 L
s•• ...
0.5 mole In 5 L
The pH ol resultant solution, when all these solutions are mixed, is
W2 ~11
(C) 13 (D) 7

17. Which woold ~ the pH of 25 ml of a 0.01 M solutlon of hydrochloric acid? The addhion of
(A) Magnetlum metal (B) 25 ml 0.02 M hydrochloric acid
(C) 25 ml 0.005 M hydrochloric acid (D) 50 ml water

18. What la the pH of solution m - by mixing equal volumes of 0.1 N H,SO,, 0.1N HNO,, 0. 1 N HCt?
w1 ~2
~3 ~)4
PMaege -2

An acicl-base tllreUon oonslsts of the conltOlled addiUon ore dl11olved base 10 a dssolved acid (or the
reverse). The pH ,of a utreUon changes t¥Very time a dtop or lltrant Is added, but the rate or this change varies
enormouSly. A lltreUon curve, graph of pH as lunctlon of the volume of litran~ displays in details how the pH
changes over the course of en acid-base Utretlon. SlgnfflcanUy, the pH changes mos1 rapidly near the
equivalence point.

19. The rOIIO<Mng Hgure represents titration urve of HCI a alnst NaOH. The pH Ill equlvllence point will be

pH , ••• • • • • • E~lvalence poit1t

.,,
Vol of NaOH lldcled ...

(A) 7 (B) 6
(C) 8 (D) 3

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20. Exnlne the UlratlDl'I curve below and mark which ol the Ulta1ion1 oolAd It represent?
13 1-- ,
12
t
pH 7

20 40 60 80
Vol d "°Id added-

(A) HCI by KOH (8) RbOH by HBr

(C) HCI by NaOH (D) All or these

lnte;or Type
10
21. Calculate approximate pH o110· M NaOH at 2s·c.

22. C&lculate pH of a resultant &Olutlon 0125 ml ol 0.1 M HCI, 50 ml ol 0.02 M HNO, and 25 ml ol 0.1 M NaOH.

23. If the equil!brium constant of BOH= = e · • oH· at 2s·c Is 2.5 • 10-<>, Ille equlllblium constant for
BOH + H' = = e· +H,O at the ume temperature 11 2.5 • 10'. •la _ __

24. Conlidet the titration ol 50 ml of 0.1 M HBr "'1th 0.1 M KOH. Calcw,te pH llller 49 ml or the b.lse haa baen
added to the 50 ml ol HBr.

25. Ionic product of water 11 10· " . pH of WIiier wl• be

Mlltrlx Match
26. Match Ille column

ColWM-11 (pH)

(A) Solution pnipared by mixing 100 ml 0.02 or (P) More than 1 but lesa than 2
M H,5O, with 100 ml 0.05 M HCI IOluUon or
(8) SotuUcn or HCI whose concentration Is 3.65 (0) 1
o/ l
(C) Solution of HCI IM\OM concentration la 0.365 (R) 2
~ _,__a_l l
(D) When 200 ml of an aqueoua aoludon ol HCI (S) 11.3
(pH • 2) 11 mixed with 300 ml of an equeoua
aolutlon of N eOH.'" H • 121
flt 13

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