Quiz – Gaseous State

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Name:_____________________________________________________Batch:_____________________________________

1. An open vessel containing air is heated from 300 K to 400 K. The fraction of air originally present which goes
out of it is:
3 1
(A) (B)
4 4
2 1
(C) (D)
3 8
2. A 0.5 dm3 flask contains gas A and another flask of 1 dm3 contains gas B at the same temperature. If density
-3 -3 1
of gas A is 3.0 g dm and of gas B is 1.5 g dm and mol. wt. of A  mol. wt.of B, then the ratio of pressure
2
exerted by gases is:
PA PA
(A) 2 (B) 1
PB PB
P P
(C) A  4 (D) A  3
PB PB

3. V versus T curves at constant pressure P1 and P2 for an ideal gas are shown in figure. P1
Which is correct?
. (A) P1 > P2 (B) P1 < P2
P2
(C) P1 = P2 (D) All of these V
T

4. If the intermolecular forces vanish away, the volume occupied by the molecules contained in 4.5 kg water at
STP will be:
(A) 5.6 m3 (B) 4.5 m3
(C) 11.2 litre (D) 11.2 m2
0
5. If pressure of a gas contained in a closed vessel is increased by 0.4% when heated by 1 C its initial
temperature must be:
(A) 250 K (B) 2500 C
(C) 2500 K (D) 250 C
0 0
6. If 10 g of a gas at atmospheric pressure are cooled from 273 C to 0 C keeping the volume constant, its
pressure would become:
(A) ½ atm (B) 1/273 atm
(C) 273 atm (D) 2 atm

7. A cylinder was filled with gaseous mixture containing CO and N2 (equal masses). The ratio of their partial
pressures in cylinder is:
(A) 1:1 (B) 1:2
(C) 2:1 (D) 1:3

8. A closed vessel contains equal number of oxygen and hydrogen molecules at a total pressure of 740 mm. If
oxygen is removed from the system, the pressure:
(A) becomes half of 740 mm (B) remains unchanged
(C) becomes 1/9 th of 740 mm (D) becomes double of 740 mm

9. The volume of ammonia obtained by the combination of 10 mL of N2 and 30 mL of H2 is:

(A) 20 mL (B) 40 mL
(C) 30 mL (D) 10 mL

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10. Four one litre flasks are separately filled with the gases, O2, F2, CH4 and CO2 under the same conditions. The
ratio of number of molecules in these gases:
(A) 2 : 2 : 4 : 3 (B) 1 : 1 : 1 : 1
(C) 1 : 2 : 3 : 4 (D) 2 : 2 : 3 : 4

11. The density of oxygen gas at 250 C is 1.458 mg/litre at one atmosphere. At what pressure will oxygen have
the density twice the value?
(A) 0.5 atm/250 C (B) 2 atm/ 250 C
0
(C) 4 atm/ 25 C (D) none of these

12. The molar volume of CO2 is maximum at:

(A) NTP (B) 00 C and 2.0 atm
(C) 1270 C and 1 atm (D) 2730 C and 2atm

13. A gas is found to have formula CO  x . Its VD is 70. The value of x must be:
(A) 3 (B) 5
(C) 6 (D) 2.5

14. A sample of pure gas has a density of 1.60 g litre-1 at 26.5o C and 680.2 mm Hg. Which of the following is
present in the sample?
(A) CH4 (B) C2H6
(C) CO2 (D) Xe

15. Which of the following pair of gases contain the same number of molecules?
(A) 16 g O2 ,14 g N 2 (B) 8 g O2 , 22 gN 2
(C) 28 g N 2 , 22 g CO2 (D) 32 g O2 ,32 g N 2

0
16. A sample of gas at 35 C and 1 atmospheric pressure occupies a volume of 3.75 litre. At what temperature
should the gas be kept, if it is required to reduce the volume to 3.0 litre at the same pressure?
0 0
(A) 26.6 C (B) 0 C
0 0
(C) 3.98 C (D) 28 C

0
17. A thin balloon filled with air at 47 C has a volume of 3.0 litre. If on placing it in a cooled room, its volume
becomes 2.7 litre, the temperature of room is:
0 0
(A) 42 C (B) 30 C
(C) 150 C (D) 0 C
0

18. One atmosphere is numerically equal to approximately:

6 2 2 2
(A) 10 dyne cm (B) 10 dyne cm
4 2 8 2
(B) 10 dyne cm (D) 10 dyne cm

19. If the pressure of N2/H2 mixture in a closed vessel is 100 atmospheres and 20% of the mixture then reacts, the
pressure at the same temperature would be:
(A) the same (B) 110 atmospheres
(C) 90 atmosphere (D) 80 atmosphere
20. Air contains 79% N2 and 21% O2 by volume. If the barometric pressure is 750 mm Hg the partial pressure of
oxygen is:
(A) 157.7 mm of Hg (B) 175.5 mm Hg
(C) 315.0 mm Hg (D) none of these

21. A gaseous mixture contains 1 g of H2, 4 g of He, 7 g of N2 and 8 g of O2. The gas having the highest partial
pressure is:
(A) H2 (B) O2
(C) He (D) N2

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22. 26 mL of CO2 are passed over hot coke. The maximum volume of CO formed is:
(A) 15 mL (B) 10 mL
(C) 32 mL (D) 52 mL

23. The density of CCl4 vapour at 00 C and 76 cm Hg in g/litre is:

(A) 11.2 (B) 77
(C) 6.88 (D) none of these

23
24. Volume occupied by 3.0110 molecules of acetylene at NTP is :
(A) 22.4 litre (B) 11.2 litre
(C) 1.12 litre (D) 2.24 litre

25. Figure shows graphs of pressure versus density for an ideal gas at two temperatures
T2
T1 and T2. Which is correct?
(A) T1  T2 (B) T1  T2 T1

Pressure
(C) T1  T2 (D) None of these

Density

26. At a constant temperature what should be the percentage increase in pressure for a 5% decrease in the
volume of gas?
(A) 5% (B) 10 %
(C) 5.26 % (D) 4.26 %

27. At 270 C a gas was compressed to half its volume. To what temperature must it be heated so that it occupies
the original volume? (P = constant)
(A) 540 C (B) 6000 C
(C) 327 K (D) 3270 C

28. The value of gas constant R is:

(A) 83 erg K-1 mol-1 (B) 0.082 litre atm
(C) 8.3 J mol-1 K-1 (D) 0.987 cal mol-1 K-1

29. An ideal gas expands according to PV = constant. On expansion, the temperature of gas:
(A) will rise
(B) will drop
(C) will remain constant
(D) cannot be determined because the external pressure is not known

30. Which of the following volume (V), temperature (T) plots represents the behaviour of one mole of an ideal gas
at one atmosphere?

(A) (B)
V(L) (38.8 L, 373 K) V(L) (28.6 L, 373 K)
(22.4 L, (22.4 L,
273 K) 273 K)

T(K) T(K)

(C) (D)
V(L) V(L)
(30.6 L, 373 K)
(22.4 L,
(22.4 L,
273 K) (14.2 L, 373 K)
273 K)

T(K) T(K)

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 ANSWERS:
1. B 2. C 3. B

4. A 5. A 6. A

7. A 8. A 9. A

10. B 11. B 12. C

13. B 14. C 15. A

16. A 17. C 18. A

19. C 20. A 21. C

22. D 23. C 24. B

25. A 26. C 27. D

28. C 29. C 30. C.

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