Daily Practice Problems

Subject: Chemistry Topic: State of Matter Course: JEE-21(3 Year’s Integrated)

Date of Modification : 07/05/2020 Sequence : C-B
C-B (Level-B) 10. The compressibility factor for an ideal gas is:
1. According to the kinetic theory of gases (A) 1.5 (B) 1.0 (C) 2.0 (D) 
(A) There are intermolecular attractions 11. According to Graham’s law at a given temperature,
(B) Molecules have considerable volume the ratio of the rates of diffusion rA / rB of gases A
(C) No intermolecular attractions and B is given by
1/2 1/2
(D) The velocity of molecules decreases after each P M  M P 
collision (A)  A   A  (B)  A   A 
P M 
B B M P 
B B
2. The Van der Waal’s equation explains the
1/2 1/2
behaviour of P M  M P 
(C)  A   B  (D)  A   B 
(A) Ideal gases (B) Real gases P M 
B A M P 
B A
(C) Vapour (D) Nonreal gases 12. 4.4 gm of a gas at STP occupies a volume of 2.24
3. Which of the following is not a crystalline solid? litre, the gas can be
(A) KCl (B) CsCl (A) O2 (B) CO (C) NO2 (D) CO2
(C) Glass (D) Rhombic sulphur
13. A certain sample of gas has a volume of 0.2 litre
4. The density of neon will be highest at
measured to 1 atm. Pressure and 0°C. At the same
(A) STP (B) 0°C, 2 atm pressure but at 273°C, its volume will be
(C) 273°C, 1 atm (D) 273°C, 2 atm (A) 0.4 litre (B) 0.8 litre
5. Absolute zero is defined as the temperature
(C) 27.8 litre (D) 55.6 litre
(A) at which all molecular motion ceases 14. If the four tubes of a car are fitted to the same
(B) at which liquid helium boils pressure with N2 , O2 , H 2 and Ne separately, then
(C) at which ether boils which one will be filled first?
(D) all of the above (A) N 2 (B) O2 (C) H 2 (D) Ne
6. At constant temperature, in a given mass of an
15. If pressure becomes double at the same absolute
ideal gas
temperature of 2 litre CO2 , then the volume
(A) The ratio of pressure and volume always
of CO2 becomes
remains constant
(B) Volume always remains constant (A) 2 litre (B) 4 litre (C) 5 litre (d) 1 litre
(C) Pressure always remains constant 16. A gaseous mixture contains 56g of N 2 , 44g of

(D) The product of pressure and volume always CO2 and 16g of CH 4 . The total pressure of the
remains constant mixture is 720 mm Hg. The partial pressure of
7. At the same temperature and pressure, which of the CH 4 is:
following gases will have the highest kinetic (A) 180 mm (B) 360 mm
energy per mole?
(C) 540 mm (D) 720 mm
(A) Hydrogen (B) Oxygen
17. Same mass of CH 4 and H 2 is taken in container.
(C) Methane (D) All are same
The partial pressure caused by H 2 is
8. Which of the following mixture of gases does not
obey Dalton’s law of Partial pressure? 8 1 1
(A) (B) (C) (D) 1
(A) O2 and CO2 (B) N 2 and O2 9 9 2
18. The major binding force of diamond, silicon and
(C) Cl 2 and O2 (D) NH 3 and HCl
quartz is
9. The temperature at which real gases obey the ideal
(A) Electrostatic force (B) Electrical attraction
gas laws over a wide range of pressure is called
(C) Covalent bond force (D) Van der Waal’s force
(A) Critical temperature
19. The density of air is 0.00130 g/ml. The vapour
(B) Boyle temperature
density of air will be
(C) Inversion temperature
(A) 0.0065 (B) 0.65 (C) 14.4816 (D) 14.56
(D) Reduced temperature
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20. Molecular weight of a gas that diffuses twice as 29. Air at sea level is dense. This is a practical
rapidly as the gas will molecular weight 64 is: application of
(A) 16 (B) 8 (C) 64 (D) 6.4 (A) Boyle’s law (B) Charle’s law
21. If P, V, T represent pressure, volume and (C) Avogadro’s law (D) Dalton’s law
temperature of a gas, the correct representation of 30. When the product of pressure and volume is
Boyle’s law is plotted against pressure for a given amount of a
1 gas, the line obtained is:
(A) V  (at constant P)
T (A) Parallel to Xaxis
(B) PV = RT (B) Parallel to Yaxis
1 (C) Linear with positive slope
(C) V  (at constant T)
P (D) Linear with negative slope
(D) PV = nRT 31. The rms velocity of CO2 at a temperature T (T in
22. Five grams each of the following gases at 87°C Kelvin) is X cm sec1 . At what temperature (in
and 750mm pressure are taken. Which of them will
Kelvin) the rms velocity of N 2O would be 4x cm
have the least volume?
sec1 ?
(A) HF (B) HCl (C) HBr (D) HI
23. A real gas most closely approaches the behaviour (A) 16T (B) 2T (C) 4T (D) 32T
of an ideal gas at 32. The following graph illustrates

(A) 15 atm and 200K (B) 1 atm and 273K

(C) 0.5 atm and 500K (D) 15 atm and 500K
24. Which one of the following statements is true?
(A) The gas equation is not valid at high pressure
and low temperature
(B) The product of pressure and volume of a fixed
amount of gas is independent of temperature (A) Dalton’s law (B) Charles’s Law
(C) Molecules of different gases have the same (C) Boyle’s law (D) Gay Lussac’s Law
kinetic energy at a give temperature 33. The ratio of rates diffusion of SO2 , O2 and CH 4 is
(D) The gas constant per molecule is called as
Boltzmann’s constant (A) 1 : 2 :2 (B) 1 : 2 : 4
25. Two separate bulbs contain ideal gas A and B. The (C) 2 : 2 : 1 (D) 1 : 2 : 2
density of gas A is twice that of B. The molecular 34. A bottle of cold drink contains 200 ml liquid in
mass of A is half that of B. The two gases are at which CO2 is 0.1 molar. Suppose CO2 behaves
the same temperature. The ratio of pressure A to like an ideal gas, the volume of the dissolved CO2
that of gas B is: at STP is
1 1 (A) 0.224 litre (B) 0.448 litre
(A) 2 (B) (C) 4 (D)
2 4 (C) 22.4 litre (D) 2.24 litre
26. Use of hot air balloons in sports and metrological 35. In the equation PV = nRT, which one cannot be
observations is an application of the numerical value of R?
(A) Boyle’s law (B) Kelvin’s law
(A) 8.31  107 erg K –1 mol –1
(C) Charle’s law (D) Brown’s law
27. For an ideal gas, the number of moles per litre in (b) 8.31  107 dyne cm K –1mol –1
terms of its pressure P, gas constant R and (C) 8.31 J K –1 mol –1
temperature T is:
(D) 8.31 atm K –1mol –1
PT P PT
(A) (B) PRT (C) (D) 36. A bottle of ammonia and a bottle of dry hydrogen
R RT P
28. The Van der Waal’s equation reduces itself to the chloride connected through a long tube are opened
ideal gas equation at simultaneously at both ends, the white ammonium
chloride ring first formed will be
(A) High pressure and low temperature
(A) at the centre of the tube
(B) low pressure and low temperature
(B) near the hydrogen chloride bottle
(C) low pressure and high temperature
(D) high pressure alone (C) near the ammonia bottle
(D) throughout the length of the tube
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37. Root mean square velocity of a gas molecule is 9. 10 ml of mixture of CH4 , C2 H 4 and CO2 are
proportional to exploded with excess O2 . A contraction of 17 ml
(A) m1/2 (B) m0 (C) m –1/2 (D) m was observed after explosion. After the treatment
38. A sample of a given mass of a gas at a constant with KOH solution there was a 2nd contraction of
temperature occupies 95 cc under a pressure of 14 ml. Find the % of gases in mixture?
9.962  104 Nm–2 . At the same temperature, its 10. 25cc of a gaseous mixture containing
N2 and N 2O is passed through a hot Cu tube. The
volume at a pressure of 10.13  104 N m –2 is:
resulting gas has a volume of 20 ml. find the
(A) 190cc (B) 93cc (C) 46.5 cc (D) 47.5 cc percentage of N2 and N 2O in the original gas
39. Equal volumes of the gases which do not react mixture (The volumes have been measured under
together are enclosed in separate vessels. This same conditions of temperature & pressure)?
pressures of 100 mm, and 400 mm respectively. If
the two vessels are joined together, then what will 
be the pressure of the resulting mixtur (temperature
remaining constant)?
(A) 125 mm (B) 500mm
(C) 1000 mm (D) 250 mm
40. There are 6.02  10 molecules each of N 2 , O2
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and H 2 which are mixed together at 760 mm and

273 K. The mass of the mixture in grams is
(A) 6.02 (B) 4.12 (C) 3.09 (D) 7]

C-B (Level-D)
1. How large a balloon could you fill with 4.0 g of He
gas at 22ºC and 720 mm of Hg?
2. Calculate the density of CO2 at 100ºC and 800
mm Hg pressure.
3. A container has 3.2 g of a certain gas at NTP.
What would be the mass of the same gas contained
in the same vessel at 200C and 16 atm. Pressure?
4. A certain quantity of a gas measured 500 mL at a
temperature of 15°C and 750 mm Hg. What
pressure is required to compress this quantity of
gas into a 400 mL vessel at a temperature of 50°C?
5. Three footballs are respectively filled with
N 2 , H 2 and He to the same pressure. In what
order are these footballs to be reinflated?
6. The ratio of rates of diffusion of two gases A and
B under same pressure is 1 : 4. If the ratio of
their masses present in the mixture is 2 : 3. What is
the ratio of their mole fraction in mixture?
7. Calculate the rms speed in cm/sec at 25°C of a free
electron and a molecule of UF6 .
8. The flask (A) and (B) have equal volumes.
Flask (A) contains H2 gas at 300K, while (B)
contains equal mass of CH 4 at 900K. Calculate the
ratio of average speed of molecules in flask (A)
and (B)
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