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SCIENCE AND
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Composites Science and Technology 66 (2006) 333–342
www.elsevier.com/locate/compscitech
a
Institute of Metallurgy, University of Bologna, V.le Risorgimento 4, I-40136 Bologna, Italy
b
DIEM, University of Bologna, V.le Risorgimento 2, I-40136 Bologna, Italy
Abstract
In this paper, the tensile properties and the low-cycle fatigue behavior of the 7005 aluminum alloy reinforced with 10 vol% of
Al2O3 particles (W7A10A composite) and 6061 aluminum alloy reinforced with 20 vol% of Al2O3 particles (W6A20A composite)
were studied. The microstructural analyses showed clustering of Al2O3 particles, irregularly shaped and with a non-uniform size.
A significant increase of the elastic modulus and tensile strength in the MMCs, respect to the unreinforced alloys, was evidenced
by the tensile tests, while the elongation to fracture decreased. The temperature effect on the tensile properties was not relevant
up to 150 C, while strength significantly decreased at 250 C, mainly in the composite with the lower content of the ceramic rein-
forcement. The low-cycle fatigue tests showed no evidence of isotropic hardening or softening for the W7A10A, and a slight cyclic
softening for the W6A20A. SEM analyses of the fracture surfaces showed that both the tensile and fatigue fracture was controlled
by interfacial decohesion (expecially for the W7A10A composite), fracture of reinforcing particles (mainly for the W6A20A com-
posite), void nucleation and growth. Also the presence of the MgAl2O4 spinel, probably, played a significant role in the mechanisms
of failure in the W6A20A composite, by promoting void nucleation at the particles–matrix interfaces, interfacial decohesion, and
also failure of the particles. These effects can be responsible of the slight softening observed in the W6A20A, under the low-cycle
fatigue conditions.
2005 Elsevier Ltd. All rights reserved.
Keywords: Metal matrix composites; Tensile tests; Low-cycle fatigue; AA7005; AA6061; Al2O3; Particles; High temperature; Clustering; MgAl2O4
spinel
0266-3538/$ - see front matter 2005 Elsevier Ltd. All rights reserved.
doi:10.1016/j.compscitech.2005.04.044
334 L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342
Table 2
T6 heat treatment conditions and measured hardness values, HRB, for the tested composites, and the literature data for the aluminum alloys matrix [32]
Material Solution treatment Quenching Aging Hardness
W6A20A 560 C – 2h H2O at 25 C 177 C – 10 h 66 ± 0.5
AA 6061 560 C – 2h H2O at 25 C 177 C – 10 h 60
W7A10A 480 C – 1h H2O at 25 C 125 C – 24 h 60 ± 0.5
AA 7005 480 C – 1h H2O at 25 C 125 C – 24 h 59
L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342 335
4 mm gauge width and 4 mm in thickness. A triangular due to the presence of the MgAl2O4 spinel, formed dur-
waveform was used, the strain amplitude range was ing composite fabrication, by reaction between the alu-
from 0.6% to 2%. The tests were carried out at constant mina particles and the magnesium present in the
cyclic frequency of 0.1 Hz and the load ratio was AA6061 matrix [38,39].
R = 1. It is important to note that the testing condi-
tions were chosen on the basis of literature data 3.2. Tensile tests
[22–27,37], since specific guidelines for fatigue tests on
particle-reinforced metal matrix composites are not The experimental results of the tensile tests carried
available. out in the two composites, at room and high tempera-
SEM analyses were carried out on the fracture sur- ture, are listed in Table 3, together with the literature
faces of the tensile and fatigue specimens, in order to data [32] for the corresponding unreinforced alloys.
investigate the mechanisms of failure.
3.1. Microstructure
Fig. 2. SEM micrograph (a) and EDS analysis (b) for the W6A20A composite.
336 L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342
Both composites displayed an increase of the elastic (Fig. 3). The anomalous behavior of the elongation to
modulus with respect to the matrix alloys, equal to failure for the W7A10A at 100 and 150 C (Table 3)
about 39% for the W6A20A and 17% for the can be explained on the basis on the wide dispersion
W7A10A at room temperature. This difference between of the experimental data. An important concern in the
the two MMCs was probably related to the higher vol- tensile tests of MMCs is, in fact, the reproducibility of
ume fraction of the particle reinforcement in the the experimental data, mainly of the elongation to fail-
W6A20A. ure. As can be seen in Fig. 4, the tensile curves of spec-
The effect of temperature on the elastic modulus was imens of same material (W7A10A), tested under the
not significant up 100 C, while a slight decrease oc- same conditions, are substantially overlapped, except
curred at 150 C; the measure at 250 C was not possible
because of the characteristics (high temperature resis-
tance) of the extensometer. 500
The incorporation of the ceramic reinforcement also
led, on both MMCs, to an increase of the proof strength 375
and ultimate tensile strength, higher in the W6A20A with
UTS, MPa
respect to the W7A10A due to the superior reinforce-
250
ment content. The different ceramic volume fraction W6A20A
and size led to high differences also in the elongation to
125
failure. At room temperature, the difference between W7A10A
Table 3
Results of the tensile tests at room and high temperature for the MMCs and the literature data for the corresponding unreinforced aluminum alloys
[32]
Material and test temperature Elastic modulus GPa 0.2% Proof strength (MPa) Ultimate tensile strength (MPa) Elongation (%)
AA7005 – RT 72 290 350 13
W7A10A – RT 85 331 375 4.3
83 325 366 3.2
84 323 369 5.1
W7A10A – 100 C 84 312 343 5.8
92 305 334 7.0
86 315 346 6.5
W7A10A – 150 C 74 277 295 5.3
80 284 303 9.1
80 287 304 6.4
W7A10A – 250 C – – 111 12.4
– – 117 12.0
– – 110 12.8
450 0.1
400
350
Stress (MPa)
300
2
0.01
250
200
150
100 0.001
1 10 100 1000 10000
50
2N Cycles
0
. W6A20A . W7A10A
0,000 0,010 0,020 0,030 0,040 0,050 0,060
Strain Fig. 5. Room temperature life-strain curves for the W7A10A and
Test 1 Test 2 Test 3
W6A20A composites.
Fig. 4. Room temperature tensile curves for the W7A10A composite.
W7A10A
380
0.4
0.5
(a)
360 0.6
0.7
0.9
1.0
340
∆σ /2 (MPa)
320
300
280
260
0 50 100 150 200 250 300
N Cycles
W6A20A
380
0.4
0.5
(b)
360 0.6
0.7
0.9
1.0
340
∆σ /2 (MPa)
320
300
280
260
0 50 100 150 200 250 300
N cycles
Fig. 6. Cyclic stress response curves at different plastic strain amplitudes (%) for the W7A10A (a) and W6A20A (b) composites.
enough to crack the particles or generate decohesion posite, while in the W7A10A the interfacial decohesion
[25,37,40–46,49]. is more evident. Large voids and dimples are caused
The above discussed mechanisms of fracture are evi- by fracture and decohesion of particles in both the mate-
dent in the tensile fractures surfaces of Fig. 7, where rials, while the small ductile dimples can be attributed to
fractured particles, surrounded by ductile regions with the constraints in plastic flow of the aluminium matrix,
fine near-featureless non-circular dimples, called ‘‘tear or to the reduction of strains induced by the particle
ridges’’, and decohesion at matrix–particles interfaces cracking which lead to the formation of tear ridges.
are present. Fracture of Al2O3 occurred in large particle The higher presence of cracked particles and tear ridges
or in regions with clusters, mainly in the W6A20A com- in the W6A20A composite, can be explained with the
L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342 339
Fig. 7. SEM micrographs of the tensile fracture surfaces of the W6A20A (a) and W7A10A (b) tested at room temperature.
Fig. 8. SEM micrographs of the tensile fracture surfaces of the W6A20A (a) and W7A10A (b) tested at 250 C.
high local plastic constraints induced by the larger-sized micromechanisms. While for the W7A10A composite
particles and by the clusters. the low-cycle fatigue tests showed no evidence of cyclic
At high temperatures the local stresses are not large hardening or softening, a slight cyclic softening was ob-
enough to crack the particles, since matrix flow stress served in the W6A20A (Fig. 6(b)). This softening is
decreases; however, the normal stress can promote inter-
facial decohesion and voids nucleation [43,50,51]. Voids
nucleation was concentrated at the interface with the
particles, where there is a high matrix strain, and at
the clusters where high local triaxial stresses are present.
As shown in Fig. 8, the fracture surfaces exhibited many
minute dimples in the matrix regions around the parti-
cles and in the voids formed due to the particle
decohesion.
In the W6A20A, both at room and high temperature,
the MgAl2O4 spinel probably plays a relevant role
on the fracture process, promoting voids nucleation, at
the particles interface, interfacial decohesion and also
failure of the particles [38,39]. These effects are probably
associated with the jagged interfaces generated by the
spinel formation [39], evidenced in the high magnifica-
tion SEM micrograph in Fig. 9. Fig. 9. SEM micrograph of the fracture surface of the W6A20A, tested
The fracture surfaces of the materials tested in fatigue at 250 C, showing a jagged particle–matrix interface, probably due to
(Fig. 10) and in tension were similar and so the fracture the MgAl2O4 spinel.
340 L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342
Fig. 10. SEM micrographs of the fracture surfaces of the low-cycle fatigue specimens tested at room temperature of W6A20A (a and b) and
W7A10A (c and d) composites.
probably due to the mutual action of interfacial decohe- • No significant variation of the tensile strength and
sion and mainly particles cracking (Fig. 10(a) and (b)) ductility with temperature was observed up to
[41,47,48,51]. 150 C, while at 250 C strength significantly
decreased, and ductility increased.
• The low-cycle fatigue tests showed no evidence of iso-
4. Conclusions tropic hardening or softening for the W7A10A, and a
slight cyclic softening for the W6A20A, probably due
In the present investigation, the tensile properties (at to the mutual action of interfacial decohesion and
room and high temperature), and the low-cycle fatigue mainly particles cracking.
behavior of two particles-reinforced composites, • SEM analyses of the fractures surfaces showed frac-
W6A20A (AA6061 reinforced with 20 vol% of Al2O3 tured particles, surrounded by ductile regions and
particles) and W7A10A (AA7005 reinforced with decohesion at the matrix–particles interfaces. Frac-
10 vol% of Al2O3 particles), were studied. ture of the particles mainly occurred in the
W6A20A composite, while interfacial decohesion
• In both composites, agglomeration or clustering of was predominant in the W7A10A. The higher pres-
the Al2O3 particles, irregularly shaped and with a ence of cracked particles and tear ridges in the
non-uniform size, are present; in the W6A20A com- W6A20A composite can be explained with the high
posite larger particles size was observed. local plastic constraints induced by the larger-sized
• The tensile tests showed an increase of the elastic particles and by the clusters. At high temperatures
modulus and tensile strength, and a decrease of the voids nucleation was mainly concentrated at the
elongation to failure in the MMCs, respect to the matrix–particles interfaces. In the W6A20A compos-
unreinforced alloys. The tensile ductility was strongly ite, the MgAl2O4 spinel probably promoted void
affected by the material inhomogeneity, mainly nucleation, at the particles interface, interfacial deco-
related to the particles size and distribution. hesion, and also failure of the particles.
L. Ceschini et al. / Composites Science and Technology 66 (2006) 333–342 341
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