Group Meeting Problems - 2021/11/06

O N
O O O
fac-Ir(ppy)3 (0.2 mol%)
+ N Ir
O DMSO, rt N N
O O 5W blue LEDs

67%
fac-Ir(ppy)3

F. Glorius et al., Org. Lett., 20, 1546 (2018)

 Group Meeting Problems - 2021/11/06
Ar (Ar = 4-MeOC H )
2 6 4

BF4
(2 mol%)
Ar O Ar H O
O2 (1 atm), hν (470 nm), O
H H
DCE, 0 °C; HO
TBSO O O
TBAF, rt;
TFA, rt

53%
J. H. George et al., Angew. Chem. Int. Ed., 58, 2791 (2019)
 Group Meeting Problems - 2021/11/13

3 O2
N

OH O FePc (2 mol%) N N
HO O N Fe N
5W white LED N N
+
N
N AcOH/H2O, rt N
OH Me Me O FePc
68%

Y.Fu et al., Org. Lett., 23, 8317 (2021)

 Group Meeting Problems - 2021/11/13

4
HO
O Me Me
SmI2
Me
Br Me
THF, rt;
PhO2C CO2Ph H O O
H2O Me
60%

D. J. Procter et al., Nature Communications, 9, 4802, (2018)

 Group Meeting Problems - 2021/12/04

6 MgBr
O O
O2 (1 atm)
S S
N t-Bu t-Bu NH OH
THF/DCM
H 78°C

66% (dr = 88:12)

Z. Song et al., Angew. Chem. Int. Ed., 60, 24644 (2021)