Professional Documents
Culture Documents
ON THE COMPOSITIONS
THAT GIVE THE MOST BEAUTIFUL COLORS
IN
FIREWORKS.
BY
F. -M. CHERTIER.
In Paris,
AT DELAUNAY’S, BOOKSELLER,
PALAIS-ROYAL, GALERIE VALOIS, Nos 182 and 183,
1836.
second draft August 2006 2
PREFACE.
In writing this Work, I did not intend to produce
a treatise on pyrotechny; my researches were
specifically on colored fires, this aspect seeming to
me to have been neglected. I had no other work to
assist me; science is silent on this subject: it is
only by repeated experiments and by trial and
error that I have obtained some results. I claim no
virtue other than that of perseverance.
I have tested nearly all the natural substances,
such as stones, marbles, chalk, shells, ores of
nearly all the metals, then the chemical products,
all the salts, the oxides, etc.
I did not restrict myself to testing them
separately, I mixed each of them with at least one,
and often with several, other substances; in this
way, I found that calomel, which produces nothing
on its own, is of an excellent effect when it is
combined with other substances. It is not used as
a divisant;
SUBSTANCES
THAT ARE USED IN THE COMPOSITION
OF COLORED FIRES.
ARSENATE OF COPPER.
This is one of the principal ingredients in the
best blue compositions. It is difficult to procure
good material; I have tested it from nearly
all of the chemical products factories without
finding any that I could use. This substance
is obtained by several procedures. There are
(6)
(7)
ARSENATE OF POTASH.
It is used only for making arsenate of copper. It
can be obtained already prepared.
BI-CARBONATE OF SODA.
BROMATE OF BARYTA.
WHITE LEAD.
It is used in only one of my compositions, and
gives a dull white.
CALOMEL,
OR MILD MERCURY PREPARED FROM THE VAPOR.
(8)
CHARCOAL.
It is used in my compositions as a divisant; only
the lightest must be used, and it must be well
pulverized.
CHALK.
It gives a crimson red, less beautiful than the red
obtained with nitrate of strontian; but it is not
hygroscopic and is stable for a long time,. I
recommend using it in color grains (1). There are
different qualities of it; it is almost impossible to
distinguish these without trying them.
Some produce a yellowish-red flame, others a
pale red, and finally some others a beautiful cherry
red.
It is necessary, before buying any, to test samples
from several vendors, and when one finds some of
good quality, to obtain a stock of it.
CARBONATE OF COPPER.
It is rare to find this of good quality, it nearly
always produces a blue-violet flame. If it is of good
quality, it must be a pure blue, although, however,
a little pale. It is used most often in violet and
(1) See below; I explain the use of these color grains, and
give the way of making them.
(9)
(10 )
CHLORATE OF POTASH.
It contains a lot of oxygen; it is the most powerful
combustion agent; it is the basis of almost all
colored fires; it must be used dry, well pulverized
and passed though a silk sieve.
( 11 )
CHLORATE OF SODA.
It gives a flame of a quite beautiful yellow, less
beautiful, however, than that produced by oxalate
of soda; as it is very costly, do not use it.
CHLORATE OF COPPER.
It is deliquescent, it can only be given a syrupy
consistency; mixed with sulfur, it burns suddenly,
without contact with fire; if a piece of paper be
impregnated with it and brought into the flame of a
candle or put on hot coals, it produces a beautiful
ragged blue flame, (not green, as certain chemists
erroneously state); it can be used mixed with
spirits of wine, for burning in little pots, it is the
only substance that, mixed with spirits of wine,
burns with a blue flame. All the other salts of
copper, dissolved in alcohol, give a green flame,
mixed, however, with a little blue: but it is the
green that dominates.
CHLORATE OF BARYTA.
It produces a very pronounced emerald green:
no other substance can replace it;
unfortunately it is very costly, less so,
however, than bromate of baryta, which is not as
( 12 )
( 13 )
ARTIFICIAL GILDING.
These are excessively thin leaves of copper, which
the slightest breath will blow away. It is used as a
divisant, it has, like calomel, the property of
modifying the red and of removing the yellowish
shade from green.
YELLOW AMBER
It is used in some yellow compositions, it deepens
the color and acts as a divisant in activating
combustion. It has to be procured as lumps and
then pulverized; because, if bought as a powder,
it is nearly always adulterated.
LITHARGE.
It is only used in the composition for turning
tubes. Use only coarse material. If it has fine
material mixed in, separate it by passing it
through a horsehair sieve. It produces beautiful
sparks; it keeps for a long time without oxidizing.
( 14 )
MALACHITE.
This is also a copper ore, it is bright green: it can
replace the blue crystals of carbonated copper
ore. It is used in the same way and in the same
proportions. I have found, however, that the blue
crystals are preferable to it.
NITRATE OF STRONTIAN.
This substance plays the principal role in colored
fires; it is the basis of purple-red, crimson, corn
poppy red, of violet and of pink. It produces a
brilliant flame that is difficult for the eye to
endure. No other substance can compare with it:
unfortunately it attracts moisture from the air,
and compositions in which it is used are difficult
( 15 )
( 16 )
( 17 )
NITRATE OF BARYTA.
This is used to make green flames. I have done
many tests with this substance: I believe I have
found some sufficiently good combinations; I give
several of them, among which there are some
having an effect almost as beautiful as those
produced by chlorate of baryta. They have the
advantage of being much less costly and less
dangerous.
LAMPBLACK.
This is used as a divisant : it forms part of the
composition of corn-poppy red and of green. Use
only the lightest grade.
OXALATE OF COPPER.
This gives a rather pale blue flame. Without
being as good as arsenate of copper, it can,
however, replace it should the need arise.
( 18 )
OXALATE OF SODA.
This is the substance that seems to me the best
for making yellow. It is far superior to other
preparations of soda, it is not hygroscopic: the
method of making being very simple, one can
easily carry it out one’s self. Dissolve over the fire,
in as little water as possible, about 14 to 15
ounces of white soda (dried carbonate of soda).
Dissolve also over the fire half a pound of oxalic
acid, always in the least water possible; because
it is essential that the two liquors be very
concentrated; without this, the precipitation will
be poor. The two solutions are passed separately
through a silk or linen sieve. Put the oxalic acid
solution into a very large vessel, so that the
agitation produced on mixing the two solutions
will not make the liquor come out of the vessel;
carefully pour the soda solution onto it, while
stirring with a piece of wood or a spatula, until
there is no more effervescence. To be sure that
the acid is completely neutralized, dip into the
mixture a piece of blue litmus paper. (This paper
can be found at makers of chemical products.) If
the paper reddens, add a little more soda
solution; add it until the paper no longer reddens,
( 19 )
PLASTER.
It produces a flame tending a little towards lilac,
it is not hygroscopic, it must be preferred for use
in color grains; used plaster, plaster casts or,
even better, pieces of broken busts, are the best.
WHITE PRECIPITATE.
A preparation of mercury, it gives a deep pink or
light crimson flame.
PHOSPHATE OF COPPER.
It is extremely difficult to procure good material;
I have however found some of excellent quality
that rated even better than arsenate of copper,
but when it had been used up, it was impossible
for me to find anything similar; I have developed,
( 20 )
( 21 )
PHOSPHATE OF AMMONIAC.
This is used only for making paper
incombustible.
REGULUS OF ANTIMONY.
This is used as a divisant, and forms part of the
composition of white, of pink and of some other
mixtures.
SULFUR.
This is used in all the compositions; this
substance is so well known that it would be
superfluous to describe it.
SULFATE OF COPPER.
Usually this is used only for making other
preparations of copper, by precipitating it
with potash or with lime; it is, however,
used in one of my compositions and gives a
passable blue; to be used for this purpose it
must be roasted; this operation is done as
follows: the sulfate is pulverized, and put on an
( 22 )
TARTRATE OF COPPER.
It can, if need be, replace arsenate of copper but
it is not as beautiful.
VERDIGRIS.
It produces a pale blue, it is used in a
composition for a passable blue.
ZINC.
Before the discovery of chlorate of potash, this
was the substance that gave the most
pronounced colors; it has greatly lost its impor-
( 23 )
( 24 )
( 25 )
( 26 )
COMPOSITIONS.
No 1. ― WHITE.
For stars. For flames.
Saltpeter . . . . . . . . . 30 parts. 30 parts.
Flowers of sulfur . . . . . . 10 12
Regulus of antimony (1) . . . 11 10
Nitrate of baryta . . . . . . “ 2
( 27 )
( 28 )
No 3. ― PALE YELLOW.
For stars, for little
suns and for grains. For flames.
Chlorate of potash . . . . 36 parts. 30 parts.
Nitrate of baryta . . . . . 30 24
Flowers of sulfur . . . . 18 18
Oxalate of soda . . . . . 6 6
Lampblack . . . . . . . 1 “
( 29 )
No 4. ― MEDIUM YELLOW,
For stars, for little suns and for grains.
( 30 )
Chlorate of potash 72 72 72 72 72
Nitrate of baryta . . 120 144 156 160 168
Flowers of sulfur . . 36 36 36 36 36
Lampblack . . . . 1 1|2 2 2 1|2 3 3 1|2
Calomel . . . . . . 1 1 1|2 2 2 1|2 3 1|2
( 31 )
( 32 )
( 33 )
( 34 )
( 35 )
No 14. ― GREEN
for garnitures of shells and rockets.
( 36 )
No 15. ― BLUE
For stars, for little suns and for grains.
Chlorate of potash . . 34 30 26
Flowers of sulfur . . . 14 14 13
English blue ash . . . 7 7 7
Arsenate of copper . . 3 3 3
Calomel . . . . . . . 2 2 2
( 37 )
No 15 continued. ― BLUE
For stars, for little suns and for grains.
Chlorate of potash . . . . . . 64 50 64 64
Flowers of sulfur . . . . . . . 30 22 30 30
English blue ash,
first quality no 1 . . . . . . . . 16 14 20 24
Arsenate of copper . . . . . . 4 8 8 8
Calomel . . . . . . . . . . . 4 4 4 4
No 16. ― BLUE
For stars and for grains.
Chlorate of potash . . . . . 36 36 36
Flowers of sulfur . . . . . . 18 18 18
Precipitate of sulfate of copper
with filtered lime water . . . . 6 6 6
English blue ash no 1 . . . . 12 15 18
Calomel . . . . . . . . . . 3 3 3
No 17. ― BLUE
For stars and for grains.
Chlorate of potash . . . . . 36 36 36
Flowers of sulfur . . . . . . 18 18 18
Precipitate of sulfate of copper
with filtered lime water . . . . 6 6 6
Carbonated copper ore in blue
crystals . . . . . . . . . . . . 10 12 14
Calomel . . . . . . . . . . . 3 3 3
( 38 )
No 18. ― BLUE
For stars and for grains.
Chlorate of potash . . . . . . 48 48 48
Flowers of sulfur . . . . . . . 24 24 25
Arsenate of copper . . . . . . 6 6 6
Carbonated copper ore . . . . 4 6 8
Calomel . . . . . . . . . . . 3 3 3
( 39 )
Chlorate of potash . . . . . 48 45 36
Flowers of sulfur . . . . . . 18 18 18
Precipitate of sulfate of copper
with filtered lime water . . . . 6 6 6
Carbonated copper ore . . . 18 20 18
Calomel . . . . . . . . . . 1 1 1
( 40 )
Chlorate of potash . . . . . . 36 45
Flowers of sulfur . . . . . . . . 14 18
English blue ash no 1 . . . . 24 26
Arsenate of copper. . . . . . . “ 2
Calomel . . . . . . . . . . . . 1 2
No 21. ― COMPOSITION
For priming blue stars.
Chlorate of potash . . . . . . . . . . . . . 36
Flowers of sulfur . . . . . . . . . . . . . . 18
Arsenate of copper . . . . . . . . . . . . . 6
Blue ash. . . . . . . . . . . . . . . . . 6
Artificial gilding. . . . . . . . . . . . . . . 2
.
Even though I have said that the blue
compositions produce a bad effect for flames, one
can, however, try the formula of no 19, and the
second formula of no 20.
They give a deep blue, but as they have little
reflection, they can be used only in a small area.
( 41 )
Chlorate of potash . . . . . . . . . . . . . 72
Nitrate of strontian . . . . . . . . . . . . . 60
Flowers of sulfur. . . . . . . . . . . . . . 48
Regulus of antimony. . . . . . . . . . . . . 24
Chlorate of potash . . . . . . . . . . . . . 45
Nitrate of strontian . . . . . . . . . . . . . 30
Flowers of sulfur. . . . . . . . . . . . . . 30
Regulus of antimony. . . . . . . . . . . . . 12
Carbonate of copper. . . . . . . . . . . . . 1
Chlorate of potash . . . . . . . . . . . . . 72
Nitrate of strontian . . . . . . . . . . . . . 60
Flowers of sulfur. . . . . . . . . . . . . . 48
Regulus of antimony. . . . . . . . . . . . . 6
Lampblack. . . . . . . . . . . . . . . . . 1
Chlorate of potash . . . . . . . . . . . . . 72
Nitrate of strontian . . . . . . . . . . . . . 60
Flowers of sulfur. . . . . . . . . . . . . . 48
Lampblack. . . . . . . . . . . . . . . . . 1
( 42 )
No 26. ― PINK
For color grains.
Chlorate of potash . . . . . . . . . . . 72 72
Chalk . . . . . . . . . . . . . . . . . 16 16
Flowers of sulfur. . . . . . . . . . . . 30 30
Carbonate of copper . . . . . . . . . . “ 1
No 27. ― VIOLET
For stars and for little suns.
Chlorate of potash . . . . . . . . . . . 42 42
Nitrate of strontian . . . . . . . . . . . 18 24
Flowers of sulfur. . . . . . . . . . . . 28 28
Carbonate of copper . . . . . . . . . . 3 4
Calomel. . . . . . . . . . . . . . . . 3 “
No 28. ― VIOLET
For color grains.
Fast. Faster.
Chlorate of potash . . . . . . . . . . . 84 72
Chalk. . . . . . . . . . . . . . . . 24 24
Flowers of sulfur. . . . . . . . . . . . 30 30
Carbonate of copper . . . . . . . . . . 6 6
Calomel. . . . . . . . . . . . . . . . 6 10
( 43 )
No 29. ― CRIMSON
For stars, for little suns and for flames.
No 30. ― COMPOSITION
For priming red stars of slow compositions.
Chlorate of potash . . . . . . . . . . . 72
Nitrate of strontian . . . . . . . . . . . 30
Flowers of sulfur. . . . . . . . . . . . 30
Lampblack . . . . . . . . . . . . . . 4
No 31. ― CRIMSON
For little grains.
Chlorate of potash . . . . . . . . . 60
Chalk . . . . . . . . . . . . . . 24
Flowers of sulfur. . . . . . . . . . 24
Carbonate of copper . . . . . . . . “ 1|2
( 44 )
Much less beautiful than the crimson made with
nitrate of strontian, it is better for little grains, for
the reason that I have already given. It can also be
used for roman candle stars that have to be kept
all winter; they are stable for a long time.
No 32. ― RED
For little grains.
No 33. ― RED
For stars and for little suns.
( 45 )
No 34. ― RED
For stars and for little suns.
Purple Purple
Chlorate of potash . . . . . . . 36 36
Nitrate of strontian . . . . . . . 108 108
Flowers of sulfur . . . . . . . . 30 30
Lampblack . . . . . . . . . . 4 “
Fine charcoal . . . . . . . . . “ 4
No 35. ― RED
For stars and for little suns.
Chlorate of potash . . . . . . . 36 36
Nitrate of strontian . . . . . . . 84 84
Flowers of sulfur . . . . . . . . 30 30
Fine, very light charcoal . . . . . 5 5
Oxalate of soda . . . . . . . . “ “ 1|2
Chlorate of potash. . . . 12 48 48
Nitrate of strontian . . . 48 72 84
Flowers of sulfur . . . . 18 36 36
Lampblack . . . . . . 3 3 4
Calomel . . . . . . . “ 4 8
( 46 )
No 37. ― RED
For stars and for little suns.
Chlorate of potash . . . . 30 30 30
Nitrate of strontian . . . . 36 36 36
Flowers of sulfur . . . . . 18 18 18
Fine charcoal . . . . . 2 “ “
Lampblack . . . . . . . “ 2 11|2
Calomel . . . . . . . . “ “ 1
Chlorate of potash . . . . 6 6 6 6
Nitrate of strontian . . . . 54 54 60 54
Flowers of sulfur . . . . . 18 24 24 18
Lampblack . . . . . . . 2 2 2 2
Calomel . . . . . . . . “ “ “ 4
Chlorate of potash . . . . . . . 8 6
Nitrate of strontian . . . . . . . 72 72
Flowers of sulfur . . . . . . . . 24 24
Lampblack . . . . . . . . . . 21|2 2
Calomel . . . . . . . . . . . . 3 4
( 47 )
( 48 )
SUPPLEMENTARY COMPOSITIONS,
OR SECOND SERIES
( 49 )
No 41. ― WHITE.
For stars. For flames.
Saltpeter. . . . . . . . 24 24 20
Nitrate of baryta . . . . . 8 12 8
Flowers of sulfur . . . . 9 9 6
Regulus of Antimony. . . 6 6 3
Orpiment . . . . . . 3 6 2
Chlorate of potash . . . . 18 18
Flowers of sulfur . . . . . 6 6
Bi-carbonate of soda . . . 4 4
Nitrate of baryta . . . . . 3 3
Lampblack . . . . . . . “ 1|4 “
Chlorate of potash . . . . 24 12
Bi-carbonate of soda . . . 10 8
Flowers of sulfur . . . . . 8 8
Lampblack . . . . . . . “ 1|4 “ 1|2
4
( 50 )
Fast. Slow.
Chlorate of potash . . . . 36 30 30
Nitrate of strontian . . . . 12 36 36
Flowers of sulfur . . . . . 12 18 18
Bi-carbonate of soda . . . 12 10 12
Yellow amber . . . . . . 12 “ “
Lampblack . . . . . . . “ 21|2 2
No 45. ― COMPOSITION
For priming yellow stars.
Chlorate of potash. . . . . . . . . 36
Nitrate of baryta . . . . . . . . . 12
Bi-carbonate of soda . . . . . . . 3
Flowers of sulfur. . . . . . . . . 18
Lampblack . . . . . . . . . . 2
( 51 )
No 47. ― GREEN.
For stars and for little suns.
Chlorate of potash . . . . . . . . 10 10
Nitrate of baryta . . . . . . . . . 20 24
Flowers of sulfur . . . . . . . . . 5 5
Lampblack . . . . . . . . . . . “ 1|4 “ 1|4
Artificial gilding . . . . . . . . . “ 5|16 “5|16
.
No 48. ― GREEN.
For stars For flames
Nitrate of baryta . . . . . . . . . 30 40
Chlorate of potash . . . . . . . . 6 6
Flowers of sulfur . . . . . . . . . 12 12
Lampblack . . . . . . . . . . . 1 1
( 52 )
No 52. ― BLUE
For stars and for little suns.
Chlorate of potash . . . . 32 29 30
Flowers of sulfur . . . . . 11 11 12
English blue ash . . . . 14 16 20
No 54. ― BLUE
For stars and for little suns.
Chlorate of potash . . . . 36 32 30
Flowers of sulfur . . . . . 13 12 12
English blue ash. . . . 14 16 18
Calomel . . . . . . . . 2 2 2
( 53 )
No 57. ― BLUE.
Chlorate of potash . . . . . . . . 54 60
Flowers of sulfur . . . . . . . . . 24 27
Roasted sulfate of copper . . . . . 30 12
Carbonated copper ore . . . . . . “ 12
( 54 )
( 55 )
No 60. ― COMPOSITION
That gives brilliance and augments the intensity of the color blue.
Chlorate of potash . . . . . . . . . . . 60
Flowers of sulfur . . . . . . . . . . . . 30
Calomel . . . . . . . . . . . . . . . 10
No 61. ― LILAC
For stars and for little grains.
Light. Deeper.
Chlorate of potash. . . . 16 16 16 16
Flowers of sulfur . . . . . 8 8 8 8
Plaster . . . . . . . . . 4 5 6 6
Carbonate of copper . . . 1 1 1 1 1|2
( 56 )
No 63. ― PINK
For stars and for little grains.
No 64. ― CRIMSON
For little suns.
Chlorate of potash . . . . . . . . . . . 12
Nitrate of strontian . . . . . . . . . . . 20
Flowers of sulfur . . . . . . . . . . . . 10
Artificial gilding . . . . . . . . . . . . 1
( 57 )
This red is not very deep, but it is very brilliant.
COLOR GRAINS.
METHOD FOR MAKING THEM.
( 58 )
( 59 )
( 60 )
( 61 )
( 62 )
LITTLE SUNS,
OR DAHLIA PINWHEELS.
( 63 )
( 64 )
( 65 )
( 66 )
( 67 )
( 68 )
( 69 )
( 70 )
( 71 )
(1) The pivots that I use for little suns, and which really
seem to me to be preferable, are large drapers’ pins.
( 72 )
DAHLIA PINWHEELS,
WITH WREATHS OF COLOR GRAINS.
( 73 )
( 74 )
last fountain, and must last for the whole time that
the pinwheel is burning; they must be charged
with four different colors, but both the same, that
is, so that when the top one gives a blue flame, the
lower one also give a flame of that same color, etc.
A space of three lignes must be left in the middle
of the disc; two little button-shaped pieces of wood
are glued above and below the disk at the centre,
to form a sort of hub to receive the pivot; the little
suns, if they are to produce all their effect, must be
placed five or six feet high.
The same number of fountains that were glued
to the front of the cardboard could be glued behind
it; the pinwheels would then last twice as long, but
could be perhaps a little too heavy.
( 75 )
( 76 )
( 77 )
( 78 )
METHOD
OF PULVERIZING SUBSTANCES QUICKLY.
( 79 )
( 80 )
( 81 )
( 82 )
( 83 )
( 84 )
TABLE.
( 86 )
( 87 )
( 88 )
deeper, n. 60 . . . . . . . . . . . . . . . . . . . . . . . . . 55
Lilac for stars n. 61. . . . . . . . . . . . . . . . . . . . . . do.
Lilac for stars n. 62. . . . . . . . . . . . . . . . . . . . . . 56
Pink for stars and for little grains n. 63. . . . . . . . . . . . do.
Crimson for little suns n. 64 . . . . . . . . . . . . . . . . . do.
Red for stars n. 65 . . . . . . . . . . . . . . . . . . . . . . 57
Corn poppy red n. 66 . . . . . . . . . . . . . . . . . . . . . do.
Color grains, how to make . . . . . . . . . . . . . . . . . . do.
Fountains made with the grains . . . . . . . . . . . . . . . 60
Match pipes, taking up less space than those ordinarily used. 61
Method of making paper incombustible. . . . . . . . . . . . do.
Little suns, or dahlia pinwheels. . . . . . . . . . . . . . . . 62
Composition for the turning tubes of little suns. . . . . . . . 63
Color tubes, method for gluing them and charging them . . . 64
Dahlia pinwheels with rings of color grains . . . . . . . 72
Method of rain proofing fireworks. . . . . . . . . . . . . . . 74
Stars without being dampened . . . . . . . . . . . . . . . . 76
Method of pulverizing substances quickly. . . . . . . . . . . 78
Some new ways of using colored fires. . . . . . . . . . . . . 80
Decorations made with flames . . . . . . . . . . . . . . . . 83
THE END