Narayana IIT Academy: India

GTM-7
Narayana IIT Academy

INDIA
Sec: Sr. IIT_IZ Date: 26-03-18
Time: 07:00 AM to 10:00 AM Max.Marks:360
Name of the Student: ______________ I.D.NO:

IMPORTANT INSTRUCTIONS: correct response of each question. (1/4)
1) Immediately fill in the particulars on this
(one fourth) marks will be deducted for
page of the Test Booklet with Blue/Black
indicating incorrect response of each
Ball Point Pen. Use of pencil is strictly
question. No deduction from the total
prohibited.
score will be made if no response is
2) The test is of 3 hours duration.
indicated for an item in the answer sheet.
3) The Test Booklet consists of 90
6) There is only one correct response for
questions. The maximum marks are 360. each question. Filling up more than one
4) There are three parts in the question response in any question will be treated as
paper A, B, C consisting of wrong response and marks for wrong
response will be deducted accordingly as
Mathematics, Physics and Chemistry
per instruction 5 above.
having 30 questions in each part of equal SYLLABUS
weightage. Each question is allotted 4 MATHS
TOTAL SYLLABUS + EXTRA SYLLABUS
(four) marks for correct response.
PHYSICS
5) Candidates will be awarded marks as
stated above in instruction No. 4 for
CHEMISTRY
Narayana IIT Academy 26-03-18_Sr.IIT_IZ_Ph-II_Jee-Main_GTM-7_Q.P
MATHS 4. The coefficient of a8b 4c 9 d 9 in
1. The range of the function 10
 abc  abd  acd  bcd  is
 1  1
f  x   sin 1  x 2    cos 1  x 2   1)1520 2)2050
 2  2
(where . denotes the greatest integer 3)3120 4)2520
function) is 5. Consider the sequence
 1,2,2,3,3,3,………where the number n
1)   2)  
2 occurs ‘n’ times .The number that occurs
1 
3)  , 0  4)  0,  as 2018th term in this sequence is
 2   2
2. The equation of the line of shortest 1)63 2)62
distance between the parabola y 2  4 x 3)64 4)61
and the circle x 2  y 2  4 x  2 y  4  0 is 1
1  1 
6.  tan  2  dx is
0  x  x 1 
1) x  y  3 2) x  y  3
 
3) 2 x  y  5 4) 2 x  y  5 1)  ln 2 2)  ln 2
2 2
3. Consider all functions that can be 3) ln 2 4)  ln 2
defined from the set A  1, 2,3 to the 7. The equation of the curve satisfying the
set B  1, 2,3, 4,5 . differential equation
A function f ( x ) is selected at random. y  x  y 3  dx  x  y 3  x  dy and passing
From these functions the probability through the point 1,1 is

that selected function satisfies 1) y 3  2 x  3 x 2 y  2
f (i )  f  j  for i  j is equal to
2) y 3  2 x  3 x 2 y  6
6 7
1) 2) 3) y 3  2 x  3 x 2 y  0
25 25
2 12 4) y 3  2 x 2  3 x  0
3) 4)
5 25
Sec: Sr.IIT_IZ Space for rough work Page: 2

 u v w dp
given by  100  12 x .If the firm
8. Let A   p q r  and B  A2 .If dx
 1 1 1  employs 25 more workers then the new
2
u  v    p  q 
2
 9; level of production of items is
2 2 1)2500 2)3500
v  w   q  r   16 ;
3)3000 4)4000
2 2
w  u   r  p  25 .Then the value of
x2
12. Tangent is drawn to ellipse  y 2  1 at
det B equals 27
   
1)36 2)100 3 3 cos  , sin   where    0,   .Then
  2 
3)144 4)169 the value of  such that the sum of
u v 2u intercepts on the axes made by the tangent
9. In ABC if AB   and AC  is minimum is
u v u
 
1) 2)
where u  v then 3 6
 
3) 4)
1) 1   cos 2 A  0 2)  cos 2 A  0 8 4
13.  p  q    q   p  is
3) 2   cos 2 A  0 4) 1  cos 2 A  0
1) equivalent to p  q
10. The distance of the point 1, 2,3 from
2) tautology
the plane x  y  z  5 measured parallel
3) Fallacy
x y z
to line   is 4) Neither tautology nor fallacy
2 3 6
1)7 unit 2)4 unit 14. The number of numbers between 1 and
1010 .which contains digit 1 is
3)1 unit 4)2 unit
11. At present, a firm is manufacturing 1) 1010  910 2) 1010  910  1
10
3) 109 4)  10 Cr 9 r
2000 items. It is estimates that the rate r 0
of change of production P with respect 15. The value of ‘p’ so that both the roots of
to additional number of workers ‘x’ is the equation  p  5  x2  2 px   p  4   0 are

positive, one is less than 2 and other is 19. Let I be the set of positive integers. R is a
lying between 2&3 lies in the interval. relation on the set I given by
49  a 
1)  
, 24  2)  5,   R   a, b   I  I / log 2   is a non negative int eger  ,
b
 4   
49  Then R is
3)  , 4 U  , 4)none of these.
 4  1)neither symmetric nor transitive but
16. If f  x  satisfies reflexive
f  7  x   f  7  x  x  R such that f  x  2)reflexive, transitive but not symmetric
has exactly 5 real roots which are all 3)neither reflexive nor transitive but
distinct such that sum of the real roots symmetric
is S then S/7 is equal to 4) equivalence relation.
1)1 2)3 20. If L1 and L2 are two lines of the family of
3)5 4)7 lines  3  2  x   4  3  y  7  5 such that

17. If Z is a complex number satisfying they are at maximum and minimum
2
z  z  2  0 , Then the value of distances from  2,3 then the equation of
z 2  z sin  for all values of  is the line through the point (1,2) and
1)equal to 4 2)equal to 6 making equal angles with L1and L2 is
3)more than 6 4)less than 6 1) x  3 y  5  0 2) 3x  y  5  0

  n   3) x  2 y  5  0 4) 2 x  y  0
  2   k  1
1   k 1   is equal
18. The sum  cot 21. The number of solutions of
n 1  3 
  sin x  cos x  1 in   x  4 where .
 
to denotes greatest integer function
3 
1)  cot 1 2 2)  cot 1 3
4 2 1)3 2)4

3)  4)  tan 1 2 3)5 4)2
2
22. A function f from the set of integers to such that 2OP.OQ  OR.OP  OR.OQ .Locus
R defined as follows
of R is
 n  3 if n is odd

f  x   n 1) 9 x  6 y  20 2) 6 x  9 y  20
 2 if n is even
3) 6 x  9 y  20 4)None
Suppose k is odd and f  f  f  k     27 .
5 5
2
26. If   xi  10   5 and   x  10   25 then
Then the sum of the digits of k is i 1 i 1
i
1)3 2)6 the standard deviation of observations

3)9 4)12 2 x1  7, 2 x2  7, 2 x3  7, 2 x4  7, 2 x5  7 is equal
23. If an and bn are positive integers and to
a 
n
 
an  bn 2  2  2 , Then lim  n  
n  b
 n
1)8 2)16
1) e 2
2)2 3)4 4)2
3) e 2
4) 2 27. Given
24. A ray of light moving parallel to the

 
 ln 1  sgn  x    x2 
; If x  0
f  x   1  cos  x then
axis of parabolic mirror

2  k ; If x  0
 y  2  4  x  1 incident at point P
(Where . , 
. and sgn x denotes greatest
then gets reflected and reflected ray
always passes through the point Q  h, k  integer function, fractional part function
and signum function respectively)
then h 2  k 2 
1) f  x  is continuous at x=0 if k=2
1)0 2)2
3)4 4)1 2)for k=1, f  x  has removable
25. A variable line L is drawn through discontinuity at x=0

O(0,0)to meet lines L1 : 2 x  3 y  5 and 3)for k=2, f  x  has non removable
L2 : 2 x  3 y  10 at point P and Q discontinuity at x=0
respectively. A point R is taken on L 4) lim f  x  exists

x0

28. A bag contains 5 distinct Red, 4 PHYSICS
distinct Green and 3 distinct Black 31. If L, R, C and V respectively represents
balls .Balls are drawn one by one inductance, resistance, capacitance and
without replacement then the potential difference, then the dimensions
probability of getting a particular red L

of are the same as those of
RCV
ball in fourth draw is
1
1 223 1) current 2)
1) 2) current
12 1188
335 5 1
3) 4) 3) charge 4)
1320 12 ch arg e
29. A vertical pole of height h stands on a 32. A particle is moving with velocity
building of height H and the angle of
 
v  K yiˆ  xjˆ , where K is a constant. The
elevation of top of the building from a
general equation for its path is
point on the ground which is 5 unit
1) y  x 2 +constant
away from the foot of building is  ,
2) y 2  x +constant
also the pole subtends an angle  at
3) xy  constant
the same point on the ground. If
4) y 2  x 2  constant
2 tan  cot   1 .Then
33. A block of mass 2kg is free to move along
1) H 3  hH 2  25 H  50h  0
2) H 3  hH 2  25H  50h  0 the x-axis, It is at rest and from t  0
3) H 3  hH 2  50 H  25h  0
onwards it is subjected to a time-
4) H 3  hH 2  25 H  50h  0
30. If A and B are two invertible square dependent force F(t) in the x direction.
matrices of the same order such that The force F(t) varies with t as shown in
 A  B  A  B   A2  B 2 then
3
the following figure. The kinetic energy
 A2 BA1 B 1  is equal to of the block after 4.5 seconds is
1) B 2 2) A2
3) A3 4) A3 B 3
F(t)
4 5
1) T 2) T
4N 5 6
4.5s
O
3s t 5 6
3) T 4) T
4 5
1)4.50 J 2)7.50 J 36. Ina series LCR circuit R  200 and the
3)5.06 J 4)14.06 J voltage and the frequency of the main
34. The potential energy function for the supply is 220 V and 50 Hz respectively.
force between two atoms in a diatomic On taking out the capacitance from the
molecule is approximately given by circuit, the current lags behind the voltage
a b
U  x  12
 6 , where a and b are by 300 . On taking out the inductor from
x x
the circuit the current leads the voltage by
constants and x is the distance between
300 .The power dissipated in the LCR
the atoms. If the dissociation energy of
circuit is
the molecule is D
1)242 W 2)305W
U  x     U at equilibrium  , D is
3)210W 4) Zero W
b2 b2
1) 2) 37. In an optics experiment, with the position
6a 2a
b2 b2
of the object fixed, a student varies the
3) 4)
12a 4a position of a convex lens and for each
35. A simple pendulum attached to the position, the screen is adjusted to get a
ceiling of a stationary lift has a time clear image of the object. A graph
period T. The distance y covered by between the object distance u and the
lift moving upwards varies with time t image distance v, from the lens, is plotted
as y  t 2 where y is in meter and t in using the same scale for the two axes. A
second. If g  10ms 1 , the time period of straight line passing through the origin
the pendulum will be and making an angle of 450 with the x-axis

meets the experimental curve at P. The out the correct output waveform from the
coordinates of P will be: next figure.
1)  f , f  2)  4 f , 4 f  A
y
f f B
3)  2 f , 2 f  4)  , 
2 2 Input A
38. Suppose an electron is attached

k
towards the origin by a force where Input B
r
‘k’ is a constant and ‘r’ is the distance Output is:
of the electron from the origin. By
applying Bohr model to this system,
(1)
the radius of the nth orbital of the
electron is found to be’ rn ’ and the (2)
kinetic energy of the electron to be

‘ Tn ’. Then which of the following is (3)
true?
1
1) Tn ; rn n 2 (4)
n
1
2) Tn ; rn n 2
n2
3) Tn independent of n, rn n 40. One mole of an ideal gas in initial state A
1 undergoes a cyclic process ABCA, as
4) Tn ; rn n
n
shown in the figure. Its pressure at A is P0
39. The logic circuit shown in the
following figure has the input
waveforms ’A ‘and ‘B’ as shown. Pick
v
42. To determine the half of radioactive
4Vo B element, a student plots a graph of
dN  t  dN  t 
ln versus t. Hence is the rate
dt dt
Vo A
C
O T of radioactive decay at time t. If the

T0
1)Internal energy at B is greater than number of radioactive nuclei of this

that at A. element decreases by a factor of P after
2)work done by the gas in process 4.16 years, find the value of P.
6
A  B is PV
0 o
5
P
3)pressure at C is 0 dN  t 
4
4 ln
dt 3
T0
4)Temperature at C is 2
2 1
2 3 4 5 6 7 8
41. At time t  0 a battery of 10 V is years
connected across points A and B in the 1)2 2)4

given circuit. If the capacitors have no 3)8 4)16
charge initially, the time t (in seconds) 43. A glass plate of reflective index 3  1.5 is
when the voltage across the capacitors coated with a thin layer of thickness t and
become 4V is refractive index  2  1.8 .Light of
2 F
2M 
wavelength  travelling in air is incident
A B
normally on the layer. It is partly reflected
2M  2 F at the upper and the lower surfaces of the
5 5
1) 3ln   2) 4 ln   layer and the two reflected rays interfere.
2 3
4 If   648nm , the least value of t for which
3) 5 ln   4) 10 ln  4 
3 the waves interfere constructively is
1)90 nm 2)180 nm 46. A beam of light consisting of two
0 0
3)108 nm 4)216 nm wavelengths 4500 A and 7500 A is used to
44. Two ideal junction diodes D1 and D2 obtain interference fringes in Young’s
double slit experiment. The distance
are connected to a battery as shown in between the slits is 1 mm and the distance
the Figure. The current supplied by the between the plane of the slits and the
battery is screen is 120 cm. what is the minimum
distance between two successive regions
D1 10
of complete darkness on the screen?
D2 20 1)4.5 mm 2)5.4 mm
(+) (-) 3)2.7 mm 4)1.2 mm
5V
47. A vernier calipers has 1 mm marks on the
1)0.25 A 2)0.5A
main scale. It has 20 equal divisions on
3)0.75 A 4) zero
the vernier scale which match with 16
45. A parallel sides slab ABCD of
main scale divisions. For this vernier
refractive index 2 is sand witch
calcipers, the least count is
between two slabs of refractive indices
1)0.02 mm 2)0.05 mm
2 and 3 as shown in the figure. The
3)0.1 mm 4)0.2 mm
minimum value of angle  such that
48. A parachutist after bailing out falls 50 m
the ray PQ suffers total internal
without friction. When he opens the
reflection at both the surfaces AB and
parachute, he decelerates at 2ms 2 .He
CD is
reaches the ground with a speed of 3 ms 1 .
O 2  2
A B
At what height did he bail out?

P 1  2 1)91 m 2)182 m
D C
3  3 3)293 m 4)111 m
1) 300 2) 450
3) 600 4) 750
49. Photoelectric effect experiments are P l
performed using three different metal
plates p,q and r having work functions
v
P  2.0eV , q  2.5eV and r  3.0eV , R R R
respectively. A light beam containing i l

wavelengths of 550 nm, 450 nm and Q i2
i1
350 nm with equal intensities
Blv 2 Blv
illuminates each of the plates. The 1) I1   I 2  ,I 
R R
correct I-V graph for the experiment is Blv 2 Blv
2) I1  I 2  ,I 
I I 3R 3R
p
q Blv
r p 3) I1  I 2  I 
q
r
R
v v
Blv Blv
1) 2) 4) I1  I 2  ,I 
6R 3R
I
r
q I
51. In a common base mode of a transistor,
p
the collector current is 5.488 mA for an
v r
q
p
v emitter current of 5.60 mA. The value of
3) 4)
the base current amplification factor   
50. A rectangular loop has a sliding
connector PQ of length l and will be
resistance R and it is moving with a 1)51 2)48

speed v as shown in the following 3)49 4)50
figure. The set up is placed in a 52. A simple pendulum has a time period of
uniform magnetic field going into the 3.0s.If the point of suspension of the
plane of the paper. The three currents pendulum starts moving vertically upward
I1 , I 2 and I are with a velocity v  Kt where K  4.4ms 2 ,

the new time period will be (Take 55. A circuit is connected as shown in the
g  10ms 1 ) following figure with the switch S open.
9 5 When the switch is closed. The total
1) s 2) s
4 3
amount of charge that flows from Y to X
3)2.5 s 4)4.4 s
is
1
53. A police van, moving at 22 ms , 3 F 6 F
X
chases a motorcyclist. The policeman
S
sounds his horn at 176 Hz. While both
3 6
of them move towards a stationary y
siren of frequency 165 Hz as shown in

9V
the following figure
police van Motorcyclist
1)0 2)54 C
stationary siren
22 ms 1
176Hz
um 3)27 C 4)81 C
166 Hz
56. Three concentric metallic spherical shells
If the motorcyclist does not observe
of radii R, 2R, 3R are given charges
any beats, his speed must be (take the
Q1 , Q2 , Q3 respectively. It is found that the
speed of sound=330 ms 1 )
surface charge densities on the outer
1) 33 ms 1 2) 22 ms 1
surfaces of the shells are equal. Then the
3) zero 4) 11 ms 1
ratio of the charges given to the shells,
54. A nucleus of mass number 220,
Q1 : Q2 : Q3 is
initially at rest, emits an  -particle. If
the Q value of the reaction is 5.5 MeV, 1)1:2:3 2)1:3:5
the energy of the emitted  -particle 3)1:4:9 4)1:8:18
will 57. A thin uniform disc has mass M and
1)4.8 MeV 2)5.4 MeV radius R. A circular hole of radius R/3 is
3)6.0 MeV 4)6.8 MeV made in the disc as shown in the figure.
The moment of inertia of the 59. A thin uniform rod of length l and mass
remaining portion of disc about an axis m is swinging freely about a horizontal
passing through O and perpendicular axis passing through its end. Its maximum
to the plane of the disc is angular speed is  . Its centre of mass
rises to a maximum height of:
R R/3
1 l 2 2 1 l 2 2
1) 2)
2 g 6 g
O O
1 l 2 2 1 l
2R 3) 4)
3 g 6 g
3
60. A block of base 10 cmx10 cm and height
1 2 15 cm is kept on an inclined plane. The
1) MR 2 2) MR 2
9 9
coefficient of friction between them is 3
1 4
3) MR 2 4) MR 2 . The inclination  of this inclined plane
3 9
58. The coordinates of a particle moving from the horizontal plane is gradually
in a plane are given by x  a cos  pt  and increased from 00 .then
y  b sin  pt  ,where a,b and p are 1)at   300 , the block will start sliding
down the plane
positive constants and b<a .Then
2)the block will remain at rest on the
1) the path of the particle is a parabola
plane up to certain  and then it will
2) the velocity and acceleration of the
topple
particle are perpendicular to each other
3)at   600 , the block will start sliding
at t   / 2 p .
down the plane and continue to do so at
3) the acceleration of the particle is
higher angles
always directed towards a focus
4)at   600 ,the block will start sliding
4) the distance travelled by the particle
down the plane and on further increasing
is time interval t  0 to t   / 2 p is a.
 .It will topple at certain  .
CHEMISTRY 64. The “spin-only” magnetic moment [in
61. One of the alloptopic form of boron is units of Bohr magneton   B  ]of Ni 2 in
  rhombohedral boron. Number of
aqueous solution would be
faces and corners in its basic building
(At.no. Ni=28):
B12 icosahedral unit are
1)0 2)1.73
1)20 and 12 respectively 3)2.84 4)4.90
2)12 and 20 respectively
65. Which of the following molecule/species
3)12 and 12 respectively is having minimum number of lone pair
4)20 and 20 respectively. on its central atom?
62. White phosphorus is a tetra atomic 1) BrF3 2) BrF4
solid P4 ( s ) at room temperature. Find
3) XeF5 4) I3
average (P-P) bond enthalpy (in HCl
66. Mg3 B2    X   MgCl2
( aq )
KJ/mol).
(Given= H sublimation of
 X   H 2O  Y   H 2 regarding [X] & [Y]
P4  s   59 KJ / mol the incorrect choice is:
1)  X  is B2 H 6 & Y  is H 3 BO3
H atomization P4  s   1265 KJ / mol )
2)  X  is BCl3 Y  is H 3 BO3
1)201 2)1206
3)301.5 4)1210.83 3)  X  with on burning in air and [Y] on
63. In the following sequence of reactions. strong heating (red heat)give same
Identify (E): compound
 , ZnCl2
Na2CO3  H2O  CO2   A  
 B    C    D  4) In Y  .Boron completes its octet by
NaOH
(E) interacting with water which results in
1) NaHCO3 2) Na2O2 release of H+ ion from water
3) Na2 ZnO2 4) ZnCO3

67. The magnetic moment of a certain gm / cm3 and 100 2 pm ,the atomic mass of
complex (A) of Co was found to be the element is  N A  6  10 23 
4.89 B.M and the EAN as 36.Co also
1)48 2)72
forms complex (B) with magnetic 3)96 4)32
moment 3.87 B.M and EAN 37, and 69. In 20 ml 0.4 M.HA solution 80 ml water
complex (C) with EAN as 36 but is added. Assuming volume to be
diamagnetic. Which of the following additive, the PH of final solution is
statements is true regarding the above K a of HA  4  10 7 , log 2  0.3 
observation? 1)4.30 2)3.75

1) The oxidation states of Co in 3)3.40 4)3.70
70. For a first order reaction, the rate constant
(A),(B)and (C) are +3.+2 and +3
is 0.04 min 1 at 270 C and 0.08 min 1 at 37 0 C .
respectively.
The activation energy of reaction is
2) Complexes (A) and (B) have sp 3 d 2
 ln 2  0.7 
hybridization state while (C) has dsp 3
1)13.02 kcal/mol 2)139.86 kcal/mol
hybridization state.
3)54.12 kcal/mol 4)13020 kcal/mol
3) The spin multiples of Co in
71. 20 gm iron pyrite, FeS 2 , is roasted
(A),(B)and (C) are 4,3 and 1
respectively completely and SO2 gas produced is
4) The oxidation states of Co in absorbed completely in 400 ml NaOH

(A),(B) and (C) are +6,+8, and +1 solution. If only 50% NaOH is used in the
respectively. reaction. The molarity of NaOH solution
68. A solid element,(metal) crystallizes in is
ABABAB…..type packing in three 5 10
1) M 2) M
3 3
dimension. If the density of the 5 20
3) M 4) M
element and its atomic radius are 5.0 6 3
o
72. E for the cell:
cell 74.
 B  concH SO
Pt  s  H 21atm   g  HCOOH 310 2 M  aq  CH 3COOH 410 2 M  aq   A  2 4
C 
H 2 1atm   g  Pt  s  Red gas
Orange colour
compound
at 250 C is NaOH+AgNO3
4 5
 K a of HCOOH  2.4 10 , K a of CH 3COOH  1.8 10 , 
  (D)
 log 2  0.3, 2.303  298  R  0.06 
 F 
yellow NH3
Red ppt.
solution
1)-0.06V 2)-0.03V solution
NaOH
3)0.06V 4) 0.03V (B) 
F 
(Gives white fumes
73. The standard enthalpies of formation with HCl)
of 1,3-butadiene(g), CO2  g  and Identify (D),and (F) respectively:
H 2 O  g  at 298K are -30,-94 and -68 1) AgCl , Cl2
kcal/mol, respectively, the enthalpy of 2) Ag 2 CrO4 , NH 3

combustion of 1,3-butadiene(g) at 298 3) Hg 2 Cl2 , NH 3
K is: (neglect resonance energy 4) CHCl2 , NH 3
concept)
75. E o for the conversion of Ce 4 into Ce 3 is
1) -550kcal/mol 1.74 V. It suggest that:
2)+650Kcal/mol 1) Ce 4 is more stable as compared to Ce 3

2) Ce 4 Will tend to change into Ce 3
3)-680kcal/mol
although Ce 4 has inert gas configuration
4)-620 kcal/mol
3) Ce 4 compounds are neither good
oxidizing nor good reducing agents
4) Ce 3 will tend to change into Ce 4
because Ce 4 has inert gas configuration

76. Which set of quantum numbers is not 80. The gradual decrease in atomic radius for
possible for the last electron of Lanthanoids elements is not obeyed by.
‘Al’(Z=13): 1)Eu 2)Lu
n l m s 3)Gd 4)none
1)3 1 -1 -1/2 81. Which of the following complex is inner
2)3 0 0 +1/2 orbital as well as low spin complex?
3)3 1 0 +1/2 3
1) Cr  H 2O 6 
4)3 1 1 -1/2 3
O 2)  Fe  CN 6 
3
CH3-C-CH2-OH 3)  Cu  CN  4 
77. Compound reduces:
2
1) Tollen’s reagent 4)  Mn  NH 3 6 
2) NaOH / I 2 solution 82. An aqueous solution containing
3)Fehling solution Hg 2 , Hg 22  , Pb 2  ,and Cd 2 ions will give
4)All of these. precipitates of …..With HCl

78. Which of the following orders is true 1) Hg 2Cl2 only
for acidic strength (Ka values) 2) PbCl2 only
1)phenol>O-cresol>O-nitrophenol 3) Hg 2Cl2 and PbCl2
4) HgCl2 and PbCl2
2) O-cresol< phenol< O-nitrophenol
3)O-cresol<O-nitrophenol<phenol
4)phenol<O-cresol<O-nitrophenol 
    P 
i Glycol / HA
79. The overall charge present on the 83. ii2 CH 3 Mgl

iiiH 2O / H 
cyclic silicate anion  Si6O18 n  is
1)6 2)12
3)18 4)24
1)
O O
2+
2)
4) Ph Ph
85. The order of reactivates among the
3) following halides for and SN1is

Cl Cl
Cl
4)
Etooc OH
I   II   III 
NaOMe
84. Ph Ph MeOH Product (major) 1)III < II < I 2) I < II < III
O 3)III < I < II 4) I < III < II
-
O
O
C
NaOH,H2O
Product
H3C
Ph Ph
1) 86. H Br
O
The main product is
-
O
O
2) Ph Ph C
HO OH
H3C
H OH
1)
-
O
O
3) Ph Ph C
H
CH3
2)HO
3) CH3CH(Br)COOH 89.
H Cl2  g   Ba  OH 2  X  aq   BaCl2  H 2O
O
C X  H 2 SO4  Y  BaSO4
H3C Heated
Y   Z  H 2O  O2
to dryness
H Br
4)
Y, Z respectively, and magnetic behavior
87. A negatively charged sol can be
exhibited by ‘Z ‘are
formed by peptizing a solution of
1) HClO4 , ClO2 , diamagnetic
1) AgI with AgNO3
2) HClO3 , ClO2 , paramagnetic
2) AgI with KI
3) Fe(OH)3 with FeCl3 3) HClO3 , Cl 2O , diamagnetic
4) Any of these 4) HClO4 , Cl2O7 , paramagnetic

88. Compound PdCl4 .6 H 2O is a hydrated 90. If volume occupied by CO2 molecules is
complex; 1 molal aqueous solution of negligible, then the pressure exerted by
it has freezing point 269.43K one mole of CO2 gas in terms of
Assuming 100% ionization of temperature (T), assuming V to be single
complex, calculate the molecular valued, is
formula of the complex, RT RT
1) P  2) P 
Kf for H 2O  1.86 K Kg mol1  4a 4 a  b
R 2T 2 R 2T 2
1)  Pd  H2 O 6 Cl4 3) P  4)
4a 4 ab
2)  Pd  H2O 4 Cl2 Cl2 .2H2O
3)  Pd  H2O 3 Cl3 Cl.3H2O
4)  Pd  H2O 2 Cl4  4H2O

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Name of the Student: ______________ I.D.NO:

From these functions the probability through the point 1,1 is

Sec: Sr.IIT_IZ Space for rough work Page: 2

to additional number of workers ‘x’ is the equation  p  5  x2  2 px   p  4   0 are

Sec: Sr.IIT_IZ Space for rough work Page: 3

distinct such that sum of the real roots symmetric

is S then S/7 is equal to 4) equivalence relation.

1)1 2)3 20. If L1 and L2 are two lines of the family of

3)5 4)7 lines  3  2  x   4  3  y  7  5 such that

1)equal to 4 2)equal to 6 making equal angles with L1and L2 is

3)more than 6 4)less than 6 1) x  3 y  5  0 2) 3x  y  5  0

1)3 2)6 the standard deviation of observations

24. A ray of light moving parallel to the

25. A variable line L is drawn through discontinuity at x=0

L2 : 2 x  3 y  10 at point P and Q discontinuity at x=0

respectively. A point R is taken on L 4) lim f  x  exists

Sec: Sr.IIT_IZ Space for rough work Page: 5

probability of getting a particular red L

Sec: Sr.IIT_IZ Space for rough work Page: 7

38. Suppose an electron is attached

kinetic energy of the electron to be

O T of radioactive decay at time t. If the

1)Internal energy at B is greater than number of radioactive nuclei of this

41. At time t  0 a battery of 10 V is years

connected across points A and B in the 1)2 2)4

respectively. A light beam containing i l

resistance R and it is moving with a 1)51 2)48

I1 , I 2 and I are with a velocity v  Kt where K  4.4ms 2 ,

Sec: Sr.IIT_IZ Space for rough work Page: 11

siren of frequency 165 Hz as shown in

the energy of the emitted  -particle 3)1:4:9 4)1:8:18

will 57. A thin uniform disc has mass M and

1)4.8 MeV 2)5.4 MeV radius R. A circular hole of radius R/3 is

Sec: Sr.IIT_IZ Space for rough work Page: 14

observation? 1)4.30 2)3.75

4) The oxidation states of Co in absorbed completely in 400 ml NaOH

kcal/mol, respectively, the enthalpy of 2) Ag 2 CrO4 , NH 3

2)+650Kcal/mol 1) Ce 4 is more stable as compared to Ce 3

Sec: Sr.IIT_IZ Space for rough work Page: 16

3)Fehling solution Hg 2 , Hg 22  , Pb 2  ,and Cd 2 ions will give

4)All of these. precipitates of …..With HCl

79. The overall charge present on the 83. ii2 CH 3 Mgl

85. The order of reactivates among the

3) following halides for and SN1is

4) Any of these 4) HClO4 , Cl2O7 , paramagnetic

Sec: Sr.IIT_IZ Space for rough work Page: 19

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