09 02 17 SR - Iit Iz Co Spark Jee Main GTM 3 Q'P

Date: 09-02-17
Time: 09:00 AM to 12:00 Noon Max.Marks:360
Name of the Student: ______________ I.D.NO:

IMPORTANT INSTRUCTIONS: for indicating incorrect response of each question. No
1) Immediately fill in the particulars on this page of the deduction from the total score will be made if no
Test Booklet with Blue/Black Ball Point Pen. Use of response is indicated for an item in the answer sheet.
pencil is strictly prohibited. 6) There is only one correct response for each question.
2) The test is of 3 hours duration. Filling up more than one response in any question
3) The Test Booklet consists of 90 questions. The will be treated as wrong response and marks for
maximum marks are 360. wrong response will be deducted accordingly as per
4) There are three parts in the question paper A, B, C instruction 5 above.
consisting of Mathematics, Physics and Chemistry SYLLABUS
having 30 questions in each part of equal weightage.
MATHS
Each question is allotted 4 (four) marks for correct
TOTAL SYLLABUS + EXTRA SYLLABUS
response.
5) Candidates will be awarded marks as stated above in
instruction No. 4 for correct response of each PHYSICS
question. (1/4) (one fourth) marks will be deducted TOTAL SYLLABUS + EXTRA SYLLABUS
CHEMISTRY
TOTAL SYLLABUS + EXTRA SYLLABUS

09-02-17_Sr.IIT-IZ-CO-SPARK_Jee-Main_GTM-3_Q'P
MATHS 5. A line is drawn from the point P(1, 1, 1)
  
1. If  3  z1  2  z2   k , then points A( z1 ) , and perpendicular to a line with direction
 2  z1  3  z2 
ratios (1,1,1) to intersect the plane
B( z2 ) , C (3, 0) and D (2, 0) (taken in
x  2 y  3z  4 at Q. The locus of point Q
clockwise sense) will
is
1) lie on a circle only for k  0
x y 5 z  2 x y 5 z  2
1)   2)  
2) lie on a circle only for k  0 1 2 1 2 1 1
3) lie on a circle  k  R 3) x  y  z 4)
x y z
 
2 3 5
4) be vertices of a square  k  (0,1)
6. In the triangle ABC the medians from B
(1  tan x )(1  tan 2 x)
2.  2 tan x
dx equal to and C are perpendicular. The value of
1 cot B  cot C cannot be

1) log | tan x | + tan x + c
2 1 2
1) 2)
1 3 3
2) log tan 2 x  c
2 tan x 4 5
3) 4)
3 3
3) log | tan x | 2 tan x  c
2 4 8
7. If x  sin  sin  sin and
4) None of these 7 7 7
3. If y, z  0 and y  z  C , then minimum 2 4 8
y  cos  cos  cos , then x2  y 2 is
7 7 7
 1  1
value of 1  1   is equal to 1) 1 2) 2
y z  
3) 3 4) 4
C 2
1)  1 2)  3
2 C 8. The quadrilateral formed by the lines
2 C y  ax  c, y  ax  d, y  bx  c and y  bx  d
3) 1 4)
C 2
has area 18. The quadrilateral formed by
the lines y  ax  c, y  ax  d, y  bx  c and
4. Let e be the eccentricity of a
y  bx  d has area 72. If a, b, c, d are
hyperbola and f (e) be the eccentricity
positive integers then the least possible
of its conjugate hyperbola then
3
value of the sum a  b  c  d is
 fff .......... f (e)
1
de is equal to 1) 13 2) 14
n times
3) 15 4) 16
1) 2 2 if n is odd 2) 4 if n is odd
3) 2 2 if n is even 4) 3 if n is even
Sr.IIT-IZ-CO-SPARK space for rough work Page 2
9. Let f (x)  x 2  6x  1 and let R denote 3) 2 4) 1
the set of points (x, y) in the XY-plane 13. The value of
2000C2  2000C5  2000C8  ......  2000C2000  ?
such that f (x)  f (y)  0 and
21999  1 21999  1
1) 2)
f (x)  f (y)  0 . Then the area of the 3 3
2 1
2000
2 1
2000
region R is 3) 4)
3 3
1) 6 2) 3  2 14. The solution curves of the differential
3) 2  8 4) 8 equation
10. A continuous function y  f (x) is  xdx  ydy  x 2  y 2   xdy  ydx   1  x 2  y2 

defined in a closed interval [7,5] . are
A(7, 4) , B(2, 6) , C(0, 0) , D(1, 6) , 1) circles of radius 1, passing through the
E(5, 6) are consecutive points on the origin
2) circles of radius 1 2 ,passing through
graph of f and AB, BC, CD, DE are
the origin
line segments. The number of real
3) circles not passing through origin
roots of the equation f f (x)  6 is 4) solution curve is not a circle
n
6k
1) 6 2) 4 15. The value of lim
n 
 k 1  3  2  3
k k k 1
 2k 1 
is
3) 2 4) 0
equal to
11. If Z is a complex number then the 1) 1 2) 2
number of complex numbers satisfying 3) 3 4) 4
16. Let S  a  N,a  100 . If the equation
the equation Z2017 = Z is
1) 3 2) 2017  tan 2 x   tan x  a  0 has real roots then
3) 2018 4) 2019 number of elements in S is, [where [.]

12. The curves greatest integer function]
C1 : y  x 2  3 ; C2 : y  kx 2 , k  1 intersect 1) 10 2) 8
each other at two different points. The 3) 9 4) 0
tangent drawn to C2 , at one of the 17. Number of solutions of the equation
4sin 2 x  tan 2 x  cot 2 x  cosec2 x  6 in 0, 
points of intersection A   a, y1  a  0
is
meets C1 again at B 1, y2  .  y1  y2  . 1) 0 2) 2
3) 8 4) 4
Then value of a  ___?
1) 4 2) 3
  2i  3 j
18. A variable line through A(6,8) meets 1
1) 2i  6 j  k 2)
the curve x 2  y2  2 at B and C. P is a 41 13
3 jk 4i  3 j  3k
point on BC such that AB, AP, AC are 3) 4)
10 14
in HP. The minimum distance of the 23. The maximum number of ways in which
origin from the locus of P is the vertices of a pyramid with square
1) 1 2) 1 2 base be assigned a number each from the
3) 1 3 4) 1 5 set 1,2,3,4,5 such that adjacent vertices
  3 
1
 sin have different numbers, is

1
19.  x  4  dx (where [x] represents
1 
1) 300 2) 420
the greatest integer less than or equal
3) 600 4) 210
to x) is equal to
24. In an arithmetic progression an , a1  0
 
1) 2)
4 2 and 3 a 8  5 a13. Let Sn be the sum to first

3) – 4)0 ' n ' terms. The value of ' n ' for which S n
4
20. The largest area of the rectangle
is maximum is
having one side on the x-axis and two
1) 10 2) 11
 x2
vertices on the curve y = e is 3) 20 4) 21
25. Let ' M ' be a 3 3 matrix such that
2 2
1) 2)
e e 2
0 1 2 M  1 0 0 and [3 4 5]
1 1
3)
2e
4)
2 e M = [0 1 0] then 6 7 8 M is equal to
21. Period of f(x) = sgn([x] + [x]) is 1) 2 1 2 2) 0 0 1
equal to (Where [.] denotes greatest 3)  1 2 0 4) 9 10 8
integer function) 26. A bag contains 3 black and 7 white balls.
1) 1 2) 2 Three balls are drawn one after other
3) 3 4) does not exist replacing the ball drawn each time along
22. The unit vector which is orthogonal to with two more balls of the same colour.
the vector a  3i  2 j  6 k and is If the third drawn ball is black, then the
coplanar with the vectors b  2 i  j  k first drawn is also black with probability
7 5
and c  i  j  k , is 1) 2)
12 12
1 3
3) 4)
4 4

27. The number of real roots of the 4) neither (i) nor (ii)

equation sin 1  6 x   sin 1  6 3 x   PHYSICS
2
31. A uniform rod AB of length 1 m is
   
where for any y   1,1 ,sin 1 y   ,
 2 2 
placed at edge of a smooth table as
shown in figure. It is hit horizontally at
is
point B from left. If the magnitude of the
1) 1 2) 2
displacement of the centre of mass in 1 s
3) 4 4) Infinity
is 5 2 m, the angular speed of rod is
28. An ellipse has the points 1,  1 and
B
 2,  1 as its foci and x  y 5  0 as one
of its tangent. The point of contact of
the tangent is Table
A
3   34 11 
1)  ,  1 2)  , 
2   9 9 
 34 11  1) 30 rad/s 2) 20 rad/s
3)  ,  4)  6,  1
 9 9 3)10 rad/s 4) 5 rad/s
29. The mean of n items is X .If first item 32. A body is fired from point P and strikes
is increased by 1, second item by 2,
third item by 3 and so on , then new at Q inside a smooth circular wall as
mean is shown in the figure. It rebounds to point
n 1 n
1) X  2) X  S (diametrically opposite to P). The
2 2
n 1 coefficient of restitution will be
3) X  n 4) X 
2 Q
30. If p, q are two propositions, then
which of the following statements is / 
P S
are true?
i) p « q is logically equivalent to
1) cot  2) 1
~ p« ~ q 3) tan  4) tan2
ii) Negation of p « q is logically 33. A cart with a mass M = 1
kg is
2
equivalent to ~ p « ~ q
connected by a string to a mass of
1) only (i) m = 200 g. At the initial moment the cart
2) only (ii) moves to the left along a horizontal plane
3) both (i),(ii)

at a speed v0 = 7 m/s. (g = 9.8 m/s2)  C1C2 
4)   |VA – VB| on each capacitor
 C1  C2 
Distance covered by cart after 5 sec is
v0 36. Two identical glass spheres filled with
M
air are connected by a horizontal glass
m
tube. The glass tube contains a pellet of
mercury at its mid point. Air in one
1)3.75 2)17.5 sphere is at 0C and the other is at 20C.
3) 20 4) zero If both the vessels are heated through
34. Two spheres each of mass 83 kg and 10C then neglecting the expansions of
radius 5 cm lie in contact in a the bulbs and the tube. Ignore the
hemispherical bowl of radius 40 cm. conduction of heat by the mercury pellet.
There is no friction between any of the 1) The mercury pellet gets displaced
contact surfaces. The contact force towards the sphere at lower temperature.
exerted by one sphere to another 2) The mercury pellet gets displaced
is…………….. (take g = 10 m/s2) towards the sphere at higher temperature.
1) 10 N 2) 20 N 3) The mercury pellet does not get
3) 30 N 4) none displaced at all.
35. For given circuit charges on capacitor 4) The temperature rise causes the pellet
C1 and C2 in steady state will be equal to expand without any displacement.
to 37. Four springs, of spring constant
VA VB
K = 100 N/m each are arranged to a pair
C1 C2
of masses 5 kg each as shown. What is
the frequency of the oscillation of the
VC
setup? [in Hz]
1) C1|VA – VC|, C2|VC – VB|
k
respectively
k k
5 kg
5 kg
2) C1|VA – VB|, C2|VA – VB| k

respectively
3) (C1 + C2) |VA – VB| on each 1) 0.16 sec1 2) 0.32 sec1
capacitor 3) 0.64 sec1 4) 1.28 sec1

38. Four resistors are connected in a 40. The figure shows to parallel metallic
square formation. Two batteries of plates having a large cross-sectional area,
emf, E and 2E are connected along the placed very close to each other so as to
diagonals as shown in the figure. The form the two plates of a parallel plate
current flowing in the resistor (R1) is capacitor. The two plates are charged to a
(R1 = R) potential difference V, so that they attract
R R one another. The separation between the
E plates is h while their capacitance is C.
R1 R
The plates are attached to two non-
conducting ropes as shown in the figure.
2E (the system is released from rest)
1) 4E 2) E cv
3R R
h
3) 3E 4) 3E
2R R
39. A current carrying loop lies in the x-y

m
plane. The magnetic field in the region
is given by B  B0kˆ  ˆj . Then choose 1) moves up 2) moves down
incorrect statement. 3) remains at rest 4) executes SHM.

y 41. Assuming all the surfaces to be
frictionless, acceleration of the block B
O shown in the figure is
 x
2
z 3 m/s
1) net force acting on the loop is zero A
for all real . 2

4 m/s
2) initial angular acceleration is C
minimum then  = 0
3) for  = 0, the loop can’t rotate a B
4) for  = 0, the loop rotate. 1)5 m/s2 2)7 m/s2

3)3.5 m/s2 4)4 m/s2
42. An elevator is going up vertically with
a constant acceleration of 2 m/s2. At
the instant when its velocity is 4 m/s a
ball is projected from the floor of the
elevator with a speed of 4 m/s relative
to the floor with an angular elevation
of 60. The time taken by the ball to
return the floor is (g = 10 m/s2).
1
1) 1 sec 2) sec
3 3
2
3) sec 4) 3 sec
3

43. In the LCR circuit, the voltmeter and by sphere to reach the bottom is t1. Now
ammeter readings are a magnetic field B is switched on parallel
400V400V to the inclined plane in downward
V
direction and sphere is again left at top of
C
50 L inclined plane. Time taken by sphere in
A
1000V, 50 Hz reaching to bottom is t2 in this case. Now
~
same experiment is repeated with
1) 200 volt, 20A 2)200 volt, 50A
magnetic field B switched on in
3)1000 volt, 50A 4)1000 volt, 20A
vertically upward direction. Time taken
44. A ray of light moving along the vector
by sphere in reaching to bottom of
ˆi  2jˆ undergoes refraction at an
inclined plane is t3 in this case. Then:
interface of two media, which is the
xz plane. The refractive index of
5
y > 0 is 2 while for y < 0 it is . The
2
unit vector along the direction of the

1) t1 < t2 = t3 2) t1 = t2 < t3
refracted ray is
3) t2 < t1 < t3 4) t1 < t2 < t3
3iˆ  5ˆj 4iˆ  3ˆj
1) 2)
34 5 47. A semi-conductor diode, whose potential
3iˆ  4ˆj 3iˆ  5 ˆj
3) 4) barrier is 0.7 volt, is connected in series
5 34
45. Potential difference across a resistance with ammeter A of resistance 0. , as
is measured as V = (20  1) volts and shown in the figure. The reading of
current flowing through it is measured ammeter is (The resistance of P-N-Diode
as i = (1  .01) A. Then the value of is 0. 7)
resistance measured by Ohm’s law Metal strip Metal strip
R = V/i is P-Type N-Type
1) (20  1.2)  2) (20  0.8) 

3) (20  1)  4) (20  0.6) . A
Ra = 0.7 
46. An experiment is carried out in which 1) 1A 2) 0.5 A

a conducting sphere is kept on the top 3) 0.1A 4) 0.0A
of smooth inclined plane. Time taken

48. A resistance-capacitor network is 1
shown in the figure. The charges on 

x
the capacitors C1 and C2 are Q1 and Q2 2
respectively. The values of Q1 and Q2

are
1) x 2) 1
5 5V C2 5
3) 2 4) both x and 1
5 5F 5
5
5 5F 5
5V
C1 5V 5V
5 5
1) 25 C, 0 C 2) 0 C, 25 C
3) 25 C, 25 C 4) 0 C, 0 C
49. An electric field given by

E  4iˆ  3(y2  2)jˆ , acts within a Gaussian
cube of side 1 m placed at origin such
that its three sides represents x, y and z
axis. The net charge enclosed with in
the cube is
1) 40 2) 30
3) 50 4) zero
50. A conducting L shape rod is rotating
with an angular velocity  as shown in
figure. Allowing the fact that electrons
are the current carriers in conductor
the electric field along the conductor at
position x depends on (mass and
charge of electron are m and e and
neglect gravity)

51. In the given circuit, it is required that it records a maximum intensity (a
the thermal power generated in R will maxima) (wavelength = ).
be maximum. The required value of R
will be
10 
h
20 V 30 V R

40 V 60 V
 
10  20  30  30  1) 2)
2 cos  2sin 
1) 10  2) 12  
3) 4)
4sin  4 cos 
3) 8  4) 6 
54. A string of length  is fixed at both ends.
52. The position of a particle describing
It is vibrating in its third overtone.
simple harmonic motion along y-axis
Maximum amplitude of the particle on
about the origin has been described in
the string is A. The amplitude of the
the adjacent figure by sinusoidal
graph. The slope of the tangential to particle at a distance /3 from one end is
1 1 1) A 2) 0
the graph at t = s is equal  , the
6 3 3A
3) 4) A/2
maximum speed of the particle is equal 2
to 55. A ray of light, travelling in a medium of

y (in cm) refractive index 2, is incident onto the
5 flat surface of a slab, the angle of
O 1 t (in sec) incidence being 37. The refractive index
10
of the material of the slab varies with
1) 1/3 m/s 2) 2/3 m/s
depth(x) from the top surface, (x) = 2
3)1 m/s 4) 2 m/s
x, where x is in ‘m’. The maximum
53. Radio waves coming at angle  to
depth reached by the ray is (take sin 37
vertical are received by a ladder after
 0.6):
reflection from a nearby water
surface directly. What can be height 37 =2
of antenna from water surface so that
x
(x)

1) 8/5 m 2) 6/5 m 2) through point A.
3) 3/5 m 4) 4/5 m 3) through point B.
56. In the figure D is an ideal diode and an 4) through the point at a distance 5 cm.
alternating voltage of peak value 10 from A.
volts is connected as input v1,Which of 58. A uniform conducting rectangular loop
the following figures represents the of sides , b and mass m carrying current
correct waveform of output voltage v0? i is hanging horizontally with the help of
R two vertical strings. There exists a
D uniform horizontal magnetic field B

~ +
v0 which is parallel to the longer side of
5V
v1  loop. The value of tension which is least
+5V is
0 0
1) 0 0
2) 15V
+5V +10V
0 0 +5V b
10V 0V
3) 4)
B
3 
57. A block of mass kg is placed on a
10
1) mg  Bb 2) mg  Bb
2 2
rough horizontal surface as shown in
mg  2iBb mg  2Bb
3) 4) .
the figure. A force of 1 N is applied at 2 2
59. A parallel microwave beam of
on end of the block and the block
wavelength  = 2cm is normally incident
remains stationary. The normal force
onto a slit and the transmitted waves are
exerted by the surface on the block
observed on a screen kept 10 m away
acts (g = 10 m/s2)
from the slit. As the detector is moved
F = 1N
30º along the screen, the microwave is
20 cm
detectable up to distance 40 cm from the

position of the central maximum. If the
B A
detector is moved a further distance of x
20 cm
cm in the same direction, a maximum is
1) through the centre of mass of the
detected. The value of x is
block.

Central
microwaves maximum
1) 80 2) 60
3) 40 4) 20
60. A block of mass (M = 1 kg) is kept on
smooth floor of a truck. One end of a
spring of force constant 100 N/m2 is
attached to the block and other end is
attached to the body of truck as shown
in the figure. At t = 0, truck begin to
move with constant acceleration 2
m/s2. The amplitude of oscillation of
block relative to the floor of truck is
M a0
k O
1) 0.06 m 2) 0.02 m
3) 0.04 m 4) 0.03 m

CHEMISTRY
61. If a container contains only gas A4 (g)
and the following reaction takes place
A4 ( g) ® 4A( g)
1)
If A (g) is considered to be a real gas
then, correct statement is .
1) The value of ‘ b ‘ increases
2) The value of ‘ b’ decreases
3) The value of ‘ b’ constant
2)
4) Cannot be predicted.
62. Which of the following statement is
incorrect?
1) Among 20 standard amino acids,
3)
only two amino acids are heterocyclic
amino acids with aromatic side chain.
2) The methylated product of ‘A’ (it is
formed in the presence of CH3OH/H+)
which is obtained by the hydrolysis
Lactose can show mutarotation 4)
3) Ascorbic acid liberate CO2 on 64. Consider the nuclear reactions,
boiling with NaHCO3 7 N 14 ( x, p) , O17 and 13 Al 27 ( m, n)15 P30
4) Methylated uracil do not form identify the x and m respectively in the

H-bonds with adenine in DNA. above reactions (where
63. For second period elements, the x= unknown particle, p = proton,
correct ionization enthalpy (Y-axis) vs m = unknown particle, n = neutron)
Zeff2 / n2 graph is ( Z eff  effective 1) a , n 2) a , a
nuclear charge, n- principal quantum 3) p,n 4) a , p
number of valence shell). 65. Which is correctly given?

1) Novolac is linear polymer

2) The complete hydrolysis product of 1) 2 2) 3
Nylon-6 has two functional groups 3) 4 4) 5
3) Melamine is Addition polymer 69. In the context with the industrial
4) The product of complete reduction preparation of hydrogen from water gas
of polyacrylonitrile cannot liberate CO  H 2  , which of the following is the
nitrogen gas on reaction with nitrous correct statement?
acid. 1) CO and H 2 are fractionally separated
66. In solid NH 3 , each NH 3 molecule has 6
using difference in their densities
other NH 3 molecules as nearest 2) CO is removed by absorption in
neighbours, H of sublimation of NH 3 aqueous Cu2Cl2 solution
at the melting point is 30.8kJ/mole and
3) H 2 is removed through occlusion with
estimated H of sublimation in the
pd
absence of hydrogen bonding is 14.4
4) CO is oxidised to CO2 with steam in
kJ per mole. The strength of H-bond in
the presence of catalyst followed by
solid NH 3 is
absorption of CO2 in alkali.
1) 5.5 kJ/mole 2) 16.4 kJ/mole
70. Calculate the amount of anilinium
3) 2.7 kJ/mole 4) 8.7 kJ/mole
sulphate (in grams) required to be added
67. Find the entropy change (in Jouls/g) of
to 500ml of 0.2 M NH3 to give solution
liquid during the evoporation at its
of pH 9.3 at 25ºC .Assume volume of
boiling point. boiling point of liquid is
solution remaining constant. Given pKb
400K. Given ebulloscopic constant of
of Aniline is 4.7 ; GMW of anilinium
liquid is 4.157 K. Kg. mole–1
sulphte = 284.
1) 8 2) 0.8
1) 14.2 2)28.4
3) 80 4) 160
3) 7.1 4) 1.42
68. Phthalimide reacted with acetyl COOH
PCl3
H D Deutirated Product(s) moist Product(s) + inorganic products
chloride in the presence of BuLi forms Br2 Ag2O
71. CH3
( C10 H7O3 N ) which further undergoes Which of the following option is

complete hydrolysis. No of products incorrect?
formed after hydrolysis is. 1) The final mixture is optically active.

2) In the final solution, yellow ppt is
also observed
3) The final mixture is optically
inactive
4) Enol form is participated in the
formation of one of the product in the
given sequence
72. To two different samples of
magnesium sulphate A and B, sodium
carbonate solution is added to sample
A and sodium bicarbonate is added to
sample B. In both cases there appears
1) White precipitate of MgCO3 in both
A and B
2) White precipitate of MgCO3 in A
and no precipitate in B
3) White precipitate of MgCO3 in A
and MgCO3 . Mg  OH  2 in B
4) White precipitate of MgCO3 .

Mg  OH  2 in A and MgCO3 in B on
boiling

73. 1 mole of NH3 ( g = 1.33) gas at 27ºC 76. When the aqueous solution of a weak
is expanded under adiabatic conditions electrolyte is on heating, the conductance
to make vol. 8 times. Final temp and of the solution:
work involved respectively are : 1) Decreases, because increased thermal
1) 150 K, -900 Cal agitation of solvent molecules offers
2) 150 K, 400 Cal. resistance to the movement of ions
3) 250 K, -1000 Cal 2) Increases, because the electrodes
4) 200 K, 800 Cal. conduct better.
74. Which of the following statement / 3) Increases, because of the dissociation
reaction are incorrectly given? of electrolyte and due to increase of

OH mobility of ions.
OCH3
CHCl3 acidification
Vanillin 4) Increases, because the electrolyte is
KOH
1) more mobile.
O OH
CH3 I2 acidification Na2Cr2O7 Ac2O 'X' CH3MgCl

Cinnamic acid Aromatic products
Ca(OH)2
2) 77.
3) Acetophenone and benzophenone The maximum value of X (consider only
can not be distinguished by 2, 4-DNP the reaction with aromatic ring) to form
test. aromatic product is.
CHO
1) 2 2) 3
CO,HCl
: (Gatterman raection)
AlCl3,CuCl 3) 4 4) 5
4)
78. Which of the following statement is
75. The type of bonds present in
wrong?
B2 H 6 .2 NH 3 are
1) SiCl4 hydrolyses in water but CCl4
1) Banana bond and covalent bond
does not
2) Banana bond and ionic bond
2) SiCl4 has higher b.pt than CCl4
3) Banana bond and coordinate bond
3) Si  Cl bond is stronger than C  Cl
4) Ionic bond, covalent bond and
bond
coordinate bond
4) The C  Cl bond length is almost equal
to the sum of the covalent radii of C and

Cl but Si  Cl bond length is shorter
*A
rate of EAS
than the sum of covalent radii of Si *B
and Cl. *C
79. Calculate solubility of AgBr in water *D
3)
if Df G0 of Ag(+aq) , Br(-aq) and AgBr( S ) ,
rate of basic
are 80, –104 and - 100KJ / mole
hydrolysis
*C
respectively *B
7600
Given temperature = K
8.314´ 2.303´ 1.4 4)
R = 8.314 J/K /mole 81. Indicate the correct statement
1) 1´ 10- 14 M/L 2) 1´ 10 M/L 1) Many salts of  PCl4  are obtained

3) 1´ 10 - 7 M/L 4) 1´ 107 M/L

when PCl5 reacts with chloride ion
NH2
acceptor such as TiCl4
CH3COCl HNO3 hydrolysis
(B) (C) (D)
pyridine H2SO4 major
2) All the trihalides of the nitrogen group
80. (A)
elements undergo easy hydrolysis by
Which of the following graph is
water to yield acidic compounds
correctly given?
3) All the elements of the nitrogen group
form penta halides
conjugate acid
*A
pKa of
4) In all oxo-acids of sulphur containing

*B
*C two sulphur atoms per molecule there is
conjugate acid S  O  S linkage

of A,B,C,D
1) 82. Which of the following statements are
*A correct.
pKa of acid
*B (I) Only from hydrogen atoms radiations

*C of Balmer series belongs to visible range
amine (II) Angular momentum of electron in
2)
Bohrs orbits of hydrogen atom can have
h h h
values 0.5 , and
p p 0.5p

(III) In hydrogen atom as principal 84. Successive values of log K  300 C  for the
quantum number increases the radial Ni 2  NH 3 system in water decreases.
separation of successive Bohrs orbits
This is due to
also increases .
1) Decrease in the probability for the
(IV) In hydrogen atom as electron goes
attack of NH 3 at Ni  H 2O bonds
nearer to nucleus it has to increases its
2) Decrease in the enthalpy of
kinetic energy to resist the nucleur
substitution of H 2O by NH 3
attraction.
3) Decrease in the entropy by the
1) I, II 2) II, III
substitution of H 2O by NH 3
3) III, IV 4) I, II, III, IV
83. 4) Increase in the electrostatic repulsion
between ligands (their peripheral
electrons)
Ph CH CH CH CH2 1 eq HCl Major product
85. In a rigid vessel at constant temperature
The structure of ‘X’ is.... the following reaction is a initiated with
1) A8(g)
Cl
2A8( g) 2A3( g) + 3A2( g) + A4( g)
CH3
; Thermodynamic and 1,4-adduct
At Equilibrium the mole fraction of A 2( g)
2) is 0.36. Then mole fraction of A8( g) is.
Cl
1) 0.14 2) 0.28
CH3
; Thermodynamic and 1,2-adduct
3) 0.42 4) 0.64
3) HNO3
Major product
Sn NaNO2 PhN2Cl
'A'
H2SO4 HCl HCl NaOH
Cl H2O,
86.
CH3 Then A is
; Kinetic and 1,2-adduct
ONa
Cl
CH3
; Kinetic and 1,4-adduct
4)
1) N2Ph

ONa NO 2
N2Ph
2) 89. Cl Br
N2Ph Which is incorrect regarding this

ONa molecule?
1) The sodium extract of this compound
3) forms blue colour solution with FeSO4 in
ONa
the presence of H 2 SO4
2) The IUPAC name of this compound is
4) N2Ph
1-bromo-3-chloro-5-nitrobenzene
87. Acidified K 2Cr2O7 will fail to
3) Sodium extract of this compound, on
distinguish between
treating with AgNO3 forms precipitate.
2- 2- 2 2
1) CO and SO
3 3 2) C2O and CO
4 3
4) Halogens are detectable if we add
2 2-
3) CO2 and SO2 4) C2O and SO
4 3
AgNO3 solution before addition of conc.
88. Which of the following statement(s) is
HNO3 to lessaign’s solution
(are) incorrect?
90. A mixture of two white solids in water
1) The co-ordinate number of each
gives white precipitate with dilute HCl
type of ion in CsCl crystal is 8
but dissolves on adding conc. HCl. The
2) A metal that crystallizes in bcc
white precipitate obtained by adding dil
structure has a co-ordination number
HCl dissolves partly in ammonium
of 6
hydroxide while the remaining part
3) A unit cell of an ionic crystal does
dissolves in sodium hydroxide. The
not share any of its ions with other unit
possible compounds of the mixture are:
cells
1) Zn  NO3 2 and AgNO3
4) The edge length of the unit cell in
2) AgNO3 and Pb ( NO3 ) 2
CsCl is 400 pico meters
(r = 166.4 pm, r = 180 pm) 3) Pb ( NO3 ) 2 and Hg ( NO3 ) 2
Cs+ Cl-
4) AgNO3 and Mn  NO3 2

09 02 17 SR - Iit Iz Co Spark Jee Main GTM 3 Q'P

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09 02 17 SR - Iit Iz Co Spark Jee Main GTM 3 Q'P

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Date: 09-02-17

Time: 09:00 AM to 12:00 Noon Max.Marks:360

Name of the Student: ______________ I.D.NO:

TOTAL SYLLABUS + EXTRA SYLLABUS

1 cot B  cot C cannot be

10. A continuous function y  f (x) is  xdx  ydy  x 2  y 2   xdy  ydx   1  x 2  y2 

3) 2018 4) 2019 number of elements in S is, [where [.]

 sin have different numbers, is

Sr.IIT-IZ-CO-SPARK space for rough work Page 4

Sr.IIT-IZ-CO-SPARK space for rough work Page 5

1)3.75 2)17.5 sphere is at 0C and the other is at 20C.

3) 20 4) zero If both the vessels are heated through

hemispherical bowl of radius 40 cm. conduction of heat by the mercury pellet.

exerted by one sphere to another 2) The mercury pellet gets displaced

is…………….. (take g = 10 m/s2) towards the sphere at higher temperature.

1) 10 N 2) 20 N 3) The mercury pellet does not get

3) 30 N 4) none displaced at all.

C1 and C2 in steady state will be equal to expand without any displacement.

to 37. Four springs, of spring constant

2) C1|VA – VB|, C2|VA – VB| k

Sr.IIT-IZ-CO-SPARK space for rough work Page 6

39. A current carrying loop lies in the x-y

incorrect statement. 3) remains at rest 4) executes SHM.

1) net force acting on the loop is zero A

for all real . 2

4) for  = 0, the loop rotate. 1)5 m/s2 2)7 m/s2

Sr.IIT-IZ-CO-SPARK space for rough work Page 8

unit vector along the direction of the

R = V/i is P-Type N-Type

1) (20  1.2)  2) (20  0.8) 

46. An experiment is carried out in which 1) 1A 2) 0.5 A

Sr.IIT-IZ-CO-SPARK space for rough work Page 9

shown in the figure. The charges on 

respectively. The values of Q1 and Q2

49. An electric field given by

Sr.IIT-IZ-CO-SPARK space for rough work Page 10

to 55. A ray of light, travelling in a medium of

Sr.IIT-IZ-CO-SPARK space for rough work Page 11

D uniform horizontal magnetic field B

detectable up to distance 40 cm from the

Sr.IIT-IZ-CO-SPARK space for rough work Page 12

Sr.IIT-IZ-CO-SPARK space for rough work Page 13

3) Ascorbic acid liberate CO2 on 64. Consider the nuclear reactions,

boiling with NaHCO3 7 N 14 ( x, p) , O17 and 13 Al 27 ( m, n)15 P30

4) Methylated uracil do not form identify the x and m respectively in the

nuclear charge, n- principal quantum 3) p,n 4) a , p

number of valence shell). 65. Which is correctly given?

Sr.IIT-IZ-CO-SPARK space for rough work Page 14

( C10 H7O3 N ) which further undergoes Which of the following option is

Sr.IIT-IZ-CO-SPARK space for rough work Page 15

4) White precipitate of MgCO3 .

Sr.IIT-IZ-CO-SPARK space for rough work Page 16

is expanded under adiabatic conditions electrolyte is on heating, the conductance

to make vol. 8 times. Final temp and of the solution:

work involved respectively are : 1) Decreases, because increased thermal

1) 150 K, -900 Cal agitation of solvent molecules offers

2) 150 K, 400 Cal. resistance to the movement of ions

3) 250 K, -1000 Cal 2) Increases, because the electrodes

4) 200 K, 800 Cal. conduct better.

74. Which of the following statement / 3) Increases, because of the dissociation

reaction are incorrectly given? of electrolyte and due to increase of

CH3 I2 acidification Na2Cr2O7 Ac2O 'X' CH3MgCl

Sr.IIT-IZ-CO-SPARK space for rough work Page 17