[2] TCY–101

Roll No. ………………….. (k) What is the relationship between Equilibrium

constant and Gibbs free energy ?
(l) What is Vulcanization ?
Section—B
TCY–101 (Short Answer Type Questions)
2. Attempt any six questions. 4 each
B. Tech. (First Semester)
(a) Derive the Henderson’s equation for the acidic
EXAMINATION, 2019 buffers.
ENGINEERING CHEMISTRY (b) Write a short note on Conducting Polymers.
Time : Three Hours (c) Define addition and condensation polymerization
Maximum Marks : 60 with suitable example and mechanism.
Note : Question paper has three Sections. Read carefully (d) Write a short note on Activation Energy on the
instructions for each Section. basis of Arrhenius equation.
Section—A (e) What are the lubricants ? Give its classification
with examples.
(Very Short Answer Type Questions)
(f) Discuss esterification and transesterification.
1. Attempt all questions. 1 each (g) Write a short note on concentration cells.
(a) Define a fuel. (h) Determine the potential of a cell, initially
(b) Write the two units of calorific value of fuel. containing 100 L each of 1.00 M Cu +2 ion and
(c) Why does low density and high density 1.00 M Zn +2 ion, after the passage of 0.1 × 106
polyethene differ in density ? Coulombs of charge.
(d) Define rate constant. Section—C
(e) Write two examples of biodegradable polymers. (Long Answer Type Questions)
(f) What are redox reactions ? 3. Attempt any three questions. 8 each
(g) What is Elastomers ? (a) (i) Briefly explain the solubility mid solubility
(h) What is titrimetric analysis ? product.
(i) What is Normality ? (ii) What do you mean by acidic and basic
(j) What is molar conductivity ? buffer solutions ?

(B-15) P. T. O. (B-15)
 [3]

(b) Prove that for second order reaction, the half life
period is inversely proportional to initial
concentration of one of reactant (when the
reactants are same).
(c) Write the preparation, two properties and two
uses of any two of the following polymers :
(i) Bakelite
(ii) PMMA
(iii) Polyurethane
(d) What is corrosion ? Explain the corrosion on the
basis of electrochemical theory.
(e) Define the terms Gross and Net Calorific value of
a fuel. Calculate the GCV of the coal in cal/gm,
when tested in the laboratory for its calorific
value in the bomb calorimeter, the following data
were obtained :
Weight of coal burnt = 0.95 gm, Weight of water
taken =500 gm, Weight of water equivalent of
bomb and calorimeter = 2000 gm, Rise in
temperature = 2.48°C, Cooling correction =
0.02°C, Fuse wire correction = 10 cal, Acid
correction = 60 cal and Latent heat of
condensation of steam is 580 cal/gm.

TCY–101

(B-15)