Capsule Programme - 2022 CP-MICRO TEST-3Q-NEET-UG(Med)

NEET-UG 2022 3Q
Capsule Course Day 6 Micro Test
CHEMISTRY
Time : 30 mins Full Marks : 60
Marks
Student’s Name ....................................................................................................................... Obtained

Centre ........................................................ Course ................................ Date ........................

Syllabus : Electrochemistry ; Functional Group - II (Aldehydes, Ketones and Carboxylic Acids) ; Functional
Group - III (Amines) ; Biomolecules and Polymers & Metallurgy

Important Instructions Consider the following reaction and identify X.

[Each question carries 4 marks. For each correct –
response the candidate will get 4 marks. For each + – OH
H 2N OH + N2Cl X
incorrect response, 1 mark will be deducted.] pH = 9 - 10

 Each of the following questions has Only One

Option Correct. Tick ( ) the appropriate answer. OH
N N
SECTION – A (12 Q : Compulsory) 1

For the given cell, NH2

Hg | Hg2 NO 3 0.001M || Hg2 NO 3 1M | Hg OH

2 2
the Ecell is
2
1 0.0185 V 2 0.0885 V N
N
3 0.0625 V 4 0.03 V NH2

Which of the following carboxylic acids undergoes OH

decarboxylation easily?
3
1 C6H5—CO—CH2—COOH N
N

2 C6H5—CO—COOH
+ –
4 H 2N N2Cl
3 C6H5 — CH —COOH
| Compound X having molecular formula C6H10O gives
OH
positive test with DNPH and hydroxylamine. It gives
negative test with Tollens reagent and Fehling
4 C6H5 — CH —COOH
solution. Yellow precipitate is obtained when it is
|
NH2 treated with I2/NaOH. The structure of compound X is

CHO
1 O 2

O
CHO C CH 3
3 4
O

PATHFINDER : 96K, S.P. Mukherjee Road, Hazra More, Kolkata-700026, Ph. 24551840 / 24544817 1
CP-MICRO TEST-3Q-NEET-UG(Med) Capsule Programme - 2022

Consider the following reactions at 1000°C : Orlon is

1 1 Addition polymer
Zn(s) O2 (g) ZnO(s) ; G° = – 360 kJ/mol
2
2 Condensation polymer
1
C O2 (g) CO (g) ; G° = – 460 kJ/mol 3 Polyacrylonitrile
2
Choose the correct statement 4 Both (1) and (3)
An aqueous solution containing 1 mol of each of
1 Zn can be oxidised to ZnO by CO
Cu(NO3)2, Mg(NO3)2 , AgNO3 and Hg2(NO3)2 is
2 ZnO can be reduced by coke electrolysed with inert electrodes. If

3 Both (1) and (2) are true   0

2

E0 Ag Ag  0.80V , E 2Hg Hg2  0.79 V

E0  Cu2  Cu   0.34 V and E Mg Mg   2.34 V

4 Both (1) and (2) are false 0 2

Glucose + 3 C6H5NH NH2 X ;

then with increasing voltage, decreasing sequence
Fructose + 3 C6H5NH NH2 Y ; then of deposition of metals on the cathode is

1 (X) and (Y) are same products 1 Ag, Cu, Hg, Mg

2 (X) and (Y) are different products 2 Ag, Hg, Cu

3 Formation of (X) is possible but (Y) is not 3 Mg, Cu, Hg, Ag

possible 4 Ag, Hg, Cu, Mg

4 Formation of (Y) is possible but (X) is not O
possible
C H COOOH
p – cresol reacts with chloroform in alkaline medium 
6 5
X (major product)
to give a compound ‘A’ which on reacting with Here X is
hydrogen cyanide gives, compound ‘B’. The later on O
acidic hydrolysis, gives chiral carboxylic acid. The COOH
structure of the carboxylic acid is 1

O
CH(OH)COOH
1 2 O

OH
O

CH2COOH O
3
2

OH
OH

Oil floatation process is applicable for concentration

3
CH(OH)COOH
of which ore?
OH
1 Galena 2 Bauxite
4 None of these
3 Hematite 4 Calamine

2 PATHFINDER : 96K, S.P. Mukherjee Road, Hazra More, Kolkata-700026, Ph. 24551840 / 24544817
 Capsule Programme - 2022 CP-MICRO TEST-3Q-NEET-UG(Med)

Statement - I : Aliphatic 1º amines can be prepared Which one of the following pairs is not correctly
by Gabriel Phthalimide synthesis. matched ?
Statement - II : Aryl halides undergo nucleophilic 1 Terylene : Condensation polymer of
substitution with anion formed by phthalimide is
Gabriel synthesis. terephthalic acid and ethylene
glycol
Choose the correct option
2 Perspex : A homopolymer of methylme-
1 Statement - I is and statement - II both true
thacrylate
2 Statement - I is and statement - II both false 3 Teflon : Thermally stable cross-linked
3 Statement - I is true, Statement - II is false polymer of phenol and
formaldehyde
4 Statement - I is false, Statement - II is true
4 Buna-S : A copolymer of 1,3 - butadiene
SECTION – B (5 Q : Optional, 3Q to be answered) and styrene

CH3CHO upon treatment with Al(OC2H5)3 produce Match Column-I with Column-II with the codes given
below
1 A mixture of CH3COOH and CH3OH Column-I Column-II
2 Only CH3COOCH2CH3 (A) Glycosidic linkage (P) Globular protein
(B) Maltase (Q) Connects two
3 Only CH3COOH monosaccharide units
4 Only CH3CH2OH (C) Peptide bond (R) Monomeric unit of
nucleic acids
Glutamic acid,
(D) Nucleotide (S) Connects two-amino
H2N—CH(CH2CH2COOH).COOH has acid units
pKa1(–COOH) = 2.2 , Codes :

 
pKa2 NH3 = 9.8 and pKa3 (R group COOH) 1 (A)  (Q) ; (B)  (P) ; (C)  (S) ; (D)  (R)
= 4.3. The isoelectric point of glutamic acid is 2 (A)  (P) ; (B)  (Q) ; (C)  (R) ; (D)  (S)
1 5.9 2 7 3 (A)  (S) ; (B)  (R) ; (C)  (Q) ; (D)  (P)
3 10.2 4 3.25 4 (A)  (R) ; (B)  (Q) ; (C)  (S) ; (D)  (P)
A cell contains two hydrogen electrodes. The negative
electrode is in contact with a solution of 10–6 M
hydrogen ions. The e.m.f. of the cell is 0.118 Volt at
25ºC. The concentration of hydrogen ions at the
positive electrode is

1 10–6 M 2 10–8 M

3 10–4 M 4 none

PATHFINDER : 96K, S.P. Mukherjee Road, Hazra More, Kolkata-700026, Ph. 24551840 / 24544817 3