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SwissChO First Round 2021 22 EN
SwissChO First Round 2021 22 EN
Chemistry Olympiad
First round
Multiple Choice : 32 Questions
Duration : 40 minutes
Aids and tools : All aids are allowed (Text books, calculators,
periodic table, etc.). However, the test has to be
solved on one’s own without the help from others.
Online participation is recommended. For the print version of the exams and
details regarding participation on paper, see chemistry.olympiad.ch/en/teachers
Good luck!
Question 1 (MC): Question 5 (MC):
What is the pH of an aqueous solution of Determine the right stoichiometric coeffi-
L HCl (pKa (HCl) � -6)?
0.67 mol cients for the following reaction:
n Al(OH)3 + m H2 SO4 → x Al2 (SO4 )3 +
A 0.67 y H2 O
B 13.1
A n: 2, m: 3, x: 1, y: 6
C 0.17
B n: 2, m: 6, x: 2, y: 6
D -6.3
C n: 1, m: 3, x: 1, y: 3
E 0.63
D n: 1, m: 6, x: 1, y: 3
Question 2 (MC): E n: 2, m: 6, x: 1, y: 3
Calculate the pH of an aqueous solution of
Question 6 (MC):
L acetic acid (pKa (AcOH) = 4.76).
2 mol
Determine the right stoichiometric coeffi-
A 2.38 cients for the following reaction:
B 4.76 a Na2 [B4 O7 ] + b SiO2 + c Na + d H2 →
C 2.46 x NaBH4 + y Na2 SiO3
D 2.23 A a: 2 , b: 7 , c: 16 , d: 16
E -3.0 B a: 1 , b: 7 , c: 16 , d: 8
Question 3 (MC): C a: 1 , b: 7 , c: 16 , d: 16
Determine the oxidation number of all atoms D x: 8 , y: 1
in the following molecule: HCO3 − E x: 1 , y: 1
A 6.44 m3 A 0.1 %
B 148 m3 B 50 %
C 6.74 L C 5.6 %
D 0.69 L D 94 %
E 6.87 · 10−4 m3 E 9.1 %
Question 10 (MC): Question 14 (MC):
Calculate the energy of one photon at 460 nm. Which is the correct equation for an alpha
decay of 235 U?
A 4.32 · 10−8 kJ
A 235 U → 231 Th2− + 4 He2+
B 4.32 · 10−8 J
B 235 U → 231 Th +4 He2+ + energy
C 9.13 · 10−32 kJ
C 235 U → 231 Th +4 He
D 4.32 · 10−19 J
D 235 U → 231 Th +4 He + energy
E 3.04 · 10−31 J
E 235 U → 231 Th2− + 4 He2+ + energy
Question 11 (MC):
Question 15 (MC):
Which is the correct expression for the equi-
librium constant of the following reaction? In which mode of radioactive decay does 99 Tc
4 NH3 + 5 O2 −
←−−→
− 4 NO + 6 H2 O decay into 99 Ru+ ?
[NO]−4 [H2 O]−6
A K= [NH3 ]4 [O2 ]5
A Alpha decay
[NO]4 [H O]6 B Beta minus decay
B K= 2
[NH3 ]4 [O2 ]5
[NH3 ][O2 ]
C Electron capture
C K= [NO][H2 O] D Gamma decay
[NH3 ]4 [O2 ]5
D K= [NO]4 [H2 O]6 E Beta plus decay
[NO][H2 O]
E K= [NH3 ][O2 ] Question 16 (MC):
Question 12 (MC): The transmission of a 0.3 molar solution of
Sudan II (a red dye) is 0.2 at a wavelength of
Calculate the combustion enthalpy of propane 500 nm and a width of 1 cm. Calculate the
(the reaction of C3 H8 with oxygen): molar extinction coefficient at 500 nm.
Δf H(CO2 ) = -393.5 kJ/mol
L
Δf H(H2 O) = -241.8 kJ/mol A 2.33 mol · cm
Δf H(C3 H8 ) = -104.0 kJ/mol B 5.36 mol L· cm
A Δc H = -2043.7 kJ/mol C 0.67 mol L· cm
B Δc H = -2251.7 kJ/mol D 10.01 mol L· cm
C Δc H = -3288.7 J/mol E 0.0067 mol L· cm
D Δc H = -3288.7 kJ/mol
E Δc H = 2043.7 kJ/mol
A C 4 H6 O
B C 3 H8 O 2
C C 3 H8 O
D C 4 H8 O 2
E C 3 H8
Question 18 (MC):
Which of the following molecules contains a
mass percentage of phosphorous of 66 % and A II carboxylic acid
a mass percentage of oxygen of 34 %? B I ketone
C V amide
A PO2
D IV nitrile
B P4 O10
E III ether
C P 4 O6
D P 2 O2 Question 21 (MC):
E P 3 O4 Which ones are the right stereoindicators of
this compound?
Question 19 (MC):
According to IUPAC, what ist the name of
the following compound?
A 1R / 2R
B 1S / 2S
C 1R / 2S
D This compound has no chiral centers.
A 5-ethyl-2,4,7-trimethylnonane E 1S / 2R
B 2,4-diethyl-5,7-dimethyloctane
C 5-ethyl-3,6,8-trimethylnonane
D 5,7-diethyl-2,4-dimethylnonane
E 5,7-diethyl-2,4-dimethyloctane
A 1 – Elimination / 2 – Elimination /
3 – Substitution
B 1 – Substitution / 2 – Elimination /
3 – Addition
C 1 – Addition / 2 – Elimination /
3 – Substitution
D None of these options.
E 1 – Addition / 2 – Substitution /
3 – Elimination
• For the energy E given to the system A The electronegativity increases from the bot-
with boundaries EA,A < E < EA,B , the tom left to the upper right.
major product is A. B The size of atoms decreases from bottom to
top.
• When the energy given to the system
E > > EA,B the major product is A. C The size of the atoms increases from the left
to the right.
• When the energy given to the system D The ionisationation energy increases from
E = EA,A the major product is B. upper right to bottom left.
• When the energy given to the system E The number of valence electrons increases
E > > EA,B the major product is B. from the left to right.
A LiF
B NaBr
C CaO
D MgO
A 5 E NaCl
B 4
C 6
D 3
E 2
A II
B IV
C This molecule doesn’t exist.
D I
E III