No.of Printed Pages: 02 D514 B.Sc. Dual Degree/M.Sc. EXAMINATION, 2021 ourth Semester) Phy., BT penis CHEMISTRY-IV Time : 2% Hours) (Maximum Marks :75 [Before answering the question-paper candidates should ensure that they have been supplied to correct and complete question-paper. No complaint, in this regard, will be entertained after the examination Note : Attempt Four questions in all. All questions carry equal marks 1. (@)_ Define the accuracy with example (©) Explain the partition coefficient in chromatography. (©) Explain in brief about plate theory for ion exchange. (4) Write the factors on which solvent extraction depends. (©) Waite the name of different types of partition chromatography: v Explain the Mean and Median by taking examples. » Explain relative mean deviation and standard deviation with the help of examples. Explain the principle and working of paper chromatography, give its application also, (3)(u21)M-0814 1 PTO. Discuss the principle of Adsorption Chromatography and write the requirements for column and give the factors affecting the column efficiency. 6. Explain the anion exchange mechanism by taking suitable example and write its applications. Write the different ion exchangers and explain their characteristics - [Explain the principle and mechanism of solvent extraction. 9. Explain the different types of solvent extraction process and give the applications of this technique.[eet Prined Page 02 S13 B.Se, Dual Degres/M.Sc. EXAMINATION, 2021 Fourth Semester) PHYSICS DPH206 Electromagnetic Theory Time : 2% Hours) [Maxi Marks: 78 [Bcfore answering the question paper candidates should easure tha they have been supplied to comect and complete queston-papet. No complaint, inthis regard, willbe entertained afer the examination [Note : Attempt Four questions in all, All questions carry equal marks 1. (a) State difeential form of Gauss Law: (©) What is diference between a Conductor and dielectric ? Explain dielectric (©) Compare betwsen Electrostatis and Magnetosttis. (€) Derive the expression of eneray density in a magnctic eld (©) What do you understand by displacement curent ? 2. (a) Derive the electric fel from electrostatic potenti (©) Derive Poison’s and Laplace's equations. What are their importance in Physics? A. (@) What is Eleetric Dipole ? Show that electric field duc wo a dipole at » point on its axis i twice at stong as that ata point a the same distance along the perpendicular axes (auznMoe3 1 Pro. (0) Derive the relationship B=ey +7, where 6, & and ® have their usual memings, A. (a) Explain Biot Savant law fr the flax density at « point due to cument flowing in a cicust clement, How will you find the direction of fux density ? (©) Discuss Curl and Divergence of Magnetic Fick. 5. (a) Explain terms Magnetisaton, Magnetic Susceptibility, magnetic permeability and establish relationship wena(tex) (©) Explain, bow will you use hysteis curve 19 sleet the material for the constracton of | @ Permanent magnets i) Electomagnets i) Transformer 6. (2) What is self inductance ? What are its units ? Find the expression for 2 @ magnetic energy stored in magnetic fel! of an inductor and compare this ‘expression withthe energy associated with capacitor C carrying the charge g Derive and explain integral and differential forms of Faraday’s laws, Deine Fores Merwe equa q(©) What is difference between a Conductor and dielectric ? Explain distecrc constant (©) Compare between Electrostatcs and Magnctostatics (@) Derive the expression of energy density in a magnetic fed (€) What do you understand by displacement current 2. (a) Derive the elect field from electostatic potential () Derive Poisson's and Laplace's equations. What are their importance in Physics ? 3. (a) What is Electric Dipole ? Show that electric feld due to a dipole at a point ‘on its axis is twice as strong as that at a point atthe same distance along the perpendicular axes. (30211-0813 1 P30. () Derive the relationship B=ey E+, where BE and ® have their usual emings 4. (@) Explain Biot Savart law for the ux density at a point due to current flowing in a circuit clement. How will you find the direction of fx density ? (©) Discuss Curl and Divergence of Magnetic Fiekd 5. () Esplin tems Maguetition, Magic Suceptbiy, magnetic emesbiliy snd eal lasonsip: went) (>) Explain, how will you use hystersis curve to select the material for the contraction of ©) Pemment mages (i) Elem (iy Tanfooer 6. (a) What is self inductance ? What are its units ? Find the expression for magnetic encrey stored in magnetic field of an inductor and compare this ‘expression withthe energy associated witha capacitor C carrying the charge q. (©) Derive and explain integral and differential forms of Faraday’s laws, 7. (a) Desive Fourier Maxwell's equations. (©) Why docs Ampere's Circuital law need modification in clectrodynamic sitation ? What is Maxwell's correction to modiy this law ? 8. (a) State Maxwell's equations. Derive the simple plane wave equation in an isotropic non-conducting medium. (6) Show that electromagnetic waves are transverse in nature and draw figure 9. Determine the boundary conditions satisfied by B, H and E, D at the interface between two media of differen permeabilities and dielectric constants. ¢av211-D613 2 60[No.of Printed Pages: 2 ps2 B.Sc, Dual Degree/M.Sc. EXAMINATION, 2021 (Fourth Semester) PHYSICS, DPHao4 Fundamentals of Nuckar and Particle Physics Time 2% Hours} [Masimum Marks 75, ‘Bcforeamsw rng the question paper candlates should ensure hat they have been supplied to coreet and complete question-papet No complaint, in this regard, willbe entertained er the examination, [Note : Attmpt Four questions in all Al questions carry equal marks. 1. (@) Draw the diagram of nuclear density. (©) Describe similarity between liquid drop and stomic nucleus (©) What is Pai Production ? (8) How Newton Interact with Mater ? (©) What ae Elementary Particle Quantum Numbers ? 2 (a) Discus, how nuclear size is determine by electron scaring ? (©) Discuss the main features of binding energy versus mass number curve. A.) Explain electric monopole, dipole and quadrupole moment of the nucle (©) Find the energy rauird wo remove the lst ighty bound newton fom 5,Ca™ Given that mC) = 39.962589u, Ca”) = 389705914 and m= 1.008665 (s200812 1 4. (@)_ Discuss the Liguid drop model of atomic mcleus, (6) Describe the flowing Emission of Gamma Ray (i) Gamow fector S. (a) Describe the bes decay and shape of beta spectrum. (©) Wit notes on the followin 6) Electron capture (i). Neutrino Hypothesis, 6 (@) Derive the Bethe Bloch formula of energy loss (©) Discs the various types of nuclear reactions 7. (a) Describe the interaction of Gamma ray with Mate. (©) Dicuss the constuction and working of GM counter | (@) Discuss im detail the fundamental interaction benween clementay parti (©) Discuss the concept of antpartces. 9. (@) Discuss the classifaton scheme of elementary particles. (©) What is quark model of neutron and ant-neutronNo.of Printed Pages: 03 RalNe. nn DSi B.Sc. Dual Degree/M.Sc. EXAMINATION, 2021 (Fourth Semester) (Main & Re-appear) PHYSICS DPH202 ‘Atomic and Molecular Theory Time : 2% Hours} [Maximum Marks : 75, [Before answering the question-paper candidatcs should ensure that hey have been supplied to correct and complete question-papet. No complaint, in this regard, will be entertained after the examination, Note : Attempt Four questions in all, All questions camry equal marks. 1.) Explain, what lead to the assignment of quantum number 12 10 the spin of ectron ? (©) What is the need of inhomogeneous magnetic field in Stem-Getlach experiment ? (©) The Lithium stom bas one 2 cleton outside a Filled inner shell, its ground state is "S,. What are the term symbols of the other alowed states, if any ? Why would you think itis ground state ? (@) Explain, how the study of vibrational spectrum ofa diatomic molecule enables 1 to determine the anharmonicity constant and equilibrium frequency of vibration ? (©) State the conditions fora vibration to be Raman active, Give examples also, (© Explain, why infra red bands are always degraded toward longer wavelength ? (3102100811 1 P7.0. 2. (@) Show that fora single valence electron atom the magnetic interaction energy AE = j4yM, Bx, where symbols have usual meanings. (b) What isthe basis of the origin of vector atom model ? What are its salient features ? How are they experimentally verified ? (2) Show that frst onder Stark effect forthe ground state of hydrogen is zero (6) Mustrate Paschen-Bank effect for the 1S —>P transition in a strnng magnetic fick (©) Explain the space quantization. 4. (@) Why is it impossible for 2 7Dyp state to exist? Explain on the basis of Hund’s rules, why the ground state of Carbon is 3Py and that of Oxygen is 3P, ? scheme, find the spectral term for N*. Also find its ©)oy 2 @ ) o 4@ © » © ‘What |s the basis of the origin of vector stom model ? What arc its salient features ? How are they experimentally verified ? ‘Show that fist onder Stk effect forthe ground state of hydrogen is zero lustre Paschen-Bank effect forthe 'S — PP transition in strong magnetic Sel Explain the space quantization. ‘Why i it impossible for 22D yy state to exist ? Explain on the basis of Hund’s rales, why the ground state of Carbon is 7P, and that of Oxygen is °P, ? ‘Using L-S coupling scheme, find the spectral tem for N*. Also find its pound energy state Show that for sp configuration thatthe total P mullet separation is same in j/ and LS coupling scheme Explain He atom specta quantum mechanically. Why does the ground He level le much deeper than the H gound level. but the excited He level agree closely with the comesponding H Level ? Prove thatthe number of tems for pd configuration is the same for LS coupling 2s that of coupling How doct the themnal distribution of the rotational levels of a diatomic ‘molecule iter tom that ofthe vibrational levels ata particlar emperstare ‘The rotational constant for the molecules in y = 0 state of the molecule is 40 car? and ¥ = 1 sate i 38.0 cnr! Find the rotational constnt in the state ve 2and r= 4 What is centrifugal distortion” Explain the effect of centrifugal distortion on moment of inertia, nergy levels and spectra ofa diatomic molecule, (au2nmoe11 2 © © ‘Oban an expression forthe energy level of a diatomic molecule taking it as vibring rotator, Discuss is spectrum and the relevant selection rule Explain ‘shy band degradation takes toward red only. nthe fundamental band of HCI, the spacing of the lines is found 10 be constant witha value of 63.6 cnr. The band is centered on a missing line at 8970 car! Find the valve of bond length and enersy of second excited state of vibrational motion of the molecule in eV. Discuss the vibrational rotational Raman spect of diatomic molecule along wth seleton rules and appropriate energy level digram. ‘The Raman spectrum of gious HBr is produced by means of a mercury lamp and fier which only transmits the mercury lines 435.3, 404.66, 407.78 nm, Raman lines are found at 481.39, 488.27 and 490.51 nm. Analysis this observation What is Raman Effect ? Explain, why Raman Anti-Stoes fines ae weaker than Raman Stokes lines Find the fundamental vibrational Sequency and force constant of CN molecule, the Raman lines are observed at 267 and 343 om. Explain what structural information about the molecule can be obtained! fom fhe analysis of Raman spectra