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Nazzel S.

Apolinar Week 3 Quarter 4

APPLICATION OF REDOX REACTION IN GALVANIC CELLS (BATTERIES)

The battery operates through electrochemical reactions called oxidation and reduction. These reactions
involve the exchange of electrons between chemical species. If a chemical species loses one or more
electrons, this is called oxidation. The opposite process, the gain of electrons, is called reduction.

In most batteries, there In the cell below, Zinc is used for the electrode on the electrons being
are different materials the left (the Anode) in contact with a solution of produced by the oxidation
at the two electrodes, Zinc (II) ions, possibly a solution of Zinc Nitrate. at the Anode could be
such that they want to used to do electrical work
react with one material as they are transferred to
Copper is used for the electrode on the right (the the Cathode where they
being oxidized and the
Cathode) in contact with a solution containing will be consumed by the
other being reduced.
Copper (II) ions, perhaps Cupric Nitrate. reduction process.

There must be a
path for the ions
to move between
the two solutions
in order for As the resistance is increased, the current decreases, and the voltage
electrons to flow increases toward a limiting value. In Chemistry, we are primarily
continuously interested in this limiting value, the maximum voltage that the
through the wire. electrochemical cell can deliver.  This maximum
This produces an voltage or electrochemical potential is a measure of the maximum
"ion current" electrical work that can be obtained from the chemical reaction occurring
within the battery within the cell, and this can be related to the Gibbs' Free Energy Change
with cations associated with the chemical reaction.
(positively -
charged ions) This cell is constructed with a Lead/Lead Sulfate
moving from anode and a Silver/Silver Sulfate cathode, both in a
anode to solution of Sodium Sulfate.  The two solutions are
cathode, and separated by an anion exchange membrane, which
anions (negatively allows negatively - charged ions to go through it,
but positively - charged ions cannot.  The voltage
- charged ions)
of this cell still depends on the current being
moving from the
drawn from it, and on the temperature.  At any
cathode toward fixed temperature, however, the maximum voltage
the anode. (at very low current) is independent of the
concentration of the electrolyte, and is equal to
the Standard Electrochemical Potential for this
reaction.

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