‘ "y Monica Bedi THe heaweh of chemi wie, sleale wll dhe Lady 4 orotin q: vente & Une mechorniin t+ ULL the date wer Jw us ohout Un peoribiliby BL Ue rrnetisy dhe base udlibabvi ells 44 about the extimt upto hich a Atadiion stake 1 aot —hL. ............ CHEMISTRY i ek xP CHEMICAL KINETIC 5 CHEMISSES “OC —T L a v bp Aeachion veug Alour aca slion eo Sr Renclisy preceed at aiapeee ots Be ed waedtaate s beeof Aqnoslag) + Nact{ag) i Ruste Of ron > G,Ha3% +8 —> —y Agck(9)-+ Nano, (ay) ey Pye “MORI Sahin + 64,0 & < i) OF eu eda yeas bpy completis,, a fomie scouettons $ 4 % 2 is Scanned with CamScannerD> contin a. hypethtiat xenctton A oa B Hew, . Rote of diteppearauce of A = = tat B 4 Rot. of -Ppearance J B 2 aid The rate of vex? roy caus be Guaprriembid a vot d ux™ = — ACAL, ALBl : AX at wane BA * TAL ie EM ce : At 2 b-t) TW dquo Asodeat LJ wuoluotic de concombiatien expend DAs wot Lh = dite Me sole punciimteaunanes Beaver 5 “ x 5 exprertion tudlreotia se Se coheas,” WY selstage Gu! abuli Care, Peial tone — titled core will tome co Me 1 volue rus te got A +e rate We pat —ve dig wa the Rate Cxfireation. > Cousicls anotlur maclion, ngA + ngB Nee + MD Say 1 Jrok a, — tata ~ 24 Atel wuLater, 1:4 dante — 1 * at 73 : * B+ —d tet t a appemane . Cc a : ae rn ~ D* Atgy ae Lon A A ND ARAAADHMMOMIMMMM MPT FH HP 3993S Scanned with CamScannerQaike dl] sote ior © Fer reendaone in bejud phere» Roh = change 14 cove 4 nenctent/ prcduct : deme bakin = ples / bby meee aie QO fr Auactions » : ne cone J renclamls © prods ore quand Heoms “partiak purcun - Rote = ata 4 atm see”) ar attin int’ or abhi! wee : ‘ é i pveroge ouate :— sale of, change of tonesubration pure Usk Time « hovrage ati = Ghornge din toneenbuiin sin pore liat = BR» duooge. oils = —LPUMOs) . 1OLNA , Ato, ~ at Ye. At ae Trwiontawceus Aalt = aoe > LAWNod .' Ato,y ae OTT OF OF FEY CECI NN I YES COS PEL T TR Scanned with CamScannerAvensge sats ot ting £ 2 C,-¢, = Au tr-t, AE Tuusteneour rot, of tina t= OA : oB Mao, Raleimer = at al = — oped Aaangent- > +A LP e Slope of tangent dt Scanned with CamScanneree Oe ee ee ey Oa |FAactors AFFECTING RATE _OF _REACTIOV . Comsembradien gf Ue raretonts 7 » a ai i) Tw vale ofa sunday ds Scanned with CamScanner€. ae D) -Possesa Aufpicint pane Ce Toinae in Ataetent- Scanned with CamScannerConcemls: fo rene olin, Tus for a Suypatabil och A+ p> Produit eS e S S & : S The seat, accoutiing Ji our Jj mort abi x ec Calle] = Klas (8? we CAL & [8] aut waslar toned rznckankt A & 8 So, K = Ante constant /velociliy me ante , ; y , t b Fer vreaclion 5 1 al Mee ante Keer be low Rate = KAI CBI? Ol mars action >. ; — lowe aatnn yin tis ate pad MOO chiswaly of dia balanced epuslirs . 2. Rokr daw exprammen ae napatent diy gqualitatun swlabiostuh bio tiv rate oh rn” & of nelatanls Wis ootially srplrewee Unt sual ae. Scanned with CamScanner7 Fer a hugbormed eat Ataclisns OA 438 — reo 4 ad Roky tows evpurrion maou be writhew as vob ~ fal” cel” oe M i amd commot Ine dadnaad "yr te hemmed honest Wares fear warn askin may He willing Ack s Keal® Cal Gant a & b on dat Ateicremebui cof of He balaned Onewital epustons aneronnneernnnnne The cout K Us cold seat comsbaut: /iveloditiy como’ /- U sueaetion out ‘ | foro Susdtlion CHetz +k, eet, t nel Lauro man action Peete rata Ir ats aww exefrwrsion vee Kiealela? i Rott coustamt (Ck) : t Fer o visoekion , A+B —— Products vats « CAND or vode = (A) (90 / ay the Comcenbealion Of Ot vuncliing apes 14 Veen ct big How ' vuln = K te {al=(B1= eet le Tus , rot, eostant ls dupimed os nt moh Oy ee Lene, De tamenbrcdsn a, eneh sanctoak i eet Adewet kth Of the temple ® ee hate combating Step Pr Rake cAduarmintey ae evnpesdton ¢) Ui ode ane @? wd po 3 Tat Or ook = at a slow 4 Nr +d N20 ot, 0 sth + 5 FS Net oe step > MOA RG ron te TN wath 80 Scanned with CamScannerChormetursteis d val comslont WHE git aan dia, about dn spud do “aston 2 16 Genin tre valus of Kale cout , fasion Bb) Recomposibcs Ve = VOLO, gan vattastad at Sefer: diene aes NG ny Nabite SHOT, Home % oS = ony oe |= 2303 tog Weenve) . Vee = [B) _Poasenrret change mutno A = Q = xeackont ae , aly) yet 9 Weck ob em teat te ° engeoob ns Tue Tat UyeM + em beb H-% at trot a 3 Scanned with CamScanneree ———— sts a = Be defeinanl or, Uren, the dum Luts oY te (tat conadnain ar a and “i Aa Fra Abo detienl reach OA 4 bB —> Peoduott Ral = RAIL B® Ord = man Ercample. Let order Arochion A Peau et Rob = kiCAl ex > -DN,p (4) —9 2Nalg) + alg) Rote =k, NADI dnd ode Jc1eaclton 2A — Product oa Rol = kA)” eK a Hg) +T) —ine(Z) Rat kK (VE) — exdane Ith? Rx B—P Rats +k, CATCB) ote» Kya” C8] Aodt Hes CATCBICED uy) pNogiit 4) re 2 ee Rot, > RIN] C02) oan Scanned with CamScannerD Pooctionas na @ + Bag —> amt (g) Fab 2 Cut ed edi © mus ordm Atcickin, Potinun 2Nw ——S Natron, fol > RINK > dn = Zo | aiuto rote Costas for dirant dn reachione the unishe rade Lonstant udepenols upow the Order d Ane reastion . Cremmal enprrision Cfo nan ordin reaction) : q 7 @ (ten) Libel hoe"! OD ew Order sceottion Rote = de =k LAT at wots dite Kk. ae oe @ — Ast_order -ceaelion Rate = dx = KCAL’ ot : _ Lor ke Mala me . ola et ASEC K 2 cee! | Scanned with CamScanner@D 2nd onde suoclion Rott = du ek tal” at me! 2k. (wl ) See k= we = wot diby sec! (mty. see D Bxd_ orden reaelion Rot. = dx 2A)" at a . at rls LS Umass LD eee a ' wee rl ata eb see gee x(walese')® ® Hop order r2aclien mob! ® tue! © Sf oredr Oe. mv gig Scanned with CamScannerMOLECULARITY > The umber puis ui raust cobde surnulterenis Ln odo to tuoty 4 Me Nett vsduin Ja called weoleelonily - Molecularists J) veenelin com be 1,247 3- > Reackin may Be slowoaified os uni molewlar , bimolrentar , diimeleentar © on the sbaiu | wolreutantiy - > Cwwlul suctlows dn ubieh, tu molreudaiuby ie Bu atm d) moles of He dufyount sonckamts oe spat chy du balomead chemical exuation Ort called ehewntakoray | vuseliont , Such veadtiony hue place 4 Ore Sap only . 4 > wrimolteulre NNO, —?N, + 2H,0 Bimolewer 2ut(q) —>ml9) +4) ToL nolecutar 2No +0, ——— 2NO, Scanned with CamScanner[ ORDER [ MOLECOLARITY 1] Sum of powers q towembralisl Total number domi of renctants Unith an ant en a He diam onbtrimentel value Ge da a Heoartio® value HF way Ar Zerw com nor be Zero May hams frortionad value Alureys Ubsle number Prowde dewe tdra ahout | olor not provide nay Susttion meth. Adem abt ax” mech Scanned with CamScannerZERD-oRDER Rx” t=0 . tek Scanned with CamScannerao ya me i) y= aint 7 Scanned with CamScannerDp © ee EE ey OIE, & SE © 2. cc aetna eG? FIRST oRveR REACTIOY ——s ee Rot. = K[AI | Reoatombs Pocoduacts tee a o tae ane ca Oe 2 ki lax) at On af gl HE wae’ dhe val qc Sk Hat. ise Oy” —_o futbuy — Aoge (aX)? wee yr = eS eee + Hig) 4 AG) | 03 oO 4 sab potad, lt ey Scanned with CamScanner| D) Gyrebh b/w Yg(fq) #t ies x ae kn Bana Tt) raph b/w slog lan) a+ kt = dna- Inla-x) Jae la-4) = Ina —kit day (ea) qh) tage. 2-30 Scanned with CamScanner: —————_—_——E————————_ 3. SEcona ogver REACTION Core -T Rol = K fal Reatkomnbs tent Powmdusar Come ne a 2 wet ao-t in | de 2 ky a0 | Cyppumtat rate op” at ( . frat ee kot ae 25 © oe beOre O Guaple fo (iz) & ee t ae ane i i e o i aaaliveape = a Scanned with CamScanner nananhhnOOLOaoahknnaan OOOVUUUT TTS FH PGA KL IAI UU SY SF FC CS POM ————e~ GD Guopin doatinten 2% alae) ss Ye ai ata-%) Alober Kae be kal ate) & exainple 3 ) ano, ——> 2No +8 Rods = Ka LNO]™ (ii) BNO ——4 NyO + NO Rob = kL NO!” Cue TL Rode = ke CA1(B) Reackank Product =o oe > ° Ee te ae be in ak ( Cr ( Kat eobv ; ( -ay}er Sse (o>) bw ant . bla Te vate 04” ky GSS, MO ate) 1 Scanned with CamScannereeambla ” MY Rook + Naor ——> Reoone + R-OH Rots =k, CRcHOR] (0x2) ui ye Rot 2k [No] [047 ae Expres & thes gated foun stor df ton Reacon. Order ieee Infegralid foro A — Product | © Jot: = Kal kee = 3-303 ‘Ay A — Product | £ woke RIAL | Ke EEE 409 faa Da Product | 2 | xoteeelal | K= -£ xe A Product | 2 pate =k (ABI kz 2:303 B(A-2) "n> (A-8)t “ha = Jelabs tar] 3A — Product 2 vote = KAP Scanned with CamScanner—PSEv00 FIRST ORDER REACTIONS nt > 1.H,coOGH, + LO coon + CoH 504 Soke =lk [cHylo0 ots] (eres s Cowes VY SSS HS NMI L LMM ULSI LAE C EHO . L PERE ; fals if | i & i SH E yh Scanned with CamScannersty = 2803, Ley 2 ay, 2 613 | Ke DL pastubacline decay aE SD Muclea vumctsory Bre Tet ordar reacting. pe , ene) Conclusion: by, for FOR doesnel dapensl ale, ty for oe pardtialar FoR us always roast, Tot bh, uundhnr we start With loo of O *eogout or Oleg wh nine a ra “the oe 4 Some aud tu, latin to o-osg frenised Bs thang fellows a FOR yurtion Scanned with CamScanner RR RR RRR Re neNeheM AMMAN MAINA IAH SAMADY HQYYD HY SF SS Ceca eCaeMvoymugygqyggugvuvcve re D and pute seadion Dart onde anion - Hh ke = ale dye = be rete") 32%) Corelusint For SOR Hy XH oO Generar Exrression FOR ty, for nin orden (oe 1 22) ty, > 2! aS (n-t) na! foment: of substance apa N tes Mt: | ras Se (Hee no ne tral 144 d BL Plots of all Lins ve inwtial cone ar diff, oxdind Zor ode “Tet onder, Second odor ty. EAA mc. Va. 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RT, RT Ine 230% bs Scanned with CamScannerPraclio’, Pruokteules Mistwbubion curve ahouiup Jom, dapendines 4 veake q vuintlinn Ebyece Of Cotalipt > Lewoe tht value cockivalicn ewnay, foatin idl be dhe rah oh the cacao ae 3 So. catalyat frovu aw ablirnals pathway or sunclion mech : Jp aaualey toe bse menue perder, & tone dpteering the enbgig amin « ee HS Caley does nok change eq” conelent th a reackish APM” Fratpe tw attarintep the eym fartin - th wo Oe calatiyer HA fuse anuett ax Backuomel oanchone Ye same Catton + ' = diosa nok ality ibls nungeg log k = bog > Ee ago3RT Ea, (obseuues| catalyst) ° = Lega deg nc) Q:303RT tog Ki = tog. 8.- Ese — ( pruaenee d codatyst.) sgreign (ar Ba) (O" £,) 2 ber Ja enact - 2 pot 3-3 03k J c. eee © ( Ea,-Ea,) (ea, Ke + li 2/303 -3038T ‘ 5ey keg LL — ( Bay Ea) Ky 230387 - Scanned with CamScannerCOLLISION THEORY A cemtecad: vuaclum peers uns only at pueuatt tf olitiere Aalto be : 7 The total number Sh, Cotkndns bien veer meng, AM tosling Abecies fox eon ee uit volume At Boe prcgienees (2) collerrog| 7 ALL Celbilons de net ututt La chowieak Juadiion . The Citlition ukion ing about the chemical aaction are eHbectne WUlitions « F There an 2 tmp baviien do a aoeliin , manned Ontrye orien & orientation bavue . ) Enengy booin Tht min amount of e sa mecst“potun in Olen ted bag hod each A coted Twurthotd enn - 2) dotentakicn Barvuey » Chemical Jerelion the an Shanthi ok su. Loe Te ce ane bond a pane eee for a bimolecular olemenkays reaélion A+8 —9 Zn Rok = Ze ee RT Zam > Clision prey q resckawkh & £8 7 eo elet pee 4 df, moleeles welh emurgies eink Ou . aoe a ey pwe Com Say that A salad ty catiiten Pry: To cceount for ebftelure CoUiroet , andther factor P cotted (avd ie ae ee facty da Ent dated . YH brekes inky oteount rasa Sauk te spy ta Se Rote > PZ pen VAT Nw & collisteny Scanned with CamScanner