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Organic Diwas
NOMENCLATURE
OF ALKANES,
ALKENES,
ALKYNES
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following structure?

A 2,2,5,5-Tetramethylhex-3-ene

B 2,2,5,5-Tetramethylhex-4-ene

C 2,2,5,5-Tetramethylhex-2-ene

D 2,2,5,5-methylhex-3-ene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following structure?

A 2,2,5,5-Tetramethylhex-3-ene

B 2,2,5,5-Tetramethylhex-4-ene

C 2,2,5,5-Tetramethylhex-2-ene

D 2,2,5,5-methylhex-3-ene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 3,3-diethenylpenta-1,2-diene B 3,3-diethenylpenta-1,4-diene

C 3,3-diethenylpenta-1,5-diene D 3,3-diethylhexa-1,4-diene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 3,3-diethenylpenta-1,2-diene B 3,3-diethenylpenta-1,4-diene

C 3,3-diethenylpenta-1,5-diene D 3,3-diethylhexa-1,4-diene
Most Expected Questions: IUPAC Nomenclature

The correct structure of


2,6-Dimethyl-dec-4-ene is:

A B

C D

NEET 2021
Most Expected Questions: IUPAC Nomenclature

The correct structure of


2,6-Dimethyl-dec-4-ene is:

A B

C D

NEET 2021
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the given compound ,


(CH3)3 CCH2 C(CH3)3

A 2, 3, 4, 4-tetramethylpentane

B 1, 2, 2, 4-tetramethylpentane

C 2, 2, 4, 4-tetramethylpentane

D 3, 3-dimethylpentane

AIIMS 2014
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the given compound ,


(CH3)3 CCH2 C(CH3)3

A 2, 3, 4, 4-tetramethylpentane

B 1, 2, 2, 4-tetramethylpentane

C 2, 2, 4, 4-tetramethylpentane

D 3, 3-dimethylpentane

AIIMS 2014
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

3-methyl-4-(3-methylprop- 3,5-dimethyl-1,4-propylhept-6-
A 1-enyl)-1-heptyne B en-1-yne

3-methyl-4-(1-methylprop- 3,5-dimethyl-4-propylhept-1-
C 2-ynyl)-1-heptene D en-6-yne
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

3-methyl-4-(3-methylprop- 3,5-dimethyl-1,4-propylhept-6-
A 1-enyl)-1-heptyne B en-1-yne

3-methyl-4-(1-methylprop- 3,5-dimethyl-4-propylhept-1-
C 2-ynyl)-1-heptene D en-6-yne
Most Expected Questions: IUPAC Nomenclature

The structure of isobutyl group in an organic


compound is

NEET 2013
Most Expected Questions: IUPAC Nomenclature

The structure of isobutyl group in an organic


compound is

A
● The structure of the isobutyl
group in the organic compound
is represented by the option C.
● When 2nd carbon of the chain B
has a methyl group attached to
it, it is called an iso group.
C

NEET 2013
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 5- Ethyl - 6 - methyloctane B 4- Ethyl - 3 - methyloctane

C 3- Ethyl - 4 - methyloctane D 2, 3 diethylheptane

2003
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 5- Ethyl - 6 - methyloctane B 4- Ethyl - 3 - methyloctane

C 3- Ethyl - 4 - methyloctane D 2, 3 diethylheptane

2003
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 1, 5 hexenyne B 1 - hexene - 5- yne

C 1 - hexyne - 5- ene D 1, 5 - hexynene

2002
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

Hex - 1 - en - 5 - yne or 1 - hexene - 5- yne

A 1, 5 hexenyne B 1 - hexene - 5- yne

C 1 - hexyne - 5- ene D 1, 5 - hexynene

2002
NOMENCLATURE
OF FUNCTIONAL
GROUPS
Most Expected Questions: IUPAC Nomenclature

The correct decreasing order of priority for the functional groups


of organic compounds in the IUPAC system of nomenclature is

D
Most Expected Questions: IUPAC Nomenclature

The correct decreasing order of priority for the functional groups


of organic compounds in the IUPAC system of nomenclature is

D
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A 5-formylhex-2-en-3-one B 5-methyl-4-oxohex-2-en-5-al

C 3-keto-2-methylhex-5-enal D 3-keto-2-methylhex-4-enal

NEET 2017
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

Aldehydes get higher


priority over ketone and
alkene in numbering of
principal carbon atom

A 5-formylhex-2-en-3-one B 5-methyl-4-oxohex-2-en-5-al

C 3-keto-2-methylhex-5-enal D 3-keto-2-methylhex-4-enal

NEET 2017
Most Expected Questions: IUPAC Nomenclature
Structure of the compound whose IUPAC name is
3 - ethyl - 2 -hydroxy- 4- methylhex - 3- en- 5- ynoic acid is :

D
NEET 2013
Most Expected Questions: IUPAC Nomenclature
Structure of the compound whose IUPAC name is
3 - ethyl - 2 -hydroxy- 4- methylhex - 3- en- 5- ynoic acid is :

3-ethyl-2-hydroxy-4-methylhex-3 C
-en-5-ynoic acid

D
NEET 2013
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A trans-2-chloro-3-iodo-2-pentene B cis-3-iodo-4-chloro-3-pentene

C trans-3-iodo-4-chloro-3-pentene D cis-2-chloro-3-iodo-2-pentene

1998, 2011
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

● The parent hydrocarbon contains 5 C atom continuous chain with one C=C
bond between second and third carbon atom.Hence, it is named as
2-pentene.
● One Cl and one I are present at second and third carbon atom respectively.
● The molecule has trans geometry across C=C bond.

A trans-2-chloro-3-iodo-2-pentene B cis-3-iodo-4-chloro-3-pentene

C trans-3-iodo-4-chloro-3-pentene D cis-2-chloro-3-iodo-2-pentene

1998, 2011
Most Expected Questions: IUPAC Nomenclature

The correct structure of 4-bromo-3-methyl


but-1-ene is

AIIMS 2008
Most Expected Questions: IUPAC Nomenclature

The correct structure of 4-bromo-3-methyl


but-1-ene is

AIIMS 2008
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 1-chloro-1-oxo-2, 3-dimethylpentane B 2-ethyl-3-methylbutanoyl chloride

C 2, 3-dimethyl pentanoyl chloride D 3, 4-dimethyl pentanoyl chloride

2006
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 1-chloro-1-oxo-2, 3-dimethylpentane B 2-ethyl-3-methylbutanoyl chloride

C 2, 3-dimethyl pentanoyl chloride D 3, 4-dimethyl pentanoyl chloride

2006
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound having the


formula CCl3 CH2 CHO is

A 2, 2, 2 - trichloropropanal

B 1, 1, 1 - trichloropropanal

C 3, 3, 3 - trichloropropanal

D 1, 2, 1 - trichloromethanal

AIIMS
1995, 2001
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound having the


formula CCl3 CH2 CHO is

A 2, 2, 2 - trichloropropanal

B 1, 1, 1 - trichloropropanal

3, 3, 3 - trichloropropanal
C 3, 3, 3 - trichloropropanal

D 1, 2, 1 - trichloromethanal

AIIMS
1995, 2001
Most Expected Questions: IUPAC Nomenclature

The incorrect IUPAC name is

2001
Most Expected Questions: IUPAC Nomenclature

The incorrect IUPAC name is

2001
Most Expected Questions: IUPAC Nomenclature

The - C - group should get priority over methyl group


∴ Correct IUPAC name is
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

4-hydroxy-4-pentenoic
A acid
B 4-hydroxy-3-pentenoic acid

4-hydroxy-4-methyl -
C hydroxy pentenoic acid D 3-ene-pentanoic acid

AIIMS 1998
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

4-hydroxy-4-pentenoic
A acid
B 4-hydroxy-3-pentenoic acid

4-hydroxy-4-methyl -
C hydroxy pentenoic acid D 3-ene-pentanoic acid

AIIMS 1998
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 3- amino - 5 - heptenoic acid B 𝛃 - amino - ઠ - heptenoic acid

5 - amino - hex - 2 -
C 5 - amino - 2- heptenoic acid D enecarboxylic acid

1995
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

As —COOH group is
highest priority group, it
is numbered one. So, the
IUPAC name is
3-amino-5- heptenoic
acid.

A 3- amino - 5 - heptenoic acid B 𝛃 - amino - ઠ - heptenoic acid

5 - amino - hex - 2 -
C 5 - amino - 2- heptenoic acid D enecarboxylic acid

1995
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

4,4 - dimethyl 2-methyl-3-hydroxypentan-5


A -3-hydroxybutanoic acid
B -oic acid

3- hydroxy -4- 4-methyl-3-hydroxypentanoic


C methylpentanoic acid
D acid
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

4,4 - dimethyl 2-methyl-3-hydroxypentan-5


A -3-hydroxybutanoic acid
B -oic acid

3- hydroxy -4- 4-methyl-3-hydroxypentanoic


C methylpentanoic acid
D acid
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

3-Hydroxycyclohex-4 5-Hydroxycyclohex-3-
A B en-1-one
-en-1-one
5-Ketocyclohex-2-
C D 3-Ketocyclohex-5-enol
enol
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

3-Hydroxycyclohex-4 5-Hydroxycyclohex-3-
A B en-1-one
-en-1-one
5-Ketocyclohex-2-
C D 3-Ketocyclohex-5-enol
enol
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-methoxy-6-nitrocyclohexene

B 3-nitro-1-methoxycyclohex-4-ene

C 5-methoxy-3-nitrocyclohexene

D 3-nitro-5-methoxycyclohexene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-methoxy-6-nitrocyclohexene

B 3-nitro-1-methoxycyclohex-4-ene

C 5-methoxy-3-nitrocyclohexene

D 3-nitro-5-methoxycyclohexene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

N, N-dimethyl cyclopropane
A carboxamide

B N-methylcyclopropanamide

C Cyclopropionamide

D None of the above


Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

N, N-dimethyl cyclopropane
A carboxamide

B N-methylcyclopropanamide

C Cyclopropionamide

D None of the above


Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-cyano-4-methyl-2-oxopentane

B 2-cyano-2-methyl-4-oxopentane

C 2,2-dimethyl-4-oxo-pentanenitrile

D 4-cyano-4-methyl-2-pentanone.
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-cyano-4-methyl-2-oxopentane

B 2-cyano-2-methyl-4-oxopentane

C 2,2-dimethyl-4-oxo-pentanenitrile

D 4-cyano-4-methyl-2-pentanone.
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 1,2,3-propane tricarboxylic acid

B 3-hydroxy-1,5-pentanedioic acid

3-hydroxy-3-keto-1,5-pentane
C dioic acid

1,3,5-trihydroxypentane-1,5-
D dione
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 1,2,3-propane tricarboxylic acid

B 3-hydroxy-1,5-pentanedioic acid

3-hydroxy-3-keto-1,5-pentane
C dioic acid

1,3,5-trihydroxypentane-1,5-
D dione
NOMENCLATURE
OF AROMATIC
COMPOUNDS
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A 1-Chloro-2-phenylethene

B 2-Chloro-1-phenylethene

C 1-Chloro-2-benzylethene

D 1-Chloro-1-benzylethene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A 1-Chloro-2-phenylethene

B 2-Chloro-1-phenylethene

C 1-Chloro-2-benzylethene

D 1-Chloro-1-benzylethene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A 1-Phenylprop-2-yne

B 3-Phenylprop-1-yne

C Prop-1-yne-3-Phenyl

D 3-Phenylprop-1-ene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A 1-Phenylprop-2-yne

B 3-Phenylprop-1-yne

C Prop-1-yne-3-Phenyl

D 3-Phenylprop-1-ene
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

2-methoxy-4- 3-bromo-6-nitro-1-
A bromonitrobenzene
B methoxybenzene
3-methoxy-4- 5-bromo-2-nitro-1-
C nitrobromobenzene D methoxybenzene
AIIMS 2018
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

2-methoxy-4- 3-bromo-6-nitro-1-
A bromonitrobenzene
B methoxybenzene
3-methoxy-4- 5-bromo-2-nitro-1-
C nitrobromobenzene D methoxybenzene
AIIMS 2018
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A Methyl 3-hydroxybenzoate

B Methyl 5-hydroxybenzoate

C Methyl 3-phenolbenzoate

D 3-hydroxy-1-methyl benzoate
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the compound is:

A Methyl 3-hydroxybenzoate

B Methyl 5-hydroxybenzoate

C Methyl 3-phenolbenzoate

D 3-hydroxy-1-methyl benzoate
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-bromo-3-cyanophenol B 2-bromo-5-hydroxybenzonitrile

2-cyano-4-
C hydroxybromobenzene D 6-bromo-3-hydroxybenzonitrile
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 4-bromo-3-cyanophenol B 2-bromo-5-hydroxybenzonitrile

2-cyano-4-
C hydroxybromobenzene D 6-bromo-3-hydroxybenzonitrile
Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 6- Amino- 4 – Hydroxybenzoic acid

B 3- Amino- 4 – carboxyphenol

C 2- Carboxy- 5 – Hydroxyaniline

D 2- Amino- 4 – Hydroxybenzoic acid


Most Expected Questions: IUPAC Nomenclature

The IUPAC name of the following compound is

A 6- Amino- 4 – Hydroxybenzoic acid

B 3- Amino- 4 – carboxyphenol

C 2- Carboxy- 5 – Hydroxyaniline

D 2- Amino- 4 – Hydroxybenzoic acid


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