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Assignment

Write the correct order of acidic strength of following compounds:

(a) CH4 (b) NH3 (c) H2O (d) H–F


Write the correct order of acidic strength of following compounds:

(a) CH4 (b) NH3 (c) H2O (d) H–F

Ans : d > c > b > a


Solution :
Write the correct order of acidic strength of following compounds:

(a) CH3–CH2–O–H (b) (c)


Write the correct order of acidic strength of following compounds:

(a) CH3–CH2–O–H (b) (c)

Ans : a > b > c


Solution :
Write the correct order of acidic strength of following compounds:

(a) F–CH2–CH2–O–H (b) NO2–CH2–CH2–O–H



(c) Br–CH2–CH2–O–H (d) NH3– CH2 –CH2 –O– H
Write the correct order of acidic strength of following compounds:

(a) F–CH2–CH2–O–H (b) NO2–CH2–CH2–O–H



(c) Br–CH2–CH2–O–H (d) NH3– CH2 –CH2 –O– H

Ans : d > b > a > c


Solution :


Write the correct order of acidic strength of following compounds:
Write the correct order of acidic strength of following compounds:

Ans : c > b > a


Solution :
Write correct order of acidic strength of following compounds:
Write correct order of acidic strength of following compounds:

Ans : a > b > c


Solution :
Write correct order of acidic strength of following compounds:
Write correct order of acidic strength of following compounds:

Ans : a > b > c


Solution :
Write correct order of acidic strength of following compounds:
Write correct order of acidic strength of following compounds:

Ans : c > a > b


Solution :
Select the strongest acid in each of the following sets :
Select the strongest acid in each of the following sets :

Ans : a
Solution :
Which one of the following is the most acidic?

A B

C D CH2=CH–CH3
Which one of the following is the most acidic?

A B

C D CH2=CH–CH3
Solution :
Which one of the following phenols will show highest acidity?

A B

C D
Which one of the following phenols will show highest acidity?

A B

C D
Solution :
Consider the following compound

A B

C D

Which of the above compounds reacts with NaHCO3 giving CO2


Consider the following compound

A B

C D

Which of the above compounds reacts with NaHCO3 giving CO2


Solution :
Compound which are stronger acid than H2CO3 gives CO2 with
NaHCO3.
⟶Compound (A), (B), (C), (D) all are stronger acid than H2CO3.
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : a > b > c > d


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : a > b > c> d


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : (ii) c > a > b


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : b > c > a


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : c > d > b > a


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : c > b > a


Solution :
Write increasing order of basic strength of following:
Write increasing order of basic strength of following:

Ans : b > a
Solution :
Select the strongest base in following compound :
Select the strongest base in following compound :

Ans : b
Solution :
In compound (b), N atom is sp3 hybridised, and l.p. of
nitrogen is localised.
Consider the basicity of the following aromatic
amines:
(I) aniline (II) p-nitroaniline
(III) p-methoxyaniline (IV) p-methylaniline
The correct order of decreasing basicity is:

A III > IV > I > II B III > IV > II > I

C I > II > III > IV D IV > III > II > I


Consider the basicity of the following aromatic
amines:
(I) aniline (II) p-nitroaniline
(III) p-methoxyaniline (IV) p-methylaniline
The correct order of decreasing basicity is:

A III > IV > I > II B III > IV > II > I

C I > II > III > IV D IV > III > II > I


Solution :
Which one of the following is least basic in character?

A B

C D
Which one of the following is least basic in character?

A B

C D
Solution :

This lone pair very much delocalised because of getting Aromaticity


so do not donate lone pair so it is least basic.
Arrange the basic strength of the following compounds.
Arrange the basic strength of the following compounds.

Ans : 1 < 2 < 3;


Solution :
Arrange the basic strength of the following compounds.
Arrange the basic strength of the following compounds.

Ans : 3 < 1 < 2


Solution :
Arrange the basic strength of the following compounds.
Arrange the basic strength of the following compounds.

Ans : 2 < 1 < 3;


Solution :
The IUPAC name for the following compound is

A 2-propylhex-1-ene

B 2-butylpent-1-ene

C 2-propyl-2- butylethene

D Propy1-1-butylethene
The IUPAC name for the following compound is

A 2-propylhex-1-ene

B 2-butylpent-1-ene

C 2-propyl-2- butylethene

D Propy1-1-butylethene
Solution :
Among the following compounds

2, 3- dimethylhexane is

A i

B ii

C iii

D iv
Among the following compounds

2, 3- dimethylhexane is

A i

B ii

C iii

D iv
Solution :
IUPAC name of the following compound is -

A 1-hydroxycyclohex-4-en-3-one

B 1-hydroxycyclohex-3-en-5-one

C 3-hydroxycyclohex-5-en-1-one

D 5-hydroxycyclohex-2-en-1-one
IUPAC name of the following compound is -

A 1-hydroxycyclohex-4-en-3-one

B 1-hydroxycyclohex-3-en-5-one

C 3-hydroxycyclohex-5-en-1-one

D 5-hydroxycyclohex-2-en-1-one
Solution :
The IUPAC name of is

A Tris(chloromethyl) methane

B 1, 3-Dichloro-2
(chloromethyl) propane
C 1-Chlorobis(chloromethyl)
ethane

D none of these
The IUPAC name of is

A Tris(chloromethyl) methane

B 1, 3-Dichloro-2
(chloromethyl) propane
C 1-Chlorobis(chloromethyl)
ethane

D none of these
The IUPAC name of

is

A 3, 5, 5-Trimethylhexane-2,
4-diol
B 2, 2, 4-Trimethylhexane-3,
5-diol
C 1, 2, 4,
4-Tetramethylpentane-1,
3-diol
D 2, 2, 4,
5-Tetramethylpentane-
3, 5-diol
The IUPAC name of

is

A 3, 5, 5-Trimethylhexane-2,
4-diol
B 2, 2, 4-Trimethylhexane-3,
5-diol
C 1, 2, 4,
4-Tetramethylpantane-1,
3-diol
D 2, 2, 4,
5-Tetramethylpantane
-3, 5-diol
The IUPAC name of

is

A 2, 3-Dihydroxybutane-1,
4-carboxylic acid
B 2, 3-Dihydroxybutane-1,
4-dioic acid
C 1, 2-Dihydroxyethane
dicarboxylic acid

D none of these
The IUPAC name of

is

A 2, 3-Dihydroxybutane-1,
4-carboxylic acid
B 2, 3-Dihydroxybutane-1,
4-dioic acid
C 1, 2-Dihydroxyethane
dicarboxylic acid

D none of these
The IUPAC name of is

A 3-Carboxy-3-hydroxypentan
edicarboxylic acid
B 2-Hydroxypropane-1, 2,
3-tricarboxylic acid
C 2-Hydroxypropane-1, 2,
3-trioic acid

D 3-Hydroxypropane-1, 2,
3-tricarboxylic acid
The IUPAC name of is

A 3-Carboxy-3-hydroxypentan
edicarboxylic acid
B 2-Hydroxypropane-1, 2,
3-tricarboxylic acid
C 2-Hydroxypropane-1, 2,
3-trioic acid

D 3-Hydroxypropane-1, 2,
3-tricarboxylic acid
The IUPAC name of
is

A (N-Bromo)-2-keto-3-methyl
butanamide
B (N-Bromo)-2-keto-4-methyl
butanamide
C (N-Bromo)-1,
2-diketo-3-methylbutana
mine carboxamide
D (N-Bromo)-1-keto-2-m
ethylpropane
The IUPAC name of
is

A (N-Bromo)-2-keto-3-methyl
butanamide
B (N-Bromo)-2-keto-4-methyl
butanamide
C (N-Bromo)-1,
2-diketo-3-methylbutana
mine carboxamide
D (N-Bromo)-1-keto-2-m
ethylpropane
The IUPAC name of
is

A 2-(Bromomethyl)-3-oxopent
ane carboxamide
B 1-Bromo-2-carbamoylpenta
n-3-one
C 5-Bromo-4-carbamoylpen
tan-3-one

D 2-(Bromomethyl)-3-ox
opentanamide
The IUPAC name of
is

A 2-(Bromomethyl)-3-oxopent
ane carboxamide
B 1-Bromo-2-carbamoylpenta
n-3-one
C 5-Bromo-4-carbamoylpen
tan-3-one

D 2-(Bromomethyl)-3-ox
opentanamide
The IUPAC name of CH3—CO—CH—CH2—CHCl is
|
CH3

A 1-Chloro-3-methylpentan-4-
on
B 1-Chloro-2-(oxoethylbutane)

C 5-Chloro-3-methylpentan-
2-one

D 3-(2-Chloroethyl)butan
-2-one
The IUPAC name of CH3—CO—CH—CH2—CHCl is
|
CH3

A 1-Chloro-3-methylpentan-4-
on
B 1-Chloro-2-(oxoethylbutane)

C 5-Chloro-3-methylpentan-
2-one

D 3-(2-Chloroethyl)butan
-2-one
The IUPAC name of
is

A 2-Hydroxypentan-4-one

B 4-Hydroxypentan-2-one

C 4-oxopentan-2-ol

D 2-oxopentan-4-ol
The IUPAC name of
is

A 2-Hydroxypentan-4-one

B 4-Hydroxypentan-2-one

C 4-oxopentan-2-ol

D 2-oxopentan-4-ol
The IUPAC name of is

A N, N-Dimethyl aminobenzene

B N, N-Dimethyl benzenamine

C (a) and (b) both are correct

D none of these
The IUPAC name of is

A N, N-Dimethyl aminobenzene

B N, N-Dimethyl benzenamine

C (a) and (b) both are correct

D none of these
The IUPAC name of is

A 2, 6-Dimethylhepta-2,
5-dienoic acid
B 3, 7-Dimethylhepta-2,
5-dienoic acid
C 1-Hydroxy-2,
6-dimethylhepta-2, 5-dienone

D none of these
The IUPAC name of is

A 2, 6-Dimethylhepta-2,
5-dienoic acid
B 3, 7-Dimethylhepta-2,
5-dienoic acid
C 1-Hydroxy-2,
6-dimethylhepta-2, 5-dienone

D none of these
The IUPAC name of is

A 2-Carboxyphenol

B 2-Hydroxybenzoic acid

C 1-Carboxy-2-hydroxybenzene

D 2-Carboxy-1-hydroxybenzene
The IUPAC name of is

A 2-Carboxyphenol

B 2-Hydroxybenzoic acid

C 1-Carboxy-2-hydroxybenzene

D 2-Carboxy-1-hydroxybenzene
The IUPAC name of the following
compound is :

A 4-Bromo-3-cyanophenol

B 2-Bromo-5-hydroxybenzonitrile

C 2-Cyano-4-hydroxybromobenzene

D 6-Bromo-3-hydroxybenzonitrile
The IUPAC name of the following
compound is :

A 4-Bromo-3-cyanophenol

B 2-Bromo-5-hydroxybenzonitrile

C 2-Cyano-4-hydroxybromobenzene

D 6-Bromo-3-hydroxybenzonitrile
How many total number of substituents
are present in the following compound ?

A 3

B 4

C 5

D 6
How many total number of substituents
are present in the following compound ?

A 3

B 4

C 5

D 6
Correct IUPAC name :

A 1-methyl-3-ethylcyclohexene

B 5-ethyl-1-methylcyclohexene

C 2-ethyl-4-methylcyclohexene

D 3-ethyl-1-methylcyclohexene
Correct IUPAC name :

A 1-methyl-3-ethylcyclohexene

B 5-ethyl-1-methylcyclohexene

C 2-ethyl-4-methylcyclohexene

D 3-ethyl-1-methylcyclohexene
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer : cyclohexane-1,3,5-triol
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer :
3,5-dibromo-2-chloro-4-ethenylcyclohexanol
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer :
cyclopropylmethyl cyclobutanecarboxylate
IUPAC name of the following compounds
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer :
2-(2-methylcyclobut-1-enyl)ethanal
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer :
5-cyclohexyl-6-hydroxy-5-methylhex-3-en-1-oic acid
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer :
2-bromo-6-chloro-3-methylidene-cyclohexanol
IUPAC name of the following compounds
IUPAC name of the following compounds

Answer : cyclohexanecarboxamide
Give the IUPAC name of the following compounds :
Give the IUPAC name of the following compounds :

Answer :

1,2,7-trimethylcyclopentadecane
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