NEET MADE EJEE Complete Handwritten Formulae Chemistry NEET and

CHEMISTRY
FORMULAE
REVISION
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Complete Formulae Revision
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MOLE
CONCEPT
FORMULAE
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MOLE CONCEPT FORMULAE
Average molar mass

of gaseous mixture
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Percentage yield
Percentage purity
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Concentration Terms
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Concentration Terms
Molarity
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Concentration Terms
Molality
Mole fraction
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Relation b/w molality

and mole fraction
Relation b/w molality

and molarity
ppm of solute
ppb of solute
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REDOX REACTIONS FORMULAE
Calculations of n-factor
For Ions: nf = |charge|
For salts: LCM of charge present on cation and anion
For Acids: nf = Basicity = No. of H+ ions an acid donates
For Bases: nf = Acidity
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Given Mass
____________
No of moles(n) =
Molar Mass
Given Mass
_____________
No of g.eq =
Equivalent Mass
Given Mass
_____________
No of g.eq =
Molar Mass/nf
No of g.eq = no. of moles x nf

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Normality
Relation b/w N and M N = M x n-factor
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Volume strength of H2O2
Volume strength of H2O2

MH2O2 = ________________________
11.2
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ATOMIC
STRUCTURE
FORMULAE
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ATOMIC STRUCTURE FORMULAE
Planck’s Quantum Theory
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Photoelectric effect
Ei = φ + (K.E)max
K.E
h𝝂 = h𝝂0 + (K.E)max
𝝂
h𝝂0
Slope = h
(K.E)max = h𝝂 - h𝝂0
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Photoelectric effect
(K.E)max = h𝝂 - h𝝂0 eV0 = h𝝂 - h𝝂0
Slope = h/e
Slope = h
K.E
V0
𝝂 𝝂
h𝝂0
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Radius of nth Bohr orbit
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Velocity of nth Bohr orbit
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Energy of e- in Bohr orbit
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De-Broglie’s hypothesis
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Heisenberg’s Uncertainty Principle
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Angular nodes Radial nodes
Angular node = l Radial node = (n-l-1)
Orbital angular momentum Spin angular momentum
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● No. of subshells in a given shell = n
● No. of orbitals in a given shell = n2
● Max no. of electrons in a shell = 2n2
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STATES OF
MATTER
FORMULAE
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STATES OF MATTER FORMULAE
Gas Laws
● Boyle’s Law: V𝝰 1/P ● Charles’s Law: V𝝰 T
● Gay Lussac’s Law: P𝝰 T
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● Ideal Gas Equation: PV = nRT
● Density form of Ideal Gas Equation: d = PM/RT
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P = constant
V 1 n 1 T1
=
P1 V 1 = n 1 P 1 n 1 T1
V 2 n 2 T2 =
P2 V 2 n 2 T= ant P 2 n 2 T2
co s t
nsta con
nt =
V
P1 V 1 T 1 n = constant P 1 V 1 n 1 T1 P & n = constant V1 = T 1

= =
P2 V 2 T 2 P 2 V 2 n 2 T2 P& V2 T 2
t V=
s tan con
on s
=c tan
V &n t
T & n = constant
P1 T 1 n 1 T1 = n 2 T2
= P1 V 1 = P 2 V 2
P2 T 2
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Dalton’s Law of Partial Pressures:
● Total pressure = P1 + P2 + P3 + …
● Partial pressure = mole fraction x total pressure
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Graham’s Law of Effusion & Diffusion
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Kinetic Gas Equation
For 1 mol of ideal gas
PV = ⅓ MVrms2
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MOLECULAR
SPEEDS
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Compressibility Van der Waals

Factor Gas Equation
Z<1 Attractive forces
Z>1 Repulsive forces
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THERMO-
DYNAMICS
FORMULAE
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THERMODYNAMICS FORMULAE
Thermodynamics Processes
● Isothermal Process: T = constant
● Isochoric Process: V = constant
● Isobaric Process: P = constant
● Adiabatic Process: q = 0 (heat exchange with surroundings = 0)
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IUPAC sign convention about heat and work
1. Work done on the system = Positive
2. Work done by the system = Negative
First Law of Thermodynamics: ΔU = q + w
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Calculation of heat
➢ Total heat capacity ➢ Molar heat capacity
➢ Specific heat capacity (s)
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Work done (W)
➢ Isobaric process: W = -Pext (V2 - V1)
➢ Isochoric process: Since 𝝙V = 0, therefore W = -Pext .𝝙V = 0
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● Work done (W) Adiabatic Process
Reversible Adiabatic Process Irreversible Adiabatic Process
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Calculation of final temp. Adiabatic Process
T1V1𝛄-1 = T2V2𝛄-1 ΔU = W = nCv (T2-T1)

= -Pext(V2-V1)
P11-𝛄 T1𝛄 = P21-𝛄 T2𝛄 T2-T1 = P (T /P -T /P )
ext 1 1 2 2
𝛄-1
Reversible process Irreversible process
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➢ Enthalpy (state function and extensive property)

𝝙H = 𝝙U + P𝝙V
➢ Relation between enthalpy and internal energy
𝝙H = 𝝙U + 𝝙ng RT
➢ Only for ideal gas: Cp - Cv = R
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➢ Entropy (S)
➢ Entropy calculation for an ideal gas undergoing expansion/compression
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➢ Gibbs Free Energy (state function and an extensive property)
𝝙G = 𝝙H - T𝝙S [Gibbs Helmholtz Equation]
● Criteria for spontaneity
● If 𝝙G is < 0; process is spontaneous

● If 𝝙G is > 0; process is non spontaneous
● If 𝝙G is = 0; system is at equilibrium
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EQUILIBRIU
M FORMULAE
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CHEMICAL EQUILIBRIUM FORMULAE
● Equilibrium Constant (K)
● Equilibrium Constant ● Equilibrium Constant in terms of

in terms of conc. (Kc) partial pressure (Kp)
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CHEMICAL EQUILIBRIUM FORMULAE
● Relation between Kp and Kc: Kp = Kc(RT)Δn
● Reaction Quotient
● Degree of dissociation (𝛂)
𝛂 = no. of moles dissociated /initial no. of moles taken
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IONIC EQUILIBRIUM FORMULAE
➢ Ostwald’s Dilution Law:
● Dissociation constant of weak acid
● For weak base
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➢ Ionic Product of water:
● Kw = [H+] [OH-] → Valid at all temperature
● Kw = [H+] [OH-] = 10-14 → Valid at 25℃
● -log Kw = -log [H+] + (-log [OH-]) = 14
● pKw = pH + pOH = 14
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Acidity and pH scale
➢ pH = -log [H+]; [H+] = 10-pH
➢ pOH = -log [OH-]; [OH-] = 10-pOH
➢ pKa = -log Ka; Ka = 10-pKa
➢ pKb = -log Kb; Kb = 10-pKb
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Salt hydrolysis
Strong Acid +
Weak Base
Strong Base +
Weak Acid
Weak Acid +
Weak Base
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Buffer Solutions
● Acidic Buffer
● Basic Buffer
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Solubility Product
Ksp = (xS)x . (yS)y = xx . yy . (S)x+y
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SOLID
STATE
FORMULAE
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SOLID STATE FORMULAE
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Property SC BCC FCC
Atomic radius (r) a/2 √3a/4 a/2√2
No. of atoms per unit cell (Z) 1 2 4
C.N. 6 8 12
Packing efficiency 52% 68% 74%
No. of voids
(a) Octahedral (Z) 4
(b) Tetrahedral (2Z) 8
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Density of unit cell
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Examples of ionic crystals
● NaCl : Coordination number (6:6)
● CsCl : Coordination number (8:8)
● Zinc blende (ZnS): Coordination number (4:4)
● Fluorite structure (CaF2): Coordination number (8:4)
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SOLUTIONS
FORMULAE
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SOLUTIONS FORMULAE
Henry’s Law
P = KH𝛘
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SOLUTIONS FORMULAE
Raoult’s Law (for volatile solutes)
PA = PAo 𝛘A
PB = PBo 𝛘B
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SOLUTIONS FORMULAE
Relative lowering of vapour pressure
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SOLUTIONS FORMULAE
Elevation in Boiling Point Depression in Freezing Point
Osmotic Pressure
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SOLUTIONS FORMULAE
Van’t Hoff factor
● In case of dissociation: i = 1 + (n-1)𝛂

● In case of association: i = 1 + (1/n-1)𝛂
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ELECTRO-
CHEMISTRY
FORMULAE
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ELECTROCHEMISTRY FORMULAE
Standard EMF
Eocell = Eocathode - Eoanode
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Nernst Equation: At 298 K
Nernst Equation: At equilibrium
=0
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Gibbs Free Energy Change
ΔGo = -nFEocell
ΔGo = -2.303 RT log Kc
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For an electrode M(s)/Mn+
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Concentration cell
Electrolyte concentration cell:
Electrode concentration cell:
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Faraday’s Law of Electrolysis
First Law
w=ZxIxt=ZxQ
Second Law
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Resistance Resistivity Conductance
Conductivity Molar Equivalent

Conductivity Conductivity
Λm
Relation b/w molar conductivity & Λm = Λeq x nf

equivalent conductivity
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Kohlrausch’s Law
(where, ΛoA+ and ΛoB- are the limiting molar

conductivity of the cation and anion respectively)
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CHEMICAL
KINETICS
FORMULAE
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CHEMICAL KINETICS FORMULAE
➢ Rate of reaction
➢ For a reaction, aA + bB → cC + dD
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➢ Instantaneous Rate
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➢ Order of Reaction and Rate law expression
For a reaction, aP + bQ → Products
Then, Rate ∝ [P]m [Q]n
Rate = k [P]m [Q]n
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➢ Units of Rate Constant: For nth order reaction
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Zero order reaction First order reaction
Integrated Rate Equation Integrated Rate Equation
Half life Half life
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First order reaction
Time taken to complete 75% of first order reaction (t75%): 2 x t1/2
Time taken to complete 87.5% of first order reaction (t87.5%): 3 x t1/2
Time taken to complete 99.9% of first order reaction (t99.9%): 10 x t1/2
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Arrhenius equation
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Dropper to Doctor
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NEET MADE EJEE Complete Handwritten Formulae Chemistry NEET and

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CHEMISTRY

Average molar mass

Relation b/w molality

Relation b/w molality

For Ions: nf = |charge|

For salts: LCM of charge present on cation and anion

For Acids: nf = Basicity = No. of H+ ions an acid donates

For Bases: nf = Acidity

No of g.eq = no. of moles x nf

Relation b/w N and M N = M x n-factor

Volume strength of H2O2

Volume strength of H2O2

Planck’s Quantum Theory

(K.E)max = h𝝂 - h𝝂0 eV0 = h𝝂 - h𝝂0

Radius of nth Bohr orbit

Velocity of nth Bohr orbit

Energy of e- in Bohr orbit

Heisenberg’s Uncertainty Principle

Angular nodes Radial nodes

Angular node = l Radial node = (n-l-1)

Orbital angular momentum Spin angular momentum

● No. of subshells in a given shell = n

● No. of orbitals in a given shell = n2

● Max no. of electrons in a shell = 2n2

● Boyle’s Law: V𝝰 1/P ● Charles’s Law: V𝝰 T

● Gay Lussac’s Law: P𝝰 T

● Ideal Gas Equation: PV = nRT

● Density form of Ideal Gas Equation: d = PM/RT

P1 V 1 T 1 n = constant P 1 V 1 n 1 T1 P & n = constant V1 = T 1

Dalton’s Law of Partial Pressures:

● Partial pressure = mole fraction x total pressure

Graham’s Law of Effusion & Diffusion

Kinetic Gas Equation

For 1 mol of ideal gas

Compressibility Van der Waals

Z<1 Attractive forces

Z>1 Repulsive forces

● Isothermal Process: T = constant

● Isochoric Process: V = constant

● Isobaric Process: P = constant

● Adiabatic Process: q = 0 (heat exchange with surroundings = 0)

IUPAC sign convention about heat and work

1. Work done on the system = Positive

2. Work done by the system = Negative

First Law of Thermodynamics: ΔU = q + w

➢ Total heat capacity ➢ Molar heat capacity

➢ Specific heat capacity (s)

Work done (W)

➢ Isobaric process: W = -Pext (V2 - V1)

➢ Isochoric process: Since 𝝙V = 0, therefore W = -Pext .𝝙V = 0

● Work done (W) Adiabatic Process

Reversible Adiabatic Process Irreversible Adiabatic Process

Calculation of final temp. Adiabatic Process

T1V1𝛄-1 = T2V2𝛄-1 ΔU = W = nCv (T2-T1)

➢ Enthalpy (state function and extensive property)

➢ Relation between enthalpy and internal energy

➢ Only for ideal gas: Cp - Cv = R

➢ Entropy calculation for an ideal gas undergoing expansion/compression

➢ Gibbs Free Energy (state function and an extensive property)

𝝙G = 𝝙H - T𝝙S [Gibbs Helmholtz Equation]

● Criteria for spontaneity

● If 𝝙G is < 0; process is spontaneous

● Equilibrium Constant (K)