Mock Test-Cbse-C-Xii-Set-2-Che

FIITJEE
MOCK TEST
for XII Board  CBSE (Term – 2)
SET  II
CHEMISTRY
Maximum Marks: 35 Time: 2 Hours
GENERAL INSTRUCTIONS: Read the following instructions carefully.

1. There are 12 questions in this question paper with internal choice.
2. SECTION A - Q. No. 1 to 3 are very short answer questions carrying 2 marks each.
3. SECTION B - Q. No. 4 to 11 are short answer questions carrying 3 marks each.
4. SECTION C- Q. No. 12 is case based question carrying 5 marks.
5. All questions are compulsory. 6. Use of log tables and calculators is not allowed
SECTION – A
1. (i) Why does the rate of a chemical reaction change by changing temperature?
1
(ii) The graph of log k versus of a reaction is given below.
T
log K
1/T(K-1)
k is the rate constant of the reaction at temperature TK. If the slope of the line is -1.5
K, what is it’s activation energy?
2. One litre solution of 0.8 M CuSO4 was electrolysed with inert electrodes by passing
1 Faraday electricity. What will be the concentration of the solution after electrolysis?
[Assume that no loss of water takes place during electrolysis]
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MOCK TEST-CBSE-TERM-2-SET-II-(C-XII)-CHEMISTRY-2
3. An heterogeneous catalysed reaction is given below

Ni
C2H4  g  H2  g    C2H6  g
In this reaction, adsorption of both C2H4 and H2 gases takes place on the surface of
nickel(Ni) catalyst
(i) Identify the adsorbate and adsorbent involved in the adsorption process.
(ii) How does the rate of reaction increases due to adsorption?
OR
An organic compound(P) undergoes aldol condensation reaction with dilute NaOH to
form product(Q). (P) forms a tertiary alcohol(R) when react with CH3MgBr followed by
hydrolysis. Reaction of (P) with I2/NaOH forms a yellow precipitate and sodium salt of
ethanoic acid
(a) What is the IUPAC name of (P)?
(b) What is the structure of (R)?
SECTION – B
4. Write the electronic configurations of the ions given below and arrange them in
decreasing order of their spin magnetic moment
Fe+, Fe2+, Fe3+
NH2 CH2NH2
5. (i) Which out of and is more basic? Why?
(ii) Why metals form stable carbonyls with lower oxidation states?
(iii) Write the products of the following reaction.
MnO2  KOH  O2 
6. Zn(s) | Zn2+(0.01 M) || Ag+(C M) | Ag(s)

(i) Write the cell reaction of above electrochemical cell
o
(ii) Under which condition(s), ECell  ECell
(iii) If the EoCell of above reaction is 1.52 V, what will be the value of standard free energy
change(Go) of above electrochemical cell?
7. O
CH3 - C - CH2 - CH3

1 2 3
In above compound, the carbon atoms are numbered with 1, 2 and 3 leaving the
group C O
functional
(i) Which carbon atom holds the most acidic hydrogen?
(ii) Which product is formed when the compound reacts with Zn – Hg/Conc.HCl?
(iii) Mention the isomers of the above compound.
8. Which charged colloids are formed in following activities?

(i) Addition of KI into AgNO3 solution
(ii) Addition of AgNO3 into KI solution
(iii) Addition of FeCl3 to hot water
9. Mention the reactions taking place in the following transformation.

NO 2
(i)
N=N OH
NH2 NO 2
(ii)
CH3 NH2
(iii)
10. Give reasons

(a) The pink colour of KMnO4 decolourises by adding a mixture of oxalic acid(H2C2O4)
and sulphuric acid.
(b) [Fe(H2O)6]3+ is a high spin complex and [Fe(CN)6]3– is a low spin complex.
(c) Yellow solution of Na2CrO4 changes to orange if H+ ions are added to it.
OR
Dissociation of AB(g) into A and B gases takes place on a metal surface. It is observed
that the concentration of AB remains constant through out the reaction
AB  g    A  g  B  g 
The partial pressure of AB is 100 mm of Hg before the reaction. After 20 seconds, the
total pressure in the container became 150 mm of Hg.
(i) What is the half-life of the reaction?
(ii) What is the rate of reaction after 20 seconds.
(iii) What is the unit of rate constant.
11. Reaction of CH3COOH with Ca(OH)2 produces compound(P). Upon heating (P) forms an
organic compound(Q). Reaction of (Q) with PCl5 forms (R).
(i) Which unknown compound on hydrolysis forms a ketone?
(ii) Which compound is formed when (Q) is treated with LiAlH4
(iii) Which unknown compound is called a salt?
OR
The conductivity of 1.5 M of an aqueous electrolyte solution is 0.36 ohm–1cm–1, The
degree of dissociation of the electrolyte is 0.2, what will be the degree of dissociation if
the solution is diluted to ten times of it’s original volume?
SECTION – C
12. Potential
energy in
-1 AB
kJ mol
A2 + B2
Reaction coordinate
The energy profile of the reaction A 2  g   B 2  g  

 2AB  g is given above.
Answer the following questions
(i) Reactants A2 and B2 have different kinetic energies. But in the diagram same energy
is assigned to both. Why?
(ii) What is the activated complex in a reaction?
(iii) What type of reaction is it? Why?(Exothermic or endothermic)
(iv) What is activation energy?
OR
What is the structure of the intermediate?
FIITJEE
MOCK TEST
for XII Board  CBSE (Term – 2)
SET  II
CHEMISTRY
HINTS & SOLUTION
1. (i) The kinetic energy of the reactants change by changing temperature. So the rate
changes
Ea
(ii) Slope 
2.303R
Ea
or,  1.5 
2.303  8.314
 Ea = 28.72 Joule
2. Moles of CuSO4 = 0.8

1F electricity deposits 1 eq or ½ mole of Cu = 0.5 mole of Cu
 Moles of CuSO4 after electrolysis = 0.8 - 0.5 = 0.3 mole
 Concentration = 0.3 M
3. (i) Adsorbate = H2, C2H4, adsorbent = Nickel

(ii) Due to heat of adsorption
OR
Propanone
(a) P = CH3COCH3
OH O
Q = H3C CCH2 C CH3
CH3
(b) R = (CH3)3COH
4. Magnetic moment order: Fe+ = Fe3+ > Fe2+
5. (i) CH2NH2
is more basic
(ii) Due to formation of strong backbond

(iii) 2MnO 2  4KOH  O2   2K 2MnO 4  2H2O
6. (i) Zn  Cu2   Zn2  Cu

(ii) C = 0.1 M
(iii) Go = -nF EoCell = -2  96500  1.52 = 293, 360 J = 293.36 KJ
7. (i) Carbon atom 1

(ii) n-butane
OH OH
(iii) The isomers are CH3CH2CH2CHO, CH2 = C - CH2 - CH3 and CH3 - C = CH - CH3
8. (i) AgI/Ag+ (ii) AgI/I– (iii) Fe(OH)3/Fe3+
9. (i) NO 2 NH2 N2Cl
Sn/HCl NaNO2
   
HCl, 5o C
OH
N=N OH
(ii) NH2 N2Cl NO 2
NaNO2 H3PO2 HNO3

     
HCl, 0o C H2SO4
(iii) CH3 COOH
MnO4 /OH Sodalime

   
 Heat
HNO3
H2SO 4
NH2 NO 2
Zn/HCl
 
10. (a) Due to formation of colourless Mn2+ ions.

(b) CN– is a strong field ligand whereas H2O is a weak field ligand.
(c) 2 CrO 24  2H  Cr2O72  H2O
Yellow Orange
OR
10. (i) 20 s
100  50
(ii)  2.5 mol L1s1
20
(iii) mol L1s1
11. (i) R
(ii) OH
CH3CHCH3
(iii) P
Cl
(P) is Ca(CH3COO)2, (Q) is CH3COCH3 & (R) is H3C C CH3
Cl
OR
0.5
1000 1000
m  K   0.36   240 ohm1cm1
M 1.5
m 240
o
  or o  0.2
m m
 mo  1200
Now after dilution
12c1  2c
K  2 2
1  1 1   2
2
or,
 0.2   c1

 22  c1 / 10
1  0.2 1  2
 22
0.5 
1  2
on solving 2  0.5
12. (i) When A2 and B2 gases are mixed, energy transfer takes place between them and
they attain a fixed energy at a given temperature.
(ii) The state in which reactant molecules contain highest energy during the reaction is
called activated complex.
(iii) It is endothermic reaction as the energy of product is greater than that of reactants.
(iv) The minimum energy that is absorbed by reactant molecules to reach the activated
complex is called activation energy.
OR
A A A A A A
B B B B B B
Reactants Intermediates Products

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FIITJEE

GENERAL INSTRUCTIONS: Read the following instructions carefully.

3. An heterogeneous catalysed reaction is given below

5. (i) Which out of and is more basic? Why?

6. Zn(s) | Zn2+(0.01 M) || Ag+(C M) | Ag(s)

CH3 - C - CH2 - CH3

8. Which charged colloids are formed in following activities?

9. Mention the reactions taking place in the following transformation.

10. Give reasons

The energy profile of the reaction A 2  g   B 2  g  

What is the structure of the intermediate?

2. Moles of CuSO4 = 0.8

3. (i) Adsorbate = H2, C2H4, adsorbent = Nickel

4. Magnetic moment order: Fe+ = Fe3+ > Fe2+

(ii) Due to formation of strong backbond

6. (i) Zn  Cu2   Zn2  Cu

7. (i) Carbon atom 1

8. (i) AgI/Ag+ (ii) AgI/I– (iii) Fe(OH)3/Fe3+

9. (i) NO 2 NH2 N2Cl

(ii) NH2 N2Cl NO 2

NaNO2 H3PO2 HNO3

(iii) CH3 COOH

MnO4 /OH Sodalime

10. (a) Due to formation of colourless Mn2+ ions.

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