Chemistry Reviewer a. 0.067 a.

IV only
b. 0.093 b. I only
1. Uranium-235 and uranium-238 have the same number of which of the following? c. 0.17 c. II and III
a. Protons and electrons d. 0.4 d. I and III
b. neutrons
c. protons 11. 2.00 g of a substance dissolved in 250 g of water produces a boiling point elevation of 21. 2.00 g of a substance dissolved in 250 g of water produces a boiling point elevation of
d. electrons 0.065oC. What is the molecular weight of the substance? 0.065oC. What is the molecular weight of the substance?
a. 63 a. 92
2. What is the valence (oxidation state) of carbon in sodium carbonate (Na2CO3)? b. 92 b. 16
a. -4 c. 16 c. 8
b. 4 d. 8 d. 63
c. 2
d. -2 12. A current of 0.075 A passes through a solution of silver nitrate for 10 munites. How 22. Oxygen reacts stoichimetrically with methane to form 14 g of carbon monoxide. How
much silver is deposited? many moles of methane are consumed?
3. Water and SO3 combine to sulfuric acid (H2SO4) according to the following reaction. How a. 0.040g a. 1 mol
many grams of water must be added to 100 g of 20% oleum (20% SO 3 and 80% H2SO4by b. 0.035 g b. 0.5 mol
weight) to produce a 95% solution ( byweight) of sulfuric acid? c. 0.030 g c. 2 mol
a. 3.3 g d. 0.050 g d. 1.5 mol
b. 14 g
c. 5.0 g 13. How many grams of copper will be deposited at an electrode if a current of 1.5 A is 23. Which o fthe following chemical formulas is incorrect?
d. 7.5 g supplied for 2 hours to a CuSO4? a. Na2CO3
a. 7.1 g b. KOH
4. During a laboratory experiment at 1.0 atm and 25oC, a student observed that oxygen gas b. 3.6 g c. Ca(OH)2
was produced by de-composition of 15 g of sodium chlorate. What was the volume of c. 48 g d. CaCI
oxygen? d. 2.4 g
a. 1.27 L 24. What are the chemical formulas for the following compounds: aluminum nitrate,
b. 6.54 L 14. What is the order of reaction with respect to reactant E and the overall order of the magnesium hydroxide, calcium oxide, and cupric carbonate?
c. 5.17 L reaction described by the following rate law? a. AINO3,Mg(OH),Ca2O3,CuCO3
d. 3.85 L a. second order with respect to E; second order overall b. AI(NO3)3,Mg(OH)2,CaO,CuCO3
b. first order with respect to E; second order overall c. AL2NO3,Mg(HO),CaO2,CuCO3
5. Which of the following does a catalyst change? c. second order with respect to E; fourth order overall d. AINO3Mg(HO)2,CaO,Cu(CO3)2
a. the activation energy of a reaction d. first order with respect to E; fourth order overall
b. the equilibrium constant of areaction 25. Nitroglycerin is made by combining glycerol, nitric acid, and sulfuric acid. What are the
c. the concentration of product at equilibrium 15. What is the term for a quantity of a susbstance to which a chemical formula can be minimum coefficients needed to balance the equation of this reactions?
d. the heat of reaction of a reaction assigned and whose mass is equal to its formula weight? a. 4,2,1,1,3,1
a. a mole b. 1,3,1,1,3,1
6. What is an isomer? b. an equivalent c. 1,3,3,1,3,2
a. a substance containing a hydroxyl ion c. a molecule d. 2,6,2,2,6,2
b. a single atom d. a one-normal solution
c. different arrangement of the same atoms 26. Which of the following occurs when table salt (NaCI) is added to continuously heated
d. a basic building block for large chemical chains 16. The pH of a 0.001 M HCI solution is boiling water?
a. 5 a. The water boils even more agitatedly.
7. The reaction shown occurs in a gaseous phase. Once equilibrium has been achieved in a b. 3 b. The temperature of the water decreases but boiling continues uninterrupted.
particular reaction vessel, additional HI gas is injected directly into the reaction vessel. c. 7 c. The water continues to boil.
Compared to the initial conditions, which of the following statemnets is correct after the new d. 1 d. The water momentarily stops boiling.
equilibrium has been achieved?
a. The amount of H2 will have decreased. 17. The half-life of radioactive carbon is approximately 5700 years. If a sample is found to 27. The final temperature of the hydrogen and chlorine described in Prob. 8 is 30oC. What is
b. The partial pressure of H2 will have decreased. have 7000 atoms after 6000 years, how many atoms were presents initially? the final pressure in the reaction vessel?
c. The amount of I2 will have increased. a. 13800 atoms a. 80 kPa
d. The partila pressure of HI will have decreased. b. 14500 atoms b. 320 kPa
c. 14300 atoms c. 240 kPa
8. Which of the following compounds would be ionic, considering the electronegativities of d. 14100 atoms d. 160 kPa
the elements?
a. I2 18. Given the following reversible chemical reaction, assume all reactants and products are 28. A wastewater treatment plant uses chlorine gas as a reactant. A tank is filled with 800
b. NO ideal gases. m3 of 20oC water, and chlorine is added at a dosage of 125 g per cubic meter of water.
c. CO a. The amount of ammonia (NH3) would halve. (Assume all of the chlorine dissolves and none initially reacts chemically.) If the atmospheric
d. KCI b. There would be no change in the amount of ammonia (NH 3) present. pressure is 1.0 atm, what is the theoretical partial pressure of the chlorine gas at the tank
c. More ammonia (NH3) would be generated. surface immediately after the gas is added?
9. An unknown gas with a temperature of 25oC and a pressure of 740 mm Hg is collected in d. The amount of ammonia (NH3) would double. a. 2.3 x 10-4 atm
a sampling bag. The volume and mass of the gas are 24.0 L and 34.9 g, respectively. Which b. 0.11 atm
chemical formula could represent the gas? 19. Which of the following statements concerning reversible reactions is false? c. 3.1 x 10-5 atm
a. N2 a. Temperature affects the direction of the reaction. d. 0.039 atm
b. H2S b. Concentration have no effect on the direction of the reaction
c. HCI c. Concentration remain constant once equilibrium is reached. 29. What family of compounds is produced from the reaction between an alcohol and a
d. Ar d. Both reactants and products are always present. carboxylic acid?
a. ether
10. What is the percentage (by mass) of htdrogen in glucose (C 6H12O6)? 20. Which of the following reactions are not balanced? b. amine
c. ester 47. A solution is adjusted from pH 8 to pH 9. The relative concentraation of the hydrogen
d. ketone 38. 6 g of a substance are dissolved in 1000 g of water. The solution freezes at -0.16oC. [H+] ion has changed by a factor of what?
What is the molecular weight of the substance? a. 1100
30. Which of the following statements pertaining to acids and bases is incorrect? a. 70 g/ mol b. 5
a. Acids conduct electricity in aqueous solutions. b. 60 g/mol c. 110
b. Bases have a pH between 7 and 14. c. 75 g/mol d. 10
c. Bases have a sour taste. d. 100 g/mol
d. Acids turn blue litmus paper red. 48. The solubility constant of stronyium sulfate, SrSO4, is 2.8 x 10-7. How many grams of
39. A gaseous mixture consists of 2 kg of oxygen, 5 kg of nitrogen, and 3 kg of xenon. What SrSO4 must be dissolved in water to produce 1 L saturated solution?
31. As the pressure of a gas increases, the solubility of that gas in a liquid is the mole fraction of the oxygen gas? a. 0.1 g
a. always increases. a. 0.24 b. 2 g
b. is not changed. b. 0.17 c. 0.00005 g
c. always decreases. c. 0.11 d. 0.0005 g
d. cannot be determined. d. 0.13
49. Which of the following elements has the largest first ionazation energy?
32. What is a distinguishing characteristic of the halogens? 40. The diameter of a spherical mothball is observed to halve in 200 days.approximately how a. CI (chlorine)
a. They are phosphorescent. long will it take for its remaining volume to become half of its volume at 200 days? b. Ar (argon)
b. Next to the noble gases, they are the most chemicallyinactive group. a. 67 days c. H (hydrogen)
c. They readily accept an electron from another atom to form compounds. b. 160 days d. Kr (krypton)
d. They have a high electrical conductivity. c. 130 days
d. 200 days 50. How many milliters of 1 M NaOH solution will 25 mL of 2 H 2SO4neutralize?
33. Enthalpy of formation is most closely defined as the a. 50 mL
a. potential energy of a substance. 41. For a given isotope of an element, the atomic number plus the atomic weight is 148, and b. 100 mL
b. energy absorbed during creation of 1 grammole of a compound from pure their difference is 58. how many protons does an atom of the isotope contain? c. 75 mL
elements. a. 45 d. 25 mL
c. energy absorbed or released during a chemical reaction. b. 90
d. sum of the enthalpy of reactions. c. 148 51. What is the molarity of a solution obtained by dis-solving 25 g of NaCI in enough water
d. 58 to produce 4 L of solution?
34. Assuming all of the energy goes into the reaction, what electrical power is required to a. 6.25
produce oxygen gas at a rate of 50 mg/s? 42. 10 g of solid PCI5 is heated in a 0.5 m3 container to 150oC, producing gaseous PCI3 and b. 0.365
CI2 gas according to the following decomposition reaction: The molecule weights of the c. 0.428
compound are What is the increase in pressure in the container when 50% (By weight) of d. 0.107
the PCI5 is decomposed?
a. 0.250 kPa 52. What is the half-life of a substance that decays to 25% of its original amount in six days?
b. 18 kPa a. 3 days
c. 0.120 kPa b. 0.08 days
d. 0.350 kPa c. 8 days
d. 12 days
43. An alkyl radical is best defined as
a. an electron that is shared in a covalent bond. 53. Two moles of sodium react with 2 moles of water to produce which of the following?
b. any functional group that substitutes for a hydrogen atom in an alkane. a. 1 mole of sodium hydroxide and 1 mole of hydrogen
a. 9.2 kW c. the remaining portion of an alkane after it loses a hydrogen atom. b. 2 moles of sodium hydroxide and 1 mole of hydrogen
b. 0.89 kW% d. cancer-causing molecules found in foods c. 1 mole of sodium hydroxide and 2 moles of hydrogen
c. 3.1 kW d. 2 moles of sodium hydroxide and 2 mole of hydrogen
d. 1.5 kW 44. It is known that ozone (O3) will decompose into oxygen (O2) at a temperature of 100o.
One mole of ozone is sealed in a container at STP (0oC and 1 atm). What will be pressure of 54. When a deliquescent substance is exposed to air, it
35. What is the oxidation number for chromium (Cr) in the compound BaCro? the container once it is heated to 100oC? a. oxidizes.
a. 2 a. 37 kPa b. becomes moist
b. 4 b. 1.4 kPa c. crystallizes.
c. 1 c. 2.1 kPa d. loses water of hydration.
d. 6 d. 210 kPa
55. Which of the following elements does not exists as a diatomic molecule under normal
36. A transportation company specializes in the shipment of pressurized gaseous materials. 45. How much water must be added to 100 mL of a 0.75 molar solution of KCI to make a (ambient) conditions?
An order is received for 100 L of a particular gas at STP (0oC and 1 atm). What minimum 0.04 molar solution? a. chlorine
volume tank is necessary to transport the gas at 25oC and a maximum pressure of 8 atm? a. 1.88 L b. oxygen
a. 14 L b. 0.188 L c. iodine
b. 12 L c. 1.78 L d. sulfur
c. 16 L d. 1.98 L
d. 10 L 56. A given sample of radioactive material has 80% of the original substance remaining after
46. While moving from left to right across the second row of the periodic table (i.e., from Li 10 years. How much will remain after 90 additional years?
37. In an experient, a compound was determined to contain 68.94% oxygen and 31.06% of to Ne), the atomic radii tend to a. 0.001
an unknown element by weight. The molecular weight of this compound is 69.7 g/mol. What a. first increase, then decrease. b. 0.017
is this compound? b. uniformly increase. c. 0.11
a. SiO4 c. remain the same. d. 0.13
b. NO2 d. uniformly decrease.
c. F2O2 57. The decay of U-238 to Pb-206 can be used to estimate the age of inorganic matter. The
d. B2O3 half-life of U-238 is 4.5 x 109 years. In a particular rock sample, the ratio of the numbers of
Pb-206 to U-238 atoms is 0.66. Assume all of the Pb-206 present is due to the decay of U- 65. A gas mixture of N2(g) and CO2(g) contained in a volume of 10.0 L has a total pressure 74. At what temperature in 0C will O2 has under a pressure of 2.4 atm? (ρ of O2= 1.43 g/L)
238. What is the age of the rock? of 0.750 atm at a temperature of 273K. The mixture is known to contain 3.00 g N2(g). What a. 645.7510C
a. 3.3x 109 yr is the partial pressure of CO2(g) in the mixture? b. 3810C
b. 1.4 x 109 yr a. 0.120 atm c. 315.570C
c. 7.0 x 109 yr b. 0.630 atm d. 318.160C
d. 9.3 x 109yr c. 0.510 atm
d. 0.240 atm 75. Macro Vee collected hydrogen gas using water displacement method. He measured the
58. How much energy is needed to convert ozone to oxygen? temperature of water using a thermometer and found out that it is 230C with the
a. 43 kcal/mol 66. Rank the following gas according to increasing effusion rates relative to O2 (reference). correponding pressure of 21.1 mmHg. Calculate the pressure of hydrogen gas under
b. 0 kcal/ mol a. F2< CO24 standard atmospheric pressure.
c. 68 kcal/mol b. F<2< CH<4< CO<2 a. 95.81 KPa
d. 140 kcal/mol c. CH42<CO2 b. 98.51 Kpa
d. CO22<2 c. 98.15 Kpa
59. The group of metals that includes lithium, sodium,potassium, rubidium, and cesium d. 95.18 Kpa
forms a closely related family known as the 67. What is the vapor pressure of 1000.0 g of a water solution at 250C that contains 124.0 g
a. rare earth group. of the nonvolatile solute ethylene glycol, C2H6O2? The vapor pressure of pure water at this 76. A sample of an unknown compound is found to be 49.3% carbons, 9.6% hydrogen,
b. halogens. temperature is 23.76 torr. Assume an ideal solution 19.2% nitrogen, and 21.9% oxygen by weight. What is its molecular formula?
c. alkali metals. a. 23.7 torr a. C3H7NO
d. alkaline earth metals. b. 24.6 torr b. C3H7NO
c. 22.8 torr c. C4H<><>
60. Hydrogen and chlorine gas combine in a 35 m3 reaction vessel to produce hydrogen d. 0.94 torr d. C4H4NO
chloride. The masses of hydrogen and chlorine are 4.5 kg and 160 kg, respectively. How
much hydrogen chloride gas is produced? 68. "::Add_Chem_004:: Consider a solution of water and a nonvolatile solute at some 77. Balance the following reaction.
a. 41 kg temperature. What combination of conditions would be sure to increase the vapor pressure a. HBrO3 + 5HBr 3H2O + 3bR2
b. 21 kg of the solution? _____" b. 3HBrO3 + HBr 2H2O + 2Br2
c. 82 kg a. Raise the temperature and add more water c. 2HBrO3 + 4HBr 3H2O + 3Br2
d. 160 kg b. Lower the temperature and add more solute d. HBrO3 + 4HBr 3H2O + Br2
c. Raise the temperature and add more solute
61. How many liters of 2M solution (i.e., a molarity of 2) can be produced from 184 g of d. Lower the temperature and add more water 78. Which of the following is the correct electron configuration of Pb?
enthyl alcohol (CH3CH2OH)? a. [Xe]6s24f146s2
a. 1.5 L 69. What is the mass of 0.01 gram-moles of Na2SO4? b. [Xe]6s25d104f146p2
b. 5.0 L a. 1.42 g c. [Xe]6s25d104f145d106p2
c. 2.0 L b. 1.19 g d. [Xe]5d104f146p2
d. 2.5 L c. 0.71 g
d. 2.38 g 79. The mole (mol) is the amount of a substance that contains as many elementary entities
62. If the current, I, is 100 A, at what rate is oxygen produced? as there are atoms in exactly
70. An ideal gas occupies a volume of 4L and has a pressure of 283.71kPa a. 12.00 grams of C.
(1atm=101.325kPa). Under 22.50C, what most likely is the identity of the gas if 0.01293 Kg b. average atomic mass of isotopes of C.
of gas is used. c. 12.01 grams/mol of C.
a. O2 d. 12.00 grams of 12C.
b. Cl2
c. F2 80. At STP the volume of 1.5 mole N2as compared to 1.0 mole O2 is
d. N2 a. higher to about three fourths
b. the same, 22.4L
71. The reaction shown proceeds in a gaseous state. At equilibrium, the concentration of the c. different by about 11.2 L
components X,Y, and Z are measured to be 5.73 x 10-2 mol/L, 2.67 x 10-2 mol/L and 4.59 x d. differ by a factor of 1.25
10-2 mol/L, respectively. What is the equilibrium constant for this reaction?
a. 18.7 mg/s a. 9.8 x 10-4mol/L 81. "::Add_Chem_008:: How many grams of glucose, C6H12O6, are necessary to prepare
b. 8.29 mg/s b. 1.7 x 10-2mol/L 656 mL of a solution with a concentration that is 0.550 molar? _____"
c. 16.7 mg/s c. 3.7 x 10-1 mol/L a. 0.00200 g
d. 9.34 mg/s d. 2.1 x 10-2mol/L b. 151 g
c. 64.9 g
63. What mass of lead nitrate, Pb(NO3)2, must be dis-solved in 1 L of water to produce a 72. If 1.5 L of an ideal gas at 250C is heated, the new volume increases 2.5 times the d. 214 g
solution that contains 20 mg of lead ions? Assume 100% ionazation. original volume. The pressure and amount of substance are held constant. What is the new
a. 43 mg temperature of gas in 0F 82. n the following reaction, which elements are the reducing and exidizing agents?
b. 52 mg a. 882 0F a. Mg is the reducing agents; O2 is the oxidizing agent.
c. 32 mg b. 8800F b. MgO is the reducing agent; Mg is the oxidizing agent.
d. 26 mg c. 820 0F c. Mg is the reducing agent;MgO is the oxidizing agent.
d. 8280F d. O2 is the reducing agent; Mg is the oxidizing agent.
64. A compound in gas form Has a mass of 0.377 g and occupies 191.6 mL at standard
conditions (0oC and 760 mm Hg). What is the formula of the compound? 73. "::Add_Chem_013::Following are three states for fluorine:1s22s12p6 1s22s22p5 83. By decreasing the pressure of an ideal gas at constant temperature and amount of
a. C3H8 1s22s22p42d1 They are, respectively: _____" substance 1/3 times the original pressure, the volume of gas will
b. CH4 a. ground, excited, impossible a. expands two thirds the original
c. C5H12 b. ground, impossible, excited b. increases three times the original
d. C2H6 c. excited, impossible, ground c. multiply by a factor of 1/3
d. excited, ground, impossible d. decreases three times the original
84. What is the gravimetric (i.e.m.,mass) percentage of oxygen in K 2CrO4? c. number
a. 0.33 94. A liquid will boil when d. radius
b. 0.66 a. its vapor pressure is equal to the melting point
c. 0.57 b. its vapor pressure is equal to the surrounding pressure 104. The gas present in electric bulbs is argon. If a samle of this gas is at a pressure of
d. 0.42 c. it is heated to a temperature that is below the boiling point. 101.325 kPa, when the volume is 0.1L and the temperature is 32oC,what must its
d. a salt has been added to the liquid temperature [in oC] be if its volumes becomes 200mL and its pressure 96 kPa?
85. There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The ZnS is roasted in excess a. 305
air to form zinc oxide (ZnO) and sulfer dioxide (S)2). How many grams of zinc can be 95. Which units could be usued to express the account absorved or released during chemical b. 105
subsequently recovered if 5% of the zinc is lost in the roasting process? reaction? c. 205
a. 340 g a. Torr and mmHg d. 405
b. 380 g b. Gram and liter
c. 320 g c. Calorie and joule 105. Which electron configuration demonstrates an atom in the excited state?
d. 400 g d. Degree and gram a. 1s22s23s1
b. 1s22s1
86. What is the enthalpy of reaction at 25oC for the combustion of ethane ( C2H6)? 96. Which of the following isotopes has the greatest number of neutrons? c. 1s22s22p4
a. -680 kcal/mol (exothermic) a. 40AR d. 1s22s2
b. -340 kcal/mol ( exothermic) b. 35Cl
c. 130 kcal/mol (endothermic) c. 31P 106. A 350. mL samle of 0.276 M HNO3 is partially neutralized by 125mL of 0.0120 M
d. 340 kcal/mol (endothermic) d. 41Ca Ca(OH)2. Find the concentration of nitric acid in the resulting solution.
a. 0.197 M
87. A silver wire has a diameter of 0.500 mm.What length of this wire contains exactly 1.00 97. When 38.0 mL of 0.1250 M H2SO4 is added to 100. mL of a solution of Pbl2, a b. 0.187 M
mol of silver? [Given: density of Ag = 10.5 g/cm3 precipitateof PbSO4 is then filtered from the solution,dried, and weighed. If the recovered c. 0.157 M
a. 51.3 mm. PbSO4 is found to have a mass of 0.0471 g, what was the concentration of iodide ions in the d. 0.167 M
b. 52.3 mm. original solution?
c. 50.3 mm. a. 3.10 x 10-3 M 107. Identify the oxidizing agent in the chemical reaction 2MnO4? + 5H2SO3 ? 2Mn2+
d. 53.3 mm. b. 3.11 x 10-3 M +5SO42? + 3H2O.
c. 3.12 x 10-2 M a. MnO4 ?
88. Which principal energy level has exactly four subshells? d. 3.11 x 10-2 M
a. 4 108. The elements that display the greatest non-metallic character are located toward which
b. 3 98. There are 500 g of zinc sulfide (ZnS) in a load of zinc ore. The ZnS is roasted in excess corner of the periodic table?
c. 1 air to form zinc oxide (ZnO) and sulfer dioxide (S)2). How many grams of zinc can be a. Lower right
d. 2 subsequently recovered if 5% of the zinc is lost in the roasting process? b. Upper right
89. Which sample demonstrate particles arranged in regular geometric pattern? a. 380 g c. Dead center
a. CO2(g) b. 320 g d. Upper left
b. CO2(aq) c. 400 g
c. CO2(l) d. 340 g 109. What mass of KCIO3 must be decomposed to produce 126 L of oxygen gas at 133oC
d. CO2(s) and 0.880 atm? (The other reaction product is solid KCI.)
99. Which substance can be decomoposed chemically? a. 282 g
90. An atom has eight electrons in a 3d subshell. How many orbitals in this subshell have an a. Hydrogen b. 272 g
unpaired electron? b. Iron c. 252 g
a. 2. c. Ammonia d. 262 g
b. 1. d. Neon
c. 4. 110. The mineral manganosite is a cmpound of manganese-55 and oxgen-16. If 77%o f the
d. 3. 100. How many liters of oxygen gas at 153oC and 0.820 atm can be produce by the mass manganosite is due to manganese,what is the empirical formula of manganosite?
decomposition of 22.4 g of solid KCIO3? (The other decomposition product is solid a. MnO2
91. Which atom is not paired with its correct ion and ionic charge. potassium chloride.) b. Mn3O4
a. Rb / Rb1- a. 9.7 L c. MnO
b. F / F1- b. 11.7 L d. MnO3
c. Li / Li1+ c. 12.7 L
d. Mg / Mg2- d. 10.7 L 111. A method of removing CO2 from a spacecraft is to allow the CO2 to react with sodium
hydroxide. (The products of the reaction are sodium carbonate and water.) What volume of
92. The Hall process for the production of the aluminun involves the reaction of the 101. Which two elements will display the most similar chemical properties? carbon dioxide at 25oC and 749 mmHg can be removed per kilogram of sodium hydroxide
aluminum oxide with elemental carbon to give aluminum metal and carbon momoxide. If the a. Litium and potassium that reacts?
yield of this reaction is 82% and aluminum ore is 71% by mass aluminum oxide,what mass b. Aluminum and calcium a. 309 L
of aluminum ore must be mined in order to produce 1.0 x 103 kg(1 metric ton) of aluminum c. Chlorine and sulfur b. 308 L
metal by the Hall process? d. Nickel and phosphorus c. 311 L
a. 3.3 x 103 kg d. 310 L
b. 3.4 x 103 kg 102. Assuming the ground state, all of the elements located in the group 12 of the periodic
c. 3.1 x 103 kg table will have the same number of 112. Which gas under a high temperature and a low pressure behaves most like an ideal
d. 3.2 x 103 kg a. electrons gas?
b. occupied principal energy levels a. Ne
93. Which of the following is not a conclusion Rutherford made from his experiment with c. nuclear particles b. O2
alpha particles being shot at a thin sheet of gold foil? d. valence electrons c. He
a. An atom is mainly empty space d. NH3
b. An atom has a negatively charged nucleus. 103. The modern periodic table is arranged based upon atomic
c. An atom has a very small, compact nucleus a. isotopes 113. The radius of the Earth is approximately 6370 km. If one could dig down straight
d. An atom's mass is concentrated in the nucleus. b. density towards the center of the Earth, one would find that the innermost 3480 km (the core) has
an average of density of about 11 g/cm3. Above that are the mantle and crust. If the 122. When active metals such as magnesium are immersed in acid solution, hydrogen gas is 132. The Hall process for the production of the aluminun involves the reaction of the
average density of the Earth is 5.5 g/cm3, what is the average density of the Earth's mantle evolved. Calculate the volume of H2(g) at 30.1oC and 0.85 atm that can be formed when aluminum oxide with elemental carbon to give aluminum metal and carbon momoxide. If the
and crust?(Recall that the volume of a sphere is given V=(4/3)?r3.) 275 mL of 0.725 M HCI solution reacts with excess Mg to give hydrogen gas and aqueous yield of this reaction is 75%, what mass of aluminum metal can be produced from the
a. 4.3 g/cm3 magnesium chloride. reaction of 1.65 x 106 of aluminum oxide with 1.50 x 106 g of carbon?
b. 4.4 g/cm3 a. 2.6 L a. 6.3 x 105 g
c. 4.5 g/cm3 b. 2.9 L b. 6.6 x 105 g
d. 3.4 g/cm3 c. 2.7 L c. 6.5 x 105 g
d. 2.8 L d. 6.4 x 105 g
114. Which setence below is incorrect?
a. Salads are heterogeneous mixtures. 123. Which sample represent a homogeneous misture? 133. It has been determined that 1.0 L of solution contain 52.7 g H2SO4, 240.8 g KMnO4,
b. Sand and water make heterogeneous mixture. a. CH3OH(g) 11.3 g K2SO4, and 5.5 g Mn2O7. The reaction equation is The molecular weights of the
c. Pure iron is a heterogeneous mixture. b. CH3OH(aq) compounds are What is the equilibrium constant for the reaction?
d. Milk is a homogeneous mixture. c. CH3OH(s) a. 1.3 x 10-3
d. CH3OH(l) b. 6.9 x 10-3
115. An object will float at the surface of a liquid if the mass of the object is less than the c. 5.2 x 10-3
mass of the lliquid that it displaces. A spherical vessel (diameter = 5.00 cm) when empty 124. In period 3 of the periodic table the atom with the largest atomic radius is located in d. 2.6 x 10-3
has a mass of 12.00 g. What is the greatest volume of water that can be placed in the vessel group
and still have the vessel float at the surface of benzene? (Given: density of water = 1.00 a.1 134. When active metals such as magnesium are immersed in acid solution, hydrogen gas is
g/cm3; density of benzene = 0.879 g/cm3) b. 3 evolved. Calculate the volume of H2(g) at 30.1oC and 0.85 atm that can be formed when
a. 25.5 L c. 17 275 mL of 0.725 M HCI solution reacts with excess Mg to give hydrogen gas and aqueous
b. 45.5 L d. 18 magnesium chloride.
c. 55.5 L a. 2.9 L
d. 35.5 L 125. A 250. mL sample of 0.0328 M HCI is partially neutralized by the addition of 100. mL of b. 2.8 L
0.0245 M NaOH.Find the concentration of hydrochloric acid in the resulting soution. c. 2.6 L
116. Which gas is expected to have the highest rate of effusion? a. 0.0173 M d. 2.7 L
a. He b. 0.0164 M
b. O2 c. 0.0174 M 135. A 2.50-L flask contains a mixture of methane (CH4) and propane (C3H8) at a pressure
c. H2O d. 0.0163 M of 1.45 atm and 20oC.When this gas mixture is then burned in excess oxygen, 8.60g of
d. F2 carbon dioxide is formed.(The other product is water.)What is the mole fraction of methane
126. What is the mass of an object that has a density of 13 g/mL and a volume of 10 mL? in the original gas mixture?
117. The mineral hausmannite is a compound of manganese-55 and oxygen-16. If 72% of a. 1.3 g/L a. 0.75
the mass of hausmannite is due to manganese, what is the empirical formula of b. 1.3 g/mL b. 0.85
hausmannite? c. 130 g/mL c. 0.93
a. MnO2 d. 0.77 g/mL d. 0.73
b. Mn3O4
c. MnO3 127. In the chemical reaction 5S + 6KNO3 + 2CaCO3 ? 3K2SO4 + 2CaSO4 + CO2 + 3N2, 136. Iron has a density of 7.78 g/cm3. What mass of iron would be required to cover a
d. MnO the oxdizing agent is football playing surface of 120 yds x 60 yds to a depth of 1.0 mm?(1 inch = 2.54 cm)
a. KNO3 a. 57 Mg
118. A book is lifted off of the floor and placed on a table that is one meter above the floor. b. 47 Mg
The book has 128. An atom in the ground state has seven valence electrons. Which electron configuration c. 27 Mg
a. gained potential energy could represent the valence electron configuration of this atom in the ground state? d. 37 Mg
b. gained kinetic energy a. 3s63p1
c. gained sound energy b. 3s23p1 137. The time required for a given volume of N2 to diffuse through an orifice is 35 sec.
d. lost chemical energy c. 3s13p6 Calculate the molecular weight of a gas which requires 50 sec to diffuse through the same
d. 3s23p5 orifice under identical conditions.
119. Which phase change is described correctly? a. 51.75 g/mole
a. Gas to solid is called sublimation. 129. Which of the following bonds would you expect to be the most polar? b. 15.57 g/mole
b. Liquid to solid is called freezing a. N-P c. 57.15 g/mole
c. Solid to liquid is called vaporization b. N-Bi d. 71.55 g/mole
d. Solid to gas is called deposition c. N-Sb
d. N-As 138. Air contains 78% N2, 21% O2, and 1% Ar, by voolume. What is the density of air
120. Calculate the volume of H2(g) at 273 K and 2.00 atm that will be formed when 275 mL 1,000. torr and?10oC?
of 0.725 M HCI solution reacts with excess Mg to give hydrogen gas and aqueous 130. At which temperature does a water sample have the highest average kinetic energy? a. 0.8 g/L
magnesium chloride. a. 100 degrees Celcius b. 1.8 g/L
a. 1.09 L b. 0 degrees Celcius c. 3.8 g/L
b. 1.11 L c. 0 K d. 2.8 g/L
c. 1.10 L d. 100 K
d. 1.12 L 139. How many cubic centimeters of ore containing 0.22% by mass gold must be processed
131. Americans combined drive about 4.0x109 miles per day and their vehicles get an to obtain $100 worth of gold? The density of the ore is 8.0 g/cm3 and the price of gold is
121. When octane (C8H18) is burned in a particular internal combustion engine, the yield of average of 20 miles per gallon of fuel used.For each 1kg of gasoline that is burned,about 3.0 $418 pre troy ounce. (14.6 troy oz = 1.0 ordinary pound,called an avoirdupois pound; 1lb =
the products (carbon dioxide and water) is 93%. What mass of carbon dioxide will be kg of carbon dioxed are produced. How many kilograms of CO2 are emitted into the 454g)
produced in this engine when 15.0 g of octane is burned with 15.0 g of oxygen gas? atmosphere each day by cars in the U.S.? One gallon of gas weighs about 3.5 kg. a. 3.2 x 102 cm3
a. 13 g a. 2.1x109 kg b. 4.2 x 102 cm3
b. 11 g b. 3.1x109 kg c. 5.2 x 102 cm3
c. 10 g c. 4.1x109 kg d. 3.3 x 102 cm3
d. 12 g d. 1.1x109 kg
140. A wastewater treatment plant uses chlorine gas as a reactant. A tank is filled with 800 b. 5.2x103 kg
m3 of 20oC water, and chlorine is added at a dosage of 125 g per cubic meter of water. c. 4.2x103 kg
(Assume all of the chlorine dissolves and none initially reacts chemically.)If the atmospheric d. 3.2x103 kg
pressure is 1.0 atm, what is the theoretical partial pressure of the chlorine gas at the tank
surface immediately after the gas is added? 148. When 20.0 mL of a 0.250 M (NH4)2S solution is added to 150.0 mL of a solution of
a. 3.1x10-5 atm Cu(NO3)2, CuS precipitate forms. The precipitate is then filtered from the solution,dried, and
b. 3.2x10-5 atm weighed. If the recovered CuS found to have a mass of 0.3491 g, what was the
c. 3.3x10-5 atm concentration of copper ions in the originalCu(NO3)2 solution?
d. 3.0x10-5 atm Select one:
a. 2.24 x 10-2 M
141. Dimenthly hydrazine (CH3)2NNH2 has been used as a fuel in space, with nitrogen b. 2.43 x 10-2 M
tetraoxide (N2O4) as the oxidizer. The products of the reaction between these two in an c. 2.34 x 10-2 M
engine are H2O, CO2, and N2. What is the mass of nitrogen tetraoxide required to burn 50 d. 2.42 x 10-2 M
kg of dimenthly hydrazine?
a. 153 kg
b. 128 kg
c. 100 kg
d. 50 kg

142. An unknown quantity of hydrogen gas has a volume of 2.5 L at STP (0o and 1 atm).
What is the mass of hydrogen?
Select one:
a. 0.19 g
b. 0.51 g
c. 0.073 g
d. 0.22 g

143. How many valence electrons are in a atom with the configuration 1s 22s22p63s23p2
Select one:
a. 5
b. 2
c. 6
d. 4

144. The mole fraction of oxygen molecules in dry air is 0.2029.What volume of dry air at
1.00 atm and 25oC is required for burning 1.00 L of hexane (C6H14, density = 0.660 g/mL)
completely, yeilding carbon dioxide and water?
Select one:
a. 8490 L
b. 8495 L
c. 8409 L
d. 8499 L

145. The first step in the Otswald process for producing nitric acid is 4NH3(g) + 5O2(G) ?
4NO(g) + 6H2O(g). If the reaction of 150 g of ammonia with 150 g of oxygen gas yeilds 87
g of nitric oxide (NO), what is the percent yeild of this reaction?
Select one:
a. 0.44
b. 0.11
c. 0.22
d. 0.33

146. A 0.850-mole sample of nitrous oxide, a gas used as anasthetic by dentists, has a
volume of 20.46 L at 123oC and 1.35 atm. What would be its volume [in L] at 468oC and
1.35 atm?
Select one:
a. 36.3
b. 37.3
c. 38.3
d. 39.3

147. A method of producing pure copper metal involves the reaction of copper(I) sulfide
with oxygen gas to give copper metal and sulfur dioxide. Suppose the yield of this reaction is
87%. What mass of a copper ore consisting of 46% copper(I) sulfide must be mined in order
to produce 1.0x103 kg (1.0 metric ton) of copper metal?
Select one:
a. 2.2x103 kg