Basic Engineering Correlation (Chemistry are 24.0 L and 34.9 g, respectively.

Which
Reviewer) chemical formula could represent the gas? 18. Given the following reversible chemical
a. N2 reaction, assume all reactants and products are
1. Uranium-235 and uranium-238 have the same b. H2S ideal gases.
number of which of the following? c. HCI a. The amount of ammonia (NH3) would halve.
a. Protons and electrons d. Ar b. There would be no change in the amount of
b. neutrons ammonia (NH3) present.
c. protons 10. What is the percentage (by mass) of htdrogen c. More ammonia (NH3) would be generated.
d. electrons in glucose (C6H12O6)? d. The amount of ammonia (NH3) would double.
a. 0.067
2. What is the valence (oxidation state) of carbon b. 0.093 19. Which of the following statements
in sodium carbonate (Na2CO3)? c. 0.17 concerning reversible reactions is false?
a. -4 d. 0.4 a. Temperature affects the direction of the
b. 4 reaction.
c. 2 11. 2.00 g of a substance dissolved in 250 g of b. Concentration have no effect on the direction
d. -2 water produces a boiling point elevation of of the reaction
0.065oC. What is the molecular weight of the c. Concentration remain constant once
*3. Water and SO3 combine to sulfuric acid substance? equilibrium is reached.
(H2SO4) according to the following reaction. How a. 63 d. Both reactants and products are always
many grams of water must be added to 100 g of b. 92 present.
20% oleum (20% SO3 and 80% H2SO4by weight) c. 16
to produce a 95% solution ( byweight) of sulfuric d. 8 20. Which of the following reactions are not
acid? balanced?
a. 3.3 g 12. A current of 0.075 A passes through a a. IV only
b. 14 g solution of silver nitrate for 10 munites. How b. I only
c. 5.0 g much silver is deposited? c. II and III
d. 7.5 g a. 0.040g d. I and III
b. 0.035 g
*4. During a laboratory experiment at 1.0 atm c. 0.030 g 21. 2.00 g of a substance dissolved in 250 g of
and 25oC, a student observed that oxygen gas d. 0.050 g water produces a boiling point elevation of
was produced by de-composition of 15 g of 0.065oC. What is the molecular weight of the
sodium chlorate. What was the volume of 13. How many grams of copper will be deposited substance?
oxygen? at an electrode if a current of 1.5 A is supplied for a. 92
a. 1.27 L 2 hours to a CuSO4? b. 16
b. 6.54 L a. 7.1 g c. 8
c. 5.17 L b. 3.6 g d. 63
d. 3.85 L c. 48 g
d. 2.4 g 22. Oxygen reacts stoichimetrically with
5. Which of the following does a catalyst change? methane to form 14 g of carbon monoxide. How
a. the activation energy of a reaction 14. What is the order of reaction with respect to many moles of methane are consumed?
b. the equilibrium constant of areaction reactant E and the overall order of the reaction a. 1 mol
c. the concentration of product at equilibrium described by the following rate law? b. 0.5 mol
d. the heat of reaction of a reaction a. second order with respect to E; second order c. 2 mol
overall d. 1.5 mol
6. What is an isomer? b. first order with respect to E; second order
a. a substance containing a hydroxyl ion overall 23. Which o fthe following chemical formulas is
b. a single atom c. second order with respect to E; fourth order incorrect?
c. different arrangement of the same atoms overall a. Na2CO3
d. a basic building block for large chemical chains d. first order with respect to E; fourth order b. KOH
overall c. Ca(OH)2
7. The reaction shown occurs in a gaseous phase. d. CaCI
Once equilibrium has been achieved in a 15. What is the term for a quantity of a
particular reaction vessel, additional HI gas is susbstance to which a chemical formula can be 24. What are the chemical formulas for the
injected directly into the reaction vessel. assigned and whose mass is equal to its formula following compounds: aluminum nitrate,
Compared to the initial conditions, which of the weight? magnesium hydroxide, calcium oxide, and cupric
following statemnets is correct after the new a. a mole carbonate?
equilibrium has been achieved? b. an equivalent a. AINO3,Mg(OH),Ca2O3,CuCO3
a. The amount of H2 will have decreased. c. a molecule b. AI(NO3)3,Mg(OH)2,CaO,CuCO3
b. The partial pressure of H2 will have decreased. d. a one-normal solution c. AL2NO3,Mg(HO),CaO2,CuCO3
c. The amount of I2 will have increased. d. AINO3Mg(HO)2,CaO,Cu(CO3)2
d. The partila pressure of HI will have decreased. 16. The pH of a 0.001 M HCI solution is
a. 5 25. Nitroglycerin is made by combining glycerol,
8. Which of the following compounds would be b. 3 nitric acid, and sulfuric acid. What are the
ionic, considering the electronegativities of the c. 7 minimum coefficients needed to balance the
elements? d. 1 equation of this reactions?
a. I2 a. 4,2,1,1,3,1
b. NO 17. The half-life of radioactive carbon is b. 1,3,1,1,3,1
c. CO approximately 5700 years. If a sample is found to c. 1,3,3,1,3,2
d. KCI have 7000 atoms after 6000 years, how many d. 2,6,2,2,6,2
atoms were presents initially?
9. An unknown gas with a temperature of 25oC a. 13800 atoms 26. Which of the following occurs when table salt
and a pressure of 740 mm Hg is collected in a b. 14500 atoms (NaCI) is added to continuously heated boiling
sampling bag. The volume and mass of the gas c. 14300 atoms water?
d. 14100 atoms a. The water boils even more agitatedly.
b. The temperature of the water decreases but b. 90
boiling continues uninterrupted. c. 148
c. The water continues to boil. d. 58
d. The water momentarily stops boiling.
*42. 10 g of solid PCI5 is heated in a 0.5 m3
27. The final temperature of the hydrogen and container to 150oC, producing gaseous PCI3 and
chlorine described in Prob. 8 is 30oC. What is the CI2 gas according to the following decomposition
final pressure in the reaction vessel? reaction: The molecule weights of the compound
a. 80 kPa are What is the increase in pressure in the
b. 320 kPa container when 50% (By weight) of the PCI 5 is
c. 240 kPa decomposed?
d. 160 kPa a. 9.2 kW a. 0.250 kPa
b. 0.89 kW% b. 18 kPa
28. A waste water treatment plant uses chlorine c. 3.1 kW c. 0.120 kPa
gas as a reactant. A tank is filled with 800 m3 of d. 1.5 kW d. 0.350 kPa
20oC water, and chlorine is added at a dosage of
125 g per cubic meter of water. (Assume all of the 35. What is the oxidation number for chromium 43. An alkyl radical is best defined as
chlorine dissolves and none initially reacts (Cr) in the compound BaCro? a. an electron that is shared in a covalent bond.
chemically.) If the atmospheric pressure is 1.0 a. 2 b. any functional group that substitutes for a
atm, what is the theoretical partial pressure of b. 4 hydrogen atom in an alkane.
the chlorine gas at the tank surface immediately c. 1 c. the remaining portion of an alkane after it
after the gas is added? d. 6 loses a hydrogen atom.
a. 2.3 x 10-4 atm d. cancer-causing molecules found in foods
b. 0.11 atm 36. A transportation company specializes in the
c. 3.1 x 10-5 atm shipment of pressurized gaseous materials. An 44. It is known that ozone (O3) will decompose
d. 0.039 atm order is received for 100 L of a particular gas at into oxygen (O2) at a temperature of 100o. One
STP (0oC and 1 atm). What minimum volume tank mole of ozone is sealed in a container at STP (0oC
29. What family of compounds is produced from is necessary to transport the gas at 25oC and a and 1 atm). What will be pressure of the
the reaction between an alcohol and a carboxylic maximum pressure of 8 atm? container once it is heated to 100oC?
acid? a. 14 L a. 37 kPa
a. ether b. 12 L b. 1.4 kPa
b. amine c. 16 L c. 2.1 kPa
c. ester d. 10 L d. 210 kPa
d. ketone
37. In an experient, a compound was determined 45. How much water must be added to 100 mL of
30. Which of the following statements pertaining to contain 68.94% oxygen and 31.06% of an a 0.75 molar solution of KCI to make a 0.04 molar
to acids and bases is incorrect? unknown element by weight. The molecular solution?
a. Acids conduct electricity in aqueous solutions. weight of this compound is 69.7 g/mol. What is a. 1.88 L
b. Bases have a pH between 7 and 14. this compound? b. 0.188 L
c. Bases have a sour taste. a. SiO4 c. 1.78 L
d. Acids turn blue litmus paper red. b. NO2 d. 1.98 L
c. F2O2
31. As the pressure of a gas increases, the d. B2O3 46. While moving from left to right across the
solubility of that gas in a liquid second row of the periodic table (i.e., from Li to
a. always increases. 38. 6 g of a substance are dissolved in 1000 g of Ne), the atomic radii tend to
b. is not changed. water. The solution freezes at -0.16oC. What is a. first increase, then decrease.
c. always decreases. the molecular weight of the substance? b. uniformly increase.
d. cannot be determined. a. 70 g/ mol c. remain the same.
b. 60 g/mol d. uniformly decrease.
32. What is a distinguishing characteristic of the c. 75 g/mol
halogens? d. 100 g/mol 47. A solution is adjusted from pH 8 to pH 9. The
a. They are phosphorescent. relative concentraation of the hydrogen [H+] ion
b. Next to the noble gases, they are the most 39. A gaseous mixture consists of 2 kg of oxygen, has changed by a factor of what?
chemicallyinactive group. 5 kg of nitrogen, and 3 kg of xenon. What is the a. 1100
c. They readily accept an electron from another mole fraction of the oxygen gas? b. 5
atom to form compounds. a. 0.24 c. 110
d. They have a high electrical conductivity. b. 0.17 d. 10
c. 0.11
33. Enthalpy of formation is most closely defined d. 0.13 *48. The solubility constant of stronyium sulfate,
as the SrSO4, is 2.8 x 10-7. How many grams of SrSO4
a. potential energy of a substance. *40. The diameter of a spherical mothball is must be dissolved in water to produce 1 L
b. energy absorbed during creation of 1 observed to halve in 200 days.approximately saturated solution?
grammole of a compound from pure elements. how long will it take for its remaining volume to a. 0.1 g
c. energy absorbed or released during a chemical become half of its volume at 200 days? b. 2 g
reaction. a. 67 days c. 0.00005 g
d. sum of the enthalpy of reactions. b. 160 days d. 0.0005 g
c. 130 days
*34. Assuming all of the energy goes into the d. 200 days 49. Which of the following elements has the
reaction, what electrical power is required to largest first ionazation energy?
produce oxygen gas at a rate of 50 mg/s? 41. For a given isotope of an element, the atomic a. CI (chlorine)
number plus the atomic weight is 148, and their b. Ar (argon)
difference is 58. how many protons does an atom c. H (hydrogen)
of the isotope contain? d. Kr (krypton)
a. 45
50. How many milliters of 1 M NaOH solution will d. 140 kcal/mol 66. Rank the following gas according to
25 mL of 2 H2SO4neutralize? increasing effusion rates relative to O2
a. 50 mL 59. The group of metals that includes lithium, (reference).
b. 100 mL sodium,potassium, rubidium, and cesium forms a. F2< CO24
c. 75 mL a closely related family known as the b. F<2< CH<4< CO<2
d. 25 mL a. rare earth group. c. CH42<CO2
b. halogens. d. CO22<2
51. What is the molarity of a solution obtained c. alkali metals.
by dis-solving 25 g of NaCI in enough water to d. alkaline earth metals. *67. What is the vapor pressure of 1000.0 g of a
produce 4 L of solution? water solution at 250C that contains 124.0 g of
a. 6.25 60. Hydrogen and chlorine gas combine in a 35 the nonvolatile solute ethylene glycol, C2H6O2?
b. 0.365 m3 reaction vessel to produce hydrogen chloride. The vapor pressure of pure water at this
c. 0.428 The masses of hydrogen and chlorine are 4.5 kg temperature is 23.76 torr. Assume an ideal
d. 0.107 and 160 kg, respectively. How much hydrogen solution
chloride gas is produced? a. 23.7 torr
52. What is the half-life of a substance that a. 41 kg b. 24.6 torr
decays to 25% of its original amount in six days? b. 21 kg c. 22.8 torr
a. 3 days c. 82 kg d. 0.94 torr
b. 0.08 days d. 160 kg
c. 8 days 68. "::Add_Chem_004:: Consider a solution of
d. 12 days 61. How many liters of 2M solution (i.e., a water and a nonvolatile solute at some
molarity of 2) can be produced from 184 g of temperature. What combination of conditions
53. Two moles of sodium react with 2 moles of enthyl alcohol (CH3CH2OH)? would be sure to increase the vapor pressure of
water to produce which of the following? a. 1.5 L the solution? _____"
a. 1 mole of sodium hydroxide and 1 mole of b. 5.0 L a. Raise the temperature and add more water
hydrogen c. 2.0 L b. Lower the temperature and add more solute
b. 2 moles of sodium hydroxide and 1 mole of d. 2.5 L c. Raise the temperature and add more solute
hydrogen d. Lower the temperature and add more water
c. 1 mole of sodium hydroxide and 2 moles of 62. If the current, I, is 100 A, at what rate is
hydrogen oxygen produced? 69. What is the mass of 0.01 gram-moles of
d. 2 moles of sodium hydroxide and 2 mole of Na2SO4?
hydrogen a. 1.42 g
b. 1.19 g
54. When a deliquescent substance is exposed to c. 0.71 g
air, it d. 2.38 g
a. oxidizes.
b. becomes moist *70. An ideal gas occupies a volume of 4L and has
c. crystallizes. a pressure of 283.71kPa (1atm=101.325kPa).
d. loses water of hydration. Under 22.50C, what most likely is the identity of
the gas if 0.01293 Kg of gas is used.
55. Which of the following elements does not a. O2
exists as a diatomic molecule under normal a. 18.7 mg/s b. Cl2
(ambient) conditions? b. 8.29 mg/s c. F2
a. chlorine c. 16.7 mg/s d. N2
b. oxygen d. 9.34 mg/s
c. iodine 71. The reaction shown proceeds in a gaseous
d. sulfur 63. What mass of lead nitrate, Pb(NO3)2, must be state. At equilibrium, the concentration of the
dis-solved in 1 L of water to produce a solution components X,Y, and Z are measured to be 5.73 x
56. A given sample of radioactive material has that contains 20 mg of lead ions? Assume 100% 10-2 mol/L, 2.67 x 10-2 mol/L and 4.59 x 10-2
80% of the original substance remaining after 10 ionazation. mol/L, respectively. What is the equilibrium
years. How much will remain after 90 additional a. 43 mg constant for this reaction?
years? b. 52 mg a. 9.8 x 10-4mol/L
a. 0.001 c. 32 mg b. 1.7 x 10-2mol/L
b. 0.017 d. 26 mg c. 3.7 x 10-1 mol/L
c. 0.11 d. 2.1 x 10-2mol/L
d. 0.13 64. A compound in gas form Has a mass of 0.377
g and occupies 191.6 mL at standard conditions 72. If 1.5 L of an ideal gas at 250C is heated, the
*57. The decay of U-238 to Pb-206 can be used (0oC and 760 mm Hg). What is the formula of the new volume increases 2.5 times the original
to estimate the age of inorganic matter. The half- compound? volume. The pressure and amount of substance
life of U-238 is 4.5 x 109 years. In a particular rock a. C3H8 are held constant. What is the new temperature
sample, the ratio of the numbers of Pb-206 to U- b. CH4 of gas in 0F
238 atoms is 0.66. Assume all of the Pb-206 c. C5H12 a. 882 0F
present is due to the decay of U-238. What is the d. C2H6 b. 8800F
age of the rock? c. 820 0F
a. 3.3x 109 yr 65. A gas mixture of N2(g) and CO2(g) contained d. 8280F
b. 1.4 x 109 yr in a volume of 10.0 L has a total pressure of 0.750
c. 7.0 x 109 yr atm at a temperature of 273K. The mixture is *73. "::Add_Chem_013::Following are three
d. 9.3 x 109yr known to contain 3.00 g N2(g). What is the states for fluorine:1s22s12p6 1s22s22p5
partial pressure of CO2(g) in the mixture? 1s22s22p42d1 They are, respectively: _____"
58. How much energy is needed to convert ozone a. 0.120 atm a. ground, excited, impossible
to oxygen? b. 0.630 atm b. ground, impossible, excited
a. 43 kcal/mol c. 0.510 atm c. excited, impossible, ground
b. 0 kcal/ mol d. 0.240 atm d. excited, ground, impossible
c. 68 kcal/mol
74. At what temperature in 0C will O2 has under d. O2 is the reducing agent; Mg is the oxidizing
a pressure of 2.4 atm? (ρ of O2= 1.43 g/L) agent.
a. 645.7510C
b. 3810C 83. By decreasing the pressure of an ideal gas at
c. 315.570C constant temperature and amount of substance
d. 318.160C 1/3 times the original pressure, the volume of
gas will
75. Macro Vee collected hydrogen gas using a. expands two thirds the original
water displacement method. He measured the b. increases three times the original
temperature of water using a thermometer and c. multiply by a factor of 1/3
found out that it is 230C with the correponding d. decreases three times the original
pressure of 21.1 mmHg. Calculate the pressure of
hydrogen gas under standard atmospheric 84. What is the gravimetric (i.e.m.,mass)
pressure. percentage of oxygen in K2CrO4?
a. 95.81 KPa a. 0.33
b. 98.51 Kpa b. 0.66
c. 98.15 Kpa c. 0.57
d. 95.18 Kpa d. 0.42
76. A sample of an unknown compound is found 85. There are 500 g of zinc sulfide (ZnS) in a load
to be 49.3% carbons, 9.6% hydrogen, 19.2% of zinc ore. The ZnS is roasted in excess air to
nitrogen, and 21.9% oxygen by weight. What is form zinc oxide (ZnO) and sulfer dioxide (S)2).
its molecular formula? How many grams of zinc can be subsequently
a. C3H7NO recovered if 5% of the zinc is lost in the roasting
b. C3H7NO process?
c. C4H<><> a. 340 g
d. C4H4NO b. 380 g
c. 320 g
77. Balance the following reaction. d. 400 g
a. HBrO3 + 5HBr 3H2O + 3bR2
b. 3HBrO3 + HBr 2H2O + 2Br2 86. What is the enthalpy of reaction at 25oC for
c. 2HBrO3 + 4HBr 3H2O + 3Br2 the combustion of ethane ( C2H6)?
d. HBrO3 + 4HBr 3H2O + Br2 a. -680 kcal/mol (exothermic)
b. -340 kcal/mol ( exothermic)
78. Which of the following is the correct electron c. 130 kcal/mol (endothermic)
configuration of Pb? d. 340 kcal/mol (endothermic)
a. [Xe]6s24f146s2
b. [Xe]6s25d104f146p2 *87. Chlorine gas can be prepared in the
c. [Xe]6s25d104f145d106p2 laboratory by the reaction of solid manganese
d. [Xe]5d104f146p2 dioxide with hydrochloric acid. (The other
reaction products are aqueous manganese
79. The mole (mol) is the amount of a substance chloride and water.)How much MnO2 should be
that contains as many elementary entities as added to excess HCI to obtain 275 mL of chlorine
there are atoms in exactly gas at 5.0oC and 650 mmHg?
a. 12.00 grams of C. a. 0.956 g
b. average atomic mass of isotopes of C. b. 0.765 g
c. 12.01 grams/mol of C. c. 0.856 g
d. 12.00 grams of 12C. d. 0.865 g
80. At STP the volume of 1.5 mole N2as compared 88. Which principal energy level has exactly four
to 1.0 mole O2 is subshells?
a. higher to about three fourths a. 3
b. the same, 22.4L b. 2
c. different by about 11.2 L c. 4
d. differ by a factor of 1.25 d. 1
81. "::Add_Chem_008:: How many grams of 89. The gas present in electric bulbs is argon. If a
glucose, C6H12O6, are necessary to prepare 656 sample of this gas is at a pressure of 101.325 kPa,
mL of a solution with a concentration that is when the volume is 0.1L and the temperature is
0.550 molar? _____" 32oC,what must its temperature [in oC] be if its
a. 0.00200 g volumes becomes 200mL and its pressure 96
b. 151 g kPa?
c. 64.9 g a. 205
d. 214 g b. 105
c. 305
82. n the following reaction, which elements are d. 405
the reducing and exidizing agents?
a. Mg is the reducing agents; O2 is the oxidizing *90. The mineral manganosite is a cmpound of
agent. manganese-55 and oxgen-16. If 77%o f the mass
b. MgO is the reducing agent; Mg is the oxidizing manganosite is due to manganese,what is the
agent. empirical formula of manganosite?
c. Mg is the reducing agent;MgO is the oxidizing a. MnO2
agent. b. Mn3O4
c. MnO
d. MnO3
91. Enthalpy of formation is most closely defined
as the
a. sum of the enthalpy of reactions.
b. potential energy of a substance.
c. energy absorbed or released during a chemical
reaction.
d. energy absorbed during creation of 1
grammole of a compound from pure elements.
92. The elements that display the greatest non-
metallic character are located toward which
corner of the periodic table?
a. Dead center
b. Upper right
c. Upper left
d. Lower right
93. Which statement is incorrect regarding
energy?
a. Energy has a mass and takes up space.
b. Enegy can be gained in a reaction
c. Energy can be given off in a reaction.
d. Energy cannot be created nor destroyed.
94. Which atom is not paired with its correct ion
and ionic charge.
a. Li / Li1+
b. Rb / Rb1-
c. Mg / Mg2-
d. F / F1-
*95. A gold wire has a diameter of 1.00 mm.
What length of this wire contains exactly 1.00
mol of gold? [Given: density of Au = 17.0 g/cm3]
a. 15.8 m
b. 13.8 m
c. 14.8 m
d. 16.8 m
96. A 350. mL samle of 0.276 M HNO3 is partially
neutralized by 125mL of 0.0120 M Ca(OH)2. Find
the concentration of nitric acid in the resulting
solution.
a. 0.157 M
b. 0.197 M
c. 0.187 M
d. 0.167 M
97. Which sample demonstrate particles
arranged in regular geometric pattern?
a. CO2(aq)
b. CO2(l)
c. CO2(g)
d. CO2(s)
98. Which sentence below is incorrect?
a. Pure iron is a heterogeneous mixture.
b. Salads are heterogeneous mixtures.
c. Milk is a homogeneous mixture.
d. Sand and water make heterogeneous mixture.
99. Which sample represent a homogeneous
mixture?
a. CH3OH(aq)
b. CH3OH(s)
c. CH3OH(g)
d. CH3OH(l)
*100. An object will float at the surface of a liquid
if the mass of the object is less than the mass of
the liquid that it displaces. A spherical vessel
(diameter = 5.00 cm) when empty has a mass of
12.00 g. What is the greatest volume of water
that can be placed in the vessel and still have the can be produced from the reaction of 1.65 x 106 solution. What is the hydoxide ion concentration
vessel float at the surface of benzene? (Given: of aluminum oxide with 1.50 x 106 g of carbon? in this solution?
density of water = 1.00 g/cm3; density of a. 6.4 x 105 g a. 3.1 x 10?5 M
benzene = 0.879 g/cm3) b. 6.3 x 105 g b. 3.2 x 10?5 M
a. 55.5 L c. 6.5 x 105 g c. 3.3 x 10?5 M
b. 45.5 L d. 6.6 x 105 g d. 3.4 x 10?5 M
c. 35.5 L
d. 25.5 L 109. Which electron configuration demonstrates *117.A copper wire has a diameter of 2.00 mm.
an atom in the excited state? What length of this wire contains exactly 1.00
101. Air contains 78% N2, 21% O2, and 1% Ar, by a. 1s2 2s1 mol of copper? [Given: density of Cu = 8.92
volume. What is the density of air 1,000. torr b. 1s2 2s2 g/cm3]
and?10oC? c. 1s2 2s2 2p4 a. 2.26 m
a. 2.8 g/L d. 1s2 2s2 3s1 b. 2.25 m
b. 3.8 g/L c. 2.28m
c. 0.8 g/L *110. A sample of mercury(II) oxide is placed in a d. 2.27 m
d. 1.8 g/L 5.00 L evacuated container and heated until it
decomposes entirely to mercury metal and 118. How many valence electrons are in a atom
102. Which units could be used to express the oxygen gas.After the container is cooled to 25oC, with the configuration 1s2 2s2 2p6 3s2 3p2
account absorbed or released during chemical the pressure of the gas inside is 1.73 atm.What a. 5
reaction? mass of mercury(II) oxide was originally placed b. 2
a. Gram and liter into the container? c. 6
b. Calorie and joule a. 154 g d. 4
c. Torr and mmHg b. 150 g
d. Degree and gram c. 152 g 119. Which of the following bonds would you
d. 153 g expect to be the most polar?
103. Dimethyl hydrazine (CH3)2NNH2 has been a. N-P
used as a fuel in space, with nitrogen tetraoxide *111. How many cubic centimeters of ore b. N-Sb
(N2O4) as the oxidizer. The products of the containing 0.22% by mass gold must be c. N-Bi
reaction between these two in an engine are processed to obtain $100 worth of gold? The d. N-As
H2O, CO2, and N2. What is the mass of nitrogen density of the ore is 8.0 g/cm3 and the price of
tetraoxide required to burn 50 kg of dimenthly gold is $418 pre troy ounce. (14.6 troy oz = 1.0 *120. A 250. mL sample of 0.0328 M HCI is
hydrazine? ordinary pound,called an avoirdupois pound; 1lb partially neutralized by the addition of 100. mL of
a. 153 kg = 454g) 0.0245 M NaOH.Find the concentration of
b. 128 kg a. 5.2 x 102 cm 3 hydrochloric acid in the resulting soution.
c. 50 kg b. 3.2 x 102 cm 3 a. 0.0174 M
d. 100 kg c. 4.2 x 102 cm 3 b. 0.0163 M
d. 3.3 x 102 cm 3 c. 0.0164 M
*104. When octane (C8H18) is burned in a d. 0.0173 M
particular internal combustion engine, the yield 112. An atom in the ground state has seven
of the products (carbon dioxide and water) is valence electrons. Which electron configuration 121. Which of the following isotopes has the
93%. What mass of carbon dioxide will be could represent the valence electron greatest number of neutrons?
produced in this engine when 15.0 g of octane is configuration of this atom in the ground state? a. 40AR
burned with 15.0 g of oxygen gas? a. 3s2 3p1 b. 41Ca
a. 10. g b. 3s1 3p6 c. 31 P
b. 13 g c. 3s6 3p1 d. 35Cl
c. 11 g d. 3s2 3p5
d. 12 g 122. An unknown quantity of hydrogen gas has a
*113. The mole fraction of oxygen molecules in volume of 2.5 L at STP (0o and 1 atm). What is
105. Which two elements will display the most dry air is 0.2029.What volume of dry air at 1.00 the mass of hydrogen?
similar chemical properties? atm and 25oC is required for burning 1.00 L of a. 0.073 g
a. Nickel and phosporus hexane (C6H14, density = 0.660 g/mL) b. 0.22 g
b. Litium and potassium completely, yeilding carbon dioxide and water? c. 0.19 g
c. Chlorine and sulfur a. 8490 L d. 0.51 g
d. Aluminum and calcium b. 8409 L
c. 8495 L 123. At which temperature does a water sample
106. Which phase change is described correctly? d. 8499 L have the highest average kinetic energy?
a. Liquid to solid is called freezing a. 0 degrees Celcius
b. Solid to liquid is called vaporization 114. What is the mass of an object that has a b. 100 K
c. Gas to solid is called sublimation. density of 13 g/mL and a volume of 10 mL? c. 0 K
d. Solid to gas is called deposition a. 0.77 g/mL d. 100 degrees Celcius
b. 1.3 g/mL
107. Assuming the ground state, all of the c. 130 g/mL 124. A liquid will boil when
elements located in the group 12 of the periodic d. 1.3 g/L a. its vapor pressure is equal to the melting point
table will have the same number of b. it is heated to a temperature that is below the
a. occupied principal energy levels 115. Which phase change is described correctly? boiling point.
b. valence electrons a. Liquid to solid is called freezing c. its vapor pressure is equal to the surrounding
c. electrons b. Gas to solid is called sublimation. pressure
d. nuclear particles c. Solid to liquid is called vaporization d. a salt has been added to the liquid
d. Solid to gas is called deposition
*108. The Hall process for the production of the 125. In the following reaction, which elements
aluminun involves the reaction of the aluminum *116. When solid iron(II) hydroxide is added to are the reducing and exidizing agents?
oxide with elemental carbon to give aluminum water,the resulting solution contains 1.4 x 10?3 g a. MgO is the reducing agent; Mg is the oxidizing
metal and carbon momoxide. If the yield of this of dissolved iron(II) hydroxide per liter of agent.
reaction is 75%, what mass of aluminum metal
b. O2 is the reducing agent; Mg is the oxidizing are sodium carbonate and water.) What volume *141. What mass of KCIO3 must be decomposed
agent. of carbon dioxide at 25oC and 749 mmHg can be to produce 126 L of oxygen gas at 133oC and
c. Mg is the reducing agents; O2 is the oxidizing removed per kilogram of sodium hydroxide that 0.880 atm? (The other reaction product is solid
agent. reacts? a. 311L KCI.)
d. Mg is the reducing agent;MgO is the oxidizing b. 309L a. 272 g
agent. c. 310L b. 252 g
d. 308L c. 262 g
126. What is a distinguishing characteristic of the d. 282 g
halogens? . 134. The time required for a given volume of N2
a.Next to the noble gases, they are the most to diffuse through an orifice is 35 sec. Calculate
chemicallyinactive group. the molecular weight of a gas which requires 50 *142. How many liters of oxygen gas at 153oC
b. They are phosphorescent. sec to diffuse through the same orifice under and 0.820 atm can be produce by the
c. They readily accept an electron from another identical conditions. decomposition of 22.4 g of solid KCIO3? (The
atom to form compounds. a. 15.57 g/mole other decomposition product is solid potassium
d. They have a high electrical conductivity. b. 51.75 g/mole chloride.)
c. 57.15 g/mole a. 12.7 L
127. An atom has eight electrons in a 3d subshell. d. 71.55 g/mole b. 11.7 L
How many orbitals in this subshell have an c. 10.7 L
unpaired electron? 135. Which substance can be decomoposed d. 9.7 L
a. 3 chemicall?
b. 4 a. Iron *143. When 20.0 mL of a 0.250 M (NH4)2S
c. 1 b. Neon solution is added to 150.0 mL of a solution of
d. 2 c. Hydrogen Cu(NO3)2, CuS precipitate forms. The precipitate
d. Ammonia is then filtered from the solution,dried, and
128. Which of the following is not a conclusion weighed. If the recovered CuS found to have a
Rutherford made from his experiment with alpha *136. An object will float at the surface of a liquid mass of 0.3491 g, what was the concentration of
particles being shot at a thin sheet of gold foil? a. if the mass of the object is less than the mass of copper ions in the originalCu(NO3)2 solution?
An atom is mainly empty space the liquid that it dislaces.A spherical vessel a. 2.42 x 10-2 M
b. An atom has a very small, compact nucleus (diameter =2.00 cm) when empty has a mass of b. 2.34 x 10-2 M
c. An atom's mass is concentrated in the nucleus. 2.00 g. What is the greatest volume of water that c. 2.43 x 10-2 M
d. An atom has a negatively charged nucleus. can be placed in the vessel and still have the d. 2.24 x 10-2 M
vessel float at the surface of the water? (Given:
*129. The radius of the Earth is approximately density of water = 1.00 g/cm3) *144. When active metals such as magnesium
6370 km. If one could dig down straight towards a. 2.17 L are immersed in acid solution, hydrogen gas is
the center of the Earth, one would find that the b. 3.19 L evolved. Calculate the volume of H2(g) at 30.1oC
innermost 3480 km (the core) has an average of c. 2.19 L and 0.85 atm that can be formed when 275 mL
density of about 11 g/cm3. Above that are the d. 2.18 L of 0.725 M HCI solution reacts with excess Mg to
mantle and crust. If the average density of the give hydrogen gas and aqueous magnesium
Earth is 5.5 g/cm3, what is the average density of 137. It has been determined that 1.0 L of solution chloride.
the Earth's mantle and crust?(Recall that the contain 52.7 g H2SO4, 240.8 g KMnO4, 11.3 g a. 2.7 L
volume of a sphere is given V=(4/3)?r3.) K2SO4, and 5.5 g Mn2O7. The reaction equation b. 2.6 L
a. 4.3 g/cm3 is The molecular weights of the compounds are c. 2.8 L
b. 3.4 g/cm3 What is the equilibrium constant for the d. 2.9 L
c. 4.4 g/cm3 reaction?
d. 4.5 g/cm3 a. 5.2 x 10-3 *145. Calcium nitrate tetrahydrate dissolves in
b. 2.6 x 10-3 cold water to the extent of 266 g per 100 cm3.
130. Which of the following statements c. 1.3 x 10-3 What is the concentration of nitrate ions in this
pertaining to acids and bases is incorrect? d. 6.9 x 10-3 slution?
a. Bases have a sour taste. a. 23.5 M
b. Acids turn blue litmus paper red. *138. A 0.850-mole sample of nitrous oxide, a b. 20.5 M
c. Bases have a pH between 7 and 14. gas used as anasthetic by dentists, has a volume c. 21.5 M
d. Acids conduct electricity in aqueous solutions. of 20.46 L at 123oC and 1.35 atm. What would be d. 22.5 M
its volume [in L] at 468oC and 1.35 atm?
*131. Calculate the volume of H2(g) at 273 K and a. 36.3 *146. The first step in the Otswald process for
2.00 atm that will be formed when 275 mL of b. 37.3 producing nitric acid is 4NH3(g) + 5O2(G) ?
0.725 M HCI solution reacts with excess Mg to c. 39.3 4NO(g) + 6H2O(g). If the reaction of 150 g of
give hydrogen gas and aqueous magnesium d. 38.3 ammonia with 150 g of oxygen gas yeilds 87 g of
chloride. nitric oxide (NO), what is the percent yeild of this
a. 1.09 L 139. Which electron configuration demonstrates reaction?
b. 1.12 L an atom in the excited state? a. 0.44
c. 1.11 L a. 1s2 2s2 2p4 b. 0.22
d. 1.10 L b. 1s2 2s1 c. 0.33
c. 1s2 2s2 3s1 d. 0.11
132. A book is lifted off of the floor and placed on d. 1s2 2s2
a table that is one meter above the floor. The *147. A silver wire has a diameter of 0.500
book has *140.A commonly occurring isotope of tin is tin- mm.What length of this wire contains exactly
a. gained kinetic energy 118, while most oxygen occurs in nature as 1.00 mol of silver? [Given: density of Ag = 10.5
b. gained potential energy oxygen-16. A molecule of tin(IV) oxide formed g/cm3
c. gained sound energy from thesse isotopes contains a. 53.3 m
d. lost chemical energy a. 87 neutrons b. 52.3 m
b. 84 neutrons c. 50.3 m
133. A method of removing CO2 from a c. 80 neutrons d. 51.3 m
spacecraft is to allow the CO2 to react with d. 85 neutrons
sodium hydroxide. (The products of the reaction
*148. Americans combined drive about 4.0x109
miles per day and their vehicles get an average of
20 miles per gallon of fuel used. For each 1kg of
gasoline that is burned,about 3.0 kg of carbon
dioxed are produced. How many kilograms of
CO2 are emitted into the atmosphere each day
by cars in the U.S.? One gallon of gas weighs
about 3.5 kg.
a. 1.1x109 kg
b. 2.1x109 kg
c. 4.1x109 kg
d. 3.1x109 kg
*155. A 2.50-L flask contains a mixture of
methane (CH4) and propane (C3H8) at a pressure
of 1.45 atm and 20°C. When this gas mixture is
then burned in excess oxygen, 8.60g of carbon
dioxide is formed. (The other product is water).
What is the mole fraction of methane in the
original gas mixture?
a. 0.93
b. 0.73
c. 0.85
d. 0.75

*149. Iron has a density of 7.78 g/cm3. What What is the mass of 0.01 gram-moles of
mass of iron would be required to cover a Na₂SO₄?
football playing surface of 120 yds x 60 yds to a
depth of 1.0 mm?(1 inch = 2.54 cm)
a. 37 Mg a. 0.71 g
b. 57 Mg
b. 2.38 g
c. 47 Mg
d. 27 Mg c. 1.19 g

*150.The mineral hausmannite is a compound of d. 1.42 g

manganese-55 and oxygen-16. If 72% of the mass
of hausmannite is due to manganese, what is the
empirical formula of hausmannite?
a. Mn3O4
b. MnO3
c. MnO
d. MnO2

*151. The mineral pyrolusite is a compound of

manganese-55 and oxygen-16. If 63% of the mass
is pyrolusite is due to manganese, what is the
empirical formula of pyrolusite? Select one:
a. Mn3O4
b. MnO3
c. MnO
d. MnO2

*152. When 38.0 mL of 0.1250 M H2SO4 is added

to 100. mL of a solution of Pbl2, a precipitateof
PbSO4 is then filtered from the solution,dried,
and weighed. If the recovered PbSO4 is found to
have a mass of 0.0471 g, what was the
concentration of iodide ions in the original
solution?
a. 3.11 x 10-3 M
b. 3.12 x 10-2 M
c. 3.10 x 10-3 M
d. 3.11 x 10-2 M

153. A method of producing pure copper metal

involves the reaction of copper(I) sulfide with
oxygen gas to give copper metal and sulfur
dioxide. Suppose the yield of this reaction is 87%.
What mass of a copper ore consisting of 46%
copper(I) sulfide must be mined in order to
produce 1.0x103 kg (1.0 metric ton) of copper
metal?
a. 4.2x103 kg
b. 5.2x103 kg
c. 2.2x103 kg
d. 3.2x103 kg

*154. In the chemical reaction 5S + 6 KNO3 + 2

CaCO3 -> 3K2SO4 + 2CaSO4 + CO2 + 3N2, the
oxidizing agent is
a. CaCO3
b. CO2
c. S
d. KNO3