Meminy

tssicnment
- ON -

Jist Law OF

hemoduna-
mics
NAME Jao uwA AmAoni
CLASS XI 3
ROLL No. -13
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Date

Fi Las ef
HERMODYNAMÝCSS
STATEMENT OF FIRST LAW OF THERMODYNAMIcs
ayCaMCaM Meithe se Ceaticd na destnayed
C Athaisgh itcaM ke Cometed o ne
AMathe

MATHEMATICAL DERIVATION
AuppaAR
ia the imtunwaal eAenau oAyAttswa
wmdar banticulan Ae Cenditiew
t h e wmoum htatEMEnqu
Auoplizd to w AudeANA
w the w.cmk done the Ayatem amd
C AA Hhe
he ww.k wtermal_NRn the AteAm

We haNe

AU 0,+W

ChamgoAM Mtamal nArqy heat Auloklied to

eAuata0 WOnkdeme on the Autesna
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S1GNIFICANCE OF FIRST LAW

chaa N Mkemak MLngu Hea Aulepliad0 AyAte
LwOk d.one
oLk A denathe chamge M Mmtitna
Louato heat aluaxhed
LE0
AU2

JMtLAA.al_Meqy AAysttstau MLmAkant.

Luhem Lwank devne
tD the
bythe Ayazea Aa tquol
he hak ahsuled by he Sustn
ADs0
UMdav ComAtam Velunsne
md CMakana
Comditae tho ChamgeMA TEpLznakia-
thu AuyAteM iMtenmal mng
AAual tD htatiakaanbeá RAN

PAV COwnk dane dunswa

AU a- PAV 1p amAIOM)
2 Au +PAV
Ay
Cwnden Lonotant vawmm

MA
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ENTHALPY OF COMBUSTION
Ahe dhamg w wthaloy peduced
Awh tww Me male
Lowakkcbely
9ayaumA a gwu tempenatu

CHLa 20,a) Coa)tt2H_oLL

tMthalky mnuation AH 820.3 KJ
CALORIFIC VALUE
JA dlimod A the mauwmk heat eneduore
uat.asmce eod au ue
JA Cooaelek humio

Value
FOOD CALORIFIG YALU E CKT Ila)
4.5
Jutta 30.4
316
32
Augan
0
16.5

Colamiki value wela

FUELS CALORIEIC VALUE (kJl
kengAeme 8
utiome (LPG) 55
we i 5
methame 55.6
Lused
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HEssS LAW
STATEMENT OF HESs's LAW
The nkhalecham4eM chasnical Heactio
the Aame Auhthan the 1eactio takea klace

Rloc M ARAenak taRa dhe mthalp he Keactiu

Adaelnuc the wtholeiee heacki.eA

CTAAAPem ding he tzpA.

M ep AH -8
AM ARMLLa Ateo A H AH + AH, +AH

S1GNIELCANCE OF HE5S'S LAN

HEAA LauAiaailiz thak he heak oHeactia
danoda 0AA the At.at.es ehtackamta Amd nerlunka
DV gk ue he maAmALn M uhich the Heactiamka
Ae hamaed mto h knaducta HeAA u alon
4uAkikiea Loa MARAMAtian mn44
enoana
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NUMERICAL
Lthat uilb be the valum hamge i 500To
Luank A olane ty Ayakt tionotainnásngidea
AAA The Annauwa.dimg tMehtaAMAtaAnk RhAAAhA
e5al Cam lOL3JD

z -So o JS P 5atm, 2 5 10) 3

W-PAV

50 5
Sx lO1.3

. 8 11 m Au

AAMationmaabaanka 5kJ heat ak canakranmt valume

Omou ita tennkanatune MAAA 1.0 15'C to 30'c Calculate
the vam Md Au

5 kT
4 AU -w

a
4 CcomAt.oM dev =O

AU 5kJ

7 5 kT
J
A 5 kT
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ACyhmdev 4.04onkaim 14kg utiame

utame a
ee.da2000 kJ a M44 p day
4 L0akimg hou lmg he uylaids
&aAk Heat COmriei.m rutamu is 2658 kI mo

mglecuulan MAAA 10 ukaane CuHio) 5

2x4+1X10
8

mdle kutane aivea 26 58 kTmel

giuu 26 S8 k mel
6 558
8 X 4X 1000

641586.206 kJ|mal

20.000 k J MAedr 1M 1 clay

6L1586.206 UAed in 641536 206
200DO

32.0193
CAwa)

iv male naphbhaleme (Ci,H) akunak

im O a 0oakamtValssone to giue CO Cmd
ab 26 The heat Malmed wwaskeumc
513 1 0 Caluulate the heat oHeactai
Comatam aAAAnA R .314 JK mul)

C H) t 120, a) loCo ()+4Ho U)

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T-25.C (213+25) K
28 K

8 . 314 T k mul
AU= -6131. 0kT

An 10-12 2 mole

AH u+PAV
AH O An RT
-5131 - 2x 8:314298
ODO

513.0 + .q55
-5143.45 CAw)

The heak a Lobuatis

aGeho acid MM ksownh calonimaLke u0aA
be -14 51kT Calankake ha
ewkhalk Comaki ekio au ak 26'

maleuan maa CH, COH 122+ 16X +1x4

24+32 +4
60
in omb Coloninmuten AV= O
AH=Au+PAV_
AV=O AH= Au
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ho o mdles M

AU -1451 kT
meleo

14.57 X 6O kJ mel
- Awe
-874 2 kJ n col