IIT - JEE 2014 (Advanced) : Code: 1

CODE : 1
IIT - JEE 2014 (Advanced)

(2) Vidyalankar : IIT JEE 2014 − Advanced : Question Paper & Solution
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IIT JEE 2014 Advanced : Question Paper & Solution (Paper – II) (3)
PART I : PHYSICS
SECTION − 1 : (Only One Option Correct Type)
This section contains 10 multiple choice questions. Each question has four choices
(A), (B), (C) and (D) out of which ONLY ONE option is correct.
1. A tennis ball is dropped on a horizontal smooth surface. It bounces back to its original
position after hitting the surface. The force on the ball during the collision is proportional
to the length of compression of the ball. Which one of the following sketches describes
the variation of its kinetic energy K with time t most appropriately? The figures are only
illustrative and not to the scale.
(A) (B)
(C) (D)
1. (B)
1 1
K = mυ2 = mg 2 t 2
2 2
2. A wire, which passes through the hole in a small bead, is bent in the form of quarter of a
circle. The wire is fixed vertically on ground as shown in the figure. The bead is released
from near the top of the wire and it slides along the wire without friction. As the bead
moves from A to B, the force it applies on the wire is
(A) always radially outwards.
(B) always radially inwards.
(C) radially outwards initially and radially inwards later.
(D) radially inwards initially and radially outwards later.
2. (D)
1
mgR(1 − cos θ) = mv 2
2
2 N
mv
∴ = 2mg(1 − cos θ)
R
mv 2
∴ N = mg cos θ − θ
R R
= mg cos θ − 2mg (1 − cos θ) R cos θ
= mg cos θ + 2 mg cos θ − 2 mg
⎛ 2⎞
= 3 mg cos θ − 2 mg = 3 mg ⎜ cos θ − ⎟
⎝ 3⎠
2
if cos θ > N is positive
3
∴ wire will exert force radially outward. so bead will exert force radially inward initially &
radially outward later.
3
3. During an experiment with a metre bridge, the galvanometer shows a null point when the
jockey is pressed at 40.0 cm using a standard resistance of 90 Ω, as shown in the figure.
The least count of the scale used in the metre bridge is 1 mm. The unknown resistance is
(A) 60 ± 0.15 Ω (B) 135 ± 0.56 Ω

(C) 60 ± 0.25 Ω (D) 135 ± 0.23 Ω
3. (C)
R 90
=
40 60
∴ R = 60 Ω
ΔR Δ1 Δ 2 0.1 0.1 5 1
= + = + = =
R 1 2 40 60 1200 240
R 60 1
ΔR = = = = 0.25
240 240 4
∴ 60 ± 0.25 Ω
4. Charges Q, 2Q and 4Q are uniformly distributed in three dielectric solid spheres 1, 2 and
3 of radii R/2, R and 2R respectively, as shown in figure. If magnitudes of the electric
fields at point P at a distance R from the centre of spheres 1, 2 and 3 are E1, E2 and E3
respectively, then
(A) E1 > E2 > E3 (B) E3 > E1 > E2

(C) E2 > E1 > E3 (D) E3 > E2 > E1
4. (C)
KQ
E1 =
R2
K2Q
E2 =
R2
KQ
E3 =
2R 2
E2 > E1 > E3
4
5. A point source S is placed at the bottom of a transparent block of height 10 mm and

refractive index 2.72. It is immersed in a lower refractive index liquid as shown in the
figure. It is found that the light emerging from the block to the liquid forms a circular
bright spot of diameter 11.54 mm on the top of the block. The refractive index of the
liquid is
(A) 1.21 (B) 1.30 (C) 1.36 (D) 1.42

5. (C)
11.54
tan θ =
2 × 10
11.54
sin θ = 11.54 μ
r=
(11.54 ) + (400)
2
2
2.72 sin θ = μ × sin 90°
11.54 θ
2.72 × =μ
2.72 10 mm
(11.54 ) 2
+ 400
μ = 1.36
6. Parallel rays of light of intensity I = 912 Wm−2 are incident on a spherical black body kept
in surroundings of temperature 300 K. Take Stefan-Boltzmann constant σ = 5.7 × 10−8
Wm−2K−4 and assume that the energy exchange with the surroundings is only through
radiation. The final steady state temperature of the black body is close to
(A) 330 K (B) 660 K (C) 990 K (D) 1550 K
6. (A)
912
σ × T4 = σ (300)4 +
4
912 4 912
T4 = (300) 4 + −8
= (300) + ×108
(4 × 5.7 × 10 ) 22.8
4 8 8
= (300) + (40 × 10 ) = (81 + 40) × 10
= 121 × 108
∴ T = 330 K
7. A metal surface is illuminated by light of two different wavelengths 248 nm and 310 nm.
The maximum speeds of the photoelectrons corresponding to these wavelengths are u1
and u2, respectively. If the ratio u1 : u2 = 2 : 1 and hc = 1240 eV nm, the work function of
the metal is nearly
(A) 3.7 eV (B) 3.2 eV (C) 2.8 eV (D) 2.5 eV
7. (A)
2
k1 ⎛u ⎞
= ⎜ 1⎟ =4
k2 ⎝ u2 ⎠
hc 1240
k1 = −φ = −φ
λ 248
k1 = (5 − φ)
1240
k2 = −φ
310
5
k2 = (4 − φ)
k1 ⎛ 5−φ ⎞
=⎜ ⎟ =4 ⇒ 5 − φ = 4(4 − φ)
k2 ⎝4−φ⎠
⇒ 5 − φ = 16 − 4φ
11
⇒ 3 φ = 11 ⇒ φ = = 3.7ev
3
8. If λCu is the wavelength of Kα X-ray line of copper (atomic number 29) and λMo is the
wavelength of the Kα X-ray line of molybdenum (atomic number 42), then the ratio
λCu/λMo is close to
(A) 1.99 (B) 2.14 (C) 0.50 (D) 0.48
8. (B)
ν = a (z − b)
ν2 z2 − b ⎛ 41 ⎞
= = ⎜ ⎟ (b = 1)
ν1 z1 − b ⎝ 28 ⎠
2
λ1 ⎛ 41 ⎞
= ⎜ ⎟ = 2.14
λ1 ⎝ 28 ⎠
1
9. A planet of radius R = X (radius of Earth) has the same mass density as Earth.
10
R
Scientists dig a well of depth on it and lower a wire of the same length and of linear
5
mass density 10−3 kgm−1 into it. If the wire is not touching anywhere, the force applied at
the top of the wire by a person holding it in place is (take the radius of Earth = 6 × 106 m
and the acceleration due to gravity on Earth is 10 ms−2)
(A) 96 N (B) 108 N (C) 120 N (D) 150 N
9. (B)
fnet = ∫ dm g′
R
gor
= ∫ λdr
4R R
5
R R
λg 0 λg o ⎛ r 2 ⎞
=
R ∫
4R
rdr = ⎜ ⎟
R ⎝ 2 ⎠ 4R
5
5
λg o ⎛ 2 16R 2 ⎞ λg o ⎛ 9R 2 ⎞
= ⎜R − ⎟= ⎜ ⎟
2R ⎝ 25 ⎠ 2R ⎝ 25 ⎠
9λ g o R
=
50
Re = 6 × 105
GM
go = = 1 m/s2
R2
1000 ×
100
9 × 10−3 × (1) 6 × 105 5400
⇒ fnet = = = 108 N
50 50
6
10. A glass capillary tube is of the shape of a truncated cone with an apex angle α so that its
two ends have cross sections of different radii. When dipped in water vertically, water
rises in it to a height h, where the radius of its cross section is b. If the surface tension of
water is S, its density is ρ, and its contact angle with glass is θ, the value of h will be (g is
the acceleration due to gravity)
2S 2S
(A) cos(θ − α) (B) cos(θ + α)
bρg bρg
2S 2S
(C) cos(θ − α 2) (D) cos(θ + α 2)
bρg bρg
10. (D)
⎛ α⎞
2π b × s cos ⎜ θ + ⎟ = π b2 h νg
⎝ 2⎠
2S ⎛ α⎞
cos ⎜ θ + ⎟ = h
bυg ⎝ 2⎠
SECTION − 2 : Comprehension Type (Only One Option Correct)

This section contains 3 paragraphs, each describing theory, experiments, data etc. Six
questions relate to the three paragraphs with two questions on each paragraph. Each
question has only one correct answer among the four given options (A), (B), (C) and (D).
Paragraph for Questions 11 & 12

In the figure a container is shown to have a movable (without friction)
piston on top. The container and the piston are all made of perfectly
insulating material allowing no heat transfer between outside and inside the
container. The container is divided into two compartments by a rigid
partition made of a thermally conducting material that allows slow transfer
of heat. The lower compartment of the container is filled with 2 moles of an
ideal monatomic gas at 700 K and the upper compartment is filled with 2
moles of an ideal diatomic gas at 400 K.
3 5
The heat capacities per mole of an ideal monatomic gas are CV = R, CP = R , and those
2 2
5 7
for an ideal diatomic gas are CV = R, CP = R .
2 2
11. Consider the partition to be rigidly fixed so that it does not move. When equilibrium is
achieved, the final temperature of the gases will be
(A) 550 K (B) 525 K (C) 513 K (D) 490 K
11. (D)
Heat loss = heat gain
n1 CP1 (T − 400) = n2 CV2 (700 − T)
7 (T − 400) = 3 (700 − T)
10 T = 4900
T = 490K
12. Now consider the partition to be free to move without friction so that the pressure of gases
in both compartments is the same. Then total work done by the gases till the time they
achieve equilibrium will be
(A) 250 R (B) 200 R (C) 100 R (D) −100 R
7
12. (D)
n1 CP1 (T − 400) = n2 CP2 (700 − T)
7 (T − 400) = 5 (700 − T)
12 T = 6300
6300 2100
T = = = 525 K
12 4
w1 = n1 R ΔT1
= 2(R) 125 = 250 R
w2 = n2 R ΔT2
= 2 (R) (−175) = − 350 R
wnet = − 100 R
Paragraph For Questions 13 & 14

A spray gun is shown in the figure where a piston pushes air out of a nozzle. A thin tube of
uniform cross section is connected to the nozzle. The other end of the tube is in a small liquid
container. As the piston pushes air through the nozzle, the liquid from the container rises into
the nozzle and is sprayed out. For the spray gun shown, the radii of the piston and the nozzle
are 20 mm and 1 mm respectively. The upper end of the container is open to the atmosphere.
13. If the piston is pushed at a speed of 5 mms−1, the air comes out of the nozzle with a speed
of
(A) 0.1 ms−1 (B) 1 ms−1 (C) 2 ms−1 (D) 8 ms−1
13. (C)
Av = constant ⇒ 5 mms1 × (20 mm)2 = ν × (1mm)2
⇒ ν = 2ms−1
14. If the density of air is ρa and that of the liquid ρ , then for a given piston speed the rate
(volume per unit time) at which the liquid is sprayed will be proportional to
ρa ρ
(A) (B) ρa ρ (C) (D) ρ
ρ ρa
14. (A)
Speed of ejection of liquid = speed of outgoing air.
In the limiting case ρL → ∞; volume flow rate = 0
Paragraph For Questions 15 & 16
The figure shows a circular loop of radius a with

two long parallel wires (numbered 1 and 2) all in
the plane of the paper. The distance of each wire
from the centre of the loop is d. The loop and the
wires are carrying the same current I. The current
in the loop is in the counterclockwise direction if
seen from above.
8
15. When d ≈ a but wires are not touching the loop, it is found that the net magnetic field on
the axis of the loop is zero at a height h above the loop. In that case
(A) current in wire 1 and wire 2 is the direction PQ and RS, respectively and h ≈ a
(B) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h ≈ a
(C) current in wire 1 and wire 2 is the direction PQ and SR, respectively and h ≈ 1.2 a
(D) current in wire 1 and wire 2 is the direction PQ and RS, respectively and h ≈ 1.2 a
15. (C)
μ ia 2
B1oop = 0
2 (h 2 + a 2 )3/2
μ 0i
2π d 2 + h 2
d
μ ia 2 μ 0i d
∴ ⋅ 2 =
2 (h + a 2 )3/2 2a d 2 + h 2
a2 a
⇒ 2 2 3/2
= 2 2
⇒ π a = 2 h2 + a2
2(h + a ) π(a + h )
2h
⇒a=
(π2 − 4)
16. Consider d >> a, and the loop is rotated about its diameter parallel to the wires by 30°
from the position shown in the figure. If the currents in the sires are in the opposite
directions, the torque on the loop at its new position will be (assume that the net field due
to the wires is constant over the loop)
μ I2a 2 μ I2a 2 3μ 0 I 2 a 2 3μ 0 I 2 a 2
(A) 0 (B) 0 (C) (D)
d 2d d 2d
16. (B)
⎛μ i⎞
B = 2⎜ 0 ⎟
⎝ 2πd ⎠
μ
∴ τ = iπa2 0 sin (30°)
πd
SECTION − 3 : Matching List Type (Only One Option Correct)

This section contains four questions, each having two matching lists. Choices for the
correct combination of elements from List-I and List-II are given as options (A), (B), (C)
and (D), out of which one is correct.
9
17. Four charges Q1, Q2, Q3 and Q4 of same magnitude are fixed along the x axis at x = −2a,
−a, +a and +2a, respectively. A positive charge q is placed on the positive y axis at a
distance b > 0. Four options of the signs of these charges are given in List I. The direction
of the forces on the charge q is given in List II. Match List I with List II and select the
correct answer using the code given below the lists.
q (0, b)
List I List II
P. Q1, Q2, Q3, Q4 all positive 1. +x
Q. Q1, Q2 positive; Q3, Q4 negative 2. −x
R. Q1, Q4 positive; Q2, Q3 negative 3. +y
S. Q1, Q3 positive; Q2, Q4 negative 4. −y
Code :
(A) P-3, Q-1, R-4, S-2 (B) P-4, Q-2, R-3, S-1
(C) P-3, Q-1, R-2, S-4 (D) P-4, Q-2, R-1, S-3
17. (A)
(P) → (3), (Q) → (1), (R) → (4), (S) → (2)
(P) → (3)
Q1 Q2 Q3 Q4
All x component will be cancelled only y will be exist i.e. along +ve.
(Q) → (1)
+ + − −
All y component will be cancelled and +ve x will exist.

(R) → (4)
+ − − +
Each pair will cancel x of each other and y of +ve pair will be smaller than −ve so net will
be along −ve y.
(S) → (2)
+ − + −
Q1 Q2 Q3 Q4
Each dipole pair will cancelled y of each other and x of Q2 − Q3 pair along −ve x is
stronger than that of Q1 − Q4 along +ve x.
10
18. Four combinations of two thin lenses are given in List I. The radius of curvature of all
curved surfaces is r and the refractive index of all the lenses is 1.5. Match lens
combinations in List I with their focal length in List II and select the correct answer using
the code given below the lists.
List I List II
P. 1. 2r
Q. 2. r/2
R. 3. −r
S. 4. r
Code :
(A) P-1, Q-2, R-3, S-4 (B) P-2, Q-4, R-3, S-1
(C) P-4, Q-1, R-2, S-3 (D) P-2, Q-1, R-3, S-4
18. (B)
(P) → (2), (Q) → (4), (R) → (3), (S) → (1)
R
f bi convex = =R
2 ( µ − 1)
R
f plano convex = = 2R
( µ − 1)
−R
f plano convex = = −2R
( µ − 1)
1 1 1 1 1 R
(P) → (2) = + = + ⇒ f eq =
f eq f1 f 2 R R 2
1 1 1 1
(Q) → (4) = + = ⇒ f eq = R
f eq 2R 2R R
1 1 1 −1
(R) → (3) =− − = ⇒ f eq = − R
f eq 2R 2R R
1 1 1 1
(S) → (1) = − = ⇒ f eq = 2R
f R 2R 2R
19. A block of mass m1 = 1 kg another mass m2 = 2 kg, are placed together (see figure) on an
inclined plane with angle of inclination θ. Various values of θ are given in List I. The
coefficient of friction between the block m1 and the plane is always zero. The coefficient
of static and dynamic friction between the block m2 and the plane are equal to μ = 0.3. In
List II expressions for the friction on block m2 are given. Match the correct expression of
the friction in List II with the angles given in List I, and choose the correct option. The
acceleration due to gravity is denoted by g.
[Useful information : tan (5.5°) ≈ 0.1; tan(11.5°) ≈ 0.2; tan(16.5°) ≈ 0.3]
11
List I List II
P. θ = 5° 1. m2g sin θ
Q. θ = 10° 2. (m1 + m2) g sin θ
R. θ = 15° 3. μm2 g cos θ
S. θ = 20° 4. μ (m1 + m2) g cos θ
Code :
(A) P-1, Q-1, R-1, S-3 (B) P-2, Q-2, R-2, S-3
(C) P-2, Q-2, R-2, S-4 (D) P-2, Q-2, R-3, S-3
19. (D)
(P) → (2), (Q) → (2), (R) → (3), (S) → (3)
for not to slip

m1
μ m2g cosθ = (m1 + m2) g sinθ μ=0
μ 2 cos θ = 3 sin θ m2
2 0.6 μ = 0.3
tan θ = μ = = 0.2
3 3
in case (P) (Q) it will not slip
⇒ friction is (m1 + m2) g sinθ θ
for (R) (S) of they must slip
so friction should be kinetic
i.e. μ m2gcos θ
20. A person in a lift is holding a water jar, which has a small hole at the lower end of its side.
When the lift is at rest, the water jet coming out of the hole hits the floor of the lift at a
distance d of 1.2 m from the person. In the following, state of the lift’s motion is given in
List I and the distance where the water jet hits the floor of the lift is given in List II.
Match the statements from List I with those in List II and select the correct answer using
the code given below the lists.
List I List II
P. Lift is accelerating vertically up. 1. d = 1.2 m
Q. Lift is accelerating vertically down with an 2. d > 1.2 m
acceleration less than the gravitational
acceleration.
R. Lift is moving vertically up with constant speed. 3. d < 1.2 m
S. Lift is falling freely. 4. No water leaks out of the jar
Code :
(A) P-2, Q-3, R-2, S-4 (B) P-2, Q-3, R-1, S-4
(C) P-1, Q-1, R-1, S-4 (D) P-2, Q-3, R-1, S-1
20. (C)
V = 2gh
2h 2H h
d = V = 2gh = 2 h(H)
g g
for other value of geff it is independent of value of geff
except geff = 0 H
⎛0⎞
where we cannot cancel g in equation ⎜ ⎟ in that case
⎝0⎠
it will not come out as there is no pressure at all
(P) (Q) (R) → (I)
(S) → (4)
12
PART II : CHEMISTRY
21. The acidic hydrolysis of ether (X) shown below is fastest when
[Figure]
(A) one phenyl group is replaced by a methyl group.

(B) one phenyl group is replaced by a para−methoxyphenyl group.
(C) two phenyl groups are replaced by two para−methoxyphenyl groups.
(D) no structural change is made to X.
21. (C)
Para −methoxy phenyl group is electrodonating which can stabilize carbocation.
22. Isomers of hexane, based on their branching, can be divided into three distinct classes as
shown in the figure.
[Figure]
The correct order of their boiling point is

(A) I > II > III (B) III > II > I (C) II > III > I (D) III > I > II
22. (B)
With increase in branching boiling point decreases.
23. The major product in the following reaction is

[Figure]
(A) (B)
(C) (D)
13
23. (D)
O
O
Cl (1) CH 3MgBr, dry ether
CH3 ⎯⎯⎯⎯⎯⎯⎯⎯ → Cl
CH3
CH3
O CH3
24. Hydrogen peroxide in its reaction with KIO4 and NH2OH respectively, is acting as a
(A) reducing agent, oxidising agent (B) reducing agent, reducing agent
(C) oxidising agent, oxidising agent (D) oxidising agent, reducing agent
24. (A)
25. The product formed in the reaction of SOCl2 with white phosphorous is
(A) PCl3 (B) SO2Cl2 (C) SCl2 (D) POCl3
25. (A)
26. Under ambient conditions, the total number of gases released as products in the final step
of the reaction scheme shown below is
(A) 0 (B) 1 (C) 2 (D) 3

26. (C)
XeF6 + 3H 2O ⎯⎯
→ XeO3 + 3Η 2 F2
XeO3 + OH − ⎯⎯
→ HXeO −4
2HXeO −4 + 2OH − ⎯⎯
→ XeO6−4 + Xe + 2H 2O + O 2
27. For the identification of β−naphthol using dye test, it is necessary to use
(A) dichloromethane solution of β−naphthol.
(B) acidic solution of β−naphthol.
(C) neutral solution of β−naphthol.
(D) alkaline solution of β−naphthol.
27. (D)
28. For the elementary reaction M → N, the rate of disappearance of M increases by a factor
of 8 upon doubling the concentration of M. The order of the reaction with respect to M is
(A) 4 (B) 3 (C) 2 (D) 1
14
28. (B)
r1 = K[M]x …(1)
8r1 = K[2M]x …(2)
x
1 ⎛1⎞
⇒ =⎜ ⎟
8 ⎝2⎠
3 n
⎛1⎞ ⎛1⎞
⇒ ⎜ ⎟ = ⎜ ⎟ ⇒x=3
⎝2⎠ ⎝2⎠
29. For the process

H 2 O() → H 2 O(g)
at T = 100 °C and 1 atmosphere pressure, the correct choice is
(A) ΔSsystem > 0 and ΔSsurroundings > 0 (B) ΔSsystem > 0 and ΔSsurroundings < 0
(C) ΔSsystem < 0 and ΔSsurroundings > 0 (D) ΔSsystem < 0 and ΔSsurroundings < 0
29. (B)
H 2O() ⎯⎯ → H 2O (g) (100°C)
ΔS > 0 system ΔS surrounding < 0
30. Assuming 2s−2p mixing is NOT operative, the paramagnetic species among the following is
(A) Be2 (B) B2 (C) C2 (D) N2
30. (B)
SECTION − 2 : Comprehension Type (Only one Option Correct)

Paragraph For Questions 31 and 32
Schemes 1 and 2 describe sequential transformation of alkynes M and N. Consider only the
major products formed in each step for both the schemes.
HO M
H
N
15
31. The product X is
H3CO
(A) (B)
H H
CH3CH 2 O
(C) (D)
H H
31. (C)
HO − CH 2 − CH 2 − C ≡ CH
NaNH 2
ⓛ
Na O − CH 2CH 2C ≡ C − Na
C2 H5Βr(leq)
H5C2O − CH 2CH 2C ≡ C − Na
CH 3I
H5C2O − CH 2CH 2C ≡ C − CH3

H 2 | Pd − BaSO 4
H 5C 2 O − CH 2 CH 2 C = C − CH 3
H H
32. The correct statement with respect to product Y is

(A) It gives a positive Tollens test and is a functional isomer of X.
(B) It gives a positive Tollens test and is a geometrical isomer of X.
(C) It gives a positive iodoform test and is a functional isomer of X.
(D) It gives a positive iodoform test and is a geometrical isomer of X.
32. (C)
CH3 − CH 2 − C ≡ CH
NaNH 2
C − C − C ≡ C − Na
OH
Br
CH3
C − C − C ≡ C − CH 2 − CH − OH
H 3O +
16
CH3
C − C − C − C − CH 2 − CH − OH
O
H 2 | Pd | C CH3
C − C − C − C − CH 2 − CH − OH
Cr2O3 CH3
C − C − C − C − CH 2 − C = O
Paragraph For Questions 33 and 34
An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to
give tetrahedral and square planar complexes, respectively. An aqueous solution of
another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous
solution of M2 on reaction with reagent S gives white precipitate which dissolves in
excess of S. The reactions are summarized in the scheme given below:
SCHEME:
33. M1, Q and R, respectively are

(A) Zn2+, KCN and HCI (B) Ni2+, HCI and KCN
2+
(C) Cd , KCN and HCI (D) Co2+, HCI and KCN
33. (B)
[NiCl4 ]−2 ←⎯⎯ ⎯ Ni +2 ←⎯⎯⎯ Ni(CN) 4
HCl KCN
tetra hedral Sq. Planar
34. Reagent S is
(A) K4[Fe(CN)6] (B) Na2HPO4 (C) K2CrO4 (D) KOH
34. (D)
Cl− KCN −
[ ZnCl4 ]−2 → Zn +2 ⎯⎯⎯→ K 2 Zn(CN) 4
⎯⎯⎯
tetra tetra
It gives a white precipitate with excess of NaOH.
17
Paragraph for Questions 35 and 36

X and Y are two volatile liquids with molar weights of 10 g mol−1 and 40 g mol−1
respectively. Two cotton plugs, one soaked in X and the other soaked in Y, are
simultaneously placed at the ends of a tube of length L = 24 cm, as shown in the figure. The
tube is filled with an inert gas at 1 atmosphere pressure and a temperature of 300 K. Vapours
of X and Y react to form a product which is first observed at a distance d cm from the plug
soaked in X. Take X and Y to have equal molecular diameters and assume ideal behaviour for
the inert gas and the two vapours.
35. The value of d in cm (shown in the figure), as estimated from Graham′s law, is
(A) 8 (B) 12 (C) 16 (D) 20
35. X M1 = 10, Y M2 = 40
x 40 x 2
= =
24 − x 10 24 − x 1
x = 48 − 2x
3x = 48
48
x= = 16
3
36. The experimental value of d is found to be smaller than the estimate obtained using
Graham′s law. This is due to
(A) larger mean free path for X as compared to that of Y.
(B) larger mean free path for Y as compared to that of X.
(C) increased collision frequency of Y with the inert gas as compared to that of X with the
inert gas.
(D) increased collision frequency of X with the inert gas as compared to that of Y with the
inert gas.
36. (D)
Larger the size of the molecules, smaller the mean free path.
πn 2σ2μav
Collision frequency (z) =
2
1
Mean free path (λ) =
2 n σ2
where, n = No. of molecules per unit molar volume.
σ = Collision diameter.
18
SECTION − 3 : Matching List Type (Only one Option Correct)

37. Different possible thermal decomposition pathways for peroxyesters are shown below.
Match each pathway from List I with an appropriate structure from List II and select the
correct answer using the code given below the lists.
List-I List-II
P. Pathway P
1.
Q. Pathway Q
2.
R. Pathway R
3.
S. Pathway S
4.
Codes :
P Q R S
(A) 1 3 4 2
(B) 2 4 3 1
(C) 4 1 2 3
(D) 3 2 1 4
37. (A)
19
38. Match the four starting materials (P,Q,R,S) given in List I with the corresponding
reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the
code given below the lists.
List I List II
P. 1. Scheme I

(i) KMnO4 , H O , heat (ii) H ⊕ , H2O
(iii) SOCl2 (iv) NH3
? C7H6N2O3
Q. 2. Scheme II
(i) Sn/HCl (ii) CH3COCl (iii) conc. H2SO4

(iv) HNO3 (v) dil.H2SO4 , heat (vi) H O
? C6H6N2O2
R. 3. Scheme III
(i) red hot iron, 873 K (ii) fuming HNO3 , H2SO4, heat
(iii) H2S.NH3 (iv) NaNO2, H2SO4 (v) hydrolysis
? C6H5NO3
S. 4. Scheme IV
(i) conc. H2SO4 , 60°C (ii) conc. HNO3, conc. H2SO4
(iii) dil. H2SO4, heat
? C6H5NO4
Code :
P Q R S
(A) 1 4 2 3
(B) 3 1 4 2
(C) 3 4 2 1
(D) 4 1 3 2
38. (C)
NO2 NH2
Re d hot HNO + H SO
3 H − C ≡ C − H ⎯⎯⎯⎯⎯ → ⎯⎯⎯⎯⎯⎯
3 2 4→ H S ⋅ NH
⎯⎯⎯⎯⎯
2 3→
iron, 873 K heat
NO2 NO2
Na NO 2
OH + Η 2SO 4
Hydrolysis
(P → 3) ←⎯⎯⎯⎯
⎯
NO2
20
NO2 NO2 NO2 NO2
⎯⎯
→ ⎯⎯
→ ⎯⎯
→
CH3 COOH C Cl C NH2
(S → 1) O O
39. Match each coordination compound in List−I with an appropriate pair of characteristics
from List − II and select the correct answer using the code given below the lists.
{en = H2NCH2CH2NH2 ; atomic numbers : Ti = 22 ; Cr = 24, C = 27, Pt = 78}
List I List II
P. [Cr(NH3)4Cl2]Cl 1. Paramagnetic and exhibits ionisation isomerism
Q. [Ti(H2O)5Cl](NO3)2 2. Diamagnetic and exhibits cis−trans isomerism
R. [Pt(en) (NH3)Cl]NO3 3. Paramagnetic and exhibits cis−trans isomerism
S. [Co(NH3)4(NO3)2]NO3 4. Diamagnetic and exhibits ionisation isomerism
Code :
P Q R S
(A) 4 2 3 1
(B) 3 1 4 2
(C) 2 1 3 4
(D) 1 3 4 2
39. (B)
(P) [Cr(NH3 ) 4 Cl2 ] Cl ⎯⎯
→ i.e. Cr +3 i.e.[Ar]18 3d3
Paramagnetic
Ma4b2 shows geometrical isomerism.
P → 3.
40. Match the orbital overlap figures shown in List−I with the description given in List− II
and select the correct answer using the code given below the lists
List I List II
P. 1. p − d π antibonding
Q. 2. d − d σ bonding
R. 3. p − d π bonding
S. 4. d − d σ antibonding
21
Code :
P Q R S
(A) 2 1 3 4
(B) 4 3 1 2
(C) 2 3 1 4
(D) 4 1 3 2
40. (D)
P → 4 (LCAO of d − d σ anti-bonding)
Q → 1 (LCAO of p − d π anti-bonding orbitals)
R → 3 (LCAO of p − d π bonding orbitals)
S → 2 (LCAO of d − d σ bonding orbitals)
PART III - MATHEMATICS

41. The function y = f(x) is the solution of the differential equation

dy xy x 4 + 2x
+ 2 =
dx x − 1 1 − x2
in (−1, 1) satisfying f(0) = 0. Then
3
2
∫ f (x) dx is
3
−
2
π 3 π 3 π 3 π 3
(A) − (B) − (C) − (D) −
3 2 3 4 6 4 6 2
41. (B)
dy
+
x
y=
x 2 + 2x ( )
dx x 2 − 1 1− x2
x 1
∫ x 2 −1dx log e 1− x 2
I.F. = e = 1− x2
= e 2
x 4 + 2x
∴ Solution is y 1 − x 2 = ∫ . 1 − x 2 dx
2
1− x
5 2
x 2x x5
⇒ y 1− x2 = + +c= + x2 + c
5 2 5
5 2
x + 5x
⇒y= (∵ f ( 0 ) = 0 )
5 1− x2
3 2 3 2
x5 x2 π 3
Now, I = ∫ 1− x2
+ ∫ 1− x2
dx = −
3 4
− 3 25 − 3 2
22
42. The following integral

π
2
17
∫π (2 cosec x) dx is equal to
4
log(1+ 2 ) log (1+ 2 )
2 ( e u + e− u ) du ( eu + e− u )17 du
16
(A) ∫ (B) ∫
0 0
log (1 + 2) log (1+ 2)
(e ) ( )
16
− u 17
(C) ∫
u
−e du (D) ∫ 2 eu − e− u du
0 0
42. (A)
π /2
17
∫ (2 cos ec(x)) dx
π /4
eu + e− u
Let 2 cosec (x) = eu + e−u ⇒ cosec (x) =
2
⎛ eu − e− u ⎞
⇒ − cosec x cot x dx = ⎜⎜ ⎟⎟ du
⎝ 2 ⎠
⇒ dx =
(e u
− e− u du)
2
⎛ eu + e− u ⎞ ⎛ eu + e− u ⎞
2⎜ ⎟ ⎜ ⎟ −1
⎝ 2 ⎠ ⎝ 2 ⎠
2du
⇒ dx = − u − u
e +e
0
∴I= ∫ −
2
e +eu−u (
e u + e− u du )
(
loge 1+ 2 )
loge 1+ 2( )
( )
16
I= ∫ 2 eu + e− u du
0
43. Coefficient of x11 in the expansion of (1 + x2)4 (1 + x3)7 (1 + x4)12 is

(A) 1051 (B) 1106 (C) 1113 (D) 1120
43. (C)
Coefficient of x11 in (1 + x2)4 (1 + x3)7 (1 + x4)12
The number of ways in variation of x,
x0 x 3 x 8
x8 x3 x0
x2 x9 x0
x4 x3 x4
Coefficient of x11 = (4C0 × 7C1 × 12C1) + (4C4 × 7C1 × 12C0) + (4C1 × 7C3 × 12C0)
+ (4C2 × 7C1 × 12C1)
= (1 × 7 × 66) + (1 × 7 × 1) + (4 × 35 × 1) + (6 × 7 × 12)
= 462 + 7 + 140 + 504 = 1113
23
44. Let f: [0, 2] → » be a function which is continuous on [0, 2] and is differentiable on (0,
2) with f(0) = 1. Let
x2
F(x) = ∫ f ( t ) dt
0
for x ∈ [0, 2]. If F′(x) = f ′(x) for all x ∈ (0, 2), then F(2) equals
(A) e2 − 1 (B) e4 − 1 (C) e − 1 (D) e4
44. (B)
f : [0, 2] → R
x2
F(x) = ∫ f( t ) dt
0
F′(x) = {f(x)} 2x Given F′(x) = f′(x)
f ′(x)
∫ f (x)
= ∫ 2x
ln f(x) = x2 + K
2
+K
f(x) = e x
f(0) = 1
eK = 1
2
f(x) = e x eK
Therefore,
2
f(x) = e x
x2
t
F(x) = ∫e dt
0
4
F(2) = ∫ e t dt
0
F(2) = [e t ] 04
F(2) = e4 − 1
45. The common tangents to the circle x2 + y2 = 2 and the parabola y2 = 8x touch the circle at
the points P, Q and the parabola at the points R, S. Then the area of the quadrilateral
PQRS is
(A) 3 (B) 6 (C) 9 (D) 15
45. (D)
Let the slope of common tangent is m.
The eqn. w.r.t. circle is y R
y = mx + 2 1 + m 2 … (1) P
and w.r.t parabola is x′

2 x
y = mx + … (2) Q
m
(1) & (2) are same S
y′
2
Therefore, 2 1 + m 2 =
m
4
2 (1 + m2) = 2
m
24
Let m2 = t
t (1 + t)= 2
t2 + t − 2 = 0
t = 1, −2
When m2 = 1, then m = ±1 and m2 = −2 is not possible.
Now eqn. of tangent are, y = x + 2 and y = − x − 2.
By solving with circle P and Q are (−1, 1) and (−1, −1)
And by solving with parabola R and S are (2, 4) and (2, −4)
By knowing the co-ordinates area is 15.
46. for x ∈ (0, π), the equation sin x + 2 sin 2x − sin 3x = 3 has
(A) infinitely many solutions (B) three solutions
(C) one solution (D) no solution
46. (D)
sinx + 2 sinx − sin 3x = 3
(2 sin 2x) − (sin 3x − sin x) = 3
(2 sin 2x) − (2 cos 2x . sin x) = 3
2(2 sin x . cos x) − 2 sin x(cos 2x) = 3
2 sin x(2 cos x − cos 2x) = 3
2 sin x{2 cos x − (2 cos2x − 1)} = 3
2 sin x{−2 cos2 x + 2 cos x + 1} = 3
{−2 cos2 x + 2 cos x + 1} will attain maximum value 3/2 when cos x = 1/2 and at the same
time sin x must be equal to 1. But it is not possible. Hence no solution.
47. In a triangle the sum of two sides is x and the product of the same two sides is y. If
x2 − c2 = y, where c is the third side of the triangle, then the ratio of the in-radius to the
circum-radius of the triangle is
3y 3y 3y 3y
(A) (B) (C) (D)
2x(x + c) 2c(x + c) 4x ( x + c ) 4c ( x + c )
47. (B)
a+b=x
ab = y c b
a+b+c=x+c
2s = x + c
a
x+c
=s
2
Given x2 − c2 = y
(a + b)2 − c2 = y
a2 + b2 + 2ab − c2 = ab
⇒ a2 + b2 − c2 = −ab
a 2 + b2 − c2 1
cos C = =−
2ab 2
C = 120°
1
ab sin C
Δ 2 y sin C y ⋅ sin120° y. 3
So, r= = = = =
s a+b+c x+c x+c 2(x + c)
2
25
c c c
R= = =
2sin C 3 3
2⋅
2
y 3
r 2(x + c) 3y
= =
R c 2c(x + c)
3
48. Six cards and six envelopes are numbered 1, 2, 3, 4, 5, 6 and cards are to be placed in
envelopes so that each envelope contains exactly one card and no card is placed in the
envelope bearing the same number and moreover the card numbered 1 is always placed in
envelope numbered 2. Then the number of ways it can be done is
(A) 264 (B) 265 (C) 53 (D) 67
48. (C)
Total Dearrangement of 6
⎛ 1 1 1 1 1 1⎞
6!⎜1 − + − + − + ⎟ = 360 − 120 + 30 − 6 + 1 = 265
⎝ 1! 2! 3! 4! 5! 6! ⎠
In these dearrangements, there are 5 ways in which card numbered 1 is going wrong.
265
So when it is going in envelop numbered 2 is = 53 ways.
5
49. Three boys and two girls stand in a queue. The probability, that the number of boys ahead
of every girl is at least one more than the number of girls ahead of her, is
1 1 2 3
(A) (B) (C) (D)
2 3 3 4
49. (A)
n(S) = 5!
n(E) = 3 ! × 2 ! × 5
n(E) 3!× 2!× 5 1
p(E) = = = .
n(S) 5! 2
50. The quadratic equation p(x) = 0 with real coefficients has purely imaginary roots. Then
the equation p(p(x)) = 0 has
(A) only purely imaginary roots
(B) all real roots
(C) two real and two purely imaginary roots
(D) neither real nor purely imaginary roots
50. (D)
When roots are purely imaginary.
Then the form of equation is x2 + K = 0
where K is positive no.
Let, p(x) = x2 + K
p(p(x)) = (p(x))2 + K
p(p(x)) = (x2 + K)2 + K
p(p(x)) = x4 + 2Kx2 + K
p(p(x)) = 0
x4 + 2Kx2 + K = 0
All coefficients are positive and no odd degree of x are present.
26
SECTION − 2 : Comprehension Type (Only One Option Correct)

Let a, r, s, t be nonzero real numbers. Let P(at2, 2at), Q, R(ar2, 2ar) and S(as2, 2as) be distinct
points on the parabola y2 = 4ax. Suppose that PQ is the focal chord and lines QR and PK are
parallel, where K is the point (2a, 0).
51. The value of r is

1 t2 +1 1 t2 −1
(A) − (B) (C) (D)
t t t t
51. (D)
P ≡ (at2, 2at), F ≡ (a, 0) P

⎛a 2a ⎞
Applying condition of collinearity, we get Q ≡ ⎜ 2 , − ⎟ R
⎝t t ⎠
Since QR || PK, F
⎛ 1⎞ (a, 0) k
2a ⎜ r + ⎟
⎝ t ⎠ = 2at
⎛ 2 1 ⎞ at 2 − 2a
⎜r − 2 ⎟ Q
⎝ t ⎠
1 t2 −1
⇒ r=t− =
t t
52. If st = 1, then the tangent at P and the normal at S to the parabola meet at a point whose
ordinate is
(t 2 + 1) 2 a(t 2 + 1) 2 a(t 2 + 1) 2 a(t 2 + 2) 2
(A) (B) (C) (D)
2t 3 2t 3 t3 t3
52. (B)
1
S=
t
x 2a a
Equation of normal at S is + y = + …………. (1)
t t t3
Equation of tangent at P is ty = x + at2 …………. (2)
Solving Eq. (1) and (2) simultaneously, we get,
( )
2
a t2 +1
y=
2t 3
27

Given that for each a ∈ (0, 1)
1− h
lim ∫ t −a (1 − t)a −1 dt , exists. Let this limit be g(a). In addition, it is given
+
h →0 h
that the function g(a) is differentiable on (0, 1).
⎛1⎞
53. The value of g ⎜ ⎟ is
⎝2⎠
π π
(A) π (B) 2π (C) (D)
2 4
53. (A)
1− h 1− h
⎛1⎞ −1/2 −1/2 1
g ⎜ ⎟ = Lt
⎝2⎠ h →0+
∫ t (1 − t) dt = Lt
h →0 +
∫ t − t2
dt
h h
1− h
dt 2t − 1 ⎞ −1 ⎛
= Lt
h →0 +
∫ 2 2
= Lt sin ⎜
h →0+ ⎝ 1 ⎠h
⎟
⎛1⎞ ⎛ 1⎞
⎜ ⎟ −⎜t − ⎟
⎝2⎠ ⎝ 2⎠
= Lt sin −1 (1 − 2h) − sin −1 (2h − 1) = π
h →0+
⎛1⎞
54. The value of g′ ⎜ ⎟ is
⎝2⎠
π π
(A) (B) π (C) − (D) 0
2 2
54. (D)
⎛1 ⎞ ⎛1⎞
g⎜ + δ⎟ − g⎜ ⎟
⎛1⎞ 2 ⎠ ⎝2⎠
g ⎜ ⎟ = Lt ⎝
⎝ 2 ⎠ h →0 δ
∫( ) dt
1− h 1 1 1 1
− −δ − +δ−1 − −1
t 2 (1 − t) 2 − t (1 − t) 2
2
h
= Lt Lt
h →0 δ→0 δ
⎛
⎜
−
1
= Lt Lt ∫ t (1 − t)
2
−
1 t −δ (1 − t)δ − 1
2
⎞
dt ⎟
( )
h →0 ⎜ δ→0 δ ⎟
⎝ ⎠
⎛ δ
⎛ 1− t ⎞ ⎛ 1− t ⎞ ⎞
1 1⎜ ⎜ ⎟ ⋅ log e ⎜ ⎟⎟
− − t ⎠
= Lt ∫ t 2 (1 − t) 2 ⎜⎜ Lt ⎝ ⎝ t ⎠ ⎟dt
⎟
h →0 ⎝ δ→0 1 ⎠
1− h 1 1
− −
= Lt
h →0
∫ t 2 (1 − t) 2 ( log e (1 − t) − log e (t) ) dt
h
1− h 1 1
⎛1⎞ − − ⎛ b b ⎞
∴ Also, g ' ⎜ ⎟ = Lt ∫ t 2 (1 − t) 2 ( log e (1 − t) − log e (t) ) dt ⎜⎜∵, ∫ f (x)dx = ∫ f (a + b − x)dx ⎟⎟
⎝ 2 ⎠ h →0 h ⎝ a a ⎠
⎛1⎞
∴ g '⎜ ⎟ = 0
⎝2⎠
28
Box 1 contains three cards bearing numbers 1, 2, 3; box 2 contains five cards bearing
numbers 1, 2, 3, 4, 5; and box 3 contains seven cards bearing numbers 1, 2, 3, 4, 5, 6, 7. A
cards is drawn from each of the boxes. Let xi be the number on the card drawn from the ith
box, i = 1, 2, 3.
55. The probability that x1 + x2 + x3 is odd, is

29 53 57 1
(A) (B) (C) (D)
105 105 105 2
55. (B)
1) If x1 = 1, x2 and x3 can be selected in 4 + 3 + 4 + 3 + 4 = 18 ways
2) If x1 = 2, (x2 , x3) can be selected in 3 + 4 + 3 + 4 + 3 = 17 ways
3) In x1 = 3, (x2 , x3) can be selected in 18 ways
18 + 17 + 18 53
∴P= =
3× 5× 7 105
56. The probability that x1, x2, x3 are in an arithmetic progression, is

9 10 11 7
(A) (B) (C) (D)
105 105 105 105
56. (C)
The favourable cases are
(1, 1, 1), (1, 2, 3), (1, 3, 5), (1, 4, 6), (2, 2, 2), (2, 3, 4), (2, 4, 6), (3, 3, 3), (3, 4, 5),
(3, 5, 7), (3, 2, 1).
11
Hence, answer is .
105
SECTION − 3 : Matching List Type (Only One Option Correct)

⎛ 2kπ ⎞ ⎛ 2kπ ⎞
57. Let zk = cos ⎜ ⎟ + i sin ⎜ ⎟ ; k = 1, 2, …, 9.
⎝ 10 ⎠ ⎝ 10 ⎠
List I List II
P. For each zk there exists a zj such that zk ⋅ zj = 1 1. True
Q. There exists a k ∈ {1, 2, …, 9} such that z1 ⋅ z = zk has no solution 2. False
z in the set of complex numbers.
1 − z1 1 − z 2 ... 1 − z9 3. 1
R. equals
10
9 ⎛ 2kπ ⎞ 4. 2
S. 1 − ∑ k =1 cos ⎜ ⎟ equals
⎝ 10 ⎠
P Q R S
(A) 1 2 4 3
(B) 2 1 3 4
(C) 1 2 3 4
(D) 2 1 4 3
29
57. (C)
2kπ
i
zK = e 10 , K = 1, 2, …. 9
2kπ
i
z = α, α2 …… α9, where α = e 10
1
10
so, all are roots z = (1)
P→1
For Option Q
z1.z = zk
α.z = zk
No z satisfy equation ⇒ Q → 2
For Option C
z10 − 1 = (z − 1) (z − z1) (z − z2) …… (z − z9)
z9 + z8 + …… + z + 1 = (z − z1 (z − z2) …… (z − z9)
Put z = 1
10 = (1 − z1) (1 − z2) …… (1 − z9)
∴ 10 = 1 − z1 1 − z 2 …… z − z9
C→3
For Option D
Sum of roots = 0
1 + z1 + z2 + …… + zq = 0
⎛ 2π 2π ⎞ ⎛ 4π 4π ⎞ ⎛ 18π 18π ⎞
1 + ⎜ cos + i sin ⎟ + ⎜ cos + i sin ⎟ + .... + ⎜ cos + i sin ⎟=0
⎝ 10 10 ⎠ ⎝ 10 10 ⎠ ⎝ 10 10 ⎠
2π 4π 18π
⇒ equate real part ⇒ 1 + cos + cos + ...... + cos =0
10 10 10
a
⎛ 2kπ ⎞
So, 1 − ∑ cos ⎜ ⎟
k =1 ⎝ 10 ⎠
= 1 − (−1) = 2
S→4
58. List I List II

(P) The number of polynomials f(x) with non-negative integer coefficients
1
of degree ≤ 2, satisfying f(0) = 0 and ∫ f (x)dx = 1, is 1 8
0
(Q) The number of points in the interval ⎡ − 13, 13 ⎤
⎣ ⎦ 2 2
at which f(x) = sin (x2) + cos (x2) attains its maximum value, is
(R) 2 3x 2
∫ ( x ) dx equals 3 4
−2 1 + e
(S) ⎛ 1 ⎞
⎜ 2 ⎛ 1+ x ⎞ ⎟
⎜ ∫ cos 2x log ⎜ ⎟ dx ⎟
⎜ −1 ⎝ 1 − x ⎠ ⎟
⎝ 2 ⎠ equals 4 0
⎛1 ⎞
⎜2 ⎛ 1+ x ⎞ ⎟
⎜⎜ ∫ cos 2x log ⎜ ⎟ dx ⎟
⎝0 ⎝ 1 − x ⎠ ⎟⎠
30
P Q R S
(A) 3 2 4 1
(B) 2 3 4 1
(C) 3 2 1 4
(D) 2 3 1 4
58. (D)
(P) → (2), (Q) → (3), (R) → (1), (S) → (4)
(P) → (2)
f(x) = ax2 + bx + c
f(0) = 0 ⇒ c = 0 a, b, c (non−negative integer coefficient)
1
∫ f ( x ) dx = 1
0
1 1
x3 x2
a + b. =1
3 0 2 0
a b
⇒ + =1
3 2
⇒ 2a + 3b = 6 (a & b non−negative integer coeff.)
(Q) → (3)
f ' ( x ) = 2x ⎡⎣cos x 2 − sin x 2 ⎤⎦ …… (1)
( ) {
f ' ( x ) = 2 ⎡ cos x 2 − sin x 2 + x − sin x 2 − cos x 2
⎣ } ( 2x )⎤⎦
( )
= 2 ⎡ cos x 2 − sin x 2 − 2x 2 ⎤ …… (2)
⎣ ⎦
f ' ( x ) = 0 ⇒ x = 0 or cosx − sinx2 = 0
2
2
⇒ tanx = 1
π
x 2 = nπ +
4
π 5π 9π 13π
x2 = , , ,
4 4 4 4
π 5π 9π 13π
But f '' ( x ) < 0 at x 2 = , , ,
4 4 4 4
(R) → (1)
2
3x 2
I= ∫ x
dx …… (1)
−2 1 + e
2
3x 2
=∫ dx
1
−2 1 +
ex
2
3x 2e x
I= ∫ ex + 1 dx …… (2)
−2
(1) + (2)
2
2 3 2
2I = ∫ 3x dx = x −2
= 8 − (−8) = 16
−2
31
I=8
(S) → (4)
1
2
⎛ 1+ x ⎞
∫1 cos 2x.log ⎜⎝ 1 − x ⎟⎠ dx = 0 as odd function.
−
2
59. List I List II

(P) 3
Let y(x) = cos (3 cos−1x), x ∈ [−1, 1], x ≠ ± .
2
1 1
1 ⎧⎪ 2 d 2 y(x) dy(x) ⎫⎪
Then ⎨
y(x) ⎪⎩
x −(1 )
dx 2
+x
dx ⎪⎭
⎬ equals
(Q) Let A1, A2, …., An (n > 2) be the vertices of a regular polygon of n

sides with its centre at the origin. Let a k be the position vector of the
2 2
( ) ( )
point Ak, k = 1, 2, …., n. If Σ nk −=11 a k × a k +1 = Σ kn =−11 a k ⋅ a k +1 , then
the minimum value of n is
(R) x 2 y2
If the normal from the point P(h, 1) on the ellipse + = 1 is
6 3 3 8
perpendicular to the line x + y = 8, then the value of h is
(S) Number of positive solutions satisfying the equation
⎛ 1 ⎞ −1 ⎛ 1 ⎞ −1 ⎛ 2 ⎞
tan −1 ⎜ ⎟ + tan ⎜ ⎟ = tan ⎜ 2 ⎟ 4 9
⎝ 2x + 1 ⎠ ⎝ 4x + 1 ⎠ ⎝x ⎠
P Q R S
(A) 4 3 2 1
(B) 2 4 3 1
(C) 4 3 1 2
(D) 2 4 1 3
59. (A)
(P) → (4), (Q) → (3), (R) → (2), (S) → (1)
(P) → (4)
y = 4x3 − 3x
dy
= 12x2 − 3
dx
d2 y
= 24x
dx 2
1 ⎧⎪ 2 d2 y dy ⎫⎪ 1
So, ⎨ (x − 1) + x ⎬ = {(x 2 − 1)24x + x(12x 2 − 3)}
y(x) ⎪⎩ dx 2 dx ⎪⎭ 3
4x − 3x
=9
(Q) → (3)
(R) → (2)
32
x1
Slope of tangent to ellipse = −
2y1
x1
Given, − = −1
2y1
x1 = 2y1
So, point P(h, 1)
So, h =2×1
h =2
(S) → (1)
1 1
+
2
tan −1 2x + 1 4x + 1 = tan −1 2
1 1 x
1−
2x + 1 4x + 1
6x + 2 2
⇒ 2
= 2
8x + 6x x
2 (3x + 1) 2
⇒ = 2
x (8x + 6) x
2
⇒ 3x + x = 8x + 6
⇒ 3x2 − 7x − 6 = 0
7 ± 7 2 − 4.3.(−6) 7 ± 11 2
x = = = 3, −
2×3 6 3
No. of +ve solution 1
(Q) → (3)
60. Let f1 : » → », f 2 :[0, ∞] → », f3 : » → » and f 4 : » → [0, ∞) be defined by
⎧⎪| x | if x < 0,
f1 (x) = ⎨ x
⎪⎩ e if x ≥ 0;
f 2 (x) = x 2 ;
⎧sin x if x < 0,
f3 (x) = ⎨
⎩ x if x ≥ 0
and
⎧⎪f 2 ( f1 (x) ) if x < 0,
f 4 (x) = ⎨
⎪⎩f 2 ( f 2 (x) ) − 1 if x ≥ 0.
List I List II
(P) f4 is 1 onto but not one−one
(Q) f3 is 2 neither continuous nor one−one
(R) f2of1 is 3 differentiable but not one-one
(S) f2 is 4 continuous and one-one
33
P Q R S
(A) 3 1 4 2
(B) 1 3 4 2
(C) 3 1 2 4
(D) 1 3 2 4
60. (D)
(P) → (1), (Q) → (3), (R) → (2), (S) → (4)
(P) → (1)
⎧⎪− x if x < 0
f1(x) = ⎨ x
⎪⎩e if x ≥ 0
f 2 (x) = x 2
⎧sin x if x < 0
f3 (x) = ⎨
⎩ x if x ≥ 0
⎪⎧f 2 (− x) if x < 0 ⎧⎪ x if x < 0 ⎧⎪ x 2
2
if x < 0
f 4 (x) = ⎨ x
=⎨ =⎨
⎩⎪f 2 (e ) if x ≥ 0 ⎪⎩(e ) − 1 if x ≥ 0 ⎪⎩e − 1 if x ≥ 0
x 2 2x
f4(x) is onto & not one-one.
(Q) → (3)
f3(x) → 3 (differentiable but not one-one)
(R) → (2)
⎧⎪f 2 (− x) if x < 0 ⎧⎪ x 2 if x < 0
f2 f1 (x) = f2 (f1(x)) = ⎨ =⎨
( ) x
⎪⎩f 2 e if x ≥ 0 ⎪⎩e if x ≥ 0
2x
(S) → (4)
f2(x) = x2 is domain [0, ∞)
⇒ continuous & one-one.
34
35

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IIT - JEE 2014 (Advanced)

(A) 60 ± 0.15 Ω (B) 135 ± 0.56 Ω

(A) E1 > E2 > E3 (B) E3 > E1 > E2

5. A point source S is placed at the bottom of a transparent block of height 10 mm and

(A) 1.21 (B) 1.30 (C) 1.36 (D) 1.42

SECTION − 2 : Comprehension Type (Only One Option Correct)

Paragraph for Questions 11 & 12

Paragraph For Questions 13 & 14

Paragraph For Questions 15 & 16

The figure shows a circular loop of radius a with

SECTION − 3 : Matching List Type (Only One Option Correct)

All y component will be cancelled and +ve x will exist.

for not to slip

(A) one phenyl group is replaced by a methyl group.

The correct order of their boiling point is

23. The major product in the following reaction is

(A) 0 (B) 1 (C) 2 (D) 3

29. For the process

SECTION − 2 : Comprehension Type (Only one Option Correct)

Paragraph For Questions 31 and 32

31. The product X is

H5C2O − CH 2CH 2C ≡ C − CH3

32. The correct statement with respect to product Y is

Paragraph For Questions 33 and 34

33. M1, Q and R, respectively are

tetra hedral Sq. Planar

Paragraph for Questions 35 and 36

SECTION − 3 : Matching List Type (Only one Option Correct)

NO2 NO2 NO2 NO2

CH3 COOH C Cl C NH2

PART III - MATHEMATICS

41. The function y = f(x) is the solution of the differential equation

42. The following integral

43. Coefficient of x11 in the expansion of (1 + x2)4 (1 + x3)7 (1 + x4)12 is

and w.r.t parabola is x′

SECTION − 2 : Comprehension Type (Only One Option Correct)

Paragraph for Questions 51 and 52

51. The value of r is

P ≡ (at2, 2at), F ≡ (a, 0) P

Paragraph for Questions 53 and 54

Paragraph for Questions 55 and 56

55. The probability that x1 + x2 + x3 is odd, is

56. The probability that x1, x2, x3 are in an arithmetic progression, is

SECTION − 3 : Matching List Type (Only One Option Correct)

58. List I List II

59. List I List II

60. Let f1 : » → », f 2 :[0, ∞] → », f3 : » → » and f 4 : » → [0, ∞) be defined by

f4(x) is onto & not one-one.

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