Q4 8

50. A
59. Given below
series LCR circuit 54. Gadolinium has a low value of third ionisation
with inductance 10 H,
capacitance 10 F, resistance 50 2 is connected to enthalpy because of StatementI
an ac sourceof voltage, V 200 In the coagu
resonant
sin(100 t) volt. If
=

the (1) small size

frequency of the LCR circuit is v, and tne power of the
high exchange enthalpy
trequency of the ac source is v, then: 12 AB+
(1) VV= 50 Hz 3) high electronegativity Statement E
high basic character
(4) In the coag
(2) y = 5Hz 55. Which statement regarding polymers is not corect?
power of th
NaC
50 Elastomers have polymer chains held together
(3) =

Hz,v= 50 Hz (1) In the light

by weak intermolecular forces. appropriat
(4) = 100 Hz; v
=
=
Hz (2) Fibers possess high tensile strength.
T
(1) Both
) Thermoplastic polymers are capable of (2) Bot
repeatedly softening and hardening on incc
Section A (Chemistry) heating and cooling respectively.
3 Sta
51. The incorrect statement (4) Thermosetting polymers are reusable. inc-
regarding enzymes is (4 Sta
(1) Enzymes are biocatalysts. 56. Which one is not correct mathematical equation for CO)
(2) Like chemical Dalton's Law of partial pressure? Here p=total
catalysts enzymes reduce the
pressure of gaseous mixture 60. The pH
activation energy of bio processes.
0.10 Ms
Enzymes are polysaccharides. (1) P=P1tP2+ P3
4) Enzymes are very specific for a particular RT RT [Given
reaction and substrate. (2) Pni V n2 (1)
3) PXP where Ppartial pressure of 2)
52. The IUPAC name of the complex -
th gas 3)
Ag(HO)]lAg(CN),] is: (4)
X= mole fraction of h
(1) dicyanidosilver() diaquaargentate() gas in gaseous 61. Which
diaquasilver(I) dicyanidoargentate() mixture
dibora
3) dicyanidosilver() diaquaargentate() (1)
(4) PXP where x,= mole fraction of ith
diaquasilver() dicyanidoargentate( gas in gaseous mixture (2)
53. Given below are two statements: one is labelled as Ppressureof th gas
Assertion (A) and the other is labelled as Reason 3)
in pure state
(R).
57. What mass of 95% pure CaCO will be required to (4)
Assertion (A): neutralise 50 mL of 0.5 M HCl solution according to
In a particular point defect, an ionic solid is 62. Giver
the following reaction?
electrically neutral, even if few of its cations are MnC
missing from its unit cells. CaCO39+ 2HCaq)CaC2ag)+CO2+2HO
Reason (R): [Calculate upto second place of decimal point]
In an ionic solid, Frenkel defect arises due to (1) 1.258
dislocation of cation from its lattice site to interstitial (2) 1.32 g
site, maintaining overall electrical neutrality. 3.65 g
Eo
3)
In the light of the above statements, choose the most (4) 9.50 g Wil
appropriate answer from the options given below wat

(1) Both (A) and (R) are correct and (R) is the 58. The IUPAC name of an element with (1)
atomic number
correct explanation of (A) 119 is
(2)
(2) Both (A) and (R) are correct but (R) is not the (1) ununennium
correct explanation of (A) ( 2 unnilennium
(3) (A) is correct but (R) is not correct (3) unununnium (4)
(4) (A) is not correct but (R) is correct (4) ununoctium
 9 Q4
59. Given below are two statements: Given below
63. are
two statements
Statementl: Statement:
In the coagulation of a negative sol,the flocculating The acidic strength of monosubstituted nitrophenol
power of the three given ions is in the order. is higher than phenol because of electron
A13t > Ba2+ > Nat withdrawing nitro group.
Statement II:
Statement Il:
In the coagulation of a positive sol, the flocculating o-nitrophenol, m-nitrophenol and p-nitrophenol will
power of the three given salts is in the order- have same acidic strength as they have one nitro
group attached to the phenolic ring.
NaCl> NaS0, > NaPC0
In the light of the above statements, choose the most
In the light of the above statements, choose the most
appropriate answer from the options given below : appropriateanswer from the options given below:
(1) Both Statement I and Statement II are correct.
(1) Both Statement I and Statement II are correct.
(2) Both Statement I and Statement II are
(2) Both Statement I and Statement II are incorrect.
incorrect.
(3) Statement I is correct but Statement II is
(3) Statement I is correct but Statement II is incorrect.
incorrect. Statement I is incorrect but Statement II is
(4)
(4) Statement I is incorrect but Statement II is correct.
correct.
64. Given below are two statements
60. The pH of the solution containing 50 mL each of StatementI:
0.10 M sodium acetate and 0.01 M acetic acidis Primary aliphatic amines react with HNO, to give
Given pK, of CH,COOH=4.57] unstable diazonium salts.
(1) 5.57 Statement :
(2) 3.57 Primary aromatic amines react with HNO, to form
diazonium salts which are stable even above 300 K.
(3) 4.57
In the light of the above statements, choose the most
(4) 2.57
appropriate answer from the options given below:
61. Which of the following statement is not correct about (1) Both Statement I and Statement II are correct.
diborane ? (2) Both Statement I and Statement II are
(1) There are two3-centre-2-electron bonds. incorrect.

(2) The four terminal B-H bonds are two centre 3 Statement I is correct but Statement II is
two electron bonds. incorrect.

The four terminal Hydrogen atoms and the (4) Statement I is incorrect but Statement II is
3) correct.
two Boron atoms lie in one plane.

(4) Both the Boron atoms are sp2 hybridised. 65. Amongst the following which one will have
maximum 'lone pair -lone pair electron repulsions?
62. Given below are half cell reactions:
(1) CIF3
MnO +8H+5 e Mn+ 4 H20, (2)
Mn*/MnO, -1.510 V (3) SF4
(4) XeF2
O2 +2H*+2e H,O,
66. The incorrect statement regarding chirality is :
Eo2/Ho =
+ 1.223 V SN1 reaction yields 1 : 1 mixture of both
(1)
enantiomers.
Will the permanganate ion, MnO liberate O, from
water in the presence of an acid? (2) The product obtained by S2 reaction of
haloalkane having chirality at the reactive site
(1) Yes, because Ecell +0.287 V
shows inversion of configuration.
(2) No, becauseEcell-0.287 V (3) Enantiomers are superimposable mirror
images on each other.
3) Yes, becauseEcell+2.733 V
(4) A racemic mixture shows zero optical
(4) No, because Eell2.733 V rotation.
Q4 10
70. Given below are two statements : o n e is labelled as
67. Which of the following is suitable to synthesize 74. Which of the fo
chlorobenzene? Assertion (A) and the other is labelled as Reason
maximum work d
Benzene,
(R).
(1) Cl2, anhydrous FeCl
Assertion (A): ICl is more reactive than I2
(2) Phenol, NaNO, HCI,CuCI
Reason (R):1-Cl bond is weakerthan I-I bond. (1) P

In the light of the above statements, choose the

most
) , HCI
appropriate answer from given below:
the options
NH2 Both (A) and (R) are correct and (R) is the
(1)
correct explanation of (A).
(4) , HCI, Heating Iso
correct but (R) is not the
(2) Both (A) and (R) are
P
correct explanation of (A).
68. Match List -Iwith List - I1. 2
is correct but (R) is not correct.
List-I (3) (A)
List-II
correct.
(Drug class) (4) (A) is not correct but (R) is
(Drug molecule)
(a) Antacids Salvarsan
71. Choose the correct statement:
Antihistamines ) Morphine
Diamond and graphite have two dimensional
3)
Analgesics/ (ii) Cimetidine (1)
network.
(d) Antimicrobials iv) Seldane
Diamond is covalent and graphite is ionic.
Choose the correct answer from the options given (2)
below (3) Diamond is sp hybridised and graphite is
(1) a)- (ii), (b)-(i), (o)- (iv), (d)-() sp2 hybridized.
P
A (a)-(ii), (b)-(iv). (C)-(i), (d)-) (4) Both diamond and graphite are used as dry
lubricants. (4)
) (a)-), (b)- (iv). (©)-(i), (d)- (i)
4) (a)-(iv), (b)-(ii), ()-(), (d)-()
72. Identify the incorrect statement from the following.

69. The given graph is a representation of kinetics of a All the five 5d orbitals are different in size 75. The Kjeldah>'s r
(1) can be used to
reaction. when compared to the respective 4d orbitals.
which one of t
Constant temperatureT All the five 4d orbitals have shapes similar to
(2) NO,
the respective 3d orbitals.

3) In an atom, all the five 3d orbitals are equal in

energy in free state. (1)
X 4) The shapes of d d and d orbitals are
The y andx axes for zero and first order reactions, similar to each other; and d2-2 and d2
respectively are are similar to each other.
(2)
zero order (y=concentration and x = time), 7 3.
(1) Identify the incorrect statement from the following
first order (y=t, andx=concentration)
(1) Alkali metals react with water to form their NH2
(2) zero order (y=concentration and r= time),
first order (y= rate constant and
hydroxides
x=concentration) (2) The oxidation number of K in KO, is +4. 3)
(3) zero order (y= rate and x=concentration), 3) lonisation enthalpy of alkali metals decreases
first order(y=t, andx=concenration) from top to bottom in the
group.
4) zero order (y= rate and x=concentration),
(4) Lithium is the strongest reducing
agent among (4)
first order (y= rate and x =t,) the alkali metals
 11 Q4
abelled as Which of the following p-V curve represents Match List - I with List - II.
s Reason 74. 76
maximum work done?
List- List II
Isothermal
(Hydrides) (Nature
ond. (1) (a) Mgtl i) Electron precise

se the most (b) Getl (i) Electron deficient

enbelow: Electron rich

V ()B1, (ii)
(R) is the
(d) HF (iv) lonic
Isothermal
Choose the correct answer from the options given
)is not the
below
2 (1) (a)-(v), (b)- (). (0)- (i), (d)- (ii)

V (2) (a)-(ii), (b) -(i), (c)-(ii), (d)- (iv)

Isothermal (a)-(i), (b)-(i), (c)- (iv), (d)- (ii)
(4) ()-(i), (b)-(Gii), (c)- (iv), (d)-()
3) P
mensional1
77. Given below are two statements:

is ionic. Statement :

raphite is The boiling points of the following hydrides of group

Isothermal 16 elements increases in the order -

P H 0 < H < H S e < HTe.

sed as dry
(4) Statement II:
The boiling points of these hydrides increase with
following. increase in molar mass.

ent in size 75. The Kjeldah>'s method for the estimation of nitrogen In the light of the above statements, choose the most
Ld orbitals. can be used to estimate the amount of nitrogen in appropriate answer from theoptionsgiven below:
which one of the following compounds?
similar to (1) Both Statement I and Statement II are correct
NO
2) Both Statement I and Statement II are
ure equal in incorrect
(1) (3) Statement I is correct but Statement II is
incorrect
orbitals are
2 and d,2 (4) Statement l is incorrect but Statement II is
correct
(2)
following 78. Which amongst the following is incorrect statement?
form their NH2
The bond orders of
(1)
are 2.5, 2, 1.5 and 1,
O,O2,0 and O
respectively.
2 is +4. 3)
(2) C, molecule has four electrons in its two
s decreases degenerate r molecular orbitals.
-N= N- Hion has one electron.
(3)
ent among (4)
o ion is diamagnetic.
 Q4 12
79. Match List I with List II. In one molal solution that contains 0.5 mole ofa
-
-

83.
List-I solute, there is
List- II
(Products formed) (Reaction of carbonyl 500 mL of solvent
(1) 86. The orde
compound with)
(a) Cyanohydrin ) 2500 g of solvent for the co

(b) Acetal
NHOH (A) N
(ii) RNH2 (3) 100 mL of solvent
(c) Schiff's base (B) N
(ii) alcohol
(4) 1000 g of solvent IN
(d) Oxime (iv) HCN is
Choose the correct
answer from the
below: options given 84. Match List - I with List - II. (1) (A
(1) 2) (C
(a)-(ii), (b)-(iv), (c)- (i), (d)- (i) List-I List-II
(3) (C
()(a)-i), (b)- (ii),(c)-(iv), (d) -(i) (a) Li ) absorbent for carbon dioxide 4) (B
(a)-(G), (b)- (i), (c)- (), (d)- (iv) (b) Na t i ) electrochemical cells 87. Given be-
(a)-(iv), (b)- (ii), (c)- (ü), (d) -

)
KOH (ii) coolant in fast breeder reactors
Stateme
80. Which compound In Luca=
amongst the following is not an alcohols
aromaticcompound? (d) Cs (iv) photoelectric cell
reactivit
Choose the correct answer from the options given Reagent
(1) below: Stateme
(1) (a)-(iv), (b)-(). (C)-(ii), (d)- (i) Primary
produce
with Lu
(2) (a)-(ii), (b)- (iv), (c)- (i), (d)- () In the li-
(2)
3) (a)-(i. (b)- (i), (c)- (iv), (d)--(i) approp
1)
4(a)-(i), (6)- (ii), ()-(). (d)-(iv) (2)
(3)
85. Given below are two statements (3)

(4 StatementI: 4)
The boiling points of aldehydes and ketones are
higher than hydrocarbons of comparable molecular 88. Which
81. At 298 K, the standard electrode masses because of weak molecular association in
potentials of Cu2+/ acetone
Cu,Zn2/Zn, Fe2t/Fe and Ag*/Ag are 0.34 V, aldehydes and ketones due to
dipole dipole
-

dilute
-0.76 V, -0.44 Vand 0.80 V, interactions.
respectively.
On the basis of standard electrode
potential, predict
which of the following reaction can not occur? Statement II: (1)
The boiling points of
(1) CuSO,(ag) +Zn(s)ZnSOg(aq) +Cu(s) aldehydes and ketones are
lower than the alcohols of similar molecular masses
(2) Cuso,(ag)+ Fe(s)> FeSOg(aq) +Cu(s) due to the absence
ofH-bonding.
3) FesO(aq)+ Zn(s)>ZnSO,(aq)+Fels)
In the light of the above 2)
statements, choose the most
(4) 2CuSOg(aq) +2Ags)2Cu(s)+ AgSO,(aq) appropriate answer from the options given below:
(1) Both StatementI and Statement II are correct.
82. RMgX +CO2eherY
ether RCOOH (2) Both Statement I and Statement II are 3)
Whatis Y in the above reaction ? incorrect.
RC00"Mg*X 3) Statement I is correct but Statement II is
2) RCOMg*X incorrect.
)RCOO"X*
(4) Statement I is incorrect but Statement II is
(4) (RCOO),Mg correct.
 13 Q4
A 10.0 L flask contains 64 g of oxygen at 2 r .
Section-B (Chemistry) 89.
(Assume O2 gas is behaving ideally). The pressure
86. The order of energy absorbed which is responsible inside the flask in bar is
for the color of complexes
(Given R 0.0831 L. bar K-l mol-)
(A) [Ni(H,O),(en),]2*
[Ni(H,O),(en)]?+ and
(1) 2.5
B) (2) 498.6
[Ni(en),12 (3) 49.8
(A)> (B) > ( )
(4) 4.9
(1)
(2) (C) (B)>(A)) 90. The correct IUPAC name of the following compournd
is
(3) (C)>(A)>(B)
4) (B)>(A)>( CI OH

87. Given below are two statements

Statement:
In Lucas test, primary, secondary and tertiary
alcohols are distinguished on the basis of their (1)1-bromo-5-chloro-4-methylhexan-3-ol
reactivity with conc. HCI+ ZnCl2, known as Lucas
26-bromo-2-chloro-4-methylhexan-4-ol
Reagent. (3) 1-bromo-4-methyl-5-chlorohexan-3-ol
Statement II: (4) 6-bromo-4-methyl-2-chlorohexan-4-ol
Primary alcohols are most reactive and immediately
produce turbidity at room temperature on reaction 91. In the neutral or faintly alkaline medium, KMnO,
with Lucas Reagent. oxidises iodide into iodate. The change in oxidation
In the light of the above statements, choose the most state.of manganese in this reaction is from
appropriate answer from the optionsgiven below:
Both StatementI and Statement II arecorrect. +7 to+4
Both Statement I and Statement II are 2) +6 to+4
(2)
incorrect (3) +7 to+3
(3) Statement I is correct but Statement II is +6 to+5
incorrect.
(4)
(4) Statement I is incorrect but Statement II is 92. The product formed from the following reaction
Correct sequence is
CN
88. Which one of the following is not formed when () LiAIH H,O
acetone reacts with 2-pentanone in the presence of i) NaNO, +HCI
dilute NaOH followed by heating?
CH
(1)
H3C CH3
CH NH2
(1)
CHS CH3
(2
O
NC
CH3
CH (2)
(3) CH3
CHS
CH

CH3 CH OH
(4) (4)
CH
Q4 14
93. The pollution due to oxides of sulphur gets 98. Match List - I with List- II.
103. Given E
enhanced due to the presenceof List-I List-II
Statem
(a) particulate matter (Ores) (Composition)
(b) ozone (a) Haematite () Fe04 Cleisto
Statem
(c) hydrocarbons (b) Magnetite (ii) ZnCO3
(ii) FeO3 Cleist
(d) hydrogen peroxide (c) Calamine
chance
(d) Kaolinite (iv) [ALOH), Si,Os)
Choose the most appropriate answer from the Choose the correct answer from the options given In thel
options given below below answen
(1) (a), (d) only (1)(a)-(i), (b)- (ii), (c)-(ii), (d) -(iv)
^

(2) (a). (b). (d) only (a)-(ii), (b) - (i), ( ) - (i), (d) - (iv) (2)
(a)-(ii), (b)-(i), ()-(iv), (d) - (i)
0)b).(©).(d)only (3)
(4) (a)-(i), (b)- (ii), ()- (i), (d) -(iv) 3)
(4(a). (c). (d) only
99. Copper crystallises in fcc unit cell with cell edge
94. Compound X on reaction with O, followed by Zn/
4)
length of 3.608 x 10-8 cm. The density of copper is
HO gives formaldehyde and 2-methyl propanal as 8.92 g cm3, Calculate the atomic mass of copper.
products. The compound X is : 63.1 u 104. The
(1)
(1) 3-Methylbut-1-ene (2) 31.55 u begin
(2) 2-Methylbut-1-ene (3) 60 u (1)
(4) 65 u
(3) 2-Methylbut-2-ene
For a first order reaction A » Products, initial
2)
(4) Pent-2-ene 100.
concentration of A is 0.1 M, which becomes 0.001 M
95. Find the emf of the cell in which the after 5 minutes. Rate constant for the reaction in 3)
following min is
reaction takes place at 298 K
(1) 1.3818 (4)
Ni(s)+2Ag* (0.001 M)- N2* (0.01 M) +2 Ag()
(2) 0.9212
2.3031
(Given that Ecell =10.5 V, =0.059 at (3) 0.4606 105. Wh
F du
298 K) 4) 0.2303

(1) 1.0385 V (1
Section A (Biology : Botany)
(2) 1.385 V
101. Exoskeleton of arthropods is composed of: (3)
3) 0.9615 V
(1) Cutin (4)
(4) 1.05 V
(2) Cellulose
106. "G
Chitin
96. 308)20,(8) (4) Glucosamine
Ph
wh
for the above reaction at 298 K, K, is found to be
3.0x 1059.If the concentration of O, at equilibrium 102. Given below are two statements: (1)
is 0.040 M then concentration of O in M is Statement I:
4.38x 10-32 Decomposition is a process in which the detritus is 3)
(1)
degraded into simpler substances by microbes.
(2) 1.9x 10-3 (4)
Statement II:
3 2.4x 1031 Decomposition is faster if the detritus is rich in lignin 107. WE
(4) 1.2x 1021 and chitin
In the light of the above statements, choose the correct
97. If radius of second Bohr orbit of the Het ion is 105.8 answer from the
options given below:
pm, what is the radius of third Bohr orbit of Li2+ (1) Both Statement I and Statement II are correct
ion?
(2
(2) Both Statement I and Statement II are
(1) 158.7 pm incorrect
(3
(2) 15.87 pm Jay Statement I is correct but Statement II is
incorrect
(3) 1.587 pm
(4) Statement I is incorrect but Statement II is
4) 158.7 A , correct