GHS Version 3 Annex 3 - H & P Codes

Copyright@United Nations, 2009. All rights reserved.
ANNEX 3
CODIFICATION OF HAZARD
STATEMENTS, CODIFICATION AND USE
OF PRECAUTIONARY STATEMENTS AND
EXAMPLES OF PRECAUTIONARY
PICTOGRAMS
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Annex 3
Section 1
CODIFICATION OF HAZARD STATEMENTS
A3.1.1 Introduction
A3.1.1.1 Hazard statement means a statement assigned to a hazard class and category that describes
the nature of the hazards of a hazardous product, including, where appropriate, the degree of hazard.
A3.1.1.2 This section contains the recommended codes assigned to each of the hazard statements
applicable to the hazard categories under the GHS.
A3.1.1.3 The hazard statement codes are intended to be used for reference purposes. They are not part
of the hazard statement text and should not be used to replace it.
A3.1.2 Codification of hazard statements
A3.1.2.1 Hazard statements are assigned a unique alphanumerical code which consists of one letter
and three numbers, as follows:
(a) the letter “H” (for “hazard statement”);
(b) a number designating the type of hazard to which the hazard statement is assigned
according to the numbering of the different parts of the GHS, as follows:
− “2” for physical hazards;

− “3” for health hazards;
− “4” for environmental hazards;
(c) two numbers corresponding to the sequential numbering of hazards arising from the
intrinsic properties of the substance or mixture, such as explosivity (codes from 200 to
210), flammability (codes from 220 to 230), etc.
A3.1.2.2 The codes to be used for designating hazard statements are listed, in numerical order, in
Table A3.1.1 for physical hazards, Table A3.1.2 for health hazards and Table A3.1.3 for environmental
hazards. Each table is divided into 4 columns containing the following information:
Column (1) The hazard statement code;
Column (2) The hazard statement text;
The text in bold should appear on the label, except as otherwise specified. The
information in italics should also appear as part of the hazard statement when the
information is known.
For example: “causes damages to organs (or state all organs affected, if known)
through prolonged or repeated exposure (state route of exposure if it is conclusively
proven that no other routes of exposure cause the hazard)”.
Column (3) Hazard class, with a reference to the chapter of the GHS where information about the
hazard class may be found.
Column (4) The hazard category or categories within a hazard class for which the use of a hazard
statement is applicable.
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A3.1.2.3 In addition to individual hazard statements, a number of combined hazard statements are
given in Table A3.1.2. The alphanumerical codes for the combined statements are constructed from the
codes for the individual statements that are combined, conjoined with the plus (“+”) sign. For example,
H300 + H310 indicates that the text to appear on the label is “Fatal if swallowed or in contact with skin”.
A3.1.2.4 All assigned hazard statements should appear on the label unless otherwise specified in
1.4.10.5.3.3. The competent authority may specify the order in which they appear. Also, where a combined
hazard statement is indicated for two or more hazard statements, the competent authority may specify
whether the combined hazard statement or the corresponding individual statements should appear on the
label, or may leave the choice to the manufacturer/supplier.
Table A3.1.1: Hazard statement codes for physical hazards
Code Physical hazard statements Hazard class (GHS chapter) Hazard

category
(1) (2) (3) (4)
H200 Unstable explosive Explosives (chapter 2.1) Unstable explosive
H201 Explosive; mass explosion hazard Explosives (chapter 2.1) Division 1.1
H202 Explosive; severe projection hazard Explosives (chapter 2.1) Division 1.2
H203 Explosive; fire, blast or projection hazard Explosives (chapter 2.1) Division 1.3
H204 Fire or projection hazard Explosives (chapter 2.1) Division 1.4
H205 May mass explode in fire Explosives (chapter 2.1) Division 1.5
H220 Extremely flammable gas Flammable gases (chapter 2.2) 1

H221 Flammable gas Flammable gases (chapter 2.2) 2
H222 Extremely flammable aerosol Flammable aerosols (chapter 2.3) 1
H223 Flammable aerosol Flammable aerosols (chapter 2.3) 2
H224 Extremely flammable liquid and vapour Flammable liquids (chapter 2.6) 1
H225 Highly flammable liquid and vapour Flammable liquids (chapter 2.6) 2
H226 Flammable liquid and vapour Flammable liquids (chapter 2.6) 3
H227 Combustible liquid Flammable liquids (chapter 2.6) 4
H228 Flammable solid Flammable solids (chapter 2.7) 1, 2
H240 Heating may cause an explosion Self-reactive substances and Type A

mixtures (chapter 2.8); and Organic
peroxides (chapter 2.15)
H241 Heating may cause a fire or explosion Self-reactive substances and Type B
mixtures (chapter 2.8); and Organic
H242 Heating may cause a fire Self-reactive substances and Types
mixtures (chapter 2.8); and Organic C, D, E, F
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids (chapter 2.9); 1
Pyrophoric solids (chapter 2.10)
H251 Self-heating; may catch fire Self-heating substances and 1
mixtures (chapter 2.11)
H252 Self-heating in large quantities; may catch fire Self-heating substances and 2
mixtures (chapter 2.11)
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Code Physical hazard statements Hazard class (GHS chapter) Hazard

category
(1) (2) (3) (4)
H260 In contact with water releases flammable Substances and mixtures which, in 1
gases which may ignite spontaneously contact with water, emit flammable
gases (chapter 2.12)
H261 In contact with water releases flammable gas Substances and mixtures which, in 2, 3
contact with water, emit flammable
gases (chapter 2.12)
H270 May cause or intensify fire; oxidizer Oxidizing gases (chapter 2.4) 1
H271 May cause fire or explosion; strong oxidizer Oxidizing liquids (chapter 2.13); 1
Oxidizing solids (chapter 2.14)
H272 May intensify fire; oxidizer Oxidizing liquids (chapter 2.13); 2, 3
Oxidizing solids (chapter 2.14)
H280 Contains gas under pressure; may explode if Gases under pressure (chapter 2.5) Compressed gas
heated Liquefied gas
Dissolved gas
H281 Contains refrigerated gas; may cause Gases under pressure (chapter 2.5) Refrigerated
cryogenic burns or injury liquefied gas
H290 May be corrosive to metals Corrosive to metals (chapter 2.16) 1
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Table A3.1.2: Hazard statement codes for health hazards
Code Health hazard statements Hazard class (GHS chapter) Hazard

category
(1) (2) (3) (4)
H300 Fatal if swallowed Acute toxicity, oral (chapter 3.1) 1, 2
H301 Toxic if swallowed Acute toxicity, oral (chapter 3.1) 3
H302 Harmful if swallowed Acute toxicity, oral (chapter 3.1) 4
H303 May be harmful if swallowed Acute toxicity, oral (chapter 3.1) 5
H304 May be fatal if swallowed and enters airways Aspiration hazard (chapter 3.10) 1
H305 May be harmful if swallowed and enters airways Aspiration hazard (chapter 3.10) 2
H310 Fatal in contact with skin Acute toxicity, dermal (chapter 3.1) 1, 2
H311 Toxic in contact with skin Acute toxicity, dermal (chapter 3.1) 3
H312 Harmful in contact with skin Acute toxicity, dermal (chapter 3.1) 4
H313 May be harmful in contact with skin Acute toxicity, dermal (chapter 3.1) 5
H314 Causes severe skin burns and eye damage Skin corrosion/irritation (chapter 3.2) 1A, 1B, 1C
H315 Causes skin irritation Skin corrosion/irritation (chapter 3.2) 2
H316 Causes mild skin irritation Skin corrosion/irritation (chapter 3.2) 3
H317 May cause an allergic skin reaction Sensitisation, skin (chapter 3.4) 1, 1A, 1B
H318 Causes serious eye damage Serious eye damage/eye irritation 1
(chapter 3.3)
H319 Causes serious eye irritation Serious eye damage/eye irritation 2A
(chapter 3.3)
H320 Causes eye irritation Serious eye damage/eye irritation 2B
(chapter 3.3)
H330 Fatal if inhaled Acute toxicity, inhalation (chapter 3.1) 1, 2

H331 Toxic if inhaled Acute toxicity, inhalation (chapter 3.1) 3
H332 Harmful if inhaled Acute toxicity, inhalation (chapter 3.1) 4
H333 May be harmful if inhaled Acute toxicity, inhalation (chapter 3.1) 5
H334 May cause allergy or asthma symptoms or Sensitisation, respiratory (chapter 3.4) 1, 1A, 1B
breathing difficulties if inhaled
H335 May cause respiratory irritation Specific target organ toxicity, single 3
exposure; Respiratory tract irritation
(chapter 3.8);
H336 May cause drowsiness or dizziness Specific target organ toxicity, single 3
exposure; Narcotic effects
(chapter 3.8)
H340 May cause genetic defects (state route of exposure if Germ cell mutagenicity (chapter 3.5) 1A, 1B
it is conclusively proven that no other routes of
exposure cause the hazard)
H341 Suspected of causing genetic defects (state route of Germ cell mutagenicity (chapter 3.5) 2
exposure if it is conclusively proven that no other
routes of exposure cause the hazard)
H350 May cause cancer (state route of exposure if it is Carcinogenicity (chapter 3.6) 1A, 1B
conclusively proven that no other routes of exposure
cause the hazard)
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category
(1) (2) (3) (4)
H351 Suspected of causing cancer (state route of exposure Carcinogenicity (chapter 3.6) 2
if it is conclusively proven that no other routes of
exposure cause the hazard)
H360 May damage fertility or the unborn child (state Reproductive toxicity (chapter 3.7) 1A, 1B
specific effect if known)(state route of exposure if it is
cause the hazard)
H361 Suspected of damaging fertility or the unborn Reproductive toxicity (chapter 3.7) 2
child (state specific effect if known)(state route of
exposure if it is conclusively proven that no other
routes of exposure cause the hazard)
H362 May cause harm to breast-fed children Reproductive toxicity, effects on or via Additional
lactation (chapter 3.7) category
H370 Causes damage to organs (or state all organs Specific target organ toxicity, single 1
affected, if known) (state route of exposure if it is exposure (chapter 3.8)
cause the hazard)
H371 May cause damage to organs (or state all organs Specific target organ toxicity, single
affected, if known)(state route of exposure if it is exposure (chapter 3.8)
2
cause the hazard)
H372 Causes damage to organs ( state all organs affected, Specific target organ toxicity, repeated
if known) through prolonged or repeated exposure exposure (chapter 3.9)
1
(state route of exposure if it is conclusively proven
that no other routes of exposure cause the hazard)
H373 May cause damage to organs ( state all organs Specific target organ toxicity, repeated
affected, if known) through prolonged or repeated exposure (chapter 3.9)
exposure (state route of exposure if it is conclusively 2
proven that no other routes of exposure cause the
hazard)
H300 Fatal if swallowed or in contact with skin Acute toxicity, oral (chapter 3.1) and 1, 2
+ acute toxicity dermal (chapter 3.1)
H310
H300 Fatal if swallowed or if inhaled Acute toxicity, oral (chapter 3.1) and 1, 2
+ acute toxicity, inhalation (chapter 3.1)
H330
H310 Fatal in contact with skin or if inhaled Acute toxicity, dermal (chapter 3.1) 1, 2
+ and acute toxicity, inhalation
H330 (chapter 3.1)
H300 Fatal if swallowed, in contact with skin or if Acute toxicity, oral (chapter 3.1), acute 1, 2
+ inhaled toxicity, dermal (chapter 3.1) and acute
H310 toxicity, inhalation (chapter 3.1)
+
H330
H301 Toxic if swallowed or in contact with skin Acute toxicity, oral (chapter 3.1) and 3
H311
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category
(1) (2) (3) (4)
H301 Toxic if swallowed or if inhaled Acute toxicity, oral (chapter 3.1) and 3
H331
H311 Toxic in contact with skin or if inhaled Acute toxicity, dermal (chapter 3.1) 3
H331 (chapter 3.1)
H301 Toxic if swallowed, in contact with skin or if Acute toxicity, oral (chapter 3.1), acute 3
+
H331
H302 Harmful if swallowed or in contact with skin Acute toxicity, oral (chapter 3.1) and 4
H312
H302 Harmful if swallowed or if inhaled Acute toxicity, oral (chapter 3.1) and 4
H332
H312 Harmful in contact with skin or if inhaled Acute toxicity, dermal (chapter 3.1) 4
H332 (chapter 3.1)
H302 Harmful if swallowed, in contact with skin or if Acute toxicity, oral (chapter 3.1), acute 4
+
H332
H303 May be harmful if swallowed or in contact with Acute toxicity, oral (chapter 3.1) and 5
+ skin acute toxicity dermal (chapter 3.1)
H313
H303 May be harmful if swallowed or if inhaled Acute toxicity, oral (chapter 3.1) and 5
H333
H313 May be harmful in contact with skin or if inhaled Acute toxicity, dermal (chapter 3.1) 5
H333 (chapter 3.1)
H303 May be harmful if swallowed, in contact with skin Acute toxicity, oral (chapter 3.1), acute 5
+ or if inhaled toxicity, dermal (chapter 3.1) and acute
+
H333
H315 Causes skin and eye irritation Skin corrosion/irritation (chapter 3.2) 2 (skin)/2A
+ and serious eye damage/eye irritation (eye)
H320 (chapter 3.3)
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Table A3.1.3: Hazard statement codes for environmental hazards
Code Environmental hazard statements Hazard class (GHS chapter) Hazard

category
(1) (2) (3) (4)
H400 Very toxic to aquatic life Hazardous to the aquatic environment,
1
acute hazard (chapter 4.1)
H401 Toxic to aquatic life Hazardous to the aquatic environment,
2
H402 Harmful to aquatic life Hazardous to the aquatic environment,
3
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment,
1
long-term hazard (chapter 4.1)
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment,
2
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment,
3
H413 May cause long lasting harmful effects to Hazardous to the aquatic environment,
4
aquatic life long-term hazard (chapter 4.1)
H420 Harms public health and the environment by Hazardous to the ozone layer
1
destroying ozone in the upper atmosphere (chapter 4.2)
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Annex 3
Section 2
CODIFICATION OF PRECAUTIONARY STATEMENTS
A3.2.1 Introduction
A3.2.1.1 A precautionary statement is a phrase (and/or pictogram) which describes recommended

measures that should be taken to minimize or prevent adverse effects resulting from exposures to a hazardous
product, or improper storage or handling of a hazardous product (see 1.4.10.5.2 (c)).
A3.2.1.2 For the purposes of the GHS, there are five types of precautionary statements: general,
prevention, response (in case of accidental spillage or exposure, emergency response and first-aid), storage
and disposal. For guidance on the use of GHS precautionary statements, including advice on the selection of
the appropriate statements for each GHS hazard class and category, see section 3 to this annex.
A3.2.1.3 This section contains the recommended codes for each of the precautionary statement
included in this annex.
A3.2.2 Codification of precautionary statements
A3.2.2.1 Precautionary statements are assigned a unique alphanumerical code which consists of one
letter and three numbers as follows:
(a) a letter “P” (for “precautionary statement”)
(b) one number designating the type of precautionary statement as follows:
– “1” for general precautionary statements;

– “2” for prevention precautionary statements;
– “3” for response precautionary statements;
– “4” for storage precautionary statements;
– “5” for disposal precautionary statements;
(c) two numbers (corresponding to the sequential numbering of precautionary statements)
A3.2.2.2 The precautionary statement codes are intended to be used for reference purposes. They are
not part of the precautionary statement text and should not be used to replace it.
A3.2.2.3 The codes to be used for designating precautionary statements are listed, in numerical order,
in Table A3.2.1 for general precautionary statements, Table A3.2.2 for prevention precautionary statements,
Table A3.2.3 for response precautionary statements, Table A3.2.4 for storage precautionary statements and
Table A3.2.5 for disposal precautionary statements.
A3.2.3 Structure of the precautionary statement codification tables
A3.2.3.1 Each table is divided into 5 columns containing the following information:
Column (1) The precautionary statement code;
Column (2) The precautionary statement text;
Column (3) The hazard class and the route of exposure, where relevant, for which the use
of a precautionary statement is recommended together with a reference to the
chapter of the GHS where information about the hazard class may be found.
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Column (4) The hazard category or categories within a hazard class for which the use of
a precautionary statement is applicable.
Column (5) Where applicable, conditions relating to the use of a precautionary

statement;
A3.2.3.2 The tables show the core part of the precautionary statements in bold print in
column (2). This is the text, except as otherwise specified, that should appear on the label. Derogations
from the recommended labelling statements are at the discretion of competent authorities.
A3.2.3.3 When a backslash or diagonal mark [/] appears in a precautionary statement text in column
(2), it indicates that a choice has to be made between the phrases they separate. In such cases, the
manufacturer or supplier can choose, or the competent authorities may prescribe the most appropriate
phrase(s). For example in P280 “Wear protective gloves/protective clothing/eye protection/face
protection" could read “wear eye protection”.
A3.2.3.4 When three full stops […] appears in a precautionary statement text in column (2), they
indicate that all applicable conditions are not listed. For example in P241 “Use explosion-proof
electrical/ventilating/lighting/.../equipment”, the use of “...” indicates that other equipment may need to be
specified. Further details of the information to be provided may be found in column (5). In such cases the
manufacturer or supplier can choose, or the competent authorities may prescribe the other conditions to be
specified.
A3.2.3.5 In cases where additional information is required or information has to be specified, this is
indicated by a relevant entry in column (5) in plain text.
A3.2.3.6 When text in italics is used in column (5), this indicates specific conditions applying to the
use or allocation of the precautionary statement. This may relate to conditions attaching to either the general
use of a precautionary statement or its use for a particular hazard class and/or hazard category. For example,
for P241 “Use explosion-proof electrical/ventilating/lighting/.../equipment”, only applies for flammable
solids “if dust clouds can occur”.
A3.2.3.7 To facilitate translation into the languages of users, precautionary statements have been
broken down into individual sentences in the tables in this section. In a number of instances the text that
appears on a GHS label requires that these be added back together. This is indicated in this annex by codes
conjoined with a plus sign “+”. For example P305 + P351 + P338 indicates that the text to appear on the
label is “IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing”. These additive precautionary statements can also be found at
the end of each of the precautionary statement tables in this section. Translation of only the single
precautionary statements is required, as this will enable the compilation of the additive precautionary
statements.
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Table A3.2.1: Codification of general precautionary statements
Code General precautionary statements Hazard class Hazard Conditions for use
category
(1) (2) (3) (4) (5)
P101 If medical advice is needed, have product
as appropriate Consumer products
container or label at hand.
P102 Keep out of reach of children. as appropriate Consumer products
P103 Read label before use. as appropriate Consumer products
Table A3.2.2: Codification of prevention precautionary statements
Code Prevention precautionary statements Hazard class Hazard Conditions for use
category
(1) (2) (3) (4) (5)
P201 Obtain special instructions before use. Explosives (chapter 2.1) Unstable
explosive
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Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2

Carcinogenicity (chapter 3.6) 1A, 1B, 2
Reproductive toxicity (chapter 3.7) 1A, 1B, 2
Reproductive toxicity, effects on or via lactation Additional
(chapter 3.7) category
P202 Do not handle until all safety precautions have Explosives (chapter 2.1) Unstable
been read and understood. explosive
category
(1) (2) (3) (4) (5)
P210 Keep away from heat/sparks/open flames/hot Explosives (chapter 2.1) Divisions 1.1, Manufacturer/supplier or the competent
surfaces. – No smoking. 1.2, 1.3, 1.4, 1.5 authority to specify applicable ignition
Flammable gases (chapter 2.2) 1, 2 source(s).
Flammable aerosols (chapter 2.3) 1, 2
Flammable liquids (chapter 2.6) 1, 2, 3
Flammable solids (chapter 2.7) 1, 2
Self-reactive substances and mixtures Types
(chapter 2.8) A, B, C, D, E, F
Pyrophoric liquids (chapter 2.9) 1
Pyrophoric solids (chapter 2.10) 1
Organic peroxides (chapter 2.15) Types
A, B, C, D, E, F
Flammable liquids (chapter 2.6) 4 - specify to keep away from flames and
hot surfaces.
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Oxidizing liquids (chapter 2.13) 1, 2, 3 - specify to keep away from heat.

Oxidizing solids (chapter 2.14) 1, 2, 3
P211 Do not spray on an open flame or other ignition Flammable aerosols (chapter 2.3) 1, 2
source.
P220 Keep/Store away from clothing/.../combustible Oxidizing gases (chapter 2.4) 1 ... Manufacturer/supplier or the
materials. Self-reactive substances and mixtures (chapter 2.8) Types competent authority to specify other
A, B, C, D, E, F incompatible materials.
Oxidizing liquids (chapter 2.13) 2, 3
Oxidizing solids (chapter 2.14) 2, 3
A, B, C, D, E, F
Oxidizing liquids (chapter 2.13) 1 - specify to keep away from clothing and
Oxidizing solids (chapter 2.14) 1 other combustible materials.
category
(1) (2) (3) (4) (5)
P221 Take any precaution to avoid mixing with Oxidizing liquids (chapter 2.13) 1, 2, 3 ... Manufacturer/supplier or the
combustibles/... Oxidizing solids (chapter 2.14) 1, 2, 3 competent authority to specify other
incompatible materials.
P222 Do not allow contact with air. Pyrophoric liquids (chapter 2.9) 1
P223 Keep away from any possible contact with water, Substances and mixtures which, in contact with 1, 2
because of violent reaction and possible flash water, emit flammable gases (chapter 2.12)
fire.
P230 Keep wetted with ... Explosives (chapter 2.1) Divisions 1.1, ... Manufacturer/supplier or the
1.2, 1.3, 1.5 competent authority to specify
appropriate material.
- if drying out increases explosion
hazard, except as needed for
manufacturing or operating processes
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(e.g. nitrocellulose).
P231 Handle under inert gas. Substances and mixtures which, in contact with 1, 2, 3
water, emit flammable gases (chapter 2.12)
P232 Protect from moisture. Substances and mixtures which, in contact with 1, 2, 3
P233 Keep container tightly closed. Flammable liquids (chapter 2.6) 1, 2, 3
Acute toxicity, inhalation (chapter 3.1) 1, 2, 3 - if product is volatile so as to generate
Specific target organ toxicity, single exposure; 3 hazardous atmosphere.
respiratory tract irritation (chapter 3.8)
Specific target organ toxicity, single exposure; 3
narcotic effects (chapter 3.8)
P234 Keep only in original container. Self-reactive substances and mixtures (chapter 2.8) Types
A, B, C, D, E, F
A, B, C, D, E, F
Substances and mixtures corrosive to metals 1
(chapter 2.16)
category
(1) (2) (3) (4) (5)
P235 Keep cool. Flammable liquids (chapter 2.6) 1, 2, 3, 4
Self-reactive substances and mixtures (chapter 2.8) Types
A, B, C, D, E, F
Self-heating substances and mixtures 1, 2
(chapter 2.11)
A, B, C, D, E, F
P240 Ground/bond container and receiving Explosives (chapter 2.1) Divisions 1.1, - if the explosive is electrostatically
equipment. 1.2, 1.3, 1.4, 1.5 sensitive.
Flammable liquids (chapter 2.6) 1, 2, 3 - if electrostatically sensitive material is
for reloading.
- if product is volatile so as to generate
hazardous atmosphere.
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Flammable solids (chapter 2.7) 1, 2 - if electrostatically sensitive material is

for reloading.
P241 Use explosion-proof Flammable liquids (chapter 2.6) 1, 2, 3 … Manufacturer/supplier or the
electrical/ventilating/lighting/.../equipment. competent authority to specify other
equipment.
Flammable solids (chapter 2.7) 1, 2 ... Manufacturer/supplier or the
competent authority to specify other
equipment.
- if dust clouds can occur.
P242 Use only non-sparking tools. Flammable liquids (chapter 2.6) 1, 2, 3
P243 Take precautionary measures against static Flammable liquids (chapter 2.6) 1, 2, 3
discharge.
P244 Keep reduction valves free from grease and oil. Oxidizing gases (chapter 2.4) 1
P250 Do not subject to grinding/shock/…/friction. Explosives (chapter 2.1) Divisions 1.1, ... Manufacturer/supplier or the
1.2, 1.3, 1.4, 1.5 competent authority to specify applicable
rough handling.
category
(1) (2) (3) (4) (5)
P251 Pressurized container: Do not pierce or burn, Flammable aerosols (chapter 2.3) 1, 2
even after use.
P260 Do not breathe Acute toxicity – inhalation (chapter 3.1) 1, 2 Manufacturer/supplier or the competent
dust/fume/gas/mist/vapours/spray. Specific target organ toxicity, single exposure 1, 2 authority to specify applicable conditions.
(chapter 3.8)
Specific target organ toxicity, repeated exposure 1, 2
(chapter 3.9)
Skin corrosion (chapter 3.2) 1A, 1B, 1C - specify do not breathe dusts or mists
Reproductive toxicity – effects on or via lactation Additional - if inhalable particles of dusts or mists
(chapter 3.7) category may occur during use.
P261 Avoid breathing Acute toxicity – inhalation (chapter 3.1) 3, 4 Manufacturer/supplier or the competent
dust/fume/gas/mist/vapours/spray. Respiratory sensitization (chapter 3.4) 1, 1A, 1B authority to specify applicable conditions.
Skin sensitization (chapter 3.4) 1, 1A, 1B
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P262 Do not get in eyes, on skin, or on clothing. Acute toxicity – dermal (chapter 3.1) 1, 2
P263 Avoid contact during pregnancy/while nursing. Reproductive toxicity – effects on or via lactation Additional
P264 Wash ... thoroughly after handling. Acute toxicity – oral (chapter 3.1) 1, 2, 3, 4 ... Manufacturer/supplier or the
Acute toxicity – dermal (chapter 3.1) 1, 2 competent authority to specify parts of the
body to be washed after handling.
Skin corrosion (chapter 3.2) 1A, 1B, 1C
Skin irritation (chapter 3.2) 2
Eye irritation (chapter 3.3) 2A, 2B
Reproductive toxicity – effects on or via lactation Additional
category
(1) (2) (3) (4) (5)
P264 Wash ... thoroughly after handling. (cont’d) Specific target organ toxicity, single exposure 1, 2 ... Manufacturer/supplier or the
(cont’d) (chapter 3.8) competent authority to specify parts of the
Specific target organ toxicity, repeated exposure 1 body to be washed after handling.
(chapter 3.9)
P270 Do not eat, drink or smoke when using this Acute toxicity – oral (chapter 3.1) 1, 2, 3, 4
product. Acute toxicity – dermal (chapter 3.1) 1, 2
Reproductive toxicity – effects on or via lactation Additional
Specific target organ toxicity, single exposure 1, 2
(chapter 3.8)
Specific target organ toxicity, repeated exposure 1
(chapter 3.9)
P271 Use only outdoors or in a well-ventilated area. Acute toxicity – inhalation (chapter 3.1) 1, 2, 3, 4
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P272 Contaminated work clothing should not be Skin sensitization (chapter 3.4) 1, 1A, 1B
allowed out of the workplace.
P273 Avoid release to the environment. Hazardous to the aquatic environment, acute 1, 2, 3 - if this is not the intended use.
hazard (chapter 4.1)
Hazardous to the aquatic environment, long-term 1, 2, 3, 4
category
(1) (2) (3) (4) (5)
P280 Wear protective gloves/protective clothing/eye Explosives (chapter 2.1) Divisions 1.1, - Specify face protection.
protection/face protection. 1.2, 1.3, 1.4, 1.5 Manufacturer/supplier or the competent
authority to specify type of equipment.
Flammable liquids (chapter 2.6) 1, 2, 3, 4 - Specify protective gloves and eye/face
Flammable solids (chapter 2.7) 1, 2 protection.
Manufacturer/supplier or the competent
Self-reactive substances and mixtures (chapter 2.8) Types A, B, C,
D, E, F
Self-heating substances and mixtures 1, 2
(chapter 2.11)
Substances and mixtures which, in contact with 1, 2, 3
Oxidizing liquids (chapter 2.13) 1, 2, 3
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Organic peroxides (chapter 2.15) Types A, B, C,
D, E, F
Acute toxicity – dermal (chapter 3.1) 1, 2, 3, 4 - Specify protective gloves/clothing.
Skin corrosion (chapter 3.2) 1A, 1B, 1C - Specify protective gloves/clothing and
eye/face protection.
Skin irritation (chapter 3.2) 2 - Specify protective gloves.
Skin sensitization (chapter 3.4) 1, 1A, 1B Manufacturer/supplier or the competent
Severe eye damage (chapter 3.3) 1 - Specify eye/face protection.
Eye irritation (chapter 3.3) 2A Manufacturer/supplier or the competent
category
(1) (2) (3) (4) (5)
P281 Use personal protective equipment as required. Explosives (chapter 2.1) Unstable
explosive
P282 Wear cold insulating gloves/face shield/eye Gases under pressure (chapter 2.5) Refrigerated
protection. liquefied gas
P283 Wear fire/flame resistant/retardant clothing. Oxidizing liquids (chapter 2.13) 1
Oxidizing solids (chapter 2.14) 1
P284 Wear respiratory protection. Acute toxicity, inhalation (chapter 3.1) 1, 2 Manufacturer/supplier or the competent
authority to specify equipment.
P285 In case of inadequate ventilation wear Respiratory sensitization (chapter 3.4) 1, 1A, 1B Manufacturer/supplier or the competent
respiratory protection. authority to specify equipment.
- 316 -
P231 Handle under inert gas. Protect from moisture. Substances and mixtures which, in contact with 1, 2, 3
+ water, emit flammable gases (chapter 2.12)
P232
P235 Keep cool. Protect from sunlight. Self-heating substances and mixtures 1, 2
+ (chapter 2.11)
P410
Table A3.2.3: Codification of response precautionary statements
Code Response precautionary statements Hazard class Hazard category Conditions for use
(1) (2) (3) (4) (5)
P301 IF SWALLOWED: Acute toxicity, oral (chapter 3.1) 1, 2, 3, 4
Aspiration hazard (chapter 3.10) 1, 2
P302 IF ON SKIN: Pyrophoric liquids (chapter 2.9) 1
Acute toxicity, dermal (chapter 3.1) 1, 2, 3, 4
P303 IF ON SKIN (or hair): Flammable liquids (chapter 2.6) 1, 2, 3
P304 IF INHALED: Acute toxicity, inhalation (chapter 3.1) 1, 2, 3, 4, 5
Respiratory sensitization (chapter 3.4) 1, 1A, 1B
- 317 -

P305 IF IN EYES: Skin corrosion (chapter 3.2) 1A, 1B, 1C
Severe eye damage (chapter 3.3) 1
P306 IF ON CLOTHING: Oxidizing liquids (chapter 2.13) 1
P307 IF exposed: Specific target organ toxicity, single exposure 1
(chapter 3.8)
P308 IF exposed or concerned: Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2
Reproductive toxicity, effects on or via Additional category
lactation (chapter 3.7)
(1) (2) (3) (4) (5)
P309 IF exposed or if you feel unwell: Specific target organ toxicity, single exposure 2
(chapter 3.8)
P310 Immediately call a POISON CENTER or Acute toxicity, oral (chapter 3.1) 1, 2, 3
doctor/physician. Acute toxicity, dermal (chapter 3.1) 1, 2
Acute toxicity, inhalation (chapter 3.1) 1, 2
P311 Call a POISON CENTER or doctor/physician. Acute toxicity, inhalation (chapter 3.1) 3
(chapter 3.8)
P312 Call a POISON CENTER or doctor/physician if Acute toxicity, oral (chapter 3.1) 4
you feel unwell. Acute toxicity, oral (chapter 3.1) 5
- 318 -
Acute toxicity, dermal (chapter 3.1) 3, 4, 5

Acute toxicity, inhalation (chapter 3.1) 4
Acute toxicity, inhalation (chapter 3.1) 5
P313 Get medical advice/attention. Skin irritation (chapter 3.2) 2, 3
P314 Get medical advice/attention if you feel unwell. Specific target organ toxicity, repeated 1, 2
exposure (chapter 3.9)
(1) (2) (3) (4) (5)
P315 Get immediate medical advice/attention. Gases under pressure (chapter 2.5) Refrigerated
liquefied gas
P320 Specific treatment is urgent (see ... on this label). Acute toxicity, inhalation (chapter 3.1) 1, 2 ... Reference to supplemental first aid
instruction.
- if immediate administration of antidote is
required.
P321 Specific treatment (see ... on this label). Acute toxicity, oral (chapter 3.1) 1, 2, 3 ... Reference to supplemental first aid
instruction.
- if immediate administration of antidote is
required.
Acute toxicity, inhalation (chapter 3.1) 3 ... Reference to supplemental first aid
instruction.
- if immediate specific measures are
required.
Skin corrosion (chapter 3.2) 1A, 1B, 1C ... Reference to supplemental first aid
- 319 -
Skin irritation (chapter 3.2) 2 instruction.

Skin sensitization (chapter 3.4) 1, 1A, 1B - manufacturer/supplier or competent
authority may specify a cleansing agent
if appropriate.
Specific target organ toxicity, single exposure 1 ... Reference to supplemental first aid
(chapter 3.8) instruction.
- if immediate measures are required.
P322 Specific measures (see ... on this label). Acute toxicity, dermal (chapter 3.1) 1, 2 ... Reference to supplemental first aid
Acute toxicity, dermal (chapter 3.1) 3, 4 instruction.
- if immediate measures such as specific
cleansing agent is advised.
P330 Rinse mouth. Acute toxicity, oral (chapter 3.1) 1, 2, 3, 4

P331 Do NOT induce vomiting. Skin corrosion (chapter 3.2) 1A, 1B, 1C
P332 If skin irritation occurs: Skin irritation (chapter 3.2) 2, 3
(1) (2) (3) (4) (5)
P333 If skin irritation or rash occurs: Skin sensitization (chapter 3.4) 1, 1A, 1B
P334 Immerse in cool water/wrap in wet bandages. Pyrophoric liquids (chapter 2.9) 1
Substances and mixtures which, in contact with 1, 2
P335 Brush off loose particles from skin. Pyrophoric solids (chapter 2.10) 1
Substances and mixtures which, in contact with 1, 2
P336 Thaw frosted parts with lukewarm water. Do Gases under pressure (chapter 2.5) Refrigerated
not rub affected area. liquefied gas
P337 If eye irritation persists: Eye irritation (chapter 3.3) 2A, 2B
P338 Remove contact lenses, if present and easy to do. Skin corrosion (chapter 3.2) 1A, 1B, 1C
Continue rinsing. Severe eye damage (chapter 3.3) 1
- 320 -
P340 Remove victim to fresh air and keep at rest in a Acute toxicity, inhalation (chapter 3.1) 1, 2, 3, 4
position comfortable for breathing. Skin corrosion (chapter 3.2) 1A, 1B, 1C
P341 If breathing is difficult, remove victim to fresh Respiratory sensitization (chapter 3.4) 1, 1A, 1B
air and keep at rest in a position comfortable for
breathing.
P342 If experiencing respiratory symptoms: Respiratory sensitization (chapter 3.4) 1, 1A, 1B
P350 Gently wash with plenty of soap and water. Acute toxicity, dermal (chapter 3.1) 1, 2
P351 Rinse cautiously with water for several minutes. Skin corrosion (chapter 3.2) 1A, 1B, 1C
(1) (2) (3) (4) (5)
P352 Wash with plenty of soap and water. Acute toxicity, dermal (chapter 3.1) 3, 4
P353 Rinse skin with water/shower. Flammable liquids (chapter 2.6) 1, 2, 3
P360 Rinse immediately contaminated clothing and Oxidizing liquids (chapter 2.13) 1
skin with plenty of water before removing Oxidizing solids (chapter 2.14) 1
clothes.
P361 Remove/Take off immediately all contaminated Flammable liquids (chapter 2.6) 1, 2, 3
clothing. Acute toxicity, dermal (chapter 3.1) 1, 2, 3
P362 Take off contaminated clothing and wash before Skin irritation (chapter 3.2) 2
reuse.
P363 Wash contaminated clothing before reuse. Acute toxicity, dermal (chapter 3.1) 1, 2, 3
- 321 -
Acute toxicity, dermal (chapter 3.1) 4

P370 In case of fire: Explosives (chapter 2.1) Divisions 1.1, 1.2,

1.3, 1.4, 1.5
Oxidizing gases (chapter 2.4) 1
Flammable liquids (chapter 2.6) 1, 2, 3, 4
Flammable solids (chapter 2.7) 1, 2
Self-reactive substances and mixtures Types A, B, C, D,
(chapter 2.8) E, F
(1) (2) (3) (4) (5)
P370 In case of fire: (cont’d) Oxidizing liquids (chapter 2.13) 1, 2, 3
(cont’d) Oxidizing solids (chapter 2.14) 1, 2, 3
P371 In case of major fire and large quantities: Oxidizing liquids (chapter 2.13) 1
P372 Explosion risk in case of fire. Explosives (chapter 2.1) Unstable
- except if explosives are 1.4S
explosives and
AMMUNITION AND COMPONENTS
Divisions 1.1, 1.2,
THEREOF.
1.3, 1.4, 1.5
P373 DO NOT fight fire when fire reaches explosives. Explosives (chapter 2.1) Unstable
explosives and
Divisions 1.1, 1.2,
1.3, 1.4, 1.5
P374 Fight fire with normal precautions from a Explosives (chapter 2.1) Division 1.4 - if explosives are 1.4S AMMUNITION
reasonable distance. AND COMPONENTS THEREOF.
P375 Fight fire remotely due to the risk of explosion. Self-reactive substances and mixtures Types A, B
- 322 -
(chapter 2.8)
Oxidizing liquids (chapter 2.13) 1
P376 Stop leak if safe to do so. Oxidizing gases (chapter 2.4) 1
P377 Leaking gas fire: Do not extinguish, unless leak Flammable gases (chapter 2.2) 1, 2
can be stopped safely.
P378 Use ... for extinction. Flammable liquids (chapter 2.6) 1, 2, 3, 4 ... Manufacturer/supplier or the competent
Flammable solids (chapter 2.7) 1, 2 authority to specify appropriate media
Self-reactive substances and mixtures Types A, B, C, D, - if water increases risk.
(chapter 2.8) E, F
(1) (2) (3) (4) (5)
P380 Evacuate area. Explosives (chapter 2.1) Unstable
explosives
Explosives (chapter 2.1) Divisions 1.1, 1.2,
1.3, 1.4, 1.5
Self-reactive substances and mixtures Types A, B
(chapter 2.8)
Oxidizing liquids (chapter 2.13) 1
P381 Eliminate all ignition sources if safe to do so. Flammable gases (chapter 2.2) 1, 2
P390 Absorb spillage to prevent material damage. Substances and mixtures corrosive to metals 1
(chapter 2.16)
P391 Collect spillage. Hazardous to the aquatic environment, acute 1
Hazardous to the aquatic environment, long- 1, 2
- 323 -
term hazard (chapter 4.1)
P301 IF SWALLOWED: Immediately call a Acute toxicity, oral (chapter 3.1) 1, 2, 3

+ POISON CENTER or doctor/physician. Aspiration hazard (chapter 3.10) 1, 2
P310
P301 IF SWALLOWED: Call a POISON CENTER Acute toxicity, oral (chapter 3.1) 4
+ or doctor/physician if you feel unwell.
P312
P301 IF SWALLOWED: Rinse mouth. Do NOT Skin corrosion (chapter 3.2) 1A, 1B, 1C
+ induce vomiting.
P330
+
P331
P302 IF ON SKIN: Immerse in cool water/wrap in Pyrophoric liquids (chapter 2.9) 1
+ wet bandages.
P334
(1) (2) (3) (4) (5)
P302 IF ON SKIN: Gently wash with plenty of soap Acute toxicity, dermal (chapter 3.1) 1, 2
+ and water.
P350
P302 IF ON SKIN: Wash with plenty of soap and Acute toxicity, dermal (chapter 3.1) 3, 4
+ water. Skin irritation (chapter 3.2) 2
P352
P303 IF ON SKIN (or hair): Remove/Take off Flammable liquids (chapter 2.6) 1, 2, 3
+ immediately all contaminated clothing. Rinse Skin corrosion (chapter 3.2) 1A, 1B, 1C
P361 skin with water/shower.
+
P353
P304 IF INHALED: Call a POISON CENTER or Acute toxicity, inhalation (chapter 3.1) 5
+ doctor/physician if you feel unwell.
P312
P304 IF INHALED: Remove victim to fresh air and Acute toxicity, inhalation (chapter 3.1) 1, 2, 3, 4
+ keep at rest in a position comfortable for
- 324 -

P340 breathing.
P304 IF INHALED: If breathing is difficult, remove Respiratory sensitization (chapter 3.4) 1, 1A, 1B
+ victim to fresh air and keep at rest in a position
P341 comfortable for breathing.
P305 IF IN EYES: Rinse cautiously with water for Skin corrosion (chapter 3.2) 1A, 1B, 1C
+ several minutes. Remove contact lenses, if Severe eye damage (chapter 3.3) 1
P351 present and easy to do. Continue rinsing.
+
P338
P306 IF ON CLOTHING: Rinse immediately Oxidizing liquids (chapter 2.13) 1
+ contaminated clothing and skin with plenty of Oxidizing solids (chapter 2.14) 1
P360 water before removing clothes.
(1) (2) (3) (4) (5)
P307 IF exposed: Call a POISON CENTER or Specific target organ toxicity, single exposure 1
+ doctor/physician. (chapter 3.8)
P311
P308 IF exposed or concerned: Get medical advice/ Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2
+ attention. Carcinogenicity (chapter 3.6) 1A, 1B, 2
P313
P309 IF exposed or if you feel unwell: Call a POISON Specific target organ toxicity, single exposure 2
+ CENTER or doctor/physician. (chapter 3.8)
P311
P332 If skin irritation occurs: Get medical advice/ Skin irritation (chapter 3.2) 2, 3
+ attention.
P313
P333 If skin irritation or rash occurs: Get medical Skin sensitization (chapter 3.4) 1, 1A, 1B
- 325 -
+ advice/attention.
P313
P335 Brush off loose particles from skin. Immerse in Pyrophoric solids (chapter 2.10) 1
+ cool water/wrap in wet bandages. Substances and mixtures which, in contact with 1, 2
P334 water, emit flammable gases (chapter 2.12)
P337 If eye irritation persists: Get medical Eye irritation (chapter 3.3) 2A, 2B
+ advice/attention.
P313
P342 If experiencing respiratory symptoms: Call a Respiratory sensitization (chapter 3.4) 1, 1A, 1B
+ POISON CENTER or doctor/physician.
P311
P370 In case of fire: Stop leak if safe to do so. Oxidizing gases (chapter 2.4) 1
+
P376
(1) (2) (3) (4) (5)
P370 In case of fire: Use ... for extinction. Flammable liquids (chapter 2.6) 1, 2, 3, 4 ... Manufacturer/supplier or the competent
+ Flammable solids (chapter 2.7) 1, 2 authority to specify appropriate media.
P378
Self-reactive substances and mixtures Types A, B, C, D, - if water increases risk.
(chapter 2.8) E, F
P370 In case of fire: Evacuate area. Explosives (chapter 2.1) Divisions 1.1, 1.2,
+ 1.3, 1.4, 1.5
P380
P370 In case of fire: Evacuate area. Fight fire Self-reactive substances and mixtures Types A, B
+ remotely due to the risk of explosion. (chapter 2.8)
- 326 -
P380
+
P375
P371 In case of major fire and large quantities: Oxidizing liquids (chapter 2.13) 1
+ Evacuate area. Fight fire remotely due to the Oxidizing solids (chapter 2.14) 1
P380 risk of explosion.
+
P375
Table A3.2.4: Codification of storage precautionary statements
Code Storage precautionary statements Hazard class Hazard category Conditions for use
(1) (2) (3) (4) (5)
P401 Store … Explosives (chapter 2.1) Unstable explosives ... in accordance with local/regional/
and Divisions 1.1, national/international regulations (to be
1.2, 1.3, 1.4, 1.5 specified).
P402 Store in a dry place. Substances and mixtures which, in contact with
1, 2, 3
P403 Store in a well-ventilated place. Flammable gases (chapter 2.2) 1, 2
Oxidizing gases (chapter 2.4) 1
Gases under pressure (chapter 2.5) Compressed gas
Liquefied gas
Refrigerated
Liquefied gas
- 327 -
Dissolved gas
A, B, C, D, E, F
Acute toxicity, inhalation (chapter 3.1) 1, 2, 3 - if product is volatile so as to
generate hazardous atmosphere.
Specific target organ toxicity, single exposure;
3
3
P404 Store in a closed container. Substances and mixtures which, in contact with
1, 2, 3
(1) (2) (3) (4) (5)
P405 Store locked up. Acute toxicity, oral (chapter 3.1) 1, 2, 3
Acute toxicity, dermal (chapter 3.1) 1, 2, 3
Acute toxicity, inhalation (chapter 3.1) 1, 2, 3
Specific target organ toxicity, single exposure
1, 2
(chapter 3.8)
3
3
- 328 -

P406 Store in corrosive resistant/... container with a Substances and mixtures corrosive to metals ... Manufacturer/supplier or the
resistant inner liner. (chapter 2.16) 1 competent authority to specify other
compatible materials.
P407 Maintain air gap between stacks/pallets. Self-heating substances and mixtures (chapter 2.11) 1, 2
P410 Protect from sunlight. Flammable aerosols (chapter 2.3) 1, 2

Gases under pressure (chapter 2.5) Compressed gas
Liquefied gas
Dissolved gas
Self-heating substances and mixtures (chapter 2.11) 1, 2
A, B, C, D, E, F
(1) (2) (3) (4) (5)
P411 Store at temperatures not exceeding …°C/…°F. Self-reactive substances and mixtures (chapter 2.8) Types ... Manufacturer/supplier or the
A, B, C, D, E, F competent authority to specify
temperature.
A, B, C, D, E, F
P412 Do not expose to temperatures exceeding 50 °C/ Flammable aerosols (chapter 2.3)
1, 2
122 °F.
P413 Store bulk masses greater than … kg/…lbs at Self-heating substances and mixtures (chapter 2.11) ... Manufacturer/supplier or the
temperatures not exceeding …°C/…°F. 1, 2 competent authority to specify mass and
temperature.
P420 Store away from other materials. Self-reactive substances and mixtures (chapter 2.8) Types
A, B, C, D, E, F
Self-heating substances and mixtures (chapter 2.11) 1, 2
- 329 -

A, B, C, D, E, F
P422 Store contents under ... Pyrophoric liquids (chapter 2.9) 1 ... Manufacturer/supplier or the
competent authority to specify
Pyrophoric solids (chapter 2.10) 1 appropriate liquid or inert gas.
P402 Store in a dry place. Store in a closed container. Substances and mixtures which, in contact with
+ water, emit flammable gases (chapter 2.12) 1, 2, 3
P404
P403 Store in a well-ventilated place. Keep container Acute toxicity, inhalation (chapter 3.1) 1, 2, 3 - if product is volatile so as to
+ tightly closed. generate hazardous atmosphere.
P233 3
3
(1) (2) (3) (4) (5)
P403 Store in a well-ventilated place. Keep cool. Flammable liquids (chapter 2.6) 1, 2, 3, 4
+
Self-reactive substances and mixtures (chapter 2.8) Types A, B, C, D,
P235
E, F
P410 Protect from sunlight. Store in a well-ventilated Gases under pressure (chapter 2.5) Compressed gas
+ place.
Liquefied gas
P403
Dissolved gas
P410 Protect from sunlight. Do not expose to Flammable aerosols (chapter 2.3)
+ temperatures exceeding 50 °C/122 °F. 1, 2
P412
P411 Store at temperatures not exceeding …°C/…°F. Organic peroxides (chapter 2.15) ... Manufacturer/supplier or the
Types A, B, C, D,
+ Keep cool. competent authority to specify
E, F
P235 temperature.
- 330 -
Table A3.2.5: Codification of disposal precautionary statements
Code Disposal precautionary statements Hazard class Hazard category Conditions for use
(1) (2) (3) (4) (5)
P501 Dispose of contents/container to ... Explosives (chapter 2.1) Unstable explosives ... in accordance with local/regional/
and Divisions 1.1, national/international regulation (to be
1.2, 1.3, 1.4, 1.5 specified).
A, B, C, D, E, F
Substances and mixtures which, in contact with water, 1, 2, 3
emit flammable gases (chapter 2.12)
- 331 -
A, B, C, D, E, F
Acute toxicity, oral (chapter 3.1) 1, 2, 3, 4
Acute toxicity, dermal (chapter 3.1) 1, 2, 3, 4
Acute toxicity, inhalation (chapter 3.1) 1, 2
(chapter 3.8)
Code Disposal precautionary statements Hazard class Hazard category Conditions for use
(1) (2) (3) (4) (5)
P501 Dispose of contents/container to ... (cont’d) Specific target organ toxicity , single exposure; 3
(cont’d) respiratory tract irritation (chapter 3.8)
Specific target organ toxicity, single exposure; narcotic 3
effects (chapter 3.8)
Specific target organ toxicity, repeated exposure 1, 2
(chapter 3.9)
Hazardous to the aquatic environment, acute hazard 1, 2, 3
(chapter 4.1)
Hazardous to the aquatic environment, long-term hazard 1, 2, 3, 4
(chapter 4.1)
P502 Refer to manufacturer/supplier for Hazardous to the ozone layer (chapter 4.2) 1
information on recovery/recycling
- 332 -
Annex 3
Section 3
USE OF PRECAUTIONARY STATEMENTS
A3.3.1 Introduction
A3.3.1.1 This section provides guidance on the use of precautionary statements consistent with the
GHS, including advice on the selection of appropriate statements for each GHS hazard class and category.
A3.3.1.2 The starting point for assigning precautionary statements is the hazard classification of the
chemical product. The system of classifying hazards in the GHS is based on the intrinsic properties of the
chemicals involved (see 1.3.2.2.1). In some systems, however, labelling may not be required for chronic
hazards on consumer product labels, if information shows that the respective risks can be excluded under
conditions of normal handling, normal use or foreseeable misuse (see Annex 5). If certain hazard statements
are not required then the corresponding precautionary statements are also not necessary (see A5.1.1).
A3.3.1.3 The guidance for assigning the phrases in this section has been developed to provide the
essential minimum phrases linking precautionary statements with relevant GHS hazard classification criteria
and type of hazard.
A3.3.1.4 Existing precautionary statements have been used to the maximum extent as the basis for the
development of this section. These existing systems have included the IPCS International Chemical Safety
Card (ICSC) Compilers Guide, the American National Standards (ANSI Z129.1), the EU classification and
labelling directives, the Emergency Response Guidebook (ERG 2004), and the Pesticide Label Review
Manual of the Environmental Protection Agency (EPA) of the United States of America.
A3.3.1.5 The goal of this section is to promote a more consistent use of precautionary statements.
Their use will reinforce safe handling procedures and will enable the key concepts and approaches to be
emphasized in training and education activities.
A3.3.1.6 This section should be seen as a living document and therefore subject to further refinement
and development over time. The basic concepts of the matrix and the philosophy given below will remain.
A3.3.2 Allocation of precautionary statements
A3.3.2.1 This section sets out a matrix which guides the selection of appropriate precautionary
statements. It includes elements for all categories of precautionary action. All specific elements relating to
particular hazard classes should be used. General elements not linked in particular to a certain hazard class or
category should also be used where relevant.
A3.3.2.2 To provide flexibility in the application of precautionary phrases, a combination of

statements is encouraged to save label space and improve their readability. Combination of phrases can also
be useful for different types of hazard where the precautionary behaviour is similar, e.g. “Keep away from
heat, sparks and open flame and store in a cool well ventilated place”.
A3.3.2.3 Precautionary statements should appear on GHS labels along with the GHS hazard
communication elements (pictograms, signal words and hazard statements). Additional supplemental
information, such as directions for use, may also be provided at the discretion of the manufacturer/supplier
and/or competent authority (see Chapter 1.2 and Chapter 1.4, para. 1.4.6.3). For some specific chemicals,
supplementary first aid, treatment measures or specific antidotes or cleansing materials may be required.
Poisons Centres and/or medical practitioners or specialist advice should be sought in such situations and
included on labels.
- 333 -
A3.3.3 General precautionary measures
A3.3.3.1 General precautionary measures should be adopted for all substances and mixtures which are
classified as hazardous to human health or the environment. To this end, the needs of and the information
sources available to three groups of users or applicators should be taken into account: the general public, the
commercial user and the industrial worker.
A3.3.3.2 The presumed observation of precautionary label information, specific safety guidelines, and
the safety data sheet for each product before use are part of the labelling requirements and occupational
health and safety procedures.
A3.3.3.3 In order to correctly implement precautionary measures concerning prevention, response,

storage and disposal, it is also necessary to have information on the composition of products at hand, so that
information shown on the container, label and safety data sheet can be taken into account when asking for
further specialist advice.
A3.3.3.4 The following general precautionary statements on the GHS label are appropriate under the
given conditions:
General GHS label, supplemental label P101 If medical advice is needed: Have
public information product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
Industrial GHS label, supplemental label none of the above
worker information, Safety Data Sheet,
workplace instructions
A3.3.4 Structure of the precautionary statements matrix
A3.3.4.1 The tables making up the matrix show the core part of the precautionary statements in bold
print. This is the text, except as otherwise specified, that should appear on the label. However, it is not
necessary to insist on identical sets of words in all situations. Derogations from the recommended labelling
statements are at the discretion of competent authorities. In all cases, clear plain language is essential to
convey information on precautionary behaviour.
A3.3.4.2 Text in italics that starts with “ - if ” or “- specify” is intended to be an explanatory

conditional note for the application of the precautionary statements and is not intended to appear on the label.
A3.3.4.3 When a backslash or diagonal mark [/] appears in a precautionary statement text, it indicates
that a choice needs to be made between the words they separate. In such cases, the manufacturer or supplier
can choose or competent authorities may prescribe the most appropriate phrase(s). For example, “Keep
away from heat/sparks/open flames/hot surfaces” could read “Keep away from heat”.
A3.3.4.4 When three full stops […] appear in a precautionary statement text, they indicate that all
applicable conditions are not listed. In such cases the manufacturer or supplier can choose, or the competent
authorities may prescribe the other conditions to be specified. For example, in the statement “Use
explosion-proof electrical/ventilating/lighting/.../equipment”, the use of “...” indicates that other
equipment may need to be specified.
A3.3.4.5 In the majority of cases, the recommended precautionary statements are independent, e.g. the
phrases for explosive hazard do not modify those related to certain health hazards and products that are
classified for both hazard classes should bear appropriate precautionary statements for both.
- 334 -
A3.3.4.6 Where a substance or mixture is classified for a number of health hazards, generally the most
stringent set of precautionary statements should be selected. This applies mainly for the preventive measures.
With respect to phrases concerning “Response”, rapid action may be crucial. For example, if a chemical is
carcinogenic and acutely toxic then the first aid measures for acute toxicity will take precedence over those
for longer term effects. In addition, medical attention to delayed health effects may be required in cases of
incidental exposure, even if not associated with immediate symptoms of intoxication.
A3.3.4.7 To protect people with different reading abilities, it might be useful to include both
precautionary pictograms and precautionary statements in order to convey information in more than one way
(see 1.4.4.1 (a)). It should be noted, however, that the protective effect of pictograms is limited and the
examples in this annex do not cover all precautionary aspects to be addressed. While pictograms can be
useful, they can be misinterpreted and are not a substitute for training.
A3.3.5 Matrix of precautionary statements by hazard class/category
A3.3.5.1 This matrix lists the recommended precautionary statements for each hazard class and hazard
category of the GHS by type of precautionary statement (see A3.2.2.1) except for general precautionary
statements. In each case the precautionary statement has the applicable code on the line immediately above.
- 335 -
EXPLOSIVES
(CHAPTER 2.1)
Symbol
Exploding bomb
Hazard category Signal word Hazard statement
Unstable explosive Danger H200 Unstable explosive
Precautionary statements
Prevention Response Storage Disposal
P201 P372 P401 P501

Obtain special instructions before use. Explosion risk in case of fire. Store ... Dispose of contents/container to ...
…in accordance with local/regional/ …in accordance with local/regional/
P202 P373
- 336 -
national/international regulations (to be national/international regulations (to

Do not handle until all safety DO NOT fight fire when fire reaches
specified). be specified).
precautions have been read and explosives.
understood.
P380
P281 Evacuate area.
Use personal protective equipment as
required.
EXPLOSIVES
(CHAPTER 2.1)
Symbol
Exploding bomb
Division 1.1 Danger H201 Explosive; mass explosion hazard
Division 1.2 Danger H202 Explosive; severe projection hazard
Division 1.3 Danger H203 Explosive; fire, blast or projection hazard
P210 P370 +P380 P401 P501
Keep away from heat/sparks/open flames/hot In case of fire: evacuate area. Store ... Dispose of contents/container to ...
surfaces. - No smoking. P372 …in accordance with … in accordance with local/
Manufacturer/supplier or the competent authority Explosion risk in case of fire. local/regional/national/international regional/national/international
to specify applicable ignition source(s). P373 regulations (to be specified). regulations (to be specified).
- 337 -
P230 DO NOT fight fire when fire reaches

Keep wetted with... explosives.
… Manufacturer/supplier or the competent
authority to specify appropriate material.
- if drying out increases explosion hazard, except
as needed for manufacturing or operating
processes (e.g. nitrocellulose).
P240
Ground/bond container and receiving
equipment.
- if the explosive is electrostatically sensitive.
P250
Do not subject to grinding/shock/…/friction.
…Manufacturer/supplier or the competent
authority to specify applicable rough handling.
P280
Wear face protection.
Manufacturer/supplier or the competent authority
to specify type of equipment.
EXPLOSIVES
(CHAPTER 2.1)
Symbol
Exploding bomb
Division 1.4 Warning H204 Fire or projection hazard
P210 P370+P380 P401 P501
Keep away from heat/sparks/open In case of fire: Evacuate area. Store ... Dispose of contents/container to...
flames/hot surfaces. - No smoking. P372 …in accordance with local/regional/ … in accordance with
Manufacturer/supplier or the competent Explosion risk in case of fire. national/international regulations (to be local/regional/national/international
- 338 -
authority to specify applicable ignition - except if explosives are 1.4S specified). regulations (to be specified).
source(s). AMMUNITION AND COMPONENTS
P240 THEREOF.
Ground/bond container and receiving P373
equipment. DO NOT fight fire when fire reaches
- if the explosive is electrostatically explosives.
sensitive. P374
P250 Fight fire with normal precautions
Do not subject to from a reasonable distance.
grinding/shock/…/friction. - If explosives are 1.4S AMMUNITION
Manufacturer/supplier or the competent AND COMPONENTS THEREOF.
authority to specify applicable rough
handling.
P280
Manufacturer/supplier or competent
EXPLOSIVES
(CHAPTER 2.1)
Symbol
No symbol
Division 1.5 Danger H205 May mass explode in fire
P210 P370 + P380 P401 P501
Keep away from heat/sparks/open flames/hot In case of fire: Evacuate area. Store ... Dispose of contents/container to ...
surfaces. - No smoking. P372 …in accordance with local/regional/ … in accordance with local/regional/
Manufacturer/supplier or the competent Explosion risk in case of fire. national/international regulations (to national/international regulations (to
authority to specify applicable ignition P373 be specified). be specified).
source(s). DO NOT fight fire when fire reaches
P230 explosives.
Keep wetted with...
- 339 -

authority to specify appropriate material.
- if drying out increases explosion hazard,
except as needed for manufacturing or
operating processes (e.g. nitrocellulose).
P240
Ground/bond container and receiving
equipment
- if the explosive is electrostatically sensitive.
P250
Do not subject to grinding/shock/…/friction.
authority to specify applicable rough handling.
P280
Manufacturer/supplier or competent authority to
specify type of equipment.
FLAMMABLE GASES
(CHAPTER 2.2)
Symbol
Flame
1 Danger H220 Extremely flammable gas
P210 P377 P403
Keep away from heat/sparks/open Leaking gas fire: Store in well-ventilated place.
flames/hot surfaces. -No smoking. Do not extinguish, unless leak can be
- 340 -
Manufacturer/supplier or competent stopped safely.

authority to specify applicable ignition P381
source(s). Eliminate all ignition sources if safe to
do so.
FLAMMABLE GASES
(CHAPTER 2.2)
Symbol
No symbol
2 Warning H221 Flammable gas
P210 P377 P403
Keep away from heat/sparks/open Leaking gas fire: Do not extinguish, Store in well-ventilated place.
flames/hot surfaces. -No smoking. unless leak can be stopped safely.
Manufacturer/supplier or the competent P381
authority to specify applicable ignition Eliminate all ignition sources if safe to
sources(s). do so.
- 341 -
FLAMMABLE AEROSOLS
(CHAPTER 2.3)
Symbol
Flame
1 Danger H222 Extremely flammable aerosol
2 Warning H223 Flammable aerosol
P210 P410 + P412
Keep away from heat/sparks/open Protect from sunlight. Do not expose
flames/hot surfaces. -No smoking. to temperatures exceeding
Manufacturer/supplier or the competent 50 ºC/122 ºF.
- 342 -
authority to specify applicable ignition

sources(s).
P211
Do not spray on an open flame or other
ignition source.
P251
Pressurized container: Do not pierce or
burn, even after use.
OXIDIZING GASES
(CHAPTER 2.4)
Symbol
Flame over circle
1 Danger H270 May cause or intensify fire; oxidizer
P220 P370 + P376 P403
Keep/Store away from In case of fire: Stop leak if safe to do so. Store in well-ventilated place.
clothing/…/combustible materials.
authority to specify other incompatible
materials.
- 343 -
P244
Keep reduction valves free from grease
and oil.
GASES UNDER PRESSURE

(CHAPTER 2.5)
Symbol
Gas cylinder
Compressed gas Warning H280 Contains gas under pressure; may explode if heated
Liquefied gas Warning H280 Contains gas under pressure; may explode if heated
Dissolved gas Warning H280 Contains gas under pressure; may explode if heated
P410 + P403
Protect from sunlight. Store in a well-
ventilated place.
- 344 -
GASES UNDER PRESSURE

(CHAPTER 2.5)
Symbol
Gas cylinder
Refrigerated liquefied gas Warning H281 Contains refrigerated gas; may cause cryogenic burns or injury
P282 P336 P403
Wear cold insulating gloves/face shield/eye Thaw frosted parts with lukewarm Store in well-ventilated place.
protection. water. Do not rub affected area.
P315
Get immediate medical
advice/attention
- 345 -
FLAMMABLE LIQUIDS
(CHAPTER 2.6)
Symbol
Flame
1 Danger H224 Extremely flammable liquid and vapour
2 Danger H225 Highly flammable liquid and vapour
3 Warning H226 Flammable liquid and vapour
P210 P303 + P361 + P353 P403 + P235 P501
Keep away from heat/sparks/open flames/hot IF ON SKIN (or hair): Remove/Take off Store in a well-ventilated Dispose of contents/container
surfaces.– No smoking. immediately all contaminated clothing. place. Keep cool. to...
Manufacturer/supplier or the competent authority to Rinse skin with water/shower. … in accordance with
specify applicable ignition source(s). P370 + P378 local/regional/national/internationa
P233 In case of fire: Use ... for extinction. l regulations (to be specified).
- 346 -
Keep container tightly closed. ... Manufacturer/supplier or the competent

P240 authority to specify appropriate media.
Ground/Bond container and receiving equipment - if water increases risk.
- if electrostatically sensitive material is for reloading.
- if product is volatile so as to generate hazardous
atmosphere.
P241
Use explosion-proof electrical/ventilating/
lighting/.../equipment.
... Manufacturer/supplier or the competent authority to
specify other equipment.
P242
Use only non-sparking tools.
P243
Take precautionary measures against static discharge.
P280
Wear protective gloves/eye protection/face protection
Manufacturer/supplier or the competent authority to
FLAMMABLE LIQUIDS
(CHAPTER 2.6)
Symbol
No symbol
4 Warning H227 Combustible liquid
P210 P370 + P378 P403 + P235 P501
Keep away from flames and hot surfaces. – No In case of fire: Use ... for extinction. Store in a well-ventilated place. Dispose of contents/container to...
smoking. ... Manufacturer/supplier or the Keep cool. in accordance with local/regional/
P280 competent authority to specify national/international regulations (to
Wear protective gloves/eye protection/face appropriate media. be specified).
protection - if water increases risk.
Manufacturer/supplier or the competent authority to
- 347 -

FLAMMABLE SOLIDS
(CHAPTER 2.7)
Symbol
Flame
1 Danger H228 Flammable solid
2 Warning H228 Flammable solid
P210 P370 + P378
Keep away from heat/sparks/open flames/hot In case of fire: Use ... for extinction
surfaces. - No smoking. ... Manufacturer/supplier or the competent
Manufacturer/supplier or the competent authority to specify appropriate media.
authority to specify applicable ignition source(s). - if water increases risk.
- 348 -
P240
Ground/Bond container and receiving
equipment.
- if electrostatically sensitive material is for
reloading.
P241
Use explosion-proof electrical/ventilating/
lighting/... /equipment.
... Manufacturer/supplier or the competent
authority to specify other equipment.
- if dust clouds can occur.
P280
Wear protective gloves/eye protection/face
protection
SELF-REACTIVE SUBSTANCES AND MIXTURES

(CHAPTER 2.8)
Symbol
Exploding bomb
Type A Danger H240 Heating may cause an explosion
P210 P370 + P378 P403 + P235 P501
Keep away from heat/sparks/open In case of fire: Use ... for extinction Store in a well-ventilated place. Dispose of contents/container to...
flames/hot surfaces. - No smoking. ... Manufacturer/supplier or the competent Keep cool. … in accordance with
Manufacturer/supplier or the competent authority to specify appropriate media. P411 local/regional/national/international
authority to specify applicable ignition - if water increases risk. Store at temperatures not regulations (to be specified).
- 349 -
source(s). P370 + P380 + P375 exceeding …°C/…°F.

P220 In case of fire: Evacuate area. Fight fire ... Manufacturer/supplier or the
Keep/Store away from remotely due to the risk of explosion. competent authority to specify
clothing/…/combustible materials. temperature.
... Manufacturer/supplier or the competent P420
authority to specify other incompatible Store away from other materials.
materials.
P234
Keep only in original container.
P280
protection.

(CHAPTER 2.8)
Symbol
Exploding bomb and flame
Type B Danger H241 Heating may cause a fire or explosion
P210 P370 + P378 P403 + P235 P501
Keep away from heat/sparks/open flames/hot In case of fire: Use ... for extinction. Store in a well-ventilated place. Dispose of contents/container to...
surfaces. - No smoking. ... Manufacturer/supplier or the competent Keep cool. …in accordance with
authority to specify applicable ignition - if water increases risk regulations (to be specified).
- 350 -
Store at temperatures not

source(s). P370 + P380 + P375 exceeding …°C/…°F.
P220 In case of fire: Evacuate area. Fight fire ... Manufacturer/supplier or the
Keep/Store away from remotely due to the risk of explosion. competent authority to specify
clothing/.../combustible materials. temperature.
... Manufacturer/supplier or the competent P420
materials.
P234
P280
protection.

(CHAPTER 2.8)
Symbol
Flame
Type C Danger H242 Heating may cause a fire
Type D Danger H242 Heating may cause a fire
Type E Warning H242 Heating may cause a fire
Type F Warning H242 Heating may cause a fire
P210 P370 + P378 P403 + P235 P501
Keep away from heat/sparks/open flames/hot In case of fire: Use ... for extinction Store in a well-ventilated place. Dispose of contents/container to...
surfaces. - No smoking. ... Manufacturer/supplier or the competent Keep cool. …in accordance with
- 351 -
authority to specify applicable ignition - if water increases risk. Store at temperatures not regulations (to be specified).
source(s). exceeding …°C/…°F.
P220 ...Manufacturer/supplier or the
Keep/Store away from competent authority to specify
clothing/…/combustible materials. temperature.
…Manufacturer/supplier or the competent P420
materials.
P234
P280
protection.
PYROPHORIC LIQUIDS
(CHAPTER 2.9)
Symbol
Flame
1 Danger H250 Catches fire spontaneously if exposed to air
P210 P302 + P334 P422
Keep away from heat/sparks/open flames/hot IF ON SKIN: Immerse in cool Store contents under ...
surfaces. - No smoking. water/wrap with wet bandages ... Manufacturer/supplier or the
Manufacturer/supplier or the competent P370 + P378 competent authority to specify
authority to specify applicable ignition In case of fire: Use ... for extinction appropriate liquid or inert gas.
- 352 -
sources(s). ... Manufacturer/supplier or the competent

Do not allow contact with air. - if water increases risk.
P280
protection.
PYROPHORIC SOLIDS
(CHAPTER 2.10)
Symbol
Flame
1 Danger H250 Catches fire spontaneously if exposed to air
P210 P335 + P334 P422
Keep away from heat/sparks/open flames/hot Brush off loose particles from skin. Store contents under ...
surfaces. - No smoking. Immerse in cool water/wrap in wet …Manufacturer/supplier or the
Manufacturer/supplier or the competent bandages. competent authority to specify
authority to specify applicable ignition P370 + P378 appropriate liquid or inert gas.
- 353 -
source(s). In case of fire: Use ... for extinction

P222 ... Manufacturer/supplier or the competent
Do not allow contact with air. authority to specify appropriate media.
P280 - if water increases risk.
protection
SELF-HEATING SUBSTANCES AND MIXTURES

(CHAPTER 2.11)
Symbol
Flame
1 Danger H251 Self-heating; may catch fire
2 Warning H252 Self-heating in large quantities; may catch fire
P235 + P410 P407
Keep cool. Protect from sunlight. Maintain air gap between
P280 stacks/pallets.
Wear protective gloves/eye protection/face P413
protection. Store bulk masses greater than …
- 354 -
Manufacturer/supplier or the competent kg/…lbs at temperatures not

authority to specify type of equipment. exceeding …°C/…°F.
... Manufacturer/supplier or the
competent authority to specify mass
and temperature.
P420
Store away from other materials.
SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(CHAPTER 2.12)
Symbol
Flame
1 Danger H260 In contact with water releases flammable gases, which may ignite spontaneously
2 Danger H261 In contact with water releases flammable gas
P223 P335 + P334 P402 + P404 P501
Keep away from any possible contact with Brush off loose particles from skin and Store in a dry place. Store in a Dispose of contents/container to...
water, because of violent reaction and immerse in cool water/wrap in wet closed container. …in accordance with
possible flash fire. bandages. local/regional/national/ international
regulations (to be specified).
- 355 -
P231 + P232 P370 + P378

Handle under inert gas. Protect from In case of fire: Use ... for extinction
moisture. ... Manufacturer/supplier or the competent
Wear protective gloves/eye protection/face - if water increases risk.
protection.
SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES
(CHAPTER 2.12)
Symbol
Flame
3 Warning H261 In contact with water releases flammable gas
P231 + P232 P370 + P378 P402 + P404 P501
Handle under inert gas. Protect from In case of fire: Use ... for extinction. Store in a dry place. Store in a Dispose of contents/container to...
moisture. ... Manufacturer/supplier or the competent closed container. ... in accordance with
P280 authority to specify appropriate media. local/regional/national/international
- if water increases risk. regulations (to be specified).
- 356 -

protection.
OXIDIZING LIQUIDS
(CHAPTER 2.13)
Symbol
Flame over circle
1 Danger H271 May cause fire or explosion; strong oxidizer
P210 P306 + P360 P501
Keep away from heat. IF ON CLOTHING: Rinse immediately Dispose of contents/container to...
P220 contaminated clothing and skin with …in accordance with local/regional/
Keep/Store away from clothing and other plenty of water before removing clothes. national/international regulations (to
combustible materials. P371 + P380 + P375 be specified).
- 357 -
P221 In case of major fire and large

Take any precaution to avoid mixing with quantities: Evacuate area. Fight fire
combustibles/... remotely due to the risk of explosion.
... Manufacturer/supplier or the competent P370 + P378
authority to specify other incompatible In case of fire: Use ... for extinction.
materials. ... Manufacturer/supplier or the competent
Wear protective gloves /eye protection/face - if water increases risk.
protection.
P283
Wear fire/flame resistant/retardant clothing.
OXIDIZING LIQUIDS
(CHAPTER 2.13)
Symbol
Flame over circle
2 Danger H272 May intensify fire; oxidizer
3 Warning H272 May intensify fire; oxidizer
P210 P370 + P378 P501
Keep away from heat. In case of fire: Use ... for extinction. Dispose of contents/container to...
P220 ... Manufacturer/supplier or the competent …in accordance with local/regional/
Keep/Store away from authority to specify appropriate media. national/international regulations (to
clothing/…/combustible materials. - if water increases risk. be specified).
- 358 -

materials.
P221
Take any precaution to avoid mixing with
combustibles/...
materials.
P280
protection.
OXIDIZING SOLIDS
(CHAPTER 2.14)
Symbol
Flame over circle
1 Danger H271 May cause fire or explosion; strong oxidizer
P210 P306 + P360 P501
Keep away from heat. IF ON CLOTHING: Rinse immediately Dispose of contents/container to...
P220 contaminated clothing and skin with …in accordance with local/regional/
Keep away from clothing and other plenty of water before removing clothes. national/international regulations (to
combustible materials. P371 + P380 + P375 be specified).
- 359 -
P221 In case of major fire and large

Take any precaution to avoid mixing with quantities: Evacuate area. Fight fire
combustibles/... remotely due to the risk of explosion.
…Manufacturer/supplier or the competent P370 + P378
authority to specify other incompatible In case of fire: Use ... for extinction.
materials. ... Manufacturer/supplier or the competent
Wear protective gloves/eye protection/face - if water increases risk.
protection.
P283
Wear fire/flame resistant/retardant clothing.
OXIDIZING SOLIDS
(CHAPTER 2.14)
Symbol
Flame over circle
2 Danger H272 May intensify fire; oxidizer
3 Warning H272 May intensify fire; oxidizer
P210 P370 + P378 P501

Keep away from heat. In case of fire: Use ... for extinction. Dispose of contents/container to...
... Manufacturer/supplier or the competent ... in accordance with
P220
- 360 -
authority to specify appropriate media. local/regional/national/international

Keep/Store away from clothing/…/
- if water increases risk. regulations (to be specified).
combustible materials.
authority to specify incompatible materials.
P221
Take any precaution to avoid mixing with
combustibles/...
materials.
P280
protection.
ORGANIC PEROXIDES
(CHAPTER 2.15)
Symbol
Exploding bomb
Type A Danger H240 Heating may cause an explosion
P210 P411 + P235 P501

Keep away from heat/sparks/open Store at temperatures not Dispose of contents/container to...
flames/hot surfaces.- No smoking. exceeding …°C/…°F. Keep cool. ... in accordance with
Manufacturer/supplier or the competent ... Manufacturer/supplier or the local/regional/national/international
- 361 -
authority to specify applicable ignition competent authority to specify regulations (to be specified).
source(s). temperature.
P220 P410
Keep/Store away from Protect from sunlight.
clothing/…/combustible materials.
P420
P234
P280
protection.
ORGANIC PEROXIDES
(CHAPTER 2.15)
Symbol
Exploding bomb and flame
Type B Danger H241 Heating may cause a fire or explosion
P210 P411 + P235 P501

Keep away from heat/sparks/open flames/hot Store at temperatures not Dispose of contents/container to...
surfaces. - No smoking. exceeding …°C/…°F. Keep cool. ... in accordance with
- 362 -
Manufacturer/supplier or the competent Manufacturer/supplier or the local/regional/national/international

authority to specify applicable ignition competent authority to specify regulations (to be specified).
source(s). temperature.
P220 P410
Keep /Store away from Protect from sunlight.
clothing/.../combustible materials.
P420
P234
P280
protection.
ORGANIC PEROXIDES
(CHAPTER 2.15)
Symbol
Flame
Type C Danger H242 Heating may cause a fire
Type D Danger H242 Heating may cause a fire
Type E Warning H242 Heating may cause a fire
Type F Warning H242 Heating may cause a fire
P210 P411 + P235 P501

- 363 -
Keep away from heat/sparks/open flames/hot Store at temperatures not exceeding Dispose of contents/container to...
surfaces. - No smoking. …°C/…°F. Keep cool. ... in accordance with
Manufacturer/supplier or the competent authority ... Manufacturer/supplier or the competent local/regional/national/international
to specify applicable ignition source(s). authority to specify temperature. regulations (to be specified).
P220 P410
Keep/Store away from clothing/.../ combustible Protect from sunlight.
materials
P420
P234
P280
protection.
Manufacturer/supplier or the competent authority
to specify type of equipment.
CORROSIVE TO METALS
(CHAPTER 2.16)
Symbol
Corrosion
1 Warning H290 May be corrosive to metals
P234 P390 P406

Keep only in original container. Absorb spillage to prevent material Store in corrosive resistant/... container
damage. with a resistant inner liner.
- 364 -

authority to specify other compatible
materials.
ACUTE TOXICITY - ORAL

(CHAPTER 3.1)
Symbol
Skull and crossbones
1 Danger H300 Fatal if swallowed
2 Danger H300 Fatal if swallowed
P264 P301 + P310 P405 P501

Wash …thoroughly after handling. IF SWALLOWED: Immediately call a Store locked up. Dispose of contents/container to...
… Manufacturer/supplier or the competent POISON CENTER or doctor/physician. ... in accordance with
- 365 -
authority to specify parts of the body to be local/regional/national/international

P321
washed after handling. regulations (to be specified).
Specific treatment (see ... on this label)
P270 ... Reference to supplemental first aid instruction.
Do not eat, drink or smoke when using this - if immediate administration of antidote is
product. required.
P330
Rinse mouth.

(CHAPTER 3.1)
Symbol
3 Danger H301 Toxic if swallowed
P264 P301 + P310 P405 P501

Wash … thoroughly after handling. IF SWALLOWED: Immediately call a POISON Store locked up. Dispose of contents/container to...
… Manufacturer/supplier or the competent CENTER or doctor/physician. ... in accordance with
- 366 -

P321
P270 ... Reference to supplemental first aid instruction.
Do not eat, drink or smoke when using this - if immediate administration of antidote is required.
product.
P330
Rinse mouth.

(CHAPTER 3.1)
Symbol
Exclamation mark
4 Warning H302 Harmful if swallowed
P264 P301 + P312 P501

Wash … thoroughly after handling. IF SWALLOWED: Call a POISON CENTER Dispose of contents/container to...
… Manufacturer/supplier or the competent or doctor/physician if you feel unwell. ... in accordance with
- 367 -
P330
Rinse mouth.
P270
Do not eat, drink or smoke when using this
product.

(CHAPTER 3.1)
Symbol
No symbol
5 Warning H303 May be harmful if swallowed
P312
Call a POISON CENTER/doctor/physician if you feel
unwell.
- 368 -
ACUTE TOXICITY - DERMAL

(CHAPTER 3.1)
Symbol
1 Danger H310 Fatal in contact with skin
2 Danger H310 Fatal in contact with skin
P262 P302 + P350 P405 P501

Do not get in eyes, on skin, or on clothing. IF ON SKIN: Gently wash with plenty of Store locked up. Dispose of contents/container to...
soap and water. ... in accordance with
P264
- 369 -
local/regional/national/international
Wash … thoroughly after handling. P310
… Manufacturer/supplier or the competent Immediately call a POISON CENTRE or
authority to specify parts of the body to be doctor/physician.
washed after handling.
P322
P270 Specific measures (see ... on this label)
Do not eat, drink or smoke when using this ... Reference to supplemental first aid
product. instruction.
- if immediate measures such as specific
P280
cleansing agent is advised.
Wear protective gloves/protective clothing.
Manufacturer/supplier or the competent P361
authority to specify type of equipment. Remove/Take off immediately all
contaminated clothing.
P363
Wash contaminated clothing before reuse.

(CHAPTER 3.1)
Symbol
3 Danger H311 Toxic in contact with skin
P280 P302 + P352 P405 P501

Store locked up.
Wear protective gloves/protective clothing. IF ON SKIN: Wash with plenty of soap and Dispose of contents/container to...
Manufacturer/supplier or the competent water. ... in accordance with
authority to specify type of equipment. local/regional/national/international
P312
- 370 -
Call a POISON CENTRE or doctor/physician

if you feel unwell.
P322
Specific measures (see ... on this label)
... Reference to supplemental first aid instruction.
- if measures such as specific cleansing agent is
advised.
P361
Remove/Take off immediately all contaminated
clothing.
P363

(CHAPTER 3.1)
Symbol
Exclamation mark
4 Warning H312 Harmful in contact with skin
P280 P302 + P352 P501

Wear protective gloves/protective clothing IF ON SKIN: Wash with plenty of soap and Dispose of contents/container to...
Manufacturer/supplier or the competent water. ... in accordance with
authority to specify type of equipment. local/regional/national/international
P312
- 371 -
Call a POISON CENTER or

doctor/physician if you feel unwell.
P322
Specific measures (see ... on this label)
... Reference to supplemental first aid
instruction.
- if measures such as specific cleansing
agent is advised.
P363

(CHAPTER 3.1)
Symbol
No symbol
5 Warning H313 May be harmful in contact with skin
P312
- 372 -
ACUTE TOXICITY - INHALATION

(CHAPTER 3.1)
Symbol
1 Danger H330 Fatal if inhaled
2 Danger H330 Fatal if inhaled
P260 P304 + P340 P403 + P233 P501

Do not breathe dust/fume/gas/mist/ IF INHALED: Remove victim to fresh Store in a well-ventilated place. Dispose of contents/container to...
vapours/spray. air and keep at rest in a position Keep container tightly closed. ... in accordance with
- 373 -
Manufacturer/supplier or the competent comfortable for breathing. - if product is volatile as to local/regional/national/international

authority to specify applicable conditions. generate hazardous atmosphere. regulations (to be specified).
P310
P271 Immediately call a POISON CENTER or P405
Use only outdoors or in a well-ventilated doctor/physician. Store locked up.
area.
P320
P284 Specific treatment is urgent (see ... on
Wear respiratory protection. this label)
Manufacturer/supplier or the competent ... Reference to supplemental first aid
authority to specify equipment. instruction.
- if immediate administration of
antidote is required.

(CHAPTER 3.1)
Symbol
3 Danger H331 Toxic if inhaled
P403 + P233
P261 P304 + P340 P501
Store in a well-ventilated place.
Avoid breathing dust/fume/gas/mist/ IF INHALED: Remove victim to fresh Dispose of content/container to…
Keep container tightly closed.
vapours/spray. air and keep at rest in a position … in accordance with
- if product is volatile so as to
- 374 -
Manufacturer/supplier or the competent comfortable for breathing. local/regional/national/international

generate hazardous atmosphere.
authority to specify applicable conditions. regulations (to be specified).
P311
P405
P271 Call a POISON CENTER or
Store locked up.
Use only outdoors or in a well-ventilated doctor/physician.
area.
P321
... Reference to supplemental first aid
instruction.
- if immediate specific measures are
required.

(CHAPTER 3.1)
Symbol
Exclamation mark
4 Warning H332 Harmful if inhaled
P261 P304 + P340

Avoid breathing dust/fume/gas/mist/ IF INHALED: Remove victim to fresh
vapours/spray. air and keep at rest in a position
Manufacturer/supplier or the competent comfortable for breathing.
authority to specify applicable conditions.
- 375 -
P312
P271 Call a POISON CENTER or
Use only outdoors or in a well-ventilated area. doctor/physician if you feel unwell.

(CHAPTER 3.1)
Symbol
No symbol
5 Warning H333 May be harmful if inhaled
P304 + P312
IF INHALED:
- 376 -
SKIN CORROSION/IRRITATION
(CHAPTER 3.2)
Symbol
Corrosion
1A to 1C Danger H314 Causes severe skin burns and eye damage
P260 P301 + P330 + P331 P405 P501
Do not breathe dusts or mists. IF SWALLOWED: Rinse mouth. Do NOT induce Store locked up. Dispose of contents/container to...
- if inhalable particles of dusts or mists may vomiting. ... in accordance with
occur during use. P303 + P361 + P353 local/regional/national/international
P264 IF ON SKIN (or hair): Remove/Take off regulations (to be specified).
- 377 -
Wash …thoroughly after handling. immediately all contaminated clothing. Rinse skin
…Manufacturer/supplier or the competent with water/shower.
authority to specify parts of the body to be P363
washed after handling. Wash contaminated clothing before reuse.
P280 P304 + P340
Wear protective gloves/protective IF INHALED: Remove victim to fresh air and keep
clothing/eye protection/face protection. at rest in a position comfortable for breathing.
P310
Immediately call a POISON CENTER or
doctor/physician.
P321
... Reference to supplemental first aid instruction.
- Manufacturer/supplier or the competent authority
may specify a cleansing agent if appropriate.
P305 + P351 + P338
IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
(CHAPTER 3.2)
Symbol
Exclamation mark
2 Warning H315 Causes skin irritation
P264 P302 + P352

Wash … thoroughly after handling. IF ON SKIN: Wash with plenty of soap
… Manufacturer/supplier or the competent and water.
authority to specify parts of the body to be
P321
- 378 -

P280 ... Reference to supplemental first aid
Wear protective gloves. instruction.
Manufacturer/supplier or the competent - Manufacturer/supplier or the competent
authority to specify type of equipment. authority may specify a cleansing agent if
appropriate.
P332 + P313
If skin irritation occurs: Get medical
advice/attention.
P362
Take off contaminated clothing and wash
before reuse.
(CHAPTER 3.2)
Symbol
No symbol
3 Warning H316 Causes mild skin irritation
P332 + P313
If skin irritation occurs: Get medical
advice/attention.
- 379 -
EYE DAMAGE/IRRITATION
(CHAPTER 3.3)
Symbol
Corrosion
1 Danger H318 Causes serious eye damage
P280 P305 + P351 + P338

Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water
Manufacturer/supplier or the competent for several minutes. Remove contact
authority to specify type of equipment. lenses, if present and easy to do.
- 380 -
Continue rinsing.
P310
Immediately call a POISON CENTER or
doctor/physician.
(CHAPTER 3.3)
Symbol
Exclamation mark
2A Warning H319 Causes serious eye irritation
P264 P305 + P351 + P338

Wash … thoroughly after handling. IF IN EYES: Rinse cautiously with water
… Manufacturer/supplier or the competent for several minutes. Remove contact
authority to specify parts of the body to be lenses, if present and easy to do.
washed after handling. Continue rinsing.
- 381 -
P280 P337 + P313

Wear eye protection/face protection. If eye irritation persists: Get medical
Manufacturer/supplier or the competent advice/attention.
(CHAPTER 3.3)
Symbol
No symbol
2B Warning H320 Causes eye irritation
P264 P305 + P351 + P338

Wash … thoroughly after handling. IF IN EYES: Rinse cautiously with water
… Manufacturer/supplier or the competent for several minutes. Remove contact
authority to specify parts of the body to be lenses, if present and easy to do. Continue
washed after handling. rinsing.
- 382 -
P337 + P313
If eye irritation persists: Get medical
advice/attention.
SENSITIZATION - RESPIRATORY
(CHAPTER 3.4)
Symbol
Health hazard
1, 1A, 1B Danger H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled
P261 P304 + P341 P501

Avoid breathing dust/fume/gas/mist/ F INHALED: If breathing is difficult, Dispose of contents/container to...
vapours/spray. remove victim to fresh air and keep at ... in accordance with
Manufacturer/supplier or the competent rest in a position comfortable for local/regional/national/international
authority to specify applicable conditions. breathing. regulations (to be specified).
- 383 -
P285 P342 + P311

In case of inadequate ventilation wear If experiencing respiratory symptoms:
respiratory protection. Call a POISON CENTER or
Manufacturer/supplier or the competent doctor/physician.
authority to specify equipment
SENSITIZATION - SKIN
(CHAPTER 3.4)
Symbol
Exclamation mark
1, 1A, 1B Warning H317 May cause an allergic skin reaction
P261 P302 + P352 P501

Avoid breathing dust/fume/gas/mist/ IF ON SKIN: Wash with plenty of soap and Dispose of contents/container to...
vapours/spray. water. ... in accordance with
Manufacturer/supplier or the competent local/regional/national/international
P333 + P313
- 384 -
If skin irritation or rash occurs: Get medical

P272 advice/attention.
Contaminated work clothing should not be
P321
allowed out of the workplace.
Wear protective gloves. instruction.
Manufacturer/supplier or the competent - Manufacturer/supplier or the competent
authority to specify type of equipment. authority may specify a cleansing agent if
appropriate.
P363
GERM CELL MUTAGENICITY

(CHAPTER 3.5)
Symbol
Health hazard
1 Danger H340 May cause genetic defects <...>
2 Warning H341 Suspected of causing genetic defects <...>
<...> (state route of exposure if it is conclusively proven that no other routes of exposure
cause the hazard)
P201 P308 + P313 P405 P501

Obtain special instructions before use. IF exposed or concerned: Get medical Store locked up. Dispose of contents/container to...
- 385 -
advice/attention. ... in accordance with

P202
Do not handle until all safety precautions
have been read and understood.
P281
required.
CARCINOGENICITY
(CHAPTER 3.6)
Symbol
Health hazard
1 Danger H350 May cause cancer <...>
2 Warning H351 Suspected of causing cancer <...>
<...> (state route of exposure if it is conclusively proven that no other routes of exposure
cause the hazard).
P201 P308 + P313 P405 P501

- 386 -

P202
P281
required.
TOXIC TO REPRODUCTION
(CHAPTER 3.7)
Symbol
Health hazard
1 Danger H360 May damage fertility or the unborn child <...> <<...>>
2 Warning H361 Suspected of damaging fertility or the unborn child <...> <<...>>
<...> (state specific effect if known)
<<...>> (state route of exposure if it is conclusively proven that no other routes of exposure
cause the hazard)
P201 P308 + P313 P405 P501

- 387 -

P202
P281
required.
TOXIC TO REPRODUCTION
(CHAPTER 3.7)
(effects on or via lactation)
Symbol
No symbol
(additional) No signal word H362 May cause harm to breast-fed children
P201 P308 + P313

Obtain special instructions before use. IF exposed or concerned: Get medical
advice/attention.
P260
- 388 -
Do not breathe dusts or mists.

- if inhalable particles of dusts or mists may
occur during use.
P263
Avoid contact during pregnancy/while
nursing.
P264
Wash … thoroughly after handling.
P270
product.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE)

(CHAPTER 3.8)
Symbol
Health hazard
1 Danger H370 Causes damage to organs <...> <<...>>
<...> (or state all organs affected if known)
cause the hazard)
P260 P307 + P311 P405 P501

Do not breathe dust/fume/gas/mist/ IF exposed: Call a POISON CENTER or Store locked up. Dispose of contents/container to...
- 389 -
vapours/spray. doctor/physician. ... in accordance with

P321
Wash …thoroughly after handling. instruction.
… Manufacturer/supplier or the competent - if immediate measures are required.
P270
product.

(CHAPTER 3.8)
Symbol
Health hazard
2 Warning H371 May cause damage to organs <...> <<...>>
<...> (or state all organs affected, if known)
cause the hazard)
P260 P309 + P311 P405 P501

Do not breathe dust/fume/gas/mist/ IF exposed or if you feel unwell: Call a Store locked up. Dispose of contents/container to...
vapours/spray. POISON CENTER or doctor/physician. ... in accordance with
- 390 -

P264
P270
product.

(CHAPTER 3.8)
Symbol
Exclamation mark
3 Warning H335 May cause respiratory irritation; or
H336 May cause drowsiness or dizziness
P261 P304 + P340 P403 + P233 P501

Avoid breathing dust/fume/gas/mist/ IF INHALED: Remove victim to fresh Store in a well-ventilated place. Dispose of contents/container to...
vapours/spray. air and keep at rest in a position Keep container tightly closed. ... in accordance with
Manufacturer/supplier or the competent comfortable for breathing. - if product is volatile so as to local/regional/national/international
- 391 -
authority to specify applicable conditions. generate hazardous atmosphere. regulations (to be specified).
P312
P271 Call a POISON CENTER or P405
Use only outdoors or in a well-ventilated doctor/physician if you feel unwell. Store locked up.
area.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)

(CHAPTER 3.9)
Symbol
Health hazard
1 Danger H372 Causes damage to organs <...> through prolonged or repeated exposure <<...>>
<...> (state all organs affected, if known)
cause the hazard)
P260 P314 P501

Do not breathe dust/fume/gas/mist/ Get medical advice/attention if you feel Dispose of contents/container to...
vapours/spray. unwell. ... in accordance with
- 392 -

P264
P270
product.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE)

(CHAPTER 3.9)
Symbol
Health hazard
2 Warning H373 May cause damage to organs <...> through prolonged or repeated exposure <<...>>
<...> (state all organs affected, if known)
cause the hazard)
P260 P314 P501

Do not breathe dust/fume/gas/mist/ Get medical advice/attention if you feel Dispose of contents/container to...
vapours/spray. unwell. ... in accordance with
- 393 -

ASPIRATION HAZARD
(CHAPTER 3.10)
Symbol
Health hazard
1 Danger H304 May be fatal if swallowed and enters airways
2 Warning H305 May be harmful if swallowed and enters airways
P301 + P310 P405 P501

IF SWALLOWED: Immediately call a Store locked up. Dispose of contents/container to...
POISON CENTER or doctor/physician. ... in accordance with
P331
- 394 -

Do NOT induce vomiting.
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD

(CHAPTER 4.1)
Symbol
Environment
1 Warning H400 Very toxic to aquatic life
P273 P391 P501

Avoid release to the environment. Collect spillage. Dispose of contents/container to...
- if this is not the intended use. ... in accordance with
- 395 -
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD

(CHAPTER 4.1)
Symbol
No symbol
2 No signal word H401 Toxic to aquatic life
3 No signal word H402 Harmful to aquatic life
P273 P501
Avoid release to the environment. Dispose of contents/container to...
- 396 -

HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD

(CHAPTER 4.1)
Symbol
Environment
1 Warning H410 Very toxic to aquatic life with long lasting effects
2 No signal word H411 Toxic to aquatic life with long lasting effects
P273 P391 P501

Avoid release to the environment. Collect spillage. Dispose of contents/container to...
- 397 -

HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM HAZARD

(CHAPTER 4.1)
Symbol
No symbol
3 No signal word H412 Harmful to aquatic life with long lasting effects
4 No signal word H413 May cause long lasting harmful effects to aquatic life
P273 P501
Avoid release to the environment. Dispose of contents/container to...
- 398 -

HAZARDOUS TO THE OZONE LAYER

(CHAPTER 4.2)
Symbol
Exclamation mark
1 Warning H420 Harms public health and the environment by destroying
ozone in the upper atmosphere
P502
Refer to manufacturer/supplier for
information on recovery/recycling
- 399 -
Annex 3
Section 4
EXAMPLES OF PRECAUTIONARY PICTOGRAMS
A3.4.1 Precautionary pictograms

From European Union (Council Directive 92/58/EEC of 24 June 1992)
From South African Bureau of Standards (SABS 0265:1999)
- 401 -

GHS Version 3 Annex 3 - H &amp; P Codes

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GHS Version 3 Annex 3 - H &amp; P Codes

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CODIFICATION OF HAZARD STATEMENTS

A3.1.2 Codification of hazard statements

(a) the letter “H” (for “hazard statement”);

− “2” for physical hazards;

Column (1) The hazard statement code;

Column (2) The hazard statement text;

Table A3.1.1: Hazard statement codes for physical hazards

Code Physical hazard statements Hazard class (GHS chapter) Hazard

H220 Extremely flammable gas Flammable gases (chapter 2.2) 1

H240 Heating may cause an explosion Self-reactive substances and Type A

Code Physical hazard statements Hazard class (GHS chapter) Hazard

H290 May be corrosive to metals Corrosive to metals (chapter 2.16) 1

Table A3.1.2: Hazard statement codes for health hazards

Code Health hazard statements Hazard class (GHS chapter) Hazard

H330 Fatal if inhaled Acute toxicity, inhalation (chapter 3.1) 1, 2

Code Health hazard statements Hazard class (GHS chapter) Hazard

Code Health hazard statements Hazard class (GHS chapter) Hazard

Table A3.1.3: Hazard statement codes for environmental hazards

Code Environmental hazard statements Hazard class (GHS chapter) Hazard

CODIFICATION OF PRECAUTIONARY STATEMENTS

A3.2.1.1 A precautionary statement is a phrase (and/or pictogram) which describes recommended

A3.2.2 Codification of precautionary statements

(a) a letter “P” (for “precautionary statement”)

(b) one number designating the type of precautionary statement as follows:

– “1” for general precautionary statements;

(c) two numbers (corresponding to the sequential numbering of precautionary statements)

A3.2.3 Structure of the precautionary statement codification tables

Column (1) The precautionary statement code;

Column (2) The precautionary statement text;

Column (5) Where applicable, conditions relating to the use of a precautionary

Table A3.2.1: Codification of general precautionary statements

Table A3.2.2: Codification of prevention precautionary statements

Germ cell mutagenicity (chapter 3.5) 1A, 1B, 2

Oxidizing liquids (chapter 2.13) 1, 2, 3 - specify to keep away from heat.

Flammable solids (chapter 2.7) 1, 2 - if electrostatically sensitive material is

Specific target organ toxicity, single exposure; 3

Specific target organ toxicity, single exposure; 3

Oxidizing solids (chapter 2.14) 1, 2, 3

Table A3.2.3: Codification of response precautionary statements

Specific target organ toxicity, single exposure; 3

Acute toxicity, dermal (chapter 3.1) 3, 4, 5

Skin irritation (chapter 3.2) 2 instruction.

P330 Rinse mouth. Acute toxicity, oral (chapter 3.1) 1, 2, 3, 4

Acute toxicity, dermal (chapter 3.1) 4

P370 In case of fire: Explosives (chapter 2.1) Divisions 1.1, 1.2,

term hazard (chapter 4.1)

P301 IF SWALLOWED: Immediately call a Acute toxicity, oral (chapter 3.1) 1, 2, 3

Skin corrosion (chapter 3.2) 1A, 1B, 1C

Table A3.2.4: Codification of storage precautionary statements

Aspiration hazard (chapter 3.10) 1, 2

P410 Protect from sunlight. Flammable aerosols (chapter 2.3) 1, 2

Organic peroxides (chapter 2.15) Types

Table A3.2.5: Codification of disposal precautionary statements

USE OF PRECAUTIONARY STATEMENTS

A3.3.2 Allocation of precautionary statements

A3.3.2.2 To provide flexibility in the application of precautionary phrases, a combination of

A3.3.3 General precautionary measures

A3.3.3.3 In order to correctly implement precautionary measures concerning prevention, response,

A3.3.4 Structure of the precautionary statements matrix

A3.3.4.2 Text in italics that starts with “ - if ” or “- specify” is intended to be an explanatory

A3.3.5 Matrix of precautionary statements by hazard class/category

P201 P372 P401 P501

national/international regulations (to be national/international regulations (to

GHS Version 3 Annex 3 - H & P Codes

GHS Version 3 Annex 3 - H & P Codes