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UNIT # 12 (PART - I)
MODERN PHYSICS (Atomic and Nuclear physics)
EXERCISE –I hc
e 6 V0
hc
–t – × 2/
e2 1 0 4
1. P(D) = 1 – e = 1 – e = 14. e 2 V0 hc 4
e2
2
1 1
1 1 1 1
1
2. TA = hr, TB = hr; TA+B = 2 4 hr 15. I
r 2 intensity becomes
4
th
2 4 1 1 6
2 4
v1 2h 0 h 0 1
16. v 2 8 10 6 ms 1
1 v2 5h 0 h 0 2
so, first hr = 1 half lives (by A)
2
next 1 hr = 4 half lives (by B) M0 1
17. M = M0e–t M 0 e t n 20 = –t
1 20
next hr = 3 half lives (by A+B)
2 n(20) n(2) n(10)
T1 / 2 t T1 / 2 t
N0 n2 n2
thus N = ( Total eight half lives)
28 t = 16.42 days
dp (2P sin ) hc 1 4hc 1
3. F F 18. 0 mv 2 ; 0 mv 12
dt t 2 3 2
F = 2npsin [n = number of photon] 4 4 1 1
0 0 mv 2 mv 12
h 3 0 3 2 2
1N= 2(n) sin 30° n = 1027
4. In photo electric effect the maximum velocity of e– 1 4 1 4
mv 12 mv 2 0 v 1 v
will corresponding to KEmax & other are less than 2 3 2 3 3
it.
N hc
0.1
19. (a) P = (b) n N (c) i n e
5. KEmax = h 100
6. For threshold frequency, h 0= 0 hc hc
h 2
K 2 2 2 K
KEmax = h–= h(–0) 20. K1 < 2
K1 hc hc 2
I saturation n where I= nh 2
1
2
K max 4eV
7. Kmax = h – Vs = 4 volts 21. Greater work function greater intercept
e e
K 1 h 1 1 1 0.5 1 22. De broglie waves are independent of shape & size
8.
K 2 h 2 2 2.5 0.5 4 of the object.
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h 1 1 1
25. = (so same) 38. R (Z 1) 2
n2 n2
p 1 2
hc 1242eV nm
36. E = = 59 keV 49. N = N1 – N2 N 0 [e t1 e t2 ]
0.021nm
1
50. 90 days 3 half lives, left i.e. 12.5%
37. High atomic no. and high melting point. 8
Disintegrated 100 – 12.5 = 87.5%
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h h
EXERCISE –II 8. (1) A 2mT (2) B
A 2mTB
nh 13.6Z 2 (3) TB = TA – 1.5 eV (4) B = 2A
1. (A) L = (B) E =
2 n2
1242
9. Kmax = eV 4.5eV
c Z U 200
(C) v (D) K =
137 n 2 Kmax = 1.7eV at cathode
Kmax = (1.7 + 2) eV at anode
1 1 1 If polarity is revered, no e– reach at collector.
2. R 2 2 , n =4
0 1 n
N0 T
10. N = N0e–t N 0 e 1/2
hc hc hc 1 1 1 2
(a)
0 1 2 0 1 2 log e 2 1
T1 / 2 Tmean =
hc hc hc hc 1 1 1 1
or 11. Assuming to be+1 0
0 1 2 3 0 1 2 3
69 E 172 69 D 172 71 C
176
1 1 1 1 1
0
72 B 176
74 A
180
3. 13.6 13.6Z 2 2
1 9 9 n
12. At t = 0 : N1 = N0
1 1
4. |K|= 13.6 2 2 = 10.2 eV At time t : N2= N0e–t
1 2
Decayed in time t (N1 – N2) = N0(1–e–t)
Probability that a radioactive nuclei does not decay
1
|U|= 27.2 2 2 = 20.4eV
1 2 N N 0 e t
in t=0 to t : N e t
0 N 0
2h h h
L =
2 2 2 13. Add equation 3 12 H 24 He + p + n
mv 2 r 3 = ke 2; m 2v2r2=
42 14. A is balanced both in mass number & atomic no.
6
m 2 n
r (constant), Also V 4
n2 m (h h 0 )
15. h = h0 + eVs ; Vs = ; eVs=h–
e
ke 2 Here =frequency of incident light and
U
m3 1 2 n6 = properties of emitter
3 6 , K.E. = 2 mv 3
n m
hc 1 1
16. E1 = 2 2
n6 n6 n1 n 2
U 3 ,
T.E. U K.E. 3
m m For second excited state to first excited state
n6 hc 1 1 hc 5
then total energy E1 =
m3 4 9 36
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P1 5 N BE/A
1
(C) P P 27
2
Z A
17. P.E. = –2(K.E.)
T.E. = (P.E.) + (K.E.) 28. = 0.173 , N = N0e–t
T.E. = –2(K.E.) + (K.E.) N = (N 0 – N 0e–t) = Decayed amount
T.E. =–(K.E.)–T.E. = K.E. K.E. = 3.4 eV
= 6.6 × 10–10 m 1
N = N 0 1
e
13.6Z 2 1
18. 122.4 = 2 Z=3; 91.8 = 122.4 1 N N 0 (1 0.37) N 0 (0.63)
1 4
So an electron of KE 91.8eV can transfer its N N 0 (0.63)
energy to this atom.
N 0 N 0 100 63%
19. Room temperature n=1 log e 2
Upon absorption excitations take place to many T1/2 = 4 year
higher states which upon de-excitation emit all U.V.,
infrared and visible light. n r hc n b hc
29. Pr = r , P b
= b
20. Room temperature n=1 so lyman series if Pr = Pb Since r > b nr > nb
27.2eV 13.6eV N hc n
21. U C k 30. (a) P = (b) i = n e 100%
(c) %
n2 n2
N
13.6eV 1 1 31. We have work is done by only electric field. Thus if
E 2
C E = 13.6eV 2 2
n n m E v, v decreases, & thus momentum of electron
decreases & vice–versa, while in magnetic field v
here in these questions C = + 27.2 eV
remains constant.
1
22. We have r , = reduced mass 150
32. For electron db = =1Å
100 50
Kq 2 mv 2e mv 2N nh
; mvere =
r re rN 2 33. In photo electric effect only one to one Interaction.
23. K > 20.4 eV for inelastic collision 1
34. N N 0 e 0 t , N ' N 0 e 10 0 t e 9 0 t
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e
24. decay : 2He4, so both Z & A decreases.
decay : +1e0 , 1
t = 9
so A will not change but Z will change (decreases) 0
decay : –1e0 ,
so A will not change but Z will change (increases) hc hc h0
35. eV1 = , eV2 , eV3 =
decay : no change in A & Z. 1 2 3
12400 2 1 1
25. V = 10 10 volt
min if 2V2 = V1 + V3
2 1 2
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(E 2 n E n ) n (E 2 n E n ) n 2 2 2 n2
2
(E 2 n )(E n ) (13.6)2 Z 4 (E 2 n )(E n ) Z
4 52. Radioactivity law is valid for large samples
4 n
39. 10 = nC2 n = 5; then 5 orbits are involved upon
coming to second excited state 53. N 1 N 0 e T1 ; N 2 N 0 e T2
so nth excited state is 6th [2nd, 3rd, 4th, 5th, 6th] R1 = N1 ; R2 = N2
(R R )
40. On coming from 4 1 energy is greater than, (N1 – N2) = N1 N 2 1 2
less than or equal to energy corresponding to
24 log e 2 log e 2
T = ;
T
V2 V2 V2 a n 4 2 4 16 (R 1 R 2 )T
41. 2 0 2 0 4 1 24 4 (N1 – N2) =
r n r0 n r0 n a 2 n1 3 81 (log e 2)
(N1 – N2) (R1 – R2)T
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42. T n3
3 54. Final product state
Ti 1 n n 1
Tf 27 m m 3
dN
55. 1 N 1 2 N 2 1 N 10 e 1 t 2 N 20 e 2 t
dt
43. No of spectral lines
n(n 1)
10 n 2 n 20 0 n=5; n=–4
2
1 hc
E = 13.6 1 =13.056; = =95nm
25 E
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Comprehension–1
EXERCISE –III
1. For Balmer series, n1 =2 (lower) ; n2=3,4 (higher)
Match the column
In transition (VI), Photon of Balmer series is
1 1 v absorbed.
1. v , KE 2 , J n,
n n r
2. In transition II : E2 = –3.4 eV, E4 = –0.85 eV
1 1
2
but r n and v 3 hc hc
n n E = 2.55 eV; E = = = 487 nm.
E
2. For given atomic number, energy and hence
frequency of K–series is more than L–series. In 3. Wavelength of radiation = 103 nm = 1030Å
one series also –line has more energy or frequency 12400
compared to that of –line. E = 12.0eV
1030Å
So difference of energy should be 12.0 eV (approx)
3. Consider two equations
Hence n 1 =1 and n 2= 3
1 (–13.6)eV (–1.51)eV
eVs = mv2max = hv – 0 ...(i)
2 Transition is V.
Intensity 4. For longest wavelength, energy difference should
no. of photoelectrons ejected/sec ...(ii)
h be minimum.So in visible portion of hydrogen atom,
(A) As frequency is increased keeping intensity minimum energy is in transition VI & IV.
constant.
1 Comprehension–2
|V s| will increases,m(v 2max) will increase.
2 2e v ev
1. i= qf =
(B) As frequency is increased and intensity is 3 2 r 3 r
decreased.
evr
1 2. M u=
|V s| will increase, m(v2max) will increase and 3
2
saturation current will decrease. evr evr evr 2evr
3. M net M u M d M d
(C) Its work function is increased photo emission 3 6 6 3
may stop. 4. Net magnetic moment in that case will be zero.
(D) If intensity is increased and frequency is
decreased. Saturation current will increase.
Comprehension–3
R0 0 A
4. (A) In half life active sample reduce = 1. Q = CV ne V
2 d
R0 2.85 10 12 10
Decay number of nuclei is = n 16
2 0.5 10 3 1.6 10 19
(B) N = N0e–t n = 8.85 × 10 9
n(2)
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hc
0 v 2
EXERCISE –IV(A)
max 1
9
2
hc 1
0 v max 2
1. Number of photons falling/s 2
1 7hc 7 6.62 10 34 3 10 8
n [for point source] 0 1.81 eV
r2 16 16 3000 10 10 1.6 10 19
n
So for new distance n' = N hc
9 6. KE max = h , Also E photo/time =
I s 18mA (i) When intensity of light is decreased numbr of
I s 2mA
9 9 photons decreases but KE max remains same
Also saturated current n (ii) When emitting surface is charged, changes. So
V d is independent of n. KEmax changes . If emitter is changed then +ve no.
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10.(i) Kinetic energy of electron in the orbits of hydrogen 15. Assuming Bohr's model to be applicable to the He
and hydrogen like atoms = |Total energy| atom too;
Kinetic energy = 3.4 eV Energy of electron = –13.6 × 4 eV= – 54.4 eV
(ii) The de–Broglie wavelength is given by initial energy of electron = 0
h h Energy of photon emitted = 544 eV
P 2Km hc
22.8mm
K = kinetic energy of electron E
Substituting the values, we have
(6.6 10 34 J s)
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R 0 – t e – 1 Rc j
hc 12400 R 0 e – t
20. min = = Å R e
eV V Now = =
Q Q 0 e – t RC Q0
12400
At 40 kV : min = = 0.31 Å 1
40000 It is independent of time if =
Wavelength of K is independent of applied RC
potential.
1 t avg 20 10 –3
3 R = = = = 200
For K X–ray : 13.6 Z 1 2 E hc C C 100 10 –6
4 K
1216
K = Å and given that EXERCISE –IV(B)
bZ 1g 2
1. =hf/2 =hf/3
1216 1 2
K =3 min
b g
Z 1
2 = 3 × 0.31
1 = 2t t=
2 After connection
(i) V + V = V 1 + V 2 (V= final common potential)
22. Activity of x = Activity of y or nx x = n y y
LM 0.693 OP LM 0.693 OP 2V =
hf 2hf
2e 3e
V
7hf
12e
nx
N (T ) Q
1/ 2 x
= ny
MN (T ) PQ
1/ 2 y
k Q 2 hf 7hf hf
(ii) For sphere–2 :
nx (T1 2 ) x 3 1 R 3 e 12e 12e
n = = =
y (T1 2 ) y 27 9
Q hfR
23. After t time active fraction No. of electrons flows n =
e 12ke 2
N
= 1 – 0·36 = 0·64 = N = e –t
0
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h h v v 1
mv 1 = & mv 2 = ; v COM 1 ˆi 2 ˆj = k 1 = k = 14.4eV= 23.04 × 10 –19 J
1 2 2 2
(iii) E max = 4 1 = 13.5 eV
v v v 12 v 22 E min = 4 3 = 0.7 eV
v 1COM 1 ˆi 2 ˆj v 1COM v 2 COM
2 2 2
mv 2 1 e2 h e2
8.(i) 2 mvr= E = –
h 2h 2h r 4 0 r 2 total
8 0 r
mv m v 2 v 2 mv 1 2
mv 2
2
1 2
dE
(ii) P (loss of energy per sec)
dt
2h 2 1 2
2 2
12 22 d e2 P0 e 2 dr P
h h 40
dt 8 0 r r4 8 0 r 2 dt r
1 2
r t
1 1 e 2 r 2 dr 8 0 P0 dt
6. (i) E = 47.2 = 13.6 Z 2 Z = 5 r0 0
4 9
1/3
1 1 6P (4 )t 3cre2 t
(ii) E = 13.6 × 25 r = r 0 0 2 0 r =r 0 1 3
3 3
9 16 e r0
13.6 25 7 (iii) For r=0, (to collapse and fall into nucleus)
eV = 16.5 eV
9 16 3cre2 t
1 – 0
hc r03
(iii) E 1 = 13.6 Z 2eV=
0 r3 10 30 10 10 100
t= 3cr 2 3 3 10 8 9 10 30 sec
12400eV A e 81
13.6 25eV = 36.4Å
nh mv 2 4e 2
9.(i) mvrn and
1 2 rn 4 0 rn2
(iv) (KE) 1st orbit = mv 2
2
0 h 2 n 2 n 2 h 2 0
9.1 10 31 (2.2 10 6 5) 2 rn 2
= 344 eV 4 e m 400 me 2
2 1.6 10 19
(PE) 1st orbit = –2KE = –688eV Z2 m
(iii) E n th 13.6 2
n
nh h
L = (n=1)
2 2 1 1
E 13.6 4 2 100 2 2 408eV
n 2
0.53 1 2 2 4
(v) Radius = (R 0 ) = 1.06×10 –11 m
z 5
10. Let the age of Earth be tyear and initially both were
7. Let n = no. of level of excited state present as N 0 ;
nC 2 = 6 (spectral lines) N 0 N0
n = 3 (3rd excited states) Nu 238 =
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t / t1 / 2 t / 4.5 10 3
2 2
No. of excited state level = n+1 = 4
2.7eV
N0
n=4 (Level B) Nu 235 t / 4.3 10 8
2
n=3
n=2 (Level A) Nu 238 140 9
2 t 1.18 10
n=1 Nu 235 1
(i) Principal quantum no. of initially excited level B =4 t= 6.0418 × 10 9 years
1 1 16
(ii) 2.7 = k k 2.7 14.4eV 11. X
A B
4 16 3
x
Ionisation energy No. of neucleus disintegrated = xt 1 e t
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0.004305 0.018883 M0
n
100 But M0–rt = M0e–t; v v 0 n M e t v 0 t
3(2.014102) 0
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EXERCISE –V(A) 1 1
10. Rquired energy = 13.6 (Z) 2 n 2 n 2 eV
1 2
ATOMIC STRUCTURE & X-RAY
1. Energy required to ionize a atom from n th orbit is
1 1
13.6 = 13.6 (3) 2 2 2 = 108.8 eV
=+ eV 1 3
n2
(4)(3)
11. Number of lines = n C 2 = 4C 2 = = 6
13.6 (2)
E2 eV 3.4eV
22
L2 (n )2
2. Energy required to remove an electron from an orbit 12. Energy = 2I
2( r 2 )
2
13.6 Z m1m 2
is + 2
eV . So, to remove the electron from where µ = reduced mass = m m
n 1 2
the first excited state of Li 2+ is
n 2 2 (m 1 m 2 )
so energy =
13.6 3 2 2m 1 m 2 r 2
E =3.4 × 9 = + 30.6 eV
22 13. Energy of radiation emitted
3. Ionization potential will be lowest for the atom in 1 1 2n 1
2
which the electrons are the farthest from the E = h E 0 Z 2
2 E 0 Z2 2 2
nucleus. So, the atom with the largest size will have (n 1) n n (n 1)
the electron the farthest from the nuclei, hence to
2n 1
remove the electron from this atom will be easiest. h E 0 Z2 4 3
133
n n
So, the atom with least ionization potential is 55 Cs .
PHOTOELECTRIC EFFECT
4. The wavelengths involved in the spectrum of
deuterium D are slightly different from that of
2
1
W0 hf0
hc W
Na Cu
14. Work function 0 WCu Na
hydrogen spectrum; because masses of two nuclei
are different.
Na WCu 4.5
2
Cu WNa 2.3
6. The energy of emitted photon is directly proportional
to the difference of the two energy levels.This
differences is maximum between level (2) and level 15. Covalent bonding electron cloud overlapping
(1) hence photon for maximum energy will be region electron
probability density
liberated for this transition only.
wave nature of electron
1 1 2h
7. Whenever an atom gets de-excited from higher to 16. hf1 0 mv 12 , hf2 0 mv 22 v12 v 22 m f1 f2
2 2
the lower orbit, it emits radiation of a given frequency
E hf f E 17. Total change i n momentum from a reflecti ng
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k mv 2
8. mv 2 k (independent or r) P
r r
h 1 2E
n mvr r n and T mv 2 is The momentum of incident radiation P
2 2 c
independent of n. 2E
Hence, momentum transferred =
c
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hc 12400
29. Ek 0 1.68 0
4000
q By solving it 0 = 1.42 eV
t
W0
The slope of K vs f graph is h which is a fundamental 31. No. of photons emitting per second from a source
constant and same for all metals at all intensifies. of power P is n = (5 × 10 24) P
hc n nhc
19. W0=4eV, max = ? ; W0 wavelength emitting or P
max 5 10
24
P
1240 10 20
4eV nm eV hc= 1240 nm-eV 0.5 10 9 m 50Å
max
5 10 24 4 10 3
max = 310 nm. And this wavlength comes in X ray region.
h 2 K1 1
2 1 36. Though the compound can emit all the four particles
2mK 1 K2 2 2 namely electrons, protons, He2+ and neutrons. But
22. According to Einstein's theory of photoelectric effect the particle neutron can't be deflected in the
Energy of incident photon = W 0 + eV 0 magnetic field, since it is a neutral particle. Hence,
W 0 = 6.2 eV; eV 0 = 5 eV the deflectable particles are protons, electrons and
Energy of incident photon = 11.2 eV He 2 + .
The wavelength corresponding to this energy is 110
nm which falls in the ultraviolet region. 38. U 238 U 234 2 He 4
Let recoil speed be V then by COLM
23. The photoelectric phenomenon is an instantaneous
phenomenon, hence the time taken by an electron 4u
234 V 4u V
to come out of metal is approximately 10 –10 sec 234
(found experimentally).
39. Rate of disintegration at any instant is directly
24. With the increase in wavelength energy of the
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On multiplying both sides by we get 46. Intensity of gamma radiation when it passes through
1 x is I I 0 e x
(N) = (N 0)e –t 1250 = 5000 e –t e t
4
I0 I
I 0 e ...(i) and 0 I 0 e ...(ii)
36 x
Taking logarithm on both sides we get
8 2
1
ln1–ln4=e –(5) 0–ln4=–5 ln 2 2 1 1
5 e 36 and e x e 3 x e 36 x 12 mm
= 0.4 ln2. 8 2
n
N 1
40. 8 have been emitted 47. We know that, where, N are the
4 – have been emitted N 0 2
2 + have been emitted radioactive nuclei left after n-half lives
reduces atomic number by 2 N0 are the initial number of nuclei and n is number
– increases atomic number by 1 3 n
+ decreases atomic number by 1 N0 / 8 1 1 1
of half-lives, n 3
So, Z eff = 92 – (8×2) + (4×1)–(2×1)= 96–18= 78 N0 8 2 2
42. In order to fuse two nuclei against repulsion, the 48. Radius of a nuclei (Mass Number) 1/3
repulsive potential energy has to be supplied by 1/3
kinetic energy i.e., PE=KE R Te 125 5 5
R Te R Al 6 fermi
R Al 27 3 3
3
7.7 × 10 –14 = kT
2 49. X n, 73 Li
3 1
7.7 × 10 –14 = × 1.38 × 10 –23 T 0n ZA X 73 Li 24 He
2
On conservating atomic number and mass numbers
T = 3.7 × 10 9 k
on both sides, we get
A = (7+4) –1 = 10
43. Applying conservation of momentum, we get
Z = (3+2) – 0 = 5
m1 v2 1 A
m1 v1 m 2 v 2 Hence, Z X 10
5 B
m 2 v1 2
M
= (mass defect) c 2 (where m = given)
2 min
p2 M M 2 12375
2 (M m ) c min Å
2m 2 2 V (in volt)
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4. Since, the wavelength () is increasing we can say 9. Radius of a nucleus is given by
that the galaxy is receding. Doppler effect can be R = R 0 A 1/3 (where R 0 = 1.25 × 10 –15 m)
given by– = 1.25 A 1/3 × 10 –15 m
Here, A is the mass number and mass of the
cv cv uranium nucleus will be m Am p
' 706 = 656 ...(i)
cv cv m p = mass of proton = A(1.67 × 10 –27 kg)
8
0.16c 0.16 3.0 10
v m/s 10. Energy is released in a process when total binding
2.16 2.16
7 energy of the nucleus (= binding energy per nucleon
v 2.2 × 10 m/s
× number of nucleons) is increased or we can say,
If we take the approximation then equation (i) can be
when total binding energy of products is more than
v the reactants. By calculation we can see that only in
written as = ...(ii) case of option (c), this happens. Given : W 2Y
c
Binding energy of reactants = 120 × 7.5 = 900
706 656
8
MeV
From here v .c (3 10 ) m/s and binding energy of products
656
= 2(60 × 8.5) = 1020 MeV > 900 MeV.
v = 0.23 × 10 8 m/s
Which is almost equal to the previous answer. Rhc
11. In hydrogen atom E n = . Also E n m
So, we may use equation (ii) also. n2
where m is the mass of the electron.
5. Atomic number of neon is 10. Here, the electron has been replaced by a particle
By the emission of two – particles, atomic number whose mass is double of an electron. Therefore, for
will be reduced by 4. Therefore, atomic number of this hypothetical atom energy in n th orbit will be
the unknown element will be Z = 10 – 4 = 6
2Rhc
Similarly mass number of the unknown element will given by E n =
be A = 22 – 2 × 4 = 14 n2
Unknown nucleus is carbon (A = 14, Z=6). The longest wavelength max (or minimum energy)
photon will correspond to the transition of particle
6. From law of conservation of momentum, from n=3 to n=2.
P 1 = P 2 (in opposite directions) hc 1 1 18
E 3 E 2 Rhc 2 2 max =
h max 2 3 5R
Now de–Broglie wavelength is given by
p 1 1
[h = Plank's constant] 12. n KE (with positive sign)
n n2
Since, momentum (p) of both the particles is equal, Potential energy U is negative and
therefore 1 = 2 1/ 2 = 1
1 1 Ze 2 1
7. Both the beta rays and the cathode rays are made up Un U n . 2
4 0 rn
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rn n
of electrons. So, only option (a) is correct. 2
(b) Gamma rays are electromagnetic waves. [because r n n ] (with negative sign)
(c) Alpha particles are doubly ionized helium atoms and 1
(d) Protons and neutrons have approximately the Similarly total energy E n (with negative sign)
n2
same mass. Therefore, when an electron jumps from some
0.693 1 excited state to the ground state, value of n will
8. (t 1/2) x = (t mean) y decrease. Therefore, kinetic energy will increase
x y x = 0.693 y
(with positive sign), potential energy and total energy
x < y Rate of decay = N will also increase but with negative sign. Thus, finally
Initially number of atoms (N) of both are equal but kinetic energy will increase, while potential and total
since y > x, therefore, y will decay at a faster rate energies will decrease.
than x.
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Also the energy of the incident electrons (80 keV) is Here R = activity of radioactive substance after n
more than the ionization energy of the K–shell R0
electrons (i.e. 72.5 keV). Therefore, characteristic half–lives (given)
6
X–ray spectrum will also be obtained because
Substituting in equation (i), we get n =4
energy of incident electron is high enough to knock
t = (n)t 1/2 = (4) (100 s) = 400 s
out the electron from K or L–shells.
22. During–decay atomic number (Z) and mass number
N x 1 (t) 1 N 0e 10 t
1 (A) does not change. So, the correct option is (c)
14. because in all other options either Z,A or both is/are
N x 2 (t) e N 0 e t e
changing.
(Initially both have same number of nuclei say N 0)
e = –t/e –10t e = e 9t, x1 = 10 and x2 =
r dU eV0
1 23. U = eV = eV 0 n | F |
r0 dr r
9 t=1 t =
9
this force will provide the necessary centripetal
15. Energy of infrared radiation is less than the energy of force.
ultraviolet radiation. In options (a), (b) and (c), energy
released will be more, while in option (d) only, energy mv 2 eV0 eV0
Hence, v ...(i)
released will be less. r r m
1
n
18. The total number of atoms can neither remain 100 4
constant (as in option a) nor can ever increase (as in
options b and c). They will continuously decrease 25. Nuclear density is constant hence, mass volume
with time. Therefore, (d) is the appropriate option. m V.
19. In second excited state n=3, 26. Given that K 1 + K 2 = 5.5 MeV ...(i)
From conservation of linear momentum, p 1 = p 2
3h
So, H = Li =
2 2K 1 (216m ) 2K 2 (4m ) as P 2Km
while 2
E Z and Z H = 1, Z Li = 3 K 2 = 54 K 1 ...(ii)
So, |E Li | = 9 |E H | or |E H | < |E Li | Solving equation (i) and (ii).
We get K 2 = KE of –particle = 5.4 MeV
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2. Time period,
nh 3h
5 Angular momentum = n = 3
2 rn rn 2 2
Tn = (in nth state) i.e. Tn
vn n
n2 9a 32
Also r = a 0 0 a 0 Z 2
1 2 2 Z
But rn n2 and n
n For de-exci tati on
Therefore, T n n3 Given T n1 = 8T n2 1 1 1 1 1
Rz 2
2 2 4R 2 2
Hence, n 1 = 2n 2 n1 n 2 n1 n 2
For n = 3 to n = 1:
3. From the relation,
1 1 1 9
4R
hc hc 1 1 9 32R
eV = V
e e For n = 3 to n = 2:
This is equation of straight line. 1 1 1 9
4R
hc 4 9 5R
Slope is tan = For n = 2 to n = 1:
e
1 1 1 3
hc hc hc 4R
1: 2:3 = : : =1:2:4 1 4 R
01 02 03
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K1 1 3h 3 2 10 34
for H, Z 2 = 2 for He + I 2
1.87 10 46 kgm 2
K2 4 8 2 4 11
8 10
Comprehension#2
3. Moment of inertia of CO molecule about centre of
1. Due to the high temperature developed as a result m1m 2
mass : I r 2 where =
of collision & fusion causes the core of fusion reactor m1 m 2
to plasma.
3 Kq 1 q 2 Kq 1 q 2 I I 1.87 10 46
2. KT 2 = 3KT = r
2 r r m 1m 2 12 16 5 / 3 10 27
m1 m 2 12 16
1.44 10 9
T =
4 10 3 8.6 10 5
15 1.3 10 10 m
Paragraph 5
T = 1.39 × 109 K 1 10 9 T 2 10 9 K
210 206
1. 84 Po 82 Pb 24 He Q
3. nt0 = 8 × 1014 × 9 × 10–1 = 7.2 × 1014 > 5 × 1014 Total energy released = M Po M Pb M He C2
nt0 = 4 × 10 23 × 1 × 1011 = 4 × 10 34 > 5 × 1014 = [(209.982876) – (205.974455 + 4.002603)] ×
nt0 = 1 × 10 24 × 4 × 1012 = 4 × 10 36 > 5 × 1014 932 MeV
= [0.005818] × 932 MeV = 5.422376 MeV
Comprehension#3 Kinetic energy of particle =
p2 h A4 206
1. E = .... (i) p= ... (ii) A Q 210 5.422376 MeV = 5.319
2m
By equation (i) and (ii) MeV = 5319 KeV
2. Only in option (C); sum of masses of product is less
h2 h 2 (n 2 )
E= then sum of mases of reactant
2m 2 2m (4a 2 )
2 4
He 36 Li . As MLi < MDeutron +
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for reaction 1 H 2
n M alpha
[ = a for stationary wave
2
Subjective
on string fixed at both end] E a–2 1. (i) Let at time t, number of radioactive nuclei are N.
h2 (6.6 10 –34 ) 2 1 Net rate of formation of nuclei of A
2. E 2
30 9 2
2m 4a 2(1.0 10 ) 4 (6.6 10 ) e N t
dN dN dN
E = 8 meV =–N =dt N dt
dt N N0 0
h h hn
3. mv = v = v n Solving this equation, we get
m m(2a)
1
N= [–(–N 0)e –t]...(i)
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E 53 = E 5 – E 3 = 3.84 eV
n(2)
(ii) (i) Substituting = 2N 0 and t =t 1/2 = in E 52 = E 5 – E 2 = 11.5 eV > 4 eV
E 43 = E 4 – E 3 = 2.64 eV
3
equation (i) we get, N = N0 E 42 = E 4 – E 2 = 10.2 eV > 4 eV
2
Hence, the energy of emitted photons in the range
(ii) Substituting = 2N 0 of 2eV and 4eV are
and t in equation (i), we get
3.3 eV during combination and
3.84 eV and 2.64 after combination.
N= = 2N 0 N = 2N 0
2. Given work function W = 1.9 eV 3. Let ground state energy (in eV) be E 1
Wavelength of incident light, = 400 nm Then, from the given condition E 2n – E 1 = 204 eV
hc E1
Energy of incident light, E 3.1eV E 1 204eV
4n 2
(Substituting the values of h, c and )
1
Therefore, maximum kinetic energy of E 1 2 '1 = 204 eV...(i)
4n
photoelectron K max = E – W = (3.1 – 1.9) = 1.2 eV
Now the situation is as shown below : E1 E1
and E 2n – E n = 40.8 eV 2
= 40.8 eV
4n n2
e
–
3
Kmax=1.2eV n=5 E 1 2 = 40.8 eV...(ii)
E5= –2.1eV 4n
Z2 1 15 4
will be E 5 13.6 eV
n2 1 2
2 1 n=2
4n 4n n2
(2)2 From equation number (ii),
E 5 = –(13.6) =2.2 eV
(5)2 4 4
E1 n 2(40.8) eV = – (2) 2 (40.8) eV
Therefore, energy released during the combination 3 3
= 1.2 – (–2.2) = 3.4 eV E 1 = –217.6 eV E 1 = – (13.6)Z 2
Similarly energies in other energy states of He + will
E1 217.6
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2 Z2 = 16 Z=4
(2) 13.6 13.6
be E 4 = –13.6 = –3.4 eV
(4)2 E min = E 2n – E 2n–1
(2)2 E1 E1 E1 E1 7
E 3 = –13.6 =–6.04 eV 2
2 E1
(3) 2 4n (2n 1)2 16 9 144
(2)2 7
E 2 =–13.6 13.6eV 144 (–217.6) eV
22
The possible transitions are E min = 10.58 eV
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dN Y p2 p2
= X N X – YN Y...(ii) the final state is: K = K 1 + K 2 =
dt 2m 2M
dN Z p2 1 1 p2 M m
= YN Y...(iii) =
dt 2 m M 2 Mm
1 amu = 1.67 × 10 –27 kg
N 0X
(ii) Given N Y(t) = e Y t
e X t Substituting the values, we get
X Y
(1.151 10 19 )2 M m
K
For N Y to be maximum
dN Y (t)
0 2 M m
dt
i.e. X N X = Y N Y... (iv) (from equation (ii)) p2 (4.002 223.610)(1.67 10 27 )
2 (4.002 1.67 10 27 )(223.61 1.67 10 27 )
t
N 0X
X (N 0 e X ) Y [e Y t e X t ]
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X Y 10 12
K 10 12 J MeV = 6.25 MeV
Y t
1.6 10 13
X Y e X
X t
1 e ( X Y ) t K=6.25 MeV
Y e Y
6.25
X 1 X (ii) Mass defect, m= amu = 0.0067 amu
n 931.470
( X – Y)t n (e) = n t
Y X Y Y Therefore, mass of parent nucleus
Substituting the values of X and Y, we have = mass of –particle + mass of daughter
nucleus+mass defect (m)
1 0.1
t n 15 n(3) t=16.48 s. = (4.002 + 223.610 + 0.0067)amu = 227.62 amu
(0.1 1 / 30) 1 / 30
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7. The reactor produces 1000 MW power or 10 9 W (i) Number of photoelectrons emitted upto t=10 s are
power of 109 J/s of power. The reactor is to function
for 10yr. Therefore, total energy which the reactor (No. of photons falling
will supply in 10yr is E = (power) (time) in unit area in unit time)
n (area time)
= (10 9 J/s) (10 × 365 × 24 × 3600 s) = 3.1536 × 10 17 J 10 6
But since the efficiency of the reactor is only 10%,
therefore actual energy needed is 10 times of it 1
= [(10) 16 × (5 × 10 –4 ) × (10)] = 5.0 × 10 7
or 3.1536 × 10 18 J. One uranium atom 10 6
liberates 200MeV of energy or 200 × 1.6 × 10 –13 or
(ii) At time t=10s charge on plate A,
3.2 × 10 –11 J of energy. So, number of uranium
q A =+ne=(5.0 × 10 7 ) (1.6 × 10 –19 ) = 8.0 × 10 –12 C
atoms needed are
and charge on plate B,
18 q B = (33.7 × 10 –12 – 8.0 × 10 –12) = 25.7 × 10 –12 C
3.1536 10
n= = 0.9855 × 10 29
3.2 10 11
(q B q A )
Electric field between the plates E =
or number of kg–moles of uranium needed are 2 A 0
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13.6 13.6
E4 = – 2
0.85eV E = 3.4eV
(4) 2 (2)2
12. Let n 0 be the number of radioactive nuclei at time
t=0. Number of nuclei decayed in time t are given E = E4 – E2 = 2.55 eV
by n 0 (1–e –t ), which is also equal to the number of
Kmax = Energy of photon – work function
beta particles emitted during the same interval of
time. For the given condition, = 2.55 – 2.0 = 0.55 eV
3 1/ 3
From equation (iii) either e–2 = 1, e–2 = 1
4 NU
2 3.861
3
but e–2 = 1 is not accepted because which means N Pb 1
1
2
3
=0. Hence, e–2 =
4
15. (i) From the relation r A1/3
– 2 n(e) = n (3) – n(4) = n(3) – 2 n(2)
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1/3 1/3
r1
A1 A2
1 We have (14)1 / 3
= n (2) – n(3) r2 A 2 4
2
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1
From equation (i) and (ii), we have 2
2
h
17. h slope = = constant ratio = 1
p 2mqV e
P m q 20. Given T ½ = 1386 sec.
4 2 8 3
mPqP
dN
10 3
dt
dN dN Fraction
18. N 0 e t n n N 0 t
dt dt
N 0 N N 0 N 0 e t
= 1 e t
dN 1 N0 N0
n n N 0 t slope year 1
dt 2
ln 2
= 1 e 1386 80
1 1
yr
2 4
4 4
= 1 e 100 1 1 = 4%
0.693 100 100
t1 / 2 1.386 given time is 3 times of t1/2
value of p is 8.
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