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FOI ATA Te THT ermtaas| AA Alm TAT CUIDS € YT @ eo BNET OLA HCA FTE HT ae (TO sra ug, wea HM tT wer A eR (sea) ; CRA BAD) tT Ny SHe jaan: oc ts Beas oe D6 ACM ARIAT Bao obs eT i ae FOR ES ry MT Ona Cola ecu _ BTA Gi Za gra &- bore APT Airot OF Yat FHA Ged g> € 0 Vecos Pron fen SETA, me Ten 2: COAT eogot ry ete ee , CR Oa) ae ee - BACHAS gin dow TEA ae |O APU GE Faas grr sRINET HTM IS Biyeralyersit 2, FOV EMG Hele 20 7 @ MIMS +m 8 -FlwsR Gay site ae (€xom ‘ OH Ate) @ Cate GE MOU AT? or aaa aor caTBA Ta Fei FAINT OG OTe GTO gh NATH a ORAS CEL WTI wnat TT FOTO YI APRN Orarte, fale CL, oI Cat wir ONT Cat ary sifpanidt seer oa + Example: ~ cls, — CH, CHa, -Uy -Bn, -7 oH, -Nlp, ~OCHs ,-NHCH, . ; Bona opm Heer yas: mH AT Cantina CxMS @- Tha fier GM HEMET (apn Dea IAT TET earns eee Oe Teton CO OTROS Conira eae Fy ADIT Lor CHO, - No, +7 COCs y -CEN 7 COOH, Soy y, 5Nog 7 511 HaS% .. BARRE! GB) + no-no, SOD + te - 4hO , AED" HySQ, +0-No, ——. NOt 4 HS0,7 +H Ho, ‘dlr-2: O4 No,t pata BT MAS Uo &-CaQor HS, Balls 3 Ae: : + HSOg” oe Ca SR BM GUBS BICOL Say d + Hes eq ATT CT CBT 8 ; 0. -5Oq} ®: @ +Ho- san ae & EE A: Hy So, + H0-s0, 4 —4A. fot HS0,- + Ha0* tna OR aaPa é set So Osseo es. ree S WTS, Sg RE Sie eT SNF COVINA edhe OTR AE ORR IE & WiTEE wee 2 : ay : x aMr-3: © deee03 tame ek oy” i. STARE ‘ier: ot 0,4 pales ey “s + Hot 7 oy 2 oO a Ss s~ OF Sa Oeee tare o st saps +420] ane oe ee RIE LAT SE TOI hor O feea ores : a6 ai Stay hone % 7 ALN CHy x + ALGa, —s [etsth aioe] cae ately 4 Tsai f A Beene STN ovr oF | med cy ae | 19K > mi eres a RY BrTHy HOT ITH Br (9, 4 1 Raa How 4) OREW IA, fa | Ria aoe Se a . =H SE here: deep: EB —Y ow — § e : 3) —_ eS —__ als yh, +H n-CHete TH-CHCHs PHeghcHy = HoH e—? “3 e+ Q a) te i 7% 7 @ some cata Br, fg So at. ie be +oH on +O aa ee 2 6 BES Reig, NCH) Fg 5 ales @ A oO o ‘aX Aa” i an A at ~ a,REEL RIE GL TOM om amt arr (2A -3 04H, - WO, ono, coo Baie open “yaRAD ar aaa HET ics sy ager I IT fr OTB oe Ter wear BAYT CHE C99 TIP or Cl GR AR pre 9 7p on Cobter J- 14) OR Gp Texter nngTns® g- aap (abr AO oe Wwe Oren Wartuada ea OTK carer Gly wrxiy gin APRICOT @aby Ceo eA ROME Kescrarce : | oss “ON “ONO ospo™ 9 =z 2) Py OO O- OG go E S 1 web hé-0 Hre-o une yweso — Ss BS Be OS 6 rd ome: =D Wo-@70" ghe-o7 Ok FH BE = 2y-0H “OS SOR ~o~ S. -oH 1 IO ee Oo i o soa O a Ge 5 (|OAM TT ML SHOTS SENT Fel + Qwow fara oof ar utiga sie ABRT OM Gram, nw, ATES YET SST oe a a 4) HNO; ~~ —> 6 $2 + KIO a far sre @ieanaig): wnyfs Ferres ROO wheS ang oe -frapar oem ormaMegrqrmys Big 2A, ZT HN A ITA fig 6G eaten IMT eo ws Gis -NH, tH ——> [ccHy - Tht, Jor andgep teh enlq 2H [crs htspe f+ Hv, [cctts 8 ] : (qa CTSITRIRLe (OPE wp Seren gree fessroree Resonanee: re. ne a ee ’ =O Bed oOrT WYANT 6” - © ota-wloma “tee (p=°) aa sear [exter] aot mer, Fige ntfs game se cronies uw BAGE were CAT HR /-An BB weer apolonratoare] CIT wer ae meta? SAWS “Bey TRAIER CR) 7-An Aol alas once Facer] Ce 6 © artear Gee cua: @ Ae Falmer ET: ardrattat GAO (pe 20) OT TIGA vier agra aT © (figar) Tat & GT COR) THT rar tO) ards wires Hae Vie WIE (0-2-5 GRO=45) TOUT w GETT (mapa & yr 0 fae TRO UT EY 1B eC AOTAT wire Fis Ht TA BEACH!) EO Sarre eH laves ene pre (6-) I wa wer artfaa (6-0) am, eH MTT Gio ape LCS coparg Wy wre HO -MPTIO GY dllaer BOT G!) teu Tamer Iq AAS orf Bea C 4aaige INu™ SR CIRTa fatty a, @ mitten, The ate mitra FAO TCO IT HKG SA CTBT Frere stra “Realter , ontial Aer emer DIRT mer or ater sTererls PEI UN. Opp gam (-n) at garaD orp wie Wt ata Glo os EAP We ater ger STGEr OO API UE sear, g ohs Sw Ss co C-o0 Hegre > 7 ne " SS RGU SDT THR HPAL WKB ,. . 6 KiCrOy ergs: Aldelyde ‘ ee thi tee ot H,O OTL POAT re taper Seon 405 , RK ee 0 42H,0 Cspae gr yay 2 R-eoels HS Soe a= Bas R-cHO 4 hick HATH TACT ; ee \ C8 AF —> & b-co9), CaF h-cHo CACOn. : GR. e00 eur {56 0 0%)Ca 4 qt~ whe Lie: SH? Hee CO > H-czrany Ayn byte af Ton HS gt Gi | hae Ys Shu Cha = =H i F ayfeilagee 3 <_l Ps FOE SECT —DR/H- He =CH-H/R 49, J Sa = H20 ) oo. chy ee ce he we Nett (se ange a H pratense ® 2:4 pup WR Ala: i H Ny nor Reso Hy NCD n0, —~ &- i be wit et +H, 0 oO ¢ @ CHyreta corelH Cilla, @ °e Ne aN @N“S 9 => Q-2-NHz +Bre,t are erie UnGia aes : . Bente F2R0BR M20 AANA RRNT Hae=Ch, + NH “heer, Hy @—clhy- NH 2 SS apr NH, HO, Sty") dy? A ————_. +n, t Nach —s 42 Hobe Hha;e%,D vy MATA GAT. Be ler: RN > RH, 7 BAN SNe, fin NHe 2 ae wt (ait bas grove 38 ose 7 7 Oo — ! \ ~~ ann ye REP | (ora aofFR 055 pga FESR opeafercrn oe spar NTS | gi Hie AF < yn Ol naamga frser N SOIRE em a Woe AY |yAm ay e330 ayone CUM |e Yraqalne tg 01 t ore He Rok repecas |" a wrt ~ Sita Orla rw (ne sk se " afar Orato fa Ree Cee omer age camer (a) i ange Mite ( 49 Dita MUI se ONT) 95° st Dior ea Rone aE ans asp" be oO UT, Qvrmatre faieat ° Rd-x + HN-e > R-G-NIER Opps IA, Radex + HN) —s age REN) +AX +k res Lely whe EWE EW oy, Naka wy. NaN?a +O —S HNO, Fn R-NH, bE HND, MADes Ie R-OH +No + y,0 | 7 | Veayige Rk na poHene 7 + pitty, HL < CM un Fass err Ree “NH +O 4 Ss a He OTHRA epientuye APR OH wyfara wee (deOo" 6 01D, _ Als oO. ol Cigeh CHgth ea CHa| So) 0c Ha, &) C000, Hs ref luc. * Cc a O +CH2Z0H ——— | O + Cy peo : Om ee fa | _ CBirech reduction | ef Olas e an@& E heeknophilie addition : Deere ene (=), BE) @® Neudle ophilie addition: =~ LOO C=0d f a Careirtar ) ® Newcleophikic substitukion ! Oe RX, R-On, (MNescbeophilic 7 @® Eleckno philic *kunanbibn * RDI OSL LLL OE. Q-%, R-oH. © sibinn in Benzene fren (6) Subskiducion in Benzene: Ehecknophiti oe P subsbiukion, (%, Nee, SOn, 1H Wy] Afoyird ) A) Pharok YB Ar-K @ IA) BPSHIW MENSome imp orckont reactions Etord Reaction CHO CHs GSE HySO, { @) + 2[0] ———» lo] +0 45°C, Mn, 2°, 3" lcholahe) CHa, Benge —oh +H one) Sry Zn | 25°C Cha CHa = +H,0 4° Chs—¢ eh + Ha! CH, Cinskent neoclion >) te dry 2, gs & chch-ol +HCh Conc) Clg Hh 3 ste 2° CS nin )® cu,—chy-ol + Hel (cone) _dmy Ge Chi, “Chr ? 19° “doesn t peoct in oom Lemperctue) [Dace proce ss: | Gros one HA 4 & | ts0okm 182c & oo | Sond rheyor neaction,| w jy et, Cuy Ae on Hey, 100 ie te a Cor <— (a) +N,a © Hott man Deg rodakion reatn' Se CON) Nig CC) $Br, +4Neoh ——> o) + Nair oe Na, COx, Cannezzand0’s reaction: Hecho + HeHo __s07- NeoH HoH Go- 30 Cired uced) + HC00Na Esterei¥ ication neaction: Conidised) CHa Coon tCH OW > Clg COON CH, + yO Helk Volhardt- “Zekinshy reoctian (v2). p CH,cool TOL RET CH,CLCOH 46, ted P A Ch + COgeoot RAP oe com +h 2City COL Nia, ————s Hg, conta + Heh, Rosenmund reduction’ ae, at. PA PanSO CH, COC +H, ae eH 4CHO TH , OF an, ES Bate. [seats Diazotizokion pens Nene tion? Naf Hod pa ao HNO, oS 0 +H,0 en > NaNa HCL 4 HN@, TNX, [Coupling seoction’. | [Coupling seoction’. | Nye Olt NooH | og Bo w@rwe.@® 115% tHNC, ———> No, +1,0-+ Sq, | : 3 ) + Kio, > AGN et +159, 4 i { NOn +H,S% Hy SOg °2 HaSPeq * 0, ———> NO, —__+ oO THN, 60°C FANS 100°C. NOg NOy @® TNT Preporotion : a Cha Nai orm L om HNOs ot Oe “E824” coe a Diniteo Nitro hem aplobre “Coy NOz » HNOs ane Tainitas koleen Se er HyS0z, , 110°C.1 oH 7 O eno, 8% yo, Se > Os @ 20°C i Picnic Acid’ | Me figsy . Ge i! + SHINO, ne) ——s, TWN, NO> 2,46 Trinidno phere. Nit tiyS4 te ® g + HNO, 2s, Oo coc NO _ zr Kolbe reoction » oH : Noy a : +0 coonn (a et Quits ——? 95"c > HO =zotm oH colt gwen Tenn wack] siegicedd on No ‘ : oc B reo o ECHCLg HNeoH > oan - +Noth. |& Williamson ethar Ss rithe sis Cits0H NaOH ——> Els ONw +H,0 : ed CyHsBNa + Cl, > GHs OCHS Meta Helen Been CHa (9) oct... 5 i Bint &. oo 00° ¢ Oo ten in fhepactin Meta flee ae. 28%, mo é ” THX, hoN—C 0 >-S0,H +H,0 pam Os tho | Brom : Brody. ‘S Re. 2,4 -DNP test Me Ae a NOq CHy-CHO + H, N- NH <> NOy Hp 4 CHyCH=NNL2)-NO, ¢ | CTellow + Orange)Tollen Reagent test’ i HCHO +2 /yO"D: | ow ay 4 + CH,CONMg £9NHz + tO Feh Jing solution Tes! | Cl,cHO +2C.0W), + Noah - aut + Re 4c Hy COON + 3H20 R- cHo 40H) anh Cone. Heh Be CH R RF ety CH) EH oe oy Cone. HEA aris eee Aldoh Conden sodion reaction , OH 5 10). NaOH CHg ~CHo + CH2 CHO eg Chg-CH-ci,;cho (20- 30°) ¢ 3 fe PRE astra@ [cnokonaldelyde HC -cHO C at A H, -¢ H, -cH Z2CH-cH Hs, é _—ch, - —— 5 as Hyo B- Eliminstion } Cooyt eff robe) 6 © 8 KOH CHa CHECH -CHe a 90%, Br Cake) Cha CH Chech, cH \o7. 3 Ch pot ye slocs Ha, Cig “KOR Gig) HS 2@ x - Ey Pa ch, Cha, fet Ch, , Oo ‘Os c Cl 88 ae CHy=C ROH ba, Ry SOG ty + Ne ES] Chy 24-6 Fost CH, FROM IK HH guy” Hah FON enIS Onden 3° Rx 2stler ey dn a F then ® 2R-I + 2Noa RR 42NoL ORT + oR 41 ton, SEM oR S 0d number ' ; ellen apsson a RoR + R-Ro+ 6Nol, dng Ean ef co ee NaN Oo |HNO, Test | © Cilg-Nl, FHNO, > Cl-OH +N E NO NaNO ® CH, - NH- CHa, + HNO, eer Cha - N- CHa Cgdlow) Q NaNO a : 3) qo Cat HN, ose Jud 4 HtNH ® O Bn. He, a + 3Qn9 ——> ore ~ [2 & | ecagni son (ned On test (hited) | Poreacekamah premarin | OH on + CH,,CO-0- OCH, > + Ch Corl NH NHCOCH, Farocebamoh Aspirin pneparstion ou a= cols, cpolt 7 OF sy eugnoco, > Oe 4 CHyCoH [ree Aspirin DOT erage | | nH a Ht Cha, -CHO + 2G 284 og —c-H tho (BT a qa potk-¢@ Hon-NO ® Ke Nes (One 9 + HNO, orm O +-H,O ye (yelow) CHN- CH Cig N=Clty NaNO, ‘Ss 2 0 CO HO NO Bromine cater test | Goa cel4 t I @ CHy=CHy tOry ——7 CHa ~ Sn Cred) Ceolorless) Br Br Ce (cH =CH +28re ae Bech = dn- Br (ted) (co lore Less) oH on OH COy be phenok @ Oo PBN. ae > > esprit Cres or test Coohite +) piowic seid,@) @ a On. ie Tt ae Be pt ecognition Cred Bn. heel (whiteh) [ Barocekaroh preparation OH ol C) + CH, CO-0- OCH, —> () + CH CooH NHo NHCOCHa Foanocetamok Aspirin pneparstion . o= cota, gM ati eoolt ot + CH{CO-0-COCH —~ LO £CH oH Aspirin DDT preparation a 4a 50 p 0 COha-CHO + 26 ae, ong e-H + too OTT Qa q boTLodoform reaction 60c @ CloCHyDH +412 4NOH ——s CHyle conditions EH CoONa +NeD + 5H,0 Y 60¢ chyw- | 6% GE) Cita, CHO +3T,44NoOH ——> CHI, + Heat 4£3,H,0 43NoT Co Q CHM, + ALy HANH AP—> CHT a, b Conc.NaoH }UNoL +3H2O + CH2¢ ooNn. Conkyhamine reaction a y Ho . + CHO, 43H OS + Oh Chlonofionm Ched smell) +3429 plangh Con biplanring Reduction ot Cyonide Ge Gtep-up procedury Ren 44py7] _LiALHg ‘Dy Ela? Re CH, N Ho7 . aioe ee Goo A nO EDS SHS mary Oi Nomencibiice of Oxporie Clamidey GU © AISI fea oh TA, TUPAC G Pret® > Oye east ia A Oye! (oF ) ates ¢ Skee ° | Sater 4 3 : a CHa” cH- oH Os be Bn NO, ; parame aT ye sTrater Foes SEIT ORT Asada OK © &-¢-0H oO C-C-€ iy eater Oa: CTR Ter TRF arate CMTE TEL Aa (e (eo. owe _ atf Coe 7... Rare Gera waxes Filey Te gach WE OR Sager intel) gar Soro TS AOE ESOT Seve eH rare | Bae sre8 se Cer Eas wrap 4 THr orriey eur CT TA CEI, ayratezrze of, and kare Cabins 4 asthe , a, ee Ov 3 ATS BY AOTLA @ n 2a = SG Riera ee: ora ta HATROY , mitt rarer ey Wor amt MCUTELE v| p a iAaya MTD WT ae = i CR | chiles sg Sutiteeys ’ i: mosey Q ee Saetnabe ee = SoD | ee aR TCD == Y iT er Ca e-ext: pe a Soe ~C- q eey ame at ea TT - +e i = TT SH cg | ~ : _aningh oon a s P a s " luT Oe et | ¢ ax< Tass WW are, Tey Oro. CRTGIT Gy ACA oe, Q MCT orfaqematia wig - GL CeCe IR AaTI Or wftola oot BAO aeT AT Cp ewor Gen ser tei Aga Etaraoes TT wu ‘: 3 Wl OH Fi ? \ " | hing C — CHg a CHa C~C He L OH CR = C=ecH, & fre tok = enok oS ey webeoat sary ISTE TI ZO2-| A 4 aa bis ' _ re MGC "ape ma Conte _ cays t- fraval _5 eyo [HAT ACTA (tn €, Hana? payee / RC — BH wae og aT “ard tare a OT (OT, 3 he Honus Gn tan O, ay Gy Hon 07 era tome Hbre Bago oF mI, Alchohok ‘7Ekar.. | HSM UCHC~O - - C=E“P=E“C ' if C-0-¢-4-¢ gC “HC-HgC CH ' : au 7H pele Be-e-c Ha a due) | Jaed (WRSe suger: erie mger aa ow {| i pk GCN AS ery iW | | LL Alicore LAF GEER? | ~ i| i f_aid | fescl—— gerer | ei Nets i 5 / aan oat se Cis WET ~ 2-2 mw Cis C= ae NH Gypwra 4 cis-kow ea An GraAr @onboncd Bt me gar fx ne 2eu , wie COeRT 7 ETO gfe HES Ter ob trav sQa- ah y ie ian 72=¢ 4 —» gg7@ Uri : aa yi bo AS HAT SB ersel” ah fa: a) fresnerce facarar FFT RU , $5 Be, ow fr Se \ Hg Cols cael? 15 iro a - | 6 a€ Ma tk ae £ =¢ % a \ 45.5 aft tS ‘ 9 Crees