EXPERIMENTAL RESULTS FOR TITRATION

Concentration of Concentration of Concentration of Concentration of

Time
hydroxide ion [OH-] in hydroxide ion carbonate ion [CO32-] in carbonate ion [HCO3-]
(min)
mg/L [Ca(OH)2-] in mg/L mg/L in mg/L

0 476 1036 30 0
2 280.5 610.5 60 0
4 102 222 60 0
6 0 0 0 248.5

USEFUL COMPARISION FROM PAPER

Parameters Paper Experimentally
1 Solubility of Ca(OH)2 in water (g/L) 1.4766 1.036
2 Absorption of CO2 (g/L) 1.125 0.616
3 Flow rate of CO2 (L/min) 1 0.147
4 Reaction time ( min-sec) 3 min 15 sec <6
5 pH 12.99 12.8
6 Stirrer (rpm) 180 absent
7 N2 purging yes no

Extra Points Experimentally paper

1 Solubility of CaO in water (g/L) when 1.1174
g/L was added 0.784
2 Moles of CO2 from outlet 0.04 0.145
3 Moles consumed in reaction as per
experiment 0.014 0.0255
 Mass of CO2 1200
absorbed by 1036
[Ca(OH)2] in mg/L
1000
0

Concentration (in mg/L)

253 800
484
610.5 616
616
600
484

400
253
222
200

0 0
0
0 1 2 3 4 5 6 7

TIME (in min)

calcium hydroxide concentration carbon dioxide absorption

 616

0
5 6 7

absorption
 TITRATION TO FIND OH CONCENTRATION DUE TO Ca(OH)2
Phenolphthalein Methyl orange

Volume of
Date Solute present Time Volume of Sample Initial burette Final burette HCl used
(min) used (ml) Reading (ml) Reading (ml)
(ml)

0 20 15 20.7 5.7
2 20 24.4 27.9 3.5
21-Jan-19 CaO
4 20 19.6 21 1.4
6 20 24.1 24.1 0

0 20 17.7 24 6.3
5%NaOH
31-Jan-19
(100+2)

0 20 12 22.3 10.3
0 20 17 23.7 6.7
0.5 20 21.2 24.6 3.4
9-Feb-19 0
1 20 29 29.7 0.7
1.5 20 13.8 13.8 0
0 20 15 25.9 10.9

0.5 20 23.1 26.7 3.6

5%NaOH
9-Feb-19 (100+2) 1 20 10.6 11.9 1.3
1.5 20 13 13 0
2 20 15.8 15.8 0
2.5 20 20.2 20.2 0
TITRATION WHEN CALCIUM HYDROXIDE POWDER IS DISSOLVED IN WATER
Saturated
24-Feb-19 Ca(OH)2 0 20 27.5 34.9 7.4
TITRATION WHEN CALCIUM OXIDE POWDER IS DISSOLVED IN 0.1 % CMC
24-Feb-19 CMC+CaO 0 20 27.9 34.7 6.8
TITRATION WHEN CALCIUM OXIDE POWDER IS DISSOLVED IN 0.1 % CMC
CMC+CaO+ Some
24-Feb-19 Some CO2 20 39.5 45.4 5.9
TITRATION WHEN CALCIUM HYDROXIDE POWDER IS DISSOLVED IN 0.1 % CMC

24-Feb-19 CMC+Ca(OH)2 0 20 23.8 31.5 7.7

TITRATION WHEN CALCIUM HYDROXIDE POWDER IS DISSOLVED IN 0.1 % CMC

CMC+Ca(OH)2+S Some
24-Feb-19 ome CO2 20 19.5 25.8 6.3
TITRATION WHEN NANO Ca(OH)2 IS PRODUCED IN 0.5% CMC MEDIUM
CMC+ Nano
24-Feb-19 Ca(OH)2 0 20 34.4 44.1 9.7
 TITRATION WHEN NANO Ca(OH)2 IS PRODUCED IN 0.5% CMC MEDIUM
CMC+ Nano
Ca(OH)2 0 20 32.5 42.6 10.1
26-Feb-19
CMC+ Nano
Ca(OH)2 some 20 34.7 43.2 8.5
TITRATION WHEN NANO Ca(OH)2 IS PRODUCED IN 0.5% CMC MEDIUM AND DILUTED WITH DF OF 10
CMC+ Nano
Ca(OH)2 0 20 21.9 22.8 0.9
26-Feb-19
CMC+ Nano
Ca(OH)2 some 20 34.3 35.2 0.9
TITRATION WHEN ONLY 5% NaOH IS PRESENT
3-Mar-19 NaOH 5% 0 10 24.4 35.5 11.1
TITRATION WHEN ONLY 0.5% CMC IS PRESENT
3-Mar-19 CMC 0.5% 0 20 38 38 0
TITRATION WHEN 5% NaOH IS PRESENT

5-Mar-19 Water (1 L) + 5% 0 20 14 19 5
NaOH (20 ml)
TITRATION WHEN CaO IS PRESENT AND NOT FILTERED AFTER STIRRING
3/20/2019 CaO 0 20 53.1 60 6.9
TITRATION WHEN NANO Ca(OH)2 IS PRODUCED IN 0.5% CMC MEDIUM WITH CO2
0 20 55.2 65.2 10
0.5 20 66.4 74.6 8.2
23-Mar-19 Nano Ca(OH)2 1 20 54.4 56.6 2.2
1.5 20 63.2 63.7 0.5
2 20 67.8 67.8 0
 Methyl orange

Volume of HCl Volume of HCl

Initial burette Final burette Total HCl CASE [OH-] ion
used for [OH-] used for [CO32-]
Reading (ml) Reading (ml) used(ml) mg/L
ion (ml) ion (ml)

20.7 20.8 5.8 P>0.5M 5.6 0.2 476

27.9 28.1 3.7 P>0.5M 3.3 0.4 280.5
21 21.2 1.6 P>0.5M 1.2 0.4 102
24.1 24.8 0.7 P=0 0 0 0

24 24.3 6.6 P>0.5M 6 0.6 510

22.6 23 11 P>0.5M 9.6 1.4 816

23.7 24 7 P>0.5M 6.4 0.6 544
24.6 24.8 3.6 P>0.5M 3.2 0.4 272
29.7 29.8 0.8 P>0.5M 0.6 0.2 51
13.8 15.6 1.8 P=0 0 0 0
25.9 26.2 11.2 P>0.5M 10.6 0.6 901

26.7 26.9 3.8 P>0.5M 3.4 0.4 289

11.9 12.1 1.5 P>0.5M 1.1 0.4 93.5
13 14 1 P=0 0 0 0
15.8 17.6 1.8 P=0 0 0 0
20.2 22.8 2.6 P=0 0 0 0

34.9 35.2 7.7 P>0.5M 7.1 0.6 603.5

34.7 35.4 7.5 P>0.5M 6.1 1.4 518.5

45.4 46.5 7 P>0.5M 4.8 2.2 408

31.5 32 8.2 P>0.5M 7.2 1 612

25.8 27 7.5 P>0.5M 5.1 2.4 433.5

44.1 45.6 11.2 P>0.5M 8.2 3 697

 42.6 43.2 10.7 P>0.5M 9.5 1.2 807.5

43.2 45.5 10.8 P>0.5M 6.2 4.6 527

D WITH DF OF 10

22.8 23 1.1 P>0.5M 0.7 0.4 59.5

35.2 35.6 1.3 P>0.5M 0.5 0.8 42.5

35.5 35.8 11.4 P>0.5M 10.8 0.6 1836

38 39.8 1.8 P=0 0 0 0

19 19.2 5.2 P>0.5M 4.8 0.4 408

60 60.2 7.1 P>0.5M 6.7 0.4 569.5

65.2 66.2 11 P>0.5M 9 2 765

74.6 76.9 10.5 P>0.5M 5.9 4.6 501.5
56.6 63.2 8.8 P<0.5M 0 4.4 0
63.7 67.8 4.6 P<0.5M 0 1 0
67.8 77.6 9.8 P=0 0 0 0
 1

[Ca(OH)2] CO2
[OH-] ion [Ca(OH)2] [Ca(OH)2] [CO32-] ion [HCO3-] consumed absorbed
mmol/L mg/L mmol/L mg/L ion mg/L
mg/L mmol/L
2
28 1036 14 30 0 3
16.5 610.5 8.25 60 0 5.75 5.75 4
6 222 3 60 0 11 11 5
0 0 0 0 3.5 14 14

30
60
[Y VALUE]
48 39

[OH-] ion (in mmol/L)

50
32 1184 16 90 0 0
16 592 8 60 0 8 8 40
3 111 1.5 30 0 14.5 14.5 32
0 0 0 0 9 16 16 30
53 90 0
20 16
17 60 0
10
5.5 60 0
0 0 5 0
0 0 9 0
0 0 13 28.5

Ca(O
35.5 1313.5 17.75 90 0 17.75

30.5 1128.5 15.25 210 0 15.25

24 888 12 330 0 12

36 1332 18 150 0 18

25.5 943.5 12.75 360 0 12.75

41 1517 20.5 450 0 20.5

47.5 1757.5 23.75 180 0 23.75

31 1147 15.5 690 0 15.5

3.5 129.5 1.75 60 0 1.75

2.5 92.5 1.25 120 0 1.25

108 180 0

0 0 9

24 60 0

33.5 1239.5 16.75 60 0

45 1665 22.5 300 0

29.5 1091.5 14.75 690 0 -0.75 -0.75
0 0 0 660 1342 14 14
0 0 0 150 1098 14 14
0 0 0 0 49
 Amount of NaOH dissolved (g) 5

Amount of water used (ml) 100

Amount of CaO added (g) 0.6714
Amount of water used for CaO(ml) 600
Molarity of HCL (M) 0.1 0.091 Experimentally found

Concentraion vs Time
60
[Y VALUE]
[OH-] ion (in mmol/L)

50

40
32
30

20 16 17

10 5.50000000000001
2.99999999999999
0 0 0 0
0
0 0.5 1 1.5 2 2.5

Time (in min)

Ca(OH)2 Ca(OH)2 & NaOH
 Concentraion vs Time

60
[Y VALUE]

50
[OH-] ion (in mmol/L)

40

32
30

20 17
16

10
5.50000000000001
2.99999999999999
0 0 0
0
0 0.5 1 1.5 2 2.5 3

Time (in min)

Ca(OH)2 Ca(OH)2 & NaOH