Scribd Logo
Upload

Welcome to Scribd!

  • D Block L02 RP

    Uploaded by

    Om
    25 views12 pages

    Original Title

    D BLOCK L02 RP

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    25 views12 pages

    D Block L02 RP

    Uploaded by

    Om

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    of 12
    Trends in the M 2+/M Standard Electrode Potentials ® An 2d seviep element a, =Ve SRP valve excebt a. a (+e 2 bet Quan 453 8.4 The EDM" /M va far copers paste (40.3), What pss Bee ‘reason for this? (Hingreomstdee its kigh SAC nd oy 4,9) by, ee +2 W290 2, @ We o> 8 war a we @ weit 4 s & bMyyohin, cam wee ovevcone son of Tere, + Wa, © {v= 3h aleve BP AMC SS dll Hyg. No evolykton fa ue It is interesting to note that the value of E foriMa, Niand Zn are ‘more negative than expected from the trend The stablity ofthe half-filled d sub-shell in Mn andthe completely filled d 10 configuration in Zn2+ are related to their E'¥ values, whereas E' for Niis related tothe highest negative AhydH © negative Abydk ; get? _. ee + : —_»® eS An examination of the E°(M”/M*) values {Table 8.2 shows the varying . trends. The low value for Sc reflects the stability of Sc’* which has a noble gas configuration. The highest value for Zn is due to the removal ee eg eseerrees relies . trends. The low value for Sc reflects the a lity of Sc* which has a noble gas configuration. The highest value for Zn is due to the removal of an electron from the stable d'° config) of Zn’, he omparatel ith vale for Mn shows that Min“) i pray stable, wherea ly low value for Fe shows the extra stability of Fe* @. The ively low value for V is related to the stability of V* Chalt-flled fy evel Unit 9). Hoc] o> Iwo 2 due to Wobel qb ss aa Cant ute a Highest 3 dve $ Pemued f elect On from al? unt antes High 2 due fy Peroves electron fron A > Fesl RA» low = ee do tush statis in dS (fet) ee | ® Higher exidehion Skate GRY t+ 04 A CMwyTy a nist ronobelidec (cut) osainertc Kase =} Another feature of fluorides is their instability in the low oxidation states e.g., VX2 (X = Cl, Br or |) ent * Vex & cof ove stable than cof in “aqueous, wactivin, Rease ee ai +2, peace ra co rn 7 OG ned chet L 3d" qst aa" 343 sre Je dine TAB AAWe 2 Jona Hydvedion High Wyre > Move Stable # cuP es wore Gable than, tla, due to High Hy Arodion, eect witcle overmMe Vigh seond TE ‘Trends inthe M3+/M2s Standard Electrode Potentials © sc43| ccf? > fow valve Pan on nigh valve oO hee o wotS| ny —> _High ale e fet Fe —F Www value * 2° | mt we ey] wt? ‘we ose @) ‘ ‘On ek eo ‘An exainination ofthe E° values for the redox couple M™/M™" (Table 8.2) shows that Mn” and Co” tong are the strongest oxidising agents in aqueous solutions. ‘The ions T¥", V" and Cr° are strong redueing agents and will iberate hydrogen from a difute acid, e.. 2 Cr tag) + 2 lag) 92 Cr"tag + Hila) High SRP enkey five 6 349 ©) ewes fist Magnetic Properties w= J vont) (BH Spimowly Hague tic Memeut Para. Raper Mo aa | (>) mnt S wna sas wJ 26 Fe® GD Se aaS ys? be Singnt2 x ¥ = 7e 2 pene li +. cw x ae 387 2 Honest ti deo ao a Steg b= county Fe® of * eeduig = ext? THT & _— ne weahonpelvd Cxdewd 4 Para moa netic befavio No t unpaired e® eked, 2 fies eet fie 3 a Me 4g az Me 56g we * calor of ion depondg _vbow “yo oN 2 Fe" + S,0,° + 280, concusim~ fe"? converted MES to Ta. CO 2 ules => _Interstiel compounds are those which are formed when small atoms Cor are trapped inside the crystal lattices of metals example, TIC, Mndlt,Fe3H, VHO 56 and THL.7 —e506— jb Fev PROPERTIES p (i) They have high melting points, higher than those of pure metals. ret ) They are very hard, some borides approach diamond in hardness. ) They retain metalic conductivity (io) They are chemieallyiner’ _, gexve cle ebvckel , Alloy Formation > vowog event ® brass (copper-zinc) ©) _ bronze (copper-tin) © German sivey cv Ni ze @ wen metal cu 8 © an wet cv on 2M ‘Oxides and Oxoanions of Metals $ 4. ——> ENT Pn #2 All the metals exceot scandium form MO oxides which are ionic ENT Bn y oo Allthe metals except a form MO oxides which are ionic te “ts Lc Lino NAT ACT. a * Maximum oxidation no coincides with erp no in 3d series obo Ky only. ae #7 Se, = —— — Hm?4 ye qr +3 fe —> Fe 202 am cf om vox" 2 Vo > the oxocations stabilise WV as VO? +, VIV as VO2+ and Ti Vas. Yo,* yot* Tioz+ see qi* my ‘ rae #2 Tot > MO covalent qe ol. 2 cr, 2vvg > low HP +s +6 +S ra +1 3 Vee Levey, < M204 eee Ac 5 rs 45 Voit _ nl Ww < wos Sas ac = MM,% + V0 > MH, Og 2 CHNMe4) = cx, + Ho org, | Were > sn. tn nd os re 1H, ad aoe eerie * —_—— mm Ss ) «4, ao mi. x Preparation of Potassium dichromate K2Cr207 sg coda, a yell step 4 FeC1204 + 8 Na2CO3 + 7 02 > 8 Na2GiO4 +2 Fe203 +8 C0; chrowike oye step? ACIDIFICATION AND FILTRATION Cys) 2Na2crOa + yell ovange al U extol - wnt Wao 1 2H,9 ret i+ > Na2Cr207 +2 Na+ + H20 - in oY Vo, t + * tow -3 voy Fe cri = feo: 2% * - Gs Note = Na, cy, Lp Move solude than Ktyer, step 3 Na2Cr207 +2 KCI-> K2C;207 +2 NaCl 4 solution depending upon pH ofthe sluion A 28 salen cyg, = O97 A, = “x yO PLT ont yellou > 0 wi ww) oe Yello eae hE ony orange ec Struck uv! p> 9 ° ° gf 0 oy 2 =2 i Ro oe a =tto <~ ct —0' cyte te e eu Qe a ee ° ° ee * ; B™ 6 cro bond (deullen’ Yevro Bond Hemi? dve 4D Resonance, Potassium dichromate Is used as. 4 primary standard in volumetricanalysis. not Na, CYL} Kya" 1 ber More Solvbole Hyg vO Sespic, eut= 6 sadn acti * xs 43 oxidising action +O @ =e (C1207 2-4 14H+ + 6e- > 20134 + 7H20 vs oridising ation ¢ Keen eq im atdic Mediu. “2 (6) ws Wee sagt Fe Ste Sy. Kiera ut (9) 2 S wh tT a ee ont cox vexmig erect 8 Kc Koc + tn + OD + + L 2 me tem (=) many yettoo green, Nv coy end ~ lor due Ab chase Ransfir — if Eee Up colvrel then the cola Ip due do cham. Transfev. 46 qt #1 +l Cro oey > rng a a a Red ie Neto orang, pink Colour if de $9 change Transfer fom Ligand Jo metal Ee of-2 Ore —aenther fe yacout A orbital Ff Hetal Hyena chant Feawsfey ® felt ko Meta chang Tromsfer CMMCT) _ v4 fe4( fe cn), — Sevell . SF due kD MCT @ cobuy Ave to polavyigahow + GW wo & wlite. Yellow Yer % if d' do dA? Lealovred then aveto aed % if di fo A> Felovred Alen dueto ded Teams tion at chow ee tek C eit for 19) tem y ot ME compos ra ° os Carona One wie = ate Kowa t aysq + nec! —> a Ged, vaboo” ofoureh due do Linet ) ine Bpehe acy ROR +6 # kur hS%4 + ny =~? MBE > See alee —h P due to LCT) 4 OL ne

    You might also like