Sulfato de Niquel - MSDS (En 7.08.2020) - Anders Peru S.A.C.

NICKEL SULPHATE 6H2O
Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830
SDS Ref.: 001102
Issue date: 6/16/2011 Revision date: 7/8/2020 Supersedes: 8/21/2018 Version: 6.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Product form : Substance
Substance name : NICKEL SULPHATE 6H2O
EC Index-No. : 028-009-00-5
EC-No. : 232-104-9
CAS-No. : 10101-97-0
REACH registration No : 01-2119439361-44-
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified uses
Use of the substance/mixture : Industrial
1.2.2. Uses advised against

No additional information available
1.3. Details of the supplier of the safety data sheet

A.M.P.E.R.E. INDUSTRIE
5/7 RUE DE BRETAGNE - P.A. DES BETHUNES
95310 SAINT-OUEN L'AUMÔNE - FRANCE
T 33 (0)1 34 32 38 00 - F 33 (0)1 30 37 14 96
fds@ampere.com
1.4. Emergency telephone number

Emergency number
Country Official advisory body Address Emergency number Comment

United Kingdom National Poisons Information Service 0344 892 0111
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Mixtures/Substances: SDS EU 2015: According to Regulation (EU)
2015/830 (REACH Annex II)
Carcinogenicity (inhalation) Category 1A H350i
Germ cell mutagenicity, Category 2 H341
Reproductive toxicity, Category 1B H360D
Specific target organ toxicity — Repeated exposure, Category 1 H372
Acute toxicity (inhal.), Category 4 H332
Acute toxicity (oral), Category 4 H302
Skin corrosion/irritation, Category 2 H315
Respiratory sensitisation, Category 1 H334
Skin sensitisation, Category 1 H317
Hazardous to the aquatic environment — Acute Hazard, Category 1 H400
Hazardous to the aquatic environment — Chronic Hazard, Category 1 H410
Full text of H statements : see section 16
Specific concentration limits:
( 0.01 ≤C ≤ 100) Skin Sens. 1, H317
( 0.1 ≤C < 1) STOT RE 2, H373
( 1 ≤C ≤ 100) STOT RE 1, H372
( 20 ≤C ≤ 100) Skin Irrit. 2, H315
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Adverse physicochemical, human health and environmental effects

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms (CLP) :
GHS08 GHS07 GHS09

Signal word (CLP) : Danger
Hazard statements (CLP) : H302+H332 - Harmful if swallowed or if inhaled.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 - Suspected of causing genetic defects.
H350i - May cause cancer by inhalation.
H360 - May damage the unborn child. (Perinatal lethality).
H372 - Causes damage to organs (respiratory tract) through prolonged or repeated
exposure (inhalation).
H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statements (CLP) : P201 - Obtain special instructions before use.
P260 - Do not breathe spray, mist, fume, gas, dust, vapours.
P273 - Avoid release to the environment.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P285 - In case of inadequate ventilation wear respiratory protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304+P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at
rest in a position comfortable for breathing.
P308+P313 - IF exposed or concerned: Get medical advice/attention.
P333+P313 - If skin irritation or rash occurs: Get medical advice/attention.
P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or
doctor/physician.
P362+P364 - Take off contaminated clothing and wash it before reuse.
P391 - Collect spillage.
Extra phrases : Restricted to professional users.
2.3. Other hazards

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
SECTION 3: Composition/information on ingredients
3.1. Substances
Name : NICKEL SULPHATE 6H2O
CAS-No. : 10101-97-0
EC-No. : 232-104-9
EC Index-No. : 028-009-00-5
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Name Product identifier % Classification according to

Regulation (EC) No.
1272/2008 [CLP]
Nickel sulphate hexahydrate (CAS-No.) 10101-97-0 100 Carc. 1A, H350i
(EC-No.) 232-104-9 Muta. 2, H341
(EC Index-No.) 028-009-00-5 Repr. 1B, H360D
(REACH-no) STOT RE 1, H372
01-2119439361-44 Acute Tox. 4 (Inhalation), H332
Acute Tox. 4 (Oral), H302
Skin Irrit. 2, H315
Resp. Sens. 1, H334
Skin Sens. 1, H317
Aquatic Acute 1, H400
Aquatic Chronic 1, H410
Specific concentration limits:

Name Product identifier Specific concentration limits
Nickel sulphate hexahydrate (CAS-No.) 10101-97-0 ( 0.01 ≤C ≤ 100) Skin Sens. 1, H317
(EC-No.) 232-104-9 ( 0.1 ≤C < 1) STOT RE 2, H373
(EC Index-No.) 028-009-00-5 ( 1 ≤C ≤ 100) STOT RE 1, H372
(REACH-no) 01-2119439361-44 ( 20 ≤C ≤ 100) Skin Irrit. 2, H315
Full text of H-statements: see section 16
3.2. Mixtures
Not applicable
SECTION 4: First aid measures
4.1. Description of first aid measures

First-aid measures general : Immediately remove contaminated clothing or footwear. Wash contaminated clothing before
reuse. Get immediate medical advice/attention.
First-aid measures after inhalation : Move the affected person away from the contaminated area and into the fresh air.
First-aid measures after skin contact : Wash off immediately with soap and plenty of water.
First-aid measures after eye contact : Remove contact lenses, if present and easy to do. Continue rinsing. Rinse immediately and
thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). Get medical
advice/attention.
First-aid measures after ingestion : Rinse mouth out with water. Never give anything by mouth to an unconscious person. If the
victim is unconscious : Place the affected person in the recovery position.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1. Extinguishing media

Suitable extinguishing media : Not combustible. The product itself does not burn. Use extinguishing media appropriate for
surrounding fire.
Unsuitable extinguishing media : No data available.
5.2. Special hazards arising from the substance or mixture

Fire hazard : In case of fire: May release harmful fumes (Sulphur oxides (SOx), Metal oxides).
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5.3. Advice for firefighters

Firefighting instructions : Prevent fire fighting water from entering the environment. Assure discharge complies with
applicable regulations.
Protection during firefighting : Wear a self contained breathing apparatus. Do not attempt to take action without suitable
protective equipment.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnel
Protective equipment : Refer to protective measures listed in Sections 7 and 8.
Emergency procedures : Avoid dust formation. Use appropriate ventilation.
6.1.2. For emergency responders

Protective equipment : For further information refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions

Do not allow to enter drains or water courses.
6.3. Methods and material for containment and cleaning up

Methods for cleaning up : Mechanically recover the product. Shovel into suitable and closed container for disposal.
Recycle or dispose of in compliance with current legislation.
6.4. Reference to other sections

SECTION 7: Handling and storage
7.1. Precautions for safe handling

Additional hazards when processed : Precautionary measures fire. / Explosion : Keep away from sources of ignition - No
smoking. Avoid dust formation.
Precautions for safe handling : Handle in accordance with good industrial hygiene and safety procedures.
Hygiene measures : Do not eat, drink or smoke when using this product. Keep away from food, drink and animal
feeding stuffs. Avoid contact with skin and eyes. Immediately remove contaminated clothing
or footwear. Wash hands before break and at end of works. Avoid breathing dust, mist or
spray. Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Keep container tightly closed. Store in a cool, well-ventilated place.
Incompatible materials : Oxidising agents. Bases.
Special rules on packaging : Store always product in container of same material as original container.
7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection
8.1. Control parameters
NICKEL SULPHATE 6H2O (10101-97-0)

DNEL/DMEL (Workers)
Acute - systemic effects, inhalation 16 mg/m³ (Ni)
Acute - local effects, inhalation 0.7 mg/m³ (Ni)
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Long-term - local effects, dermal 0.00044 mg/cm² (Ni)
Long-term - systemic effects, inhalation 0.05 mg/m³ (Ni)
Long-term - local effects, inhalation 0.05 mg/m³ (Ni)
DNEL/DMEL (General population)

Acute - systemic effects, inhalation 9.6 mg/m³ (Ni)
Acute - systemic effects, oral 0.012 mg/kg/d (Ni)
Acute - local effects, inhalation 0.4 mg/m³ (Ni)
Long-term - systemic effects,oral 0.02 mg/kg/d (Ni)
Long-term - systemic effects, inhalation 0.00002 mg/m³ (Ni)
Long-term - local effects, inhalation 0.00002 mg/m³ (Ni)
PNEC (Water)
PNEC aqua (freshwater) 3.6 µg/L (Ni)
PNEC aqua (marine water) 8.6 µg/L (Ni)
PNEC (Soil)
PNEC soil 29.9 mg/kg (Ni)
PNEC (Oral)
PNEC oral (secondary poisoning) mammalian : 0,73 mg/kg (Ni) / Birds : 5.0 mg/kg (Ni)
PNEC (STP)
PNEC sewage treatment plant 0.33 mg/l (Ni)
Nickel sulphate hexahydrate (10101-97-0)

DNEL/DMEL (Workers)
Acute - systemic effects, inhalation 16 mg/m³
Acute - local effects, inhalation 0.7 mg/m³
Long-term - local effects, dermal 0.00044 mg/cm²
Long-term - systemic effects, inhalation 0.05 mg/m³
Long-term - local effects, inhalation 0.05 mg/m³
DNEL/DMEL (General population)

Acute - systemic effects, inhalation 9.6 mg/m³
Acute - systemic effects, oral 0.012 mg/kg/d
Acute - local effects, inhalation 0.4 mg/m³
Long-term - systemic effects,oral 0.02 mg/kg bodyweight/day
Long-term - systemic effects, inhalation 0.00002 mg/m³
PNEC (Water)
PNEC aqua (freshwater) 3.6 µg/L (Ni)
PNEC aqua (marine water) 8.6 µg/L (Ni)
PNEC (Soil)
PNEC soil 29.9 mg/kg (Ni)
PNEC (Oral)
PNEC oral (secondary poisoning) mammalian (rat) : 0,73 mg/kg / Birds : 5.0 mg/kg
PNEC (STP)
PNEC sewage treatment plant 0.33 mg/l (Ni)
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8.2. Exposure controls
Hand protection:
Sufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of risk of skin contact with the
product . Before use, the protective glove should be tested in any case for its specific work-station suitability (i.e. mechanical resistance, product
compatibility and antistatic properties). Adhere to the manufacturer’s instructions and information relating to the use, storage, care and
replacement of protective gloves. Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to
avoid permanent use of protective gloves.
Eye protection:
Safety glasses (EN 166)
Skin and body protection:
Use chemically protective clothing
Respiratory protection:
Do not exceed the occupational exposure limits (OEL). Use recommended respiratory protection
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties

Physical state : Solid
Appearance : Crystalline solid.
Colour : Slightly yellow to green.
Odour : No data available
Odour threshold : No data available
pH : No data available
Relative evaporation rate (butylacetate=1) : No data available
Melting point : 840 °C ANHYDROUS FORM - 53 °C (10101-97-0)
Freezing point : No data available
Boiling point : No data available
Flash point : Not applicable
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : Not applicable
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 3.68 g/cm³ ANHYDROUS FORM - 2.07 g/cm3 (10101-97-0)
Solubility : Water: 293 g/l ANHYDROUS FORM(20°C) - 625 g/l (10101-97-0)(0°c)
Partition coefficient n-octanol/water (Log Pow) : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available
Explosive limits : No data available
9.2. Other information

SECTION 10: Stability and reactivity
10.1. Reactivity
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10.2. Chemical stability

Stable in use and storage conditions as recommended in item 7.
10.3. Possibility of hazardous reactions

10.4. Conditions to avoid

10.5. Incompatible materials

Oxidizing agent. Bases.
10.6. Hazardous decomposition products

Sulphur oxides (SOx). Metal oxides. (Toxic fumes).
SECTION 11: Toxicological information
11.1. Information on toxicological effects

Acute toxicity (oral) : Harmful if swallowed or in contact with skin.
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Harmful if inhaled.
Additional information : Dust of the product, if present, may cause respiratory irritation after an excessive inhalation
exposure
Respiratory or skin sensitisation

LD50 oral rat 361.9 mg/kg bodyweight (OECD 425)
LC50 inhalation rat (mg/l) 2.48 mg/l (OECD 403) - 4h
Skin corrosion/irritation : Causes skin irritation.

Additional information : Not irritating to rabbits on cutaneous application
(OECD 404 method)
Serious eye damage/irritation : Not classified
Additional information : Not irritating to rabbits on ocular application
(OECD 405 method)
If dust are formed : Mechanical irritation may be expected.
Respiratory or skin sensitisation : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an
allergic skin reaction.
Additional information : Sensitizer ECHA
Germ cell mutagenicity : Suspected of causing genetic defects.
Additional information : Chromosomal aberration test
(Hamster) ECHA
Carcinogenicity : May cause cancer by inhalation.

NOAEL, oral, rat 11 (Reference substance : Nickel (OECD 451 method) - Source : ECHA)
Reproductive toxicity : May damage the unborn child.

Additional information : , rat: 10 mg/kg (1 day, Reference substance : Nickel (OECD 416 method))
NOAEC: 2 mg/m3
STOT-single exposure : Not classified
STOT-repeated exposure : Causes damage to organs (respiratory tract) through prolonged or repeated exposure
(inhalation).
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NOAEC, Inhalation 0,027 mg/m³ (Target organ : lungs - Reference substance : CAS 7440-02-0 (OECD 453
method) - Source : CSR)
Aspiration hazard : Not classified
SECTION 12: Ecological information
12.1. Toxicity
Hazardous to the aquatic environment, short-term : Very toxic to aquatic life.
(acute)
Hazardous to the aquatic environment, long-term : Very toxic to aquatic life with long lasting effects.
(chronic)

LC50 fish 1 15.3 mg/l Oncorhynchus mykiss - 96h - Reference substance : CAS 7718-54 - Source :
ECHA
EC50 Daphnia 1 > 200 mg/l - 48 h - Ceriodaphnia dubia - Reference substance : CAS 7718-54 - Source :
ECHA
EC50 other aquatic organisms 2 33 mg/l (Toxic to bacteria) ACTIVATED SLUDGE - 30 min - Reference substance : CAS
13138-45-9 (ISO 8192) - Source : ECHA
EC50 72h algae (1) 81.5 – 148 mg/l - Pseudokirchneriella subcapitata - Reference substance : CAS 7718-54
(OECD 201 method)
NOEC chronic fish 108.9 µg/L 30 days - Pimephales promelas - Reference substance : CAS 7718-54 -
Source : ECHA
NOEC chronic crustacea 90 µg/L 21 days - Daphnia magna - Reference substance : CAS 7718-54 (OECD 211
method) - Source : ECHA
12.2. Persistence and degradability

Persistence and degradability No data available.
12.3. Bioaccumulative potential

Bioaccumulative potential No data available.
12.4. Mobility in soil

Ecology - soil No data available.
12.5. Results of PBT and vPvB assessment

This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII
This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII
12.6. Other adverse effects

Other adverse effects : Prevent entry to sewers and public waters. Do not bring to dump.
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SECTION 13: Disposal considerations
13.1. Waste treatment methods

Regional legislation (waste) : Comply with local regulations for disposal.
Waste treatment methods : For disposal within the EC, the appropriate code according to the European Waste
Catalogue (EWC) should be used. Empty containers should be taken for recycling, recovery
or waste in accordance with local regulation.
SECTION 14: Transport information

In accordance with ADR / RID / IMDG / IATA / ADN
14.1. UN number
UN-No. (ADR) : UN 3077
UN-No. (IMDG) : UN 3077
UN-No. (IATA) : UN 3077
UN-No. (ADN) : UN 3077
UN-No. (RID) : UN 3077
14.2. UN proper shipping name

Proper Shipping Name (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (IATA) : Environmentally hazardous substance, solid, n.o.s.
Proper Shipping Name (ADN) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper Shipping Name (RID) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Transport document description (ADR) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Nickel
sulphate hexahydrate(10101-97-0)), 9, III, (E)
Transport document description (IMDG) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III,
MARINE POLLUTANT
Transport document description (IATA) : UN 3077 Environmentally hazardous substance, solid, n.o.s., 9, III
Transport document description (ADN) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
Transport document description (RID) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., 9, III
14.3. Transport hazard class(es)
ADR
Transport hazard class(es) (ADR) : 9
Danger labels (ADR) : 9
IMDG
Transport hazard class(es) (IMDG) : 9
Danger labels (IMDG) : 9
IATA
Transport hazard class(es) (IATA) : 9
Danger labels (IATA) : 9
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ADN
Transport hazard class(es) (ADN) : 9
Danger labels (ADN) : 9
RID
Transport hazard class(es) (RID) : 9
Danger labels (RID) : 9
14.4. Packing group

Packing group (ADR) : III
Packing group (IMDG) : III
Packing group (IATA) : III
Packing group (ADN) : III
Packing group (RID) : III
14.5. Environmental hazards

Dangerous for the environment : Yes
Marine pollutant : Yes
Other information : No supplementary information available
14.6. Special precautions for user
Overland transport
Classification code (ADR) : M7
Special provisions (ADR) : 274, 335, 601, 375
Limited quantities (ADR) : 5kg
Excepted quantities (ADR) : E1
Packing instructions (ADR) : P002, IBC08, LP02, R001
Mixed packing provisions (ADR) : MP10
Portable tank and bulk container instructions (ADR) : T1, BK1, BK2
Portable tank and bulk container special provisions : TP33
(ADR)
Tank code (ADR) : SGAV, LGBV
Vehicle for tank carriage : AT
Transport category (ADR) : 3
Special provisions for carriage - Packages (ADR) : V13
Special provisions for carriage - Bulk (ADR) : VC1, VC2
Special provisions for carriage - Loading, unloading : CV13
and handling (ADR)
Hazard identification number (Kemler No.) : 90
Orange plates :
Tunnel restriction code (ADR) : E

EAC code : 2Z
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Transport by sea
Special provisions (IMDG) : 274, 335, 966, 967, 969
Limited quantities (IMDG) : 5 kg
Excepted quantities (IMDG) : E1
Packing instructions (IMDG) : P002, LP02
Special packing provisions (IMDG) : PP12
IBC packing instructions (IMDG) : IBC08
IBC special provisions (IMDG) : B3
Tank instructions (IMDG) : T1, BK1, BK2, BK3
Tank special provisions (IMDG) : TP33
EmS-No. (Fire) : F-A
EmS-No. (Spillage) : S-F
Stowage category (IMDG) : A
Stowage and handling (IMDG) : SW23
Air transport
PCA Excepted quantities (IATA) : E1
PCA Limited quantities (IATA) : Y956
PCA limited quantity max net quantity (IATA) : 30kgG
PCA packing instructions (IATA) : 956
PCA max net quantity (IATA) : 400kg
CAO packing instructions (IATA) : 956
CAO max net quantity (IATA) : 400kg
Special provisions (IATA) : A97, A158, A179, A197
ERG code (IATA) : 9L
Inland waterway transport
Classification code (ADN) : M7
Special provisions (ADN) : 274, 335, 375, 601
Limited quantities (ADN) : 5 kg
Excepted quantities (ADN) : E1
Carriage permitted (ADN) : T* B**
Equipment required (ADN) : PP, A
Number of blue cones/lights (ADN) : 0
Rail transport
Classification code (RID) : M7
Special provisions (RID) : 274, 335, 375, 601
Limited quantities (RID) : 5kg
Excepted quantities (RID) : E1
Packing instructions (RID) : P002, IBC08, LP02, R001
Special packing provisions (RID) : PP12, B3
Mixed packing provisions (RID) : MP10
Portable tank and bulk container instructions (RID) : T1, BK1, BK2
Portable tank and bulk container special provisions : TP33
(RID)
Tank codes for RID tanks (RID) : SGAV, LGBV
Transport category (RID) : 3
Special provisions for carriage – Packages (RID) : W13
Special provisions for carriage – Bulk (RID) : VC1, VC2
Special provisions for carriage - Loading, unloading : CW13, CW31
and handling (RID)
Colis express (express parcels) (RID) : CE11
Hazard identification number (RID) : 90
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-Regulations
The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:
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Reference code Applicable on Entry title or description
28. NICKEL SULPHATE 6H2O ; Nickel Substances which are classified as carcinogen category 1A or 1B in Part 3 of
sulphate hexahydrate Annex VI to Regulation (EC) No 1272/2008 and are listed in Appendix 1 or
Appendix 2, respectively.
30. NICKEL SULPHATE 6H2O ; Nickel Substances which are classified as reproductive toxicant category 1A or 1B in
sulphate hexahydrate Part 3 of Annex VI to Regulation (EC) No 1272/2008 and are listed in Appendix 5
or Appendix 6, respectively.
NICKEL SULPHATE 6H2O is not on the REACH Candidate List
NICKEL SULPHATE 6H2O is not on the REACH Annex XIV List
NICKEL SULPHATE 6H2O is not subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 july 2012 concerning
the export and import of hazardous chemicals.
NICKEL SULPHATE 6H2O is not subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on
persistent organic pollutants
15.1.2. National regulations

15.2. Chemical safety assessment

For this substance a chemical safety assessment has been carried out
SECTION 16: Other information
Indication of changes:
Exposure scenario.
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Abbreviations and acronyms:
ACGIH : American Conference of Governmental Industrial Hygienists

ADN: European Agreement concerning international carriage of Dangerous goods by Inland waterways
ADR: European Agreement concerning international carriage of Dangerous goods by Road
AF : Assessment factor
AGS : Ausschuss für Gefahrstoffe
ATE : Acute Toxicity Estimate
ATEX : ATmosphère Explosive
BAF : Bioaccumulation Factors
BCF : Bioconcentration factor
Bw: Body weight
CAS: Chemical Abstracts Service
CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act
CLP : Classification, labelling, packaging
CSA : Chemical Safety Assessment
CSR: Chemical Safety Report
DFG : German research Foundation
DMEL : Derived maximum effect level
DNEL: Derivative No effect Level
DOT : US Departement of Transportation
DU : Downstream User
EC: European Community
EC No : European Community Number
EC50 : Half maximal effective concentration
ECHA : European Chemicals Agency
EINECS : European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
ELV : Emission limit values
EN: European Norm
ERV : Ecotoxicological Reference Value
EUH: European Hazard Statement
EWC : European Waste catalogue
GefStoffV: Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany)
GHS : Globally Harmonized System of Classification and Labelling of Chemicals
HSDB : Hazardous Substances Data Bank
IARC : International Agency for Research on Cancer
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
IBC : International Bulk Chemical
IC50: Median Inhibition concentration
ICAO: International Civil Aviation Organization
ICAO-TI : Technical Instructions by the "International Civil Aviation Organization" (ICAO)
ICSC : International Chemical Safety Cards
IDLH : Immediately Dangerous to Life or Health
IMDG: International Maritime Dangerous Goods
INCI : International Nomenclature of Cosmetic Ingredient
IUCLID : International Uniform Chemical Information Database
KSt : Explosion coefficient
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LC50: Median lethal concentration

LD50 : Median lethal dose
LEL : Lower Explosion Limit/Lower Explosive Limit
LEV : Local Exhaust Ventilation
LOEC : Lowest Observed Effect Concentration - LOEL : Lowest Observed Effect Level
LTE : Long Term Exposure
LTEL : Long Term Exposure Limit
MARPOL : MARine POLlution
mg/m3 : Milligrams per Cubic Metre
MMAD : Mass median aerodynamic diameter
MSDS : Material Safety Data Sheet
NOAEL : No-observed-adverse-effect-level - LOAEL : Lowest Observed Adverse Effect Level
NOEC : No observed effect concentration
NOEL : No observed effect level
N.O.S : Not Otherwise Specified
NTP : U.S. National Toxicology Program
OECD : Organisation for Economic Co-operation and Development
OEL : Operator exposure level
OSHA : Occupational Safety and Health Administration
PBT: Persistent, bioaccumulative, Toxic
PEC : Predicted effect level
PEL : Permissible Exposure Limit
pH : relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).
PNEC: Predicted no effect concentration
PP : Severe Marine Pollutant
PPE : Personal Protective Equipement
ppm : Parts Per Million
RCRA : Resource Conservation and Recovery Act
REACH : EC Regulation on Registration, Evaluation and Authorisation of Chemicals (Regulation (EC)
N°1907/2006 as amended)
RID : Regulations concerning the International Carriage of Dangerous Goods by Rail
RQ : Reportable Quantity measured in pounds (304, CERCLA)
RRN : REACH Registration Numbers
SARA : Superfund Amendments and Reauthorization Act
STE : Short-term exposure
STEL : Short Term Exposure Limit
STOT-RE : Specific target organ toxicity, Repeated exposure
STOT-SE : Specific Target Organ Toxicity, Single exposure
SVHC : Substance of Very High Concern
TCLo : Toxic Concentration Low
TDLo : Toxic Dose Low
TLV : Threshold Limit Value
TPQ : Threshold Planning Quantity measured in pounds (302)
TQ : Threshold Quantity measured in pounds (CAA)
TWA : Time Weighted Average
TWA/OEL : Time Weighted Average or Occupational Exposure Limit.
UEL : Upper Explosion Limit/Upper Explosive Limit
UWM : Unit World Model
vPvB - very Persistent, very Bioaccumulative substance
WEL : Work Exposure Limit
WGK : Wassergefährdungskasse (Water Hazard Class under Germanan Federal Water Management Act)
Full text of H- and EUH-statements:
Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4
Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4
Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1
Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1
Carc. 1A Carcinogenicity (inhalation) Category 1A
Muta. 2 Germ cell mutagenicity, Category 2
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Safety Data Sheet
Repr. 1B Reproductive toxicity, Category 1B
Resp. Sens. 1 Respiratory sensitisation, Category 1
Skin Irrit. 2 Skin corrosion/irritation, Category 2
Skin Sens. 1 Skin sensitisation, Category 1
STOT RE 1 Specific target organ toxicity — Repeated exposure, Category 1
STOT RE 2 Specific target organ toxicity — Repeated exposure, Category 2
H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H373 May cause damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
SDS EU (REACH Annex II)
DISCLAIMER
The information contained in this sheet comes from reliable sources. It has been drawn up based on our knowledge at the time of the most recent
update, as indicated. This information is intended as an aid to the user and should not be considered as a guarantee.
Conditions or methods of handling, storage, use or disposal of the product are outside our control, and we may not be held responsible for any loss,
damage or expenses incurred as a result of, or in connection with, the latter.
All substances or mixtures can present unknown dangers and must be used with caution. We cannot guarantee that all dangers have been set out
in an exhaustive manner.
This sheet has been drawn up for, and must be used for, this product only. If the product is used as a component in another product, the information
given with it may not be applicable.
This sheet does not under any circumstances exempt the user from complying with all laws, regulations and administrative requirements related to
the product, health and safety, and the protection of human health and the environment.
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NICKEL SULPHATE (update 2019)
ES FOR COMMUNICATION
Substance Name: NICKEL SULPHATE (update 2019)

EC Number: 232-104-9
CAS Number: 7786-81-4
Registration Number:
Date of Generation/Revision: 18/06/2019
Author: EBRC Consulting GmbH
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Table of Contents
0.General provisions related to conditions of use and guidance to downstream users
0.1. Good occupational hygiene practice ........................................͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘ϰ

0.2. General provisions related to personal protective equipment for workers .͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘ϰ
0.3. Generic guidance to DU to evaluate whether he works inside the boundaries set by the ES
0.4. Man via the environment exposure and risk characterisation assessments͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘͘ϲ
1. ES 1: Use at industrial sites; Intermediate use of nickel sulphate for the manufacture of nickel metal
................................................................................................................................................................ 8
1.1. Title section ................................................................................................................................. 8
1.2. Conditions of use affecting exposure.......................................................................................... 8
1.3. Exposure estimation and reference to its source ....................................................................... 9
1.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES .............. 10
2. ES 2: Use at industrial sites; Use of nickel sulphate for the manufacture of nickel salts ................. 11
2.1. Title section ............................................................................................................................... 11
2.2. Conditions of use affecting exposure........................................................................................ 11
2.3. Exposure estimation and reference to its source ..................................................................... 13
3. ES 3: Use at industrial sites; Use of nickel sulphate for the manufacture of nickel-containing inorganic
pigments ................................................................................................................................................ 16
3.1. Title section ............................................................................................................................... 16
4. ES 4: Formulation or re-packing; Use of nickel sulphate in formulating and repackaging of surface
treatment products ................................................................................................................................ 22
4.1. Title section ............................................................................................................................... 22
5. ES 5: Use at industrial sites; Use of nickel sulphate in metal surface treatment (nickel electroplating,
nickel electroforming and nickel electroless technologies) ................................................................... 29
5.1. Title section ............................................................................................................................... 29
6. ES 6: Use at industrial sites; Use of nickel sulphate for surface treatment of anodised aluminium
sheets .................................................................................................................................................... 36
6.1. Title section ............................................................................................................................... 36
7. ES 7: Use at industrial sites; Use of nickel sulphate in selective plating in industrial settings ......... 42
7.1. Title section ............................................................................................................................... 42
Generated by Chesar 3.4 ES for communication 2
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8. ES 8: Use at industrial sites; Use of nickel sulphate in the production of abrasive tools ................. 47
8.1. Title section ............................................................................................................................... 47
9. ES 9: Use at industrial sites; Use of nickel sulphate for the production of plated electrodes in the
battery sector ........................................................................................................................................ 53
9.1. Title section ............................................................................................................................... 53
10. ES 10: Use at industrial sites; Use of nickel sulphate for the manufacture of nickel dihydroxide in the
battery sector ........................................................................................................................................ 59
10.1. Title section ............................................................................................................................. 59
10.2. Conditions of use affecting exposure...................................................................................... 59
10.3. Exposure estimation and reference to its source ................................................................... 62
10.4. Guidance to DU to evaluate whether he works inside the boundaries set by the ES ............ 64
11. ES 11: Formulation or re-packing; Use of nickel sulphate in the formulation of micronutrient
additives for biogas production ............................................................................................................. 65
11.1. Title section ............................................................................................................................. 65
12. ES 12: Use at industrial sites; Use of nickel sulphate and nickel sulphate-derived micronutrients in
biogas production .................................................................................................................................. 71
12.1. Title section ............................................................................................................................. 71
13. ES 13: Widespread use by professional workers; Use of nickel sulphate and nickel sulphate-derived
micronutrients in compostable bags in biogas production .................................................................... 75
13.1. Title section ............................................................................................................................. 75
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0. General provisions related to conditions of use

and guidance to downstream users
All provisions given in this section generally apply to each exposure scenario (ES) included below. They
are to be supplemented or exchanged by more specific measures as given in the applicable exposure
scenario as appropriate.
0.1. Good occupational hygiene practice

Good occupational hygiene practices are required to ensure safe handling of the substance. In general,
inhalation (e.g. dust should not be blown off with compressed air) and ingestion must be avoided (e.g.
no eating and smoking in the workplace, regular cleaning with suitable cleaning devices). Any
contaminated clothing should not be taken home. Good general ventilation in the workplace should
ensure an adequate supply of fresh air. Regular training in workplace hygiene practice and proper use
of personal protective equipment (if relevant) are required.
0.2. General provisions related to personal protective

equipment for workers
Use of personal protective equipment (PPE) for each of the exposure routes listed below is required as
described here, unless exposure to the substance can be excluded for the respective route(s) of
exposure. Such exclusion of exposure may be determined by:
(i) the physical appearance of the substance in the specific type of application (e.g. wetting the
substance can effectively prevent from the emission of dust),
(ii) the emission potential resulting from the nature of the process (e.g. splashes, emission of dust can
be excluded in a closed process),
(iii) applied exposure prevention measures (segregation of the emission source or separation of the
worker from the emission source), and
(iv) the amount of the handled/emitted material during use in relation to the room size (i.e. dilution
factor) under consideration of the prevailing air exchange rates during use.
If PPE needs to be used, refer to section 8 of the SDS for further specification of such equipment.
0.2.1. Dermal route (skin protection)

Skin protective equipment should be selected in consideration of mechanical (acc. to EN 388,
mechanical risks), cold or heat stress (acc. to EN 407, thermal risks) or any other physico-chemical
hazards as relevant for the conducted tasks and working environment in addition to the effectiveness of
the equipment to control exposure. Certified safety clothing including coveralls and safety shoes have to
be worn. The following requirements for gloves are to be met:
- Due to the classification of the substance, gloves and skin protective clothing have to be worn for
precautionary reasons unless dermal exposure can be excluded (please see above).
- If gloves are to be worn, either due to these general provisions or due to specific requirements set
in the ES, they have to comply with EN 374.
- Any prescribed gloves have to be changed according to manufacturer’s information or when
damaged, whatever is the earlier.
0.2.2. Inhalation route (respiratory protection)

Specific information on the required assigned protection factor (APF) may be provided in the
occupational exposure scenarios below. Respiratory protective equipment (RPE) should be selected
based on the given APF according to EN 529 and should comply with national legislation. The following
requirements for RPE are to be met in any case:
- Due to the classification of the substance, RPE has to be worn for precautionary reasons unless
inhalation exposure can be excluded (please see above).
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- If RPE has to be worn, either due to these general provisions or due to specific requirements set in
the ES, an APF of 10 represents the required minimum level of protection.
If RPE is to be worn then the following principles are to be implemented in parallel:

The duration of work should take into account the additional physiological stress for the worker due to
the breathing resistance and mass of the RPE itself and due to the increased thermal stress by
enclosing the head. In addition, it shall be considered that the worker’s capability of using tools and of
communicating are reduced during the wearing of RPE.
For reasons as given above, the worker should therefore:

(i) be healthy (especially in view of medical problems that may affect the use of RPE), and
(ii) have suitable facial characteristics reducing leakages between face and mask (in view of scars
and facial hair).
The devices recommended in the ES which rely on a tight face seal will not provide the required
protection unless they fit the contours of the face properly and securely. The employer and
self-employed persons have legal responsibilities for the maintenance and supply of respiratory
protective devices and the management of their correct use in the workplace. Therefore, they should
define and document a suitable policy for a respiratory protective device programme including training
of workers.
0.2.3. Eye/face protection

Eye/face protective equipment is to be selected in consideration of local effects caused by the
substance, mechanical, cold or heat stress or any other physico-chemical hazards as relevant for the
conducted tasks and working environment in addition to the effectiveness of the equipment to control
exposure. The following requirements for eye/face protective equipment are to be met:
- Avoid direct contact of the eyes with the substance.

- Suitable eye protection equipment (e.g. goggles or visors) must be worn.
- Face protection must be worn unless such protection is provided by any eye protection (e.g. face
covering visor) and/or RPE used.
0.3. Generic guidance to DU to evaluate whether he works

inside the boundaries set by the ES
In any of the included exposure scenarios (ES) below, the downstream user (DU) works inside the
boundaries set by the ES if the given operational conditions (OCs) and risk management measures
(RMMs) as described in the ES are met. In cases in which the DU’s conditions are not explicitly included
in the generic conditions described in the ES, the DU has to ensure that his specific OCs and
implemented RMMs are compliant. If the concentration of the substance in mixture is not explicitly
stated in the ES this does not represent a restriction (i.e. up to 100 % of the substance could be used).
Depending on the basis for the exposure assessment conducted for the ES, this needs to be done in
different ways as described separately for environmental and occupational ES below.
0.3.1. Occupational exposure scenarios

The occupational exposure assessment may be either based on monitoring data (including analogous
or published data) or based on exposure assessment models. Depending on which method has been
used for exposure assessment, different ways for compliance checking are to be followed as given
below.
0.3.1.1. Monitoring data used as basis for assessment

If the exposure assessment in the ES is based on monitoring data, the same approach can be used by
DUs for compliance checking. Please note that 6 measurements per workplace are required for an
exposure assessment as a minimum. Depending on the variability of the data sets (expressed as the
geometric standard deviation) and the level of the resulting risk characterisation ratio, additional
measurements may be required. Only measurements of personal exposure to the inhalable fraction of
airborne dust (according to EN 481) should be used. The exposure data shall either be applicable to the
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length of a specific task to be assessed or to a full-shift (i.e. sampled over a duration of at least 120 min)
if the task to be assessed is conducted for a significant portion of the work shift. From the exposure data
set, the maximum likelihood estimate of the upper 90 % confidence limit for the 75th percentile of the
exposure distribution is to be used as a reasonable worst case estimate for comparison with the
reported exposure level in the associated contributing ES. Respiratory protective equipment (RPE) may
be taken into account by applying the assigned protection factor as given in EN 529:2005.
0.3.1.1.1. Specific considerations for efficiency values for RMMs prescribed in

occupational exposure scenarios
When personal exposure data are used to evaluate whether the conditions prescribed in the ES are
met, the efficiency of the RMMs implemented does not need to be separately assessed given that
monitored exposure levels are in compliance with those reported for the ES after consideration of any
PPE worn.
0.3.1.1.2. Deviations from the conditions of use if monitoring data were used for
exposure assessment
Any deviations from the given conditions of use require either to:
(i) inform the supplier of the SDS about these deviations and to request a reflection of these
deviations in an ES or
(ii) prepare a DU CSR (according to Article 37(4)) to be notified to ECHA and to be kept as in-house
documentation.
0.3.1.2. Use of exposure models

If the exposure assessment in the ES is based on modelled data, the same model can be used to justify
specific slight deviations from the generic conditions described in the ES. All parameters needed to run
the exposure estimation tool MEASE (version 1.02.01; available on www.ebrc.de/mease.html) can be
found in the ES. It is noted that the installation of the prescribed RMMs is mandatory and that
exclusively the modification of the personal protective equipment (PPE) used is allowed as deviation.
The only parameters which may therefore be modified in the MEASE-calculation are consequently:
(i) concentration in mixture (only lower concentrations),

(ii) efficiency of the installed RMMs (only higher efficiencies), and
(iii) type of PPE to be used.
0.3.1.2.1. Specific considerations for efficiency values for RMMs prescribed in

occupational exposure scenarios
Any efficiency values reported in the ES represent typical efficiencies for a given industry sector after
evaluating conditions of use as made available to the consultants and are therefore considered to
adequately approximate to actual efficiencies. If downstream users want to evaluate whether
prescribed efficiencies are met, exposure monitoring could be conducted. In such a case, monitored
exposure levels should be at or lower than reported for the ES after consideration of any PPE worn.
Further information on efficiency values can be found in the glossary of MEASE.
0.3.1.2.2. Deviations from the conditions of use if exposure models were used
for exposure assessment
Further deviations from the given conditions of use or if the DU assessment is to be based on
monitoring data require either to:
(i) inform the supplier of the SDS about these deviations and to request a reflection of these
deviations in an ES or
(ii) prepare a DU CSR (according to Article 37(4)) to be notified to ECHA and to be kept as in-house
documentation.
0.3.2. Environmental exposure scenarios
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0.3.2.1. Deviations from the conditions of use

This can be done by using the MetalEUSES scaling tool (free download:
http://www.arche-consulting.be/tools/du-scaling-tool/) to estimate the associated exposure. Following
parameters can be scaled: amount used at local site, number of emission days, discharge effluent rate,
dilution factor (or flow rate of the river), presence/absence of municipal sewage treatment plant (STP),
removal rate municipal STP, use of municipal sludge on agricultural soil, and release factors to air and
water.
0.4. Man via the environment exposure and risk

characterisation assessments
Inhalation is the critical exposure pathway for humans via the environment. The PEC for air at site
neighbouring residential areas should be lower than the chronic inhalation DNEL for the general public
of 60 ng Ni/m3 as annual average in PM10 in order to demonstrate adequate control of risk (RCR<1) for
Man via the Environment (MvE).
Hereto a Generic safe use Exposure Scenario for MvE was developed based on the EUSES model.
The MvE Generic ES is defined as the product of tonnage (T) and emission factor to air (EF) being lower
than 74000 g Ni/year. The value of 74000 g Ni/year is derived by using EUSES model to back-calculate
the product of T and EF that results in a local air concentration (Clocal) of 56.6 ng Ni/m3. The value of 56.6
ng Ni/m3 is derived from the difference between the DNEL of 60 ng Ni/m3 and the EU regional
background concentration (Cregional) of 3.4 ng Ni/m3 (average of P90 annual concentration for the years
2013, 2014 and 2015).
Safe use ES Tonnage Emission Tonnage × Clocal Cregional PEClocal RCR =

for all sectors (Ni T factor emission (ng/m3) (ng/m3) (ng/m3) PEC/DNEL
according to /year) (g Ni/T) factor (DNEL= 60
Tier 1 (EUSES (g Ni/year) ng/m3)
model) Sector
All T EF T × EF < <56.6 3.4* <60 <1
74000
*: EU average of country P90 annual Ni concentrations (2013, 2014 and 2015)
If a site is not compliant with these conditions, meaning that the product of tonnage and emission factor
is above 74000 g Ni/year, a tiered approach including site-specific modelling can be applied to
demonstrate safe use.
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1. ES 1: Use at industrial sites; Intermediate use of

nickel sulphate for the manufacture of nickel metal
1.1. Title section
Sector of use: Manufacture of bulk, large scale chemicals (including petroleum products) (SU 8),
Manufacture of fine chemicals (SU 9)
Environment
1: Intermediate use of nickel sulphate for the manufacture of nickel metal - Direct ERC 6a
discharge to fresh water
Worker
2: Reaction step PROC 2
3: Chemical reduction PROC 1
4: Wet cleaning PROC 28
1.2. Conditions of use affecting exposure

1.2.1. Control of environmental exposure: Intermediate use of nickel
sulphate for the manufacture of nickel metal - Direct discharge to
fresh water (ERC 6a)
Amount used, frequency and duration of use (or from service life)
Daily amount per site <= 190 tonnes/day (All the amounts and concentrations are expressed as Ni as
this is the driver for the environmental risk assessment.)
Annual amount per site <= 6.94E4 tonnes/year
Emission days >= 365 days/year
Technical and organisational conditions and measures
Chemical precipitation or sedimentation or filtration or electrolysis or reverse osmosis or ion exchange
Electrostatic precipitator or wet electrostatic precipitator or cyclones or fabric/bag filter or
ceramic/metal mesh filter or wet scrubber
Conditions and measures related to external treatment of waste (including article waste)
Dispose of waste product or used containers according to local regulations.
Other conditions affecting environmental exposure
Receiving surface water flow >= 1.78E6 m3/day
Assumed effluent discharge flow from site >= 2E3 m3/day
No discharge to marine water assumed
Receiving water dilution (fresh or marine) >= 892
1.2.2. Control of worker exposure: Reaction step (PROC 2)

Product (article) characteristics
Physical form covered in this ES: Solution.
Amount used (or contained in articles), frequency and duration of use/exposure
Covers daily exposures up to 8 hours
Use of a local exhaust ventilation with standard efficiency is required.
Use in closed process
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves tested to EN374.; For further specification, refer to section 8 of the SDS.
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1.2.3. Control of worker exposure: Chemical reduction (PROC 1)

Automated task
Use of an integrated local exhaust ventilation with standard efficiency is required.
Closed and ventilated (positive pressure) control room, contamination from outside is minimised by
measures such as dust-captures for shoes.
1.2.4. Control of worker exposure: Wet cleaning (PROC 28)

Maximum emission potential covered in this ES: Very low.
Physical form covered in this ES: Solution and other liquid materials, e.g. suspensions are also
covered.
Cleaning machines such as power sweeper, no direct manual cleaning.
Covers use at ambient temperatures.
1.3. Exposure estimation and reference to its source

1.3.1. Environmental release and exposure: Intermediate use of
nickel sulphate for the manufacture of nickel metal - Direct
discharge to fresh water (ERC 6a)
Release route Release rate Release estimation method
Water 5.377 kg/day Estimated release factor
Air 6.688 kg/day Estimated release factor
Soil 0 kg/day Estimated release factor
Protection target Exposure estimate RCR

Fresh water 5.06E-3 mg/L (EUSES 2.1.2) 0.713
Sediment (freshwater) 90.2 mg/kg dw (PEC sediment calculation method 0.828
for metals)
Agricultural soil 17.01 mg/kg dw (EUSES 2.1.2) 0.569
1.3.2. Worker exposure: Reaction step (PROC 2)

Route of exposure and type of Exposure estimate RCR
effects
Inhalation, systemic, long term 0.022 mg/m³ (Measured data) 0.44
Inhalation, systemic, acute 0.067 mg/m³ (Measured data) < 0.01
Inhalation, local, long term 0.022 mg/m³ (Measured data) 0.44
Inhalation, local, acute 0.067 mg/m³ (Measured data) 0.042
Dermal, local, long term 0.06 µg/cm² (Measured data) 0.136
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effects
Combined, systemic, long term 0.44
Combined, systemic, acute < 0.01
1.3.3. Worker exposure: Chemical reduction (PROC 1)

effects
Inhalation, systemic, long term 3E-3 mg/m³ (Measured data) 0.06
Inhalation, local, long term 3E-3 mg/m³ (Measured data) 0.06
Inhalation, local, acute 0.01 mg/m³ (Measured data) < 0.01
1.3.4. Worker exposure: Wet cleaning (PROC 28)

effects
1.4. Guidance to DU to evaluate whether he works inside

the boundaries set by the ES
Guidance: Please refer to Section 0.3 of this “ES for Communication”.
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2. ES 2: Use at industrial sites; Use of nickel sulphate

for the manufacture of nickel salts
2.1. Title section
Sector of use: Manufacture of fine chemicals (SU 9)
Environment
1: Use of nickel sulphate for the manufacture of nickel salts - Direct discharge to ERC 6a
fresh water
2: Use of nickel sulphate for the manufacture of nickel salts - Direct discharge to ERC 6a
marine water
Worker
3: Raw material handling (solutions) PROC 8b
4: Raw material handling (low dusty materials) PROC 26
5: Reaction with other chemicals PROC 2
7: Cleaning/removal of dust PROC 28

2.2.1. Control of environmental exposure: Use of nickel sulphate for
the manufacture of nickel salts - Direct discharge to fresh water
(ERC 6a)
Daily amount per site <= 5.361 tonnes/day (All the amounts and concentrations are expressed as Ni
as this is the driver for the environmental risk assessment.)
Receiving water dilution (fresh or marine) >= 1E3
Receiving surface water flow >= 2E6 m3/day

the manufacture of nickel salts - Direct discharge to marine water
(ERC 6a)
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No discharge to freshwater assumed
2.2.3. Control of worker exposure: Raw material handling (solutions)

(PROC 8b)
covered.
2.2.4. Control of worker exposure: Raw material handling (low dusty

materials) (PROC 26)
Maximum emission potential covered in this ES: Low.
Physical form covered in this ES: Solid.
Ensure automation of the process as far as technically feasible.
Semi-closed system
2.2.5. Control of worker exposure: Reaction with other chemicals

(PROC 2)
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Closed process with occasional opening.


covered.
2.2.7. Control of worker exposure: Cleaning/removal of dust (PROC

28)
Physical form covered in this ES: Residual dust.
Cleaning is conducted using cleaning machines, in particular hovering is applied and the use of
compressed air is omitted.
APF of RPE = 20 (95% respiratory protection). For further specification, refer to section 8 of the SDS.

2.3.1. Environmental release and exposure: Use of nickel sulphate
for the manufacture of nickel salts - Direct discharge to fresh water
(ERC 6a)

for metals)
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for the manufacture of nickel salts - Direct discharge to marine

water (ERC 6a)

Marine water 3.63E-3 mg/L (EUSES 2.1.2) 0.422
Sediment (marine water) 103.6 mg/kg dw (PEC sediment calculation 0.95
method for metals)
2.3.3. Worker exposure: Raw material handling (solutions) (PROC

8b)
effects
2.3.4. Worker exposure: Raw material handling (low dusty materials)

(PROC 26)
effects
2.3.5. Worker exposure: Reaction with other chemicals (PROC 2)

effects
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effects

effects
2.3.7. Worker exposure: Cleaning/removal of dust (PROC 28)

effects

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for the manufacture of nickel-containing inorganic
pigments
3.1. Title section
Sector of use: Manufacture of fine chemicals (SU 9)
Environment
1: Use of nickel sulphate for the manufacture of nickel-containing inorganic ERC 6a
pigments - Discharge to fresh water via municipal sewage treatment plant
pigments - Direct discharge to fresh water
pigments - Direct discharge to marine water
Worker
4: Raw material handling PROC 26
5: Closed mixing and transfer process PROC 2
6: Automated transfer process PROC 8b
7: Drying and calcining PROC 22, PROC
9, PROC 4, PROC
2

the manufacture of nickel-containing inorganic pigments -
Discharge to fresh water via municipal sewage treatment plant (ERC
6a)
Annual amount per site <= 156 tonnes/year
Conditions and measures related to biological sewage treatment plant
Municipal sewage treatment plant is assumed.
Assumed domestic sewage treatment plant flow >= 2E3 m3/day
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the manufacture of nickel-containing inorganic pigments - Direct
Assumed effluent discharge flow from site >= 225 m3/day

the manufacture of nickel-containing inorganic pigments - Direct
discharge to marine water (ERC 6a)
Local marine water dilution factor 100
3.2.4. Control of worker exposure: Raw material handling (PROC 26)

Maximum emission potential covered in this ES: High.
Physical form covered in this ES: Solid, powder / dust.
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Frequency of task: Once per shift.

3.2.5. Control of worker exposure: Closed mixing and transfer

process (PROC 2)
Physical form covered in this ES: Damp solid.
Automated task
3.2.6. Control of worker exposure: Automated transfer process

(PROC 8b)
Maximum emission potential covered in this ES: High.
Ensure segregation of worker from the source.
Use of an integrated local exhaust ventilation with standard efficiency is required.
3.2.7. Control of worker exposure: Drying and calcining (PROC 22,

PROC 9, PROC 4, PROC 2)
Semi-closed system
Manufacturing and processing of minerals and/or metals at substantially elevated temperature

covered.
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28)

for the manufacture of nickel-containing inorganic pigments -
6a)

for metals)
Sewage Treatment Plant 6.2E-3 mg/L (EUSES 2.1.2) 0.019

for the manufacture of nickel-containing inorganic pigments - Direct
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for metals)

for the manufacture of nickel-containing inorganic pigments - Direct
discharge to marine water (ERC 6a)

Sediment (marine water) 33.2 mg/kg dw (PEC sediment calculation method 0.305
for metals)
3.3.4. Worker exposure: Raw material handling (PROC 26)

effects
3.3.5. Worker exposure: Closed mixing and transfer process (PROC

2)
effects
3.3.6. Worker exposure: Automated transfer process (PROC 8b)

effects
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effects
3.3.7. Worker exposure: Drying and calcining (PROC 22, PROC 9,

PROC 4, PROC 2)
effects

effects

effects

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4. ES 4: Formulation or re-packing; Use of nickel

sulphate in formulating and repackaging of surface
treatment products
4.1. Title section
Product category: Metal surface treatment products (PC 14)
Environment
1: Use of nickel sulphate in formulating and repackaging of surface treatment ERC 2
products - Discharge to fresh water via municipal sewage treatment plant
products - Direct discharge to fresh water
products - Direct discharge to marine water
Worker
4: Raw material handling (fully contained) PROC 1
5: Raw material handling (solutions) PROC 8b, PROC 9
6: Mixing PROC 3, PROC 5
7: Filling of solutions PROC 8b, PROC 9
8: Laboratory testing PROC 15

4.2.1. Control of environmental exposure: Use of nickel sulphate in
formulating and repackaging of surface treatment products -
2)
37/91

formulating and repackaging of surface treatment products - Direct
discharge to fresh water (ERC 2)

formulating and repackaging of surface treatment products - Direct
discharge to marine water (ERC 2)
4.2.4. Control of worker exposure: Raw material handling (fully

contained) (PROC 1)
38/91
Automated task
4.2.5. Control of worker exposure: Raw material handling (solutions)

(PROC 8b, PROC 9)
covered.
4.2.6. Control of worker exposure: Mixing (PROC 3, PROC 5)

Automated task
4.2.7. Control of worker exposure: Filling of solutions (PROC 8b,

PROC 9)
covered.
4.2.8. Control of worker exposure: Laboratory testing (PROC 15)

Amount per use < 1 kg
39/91

Use of an extraction hood with standard efficiency is required.

covered.

28)

in formulating and repackaging of surface treatment products -
2)
Air 9.3E-3 kg/day Estimated release factor

for metals)
40/91

Sewage Treatment Plant 6.47E-3 mg/L (EUSES 2.1.2) 0.02

Direct discharge to fresh water (ERC 2)

for metals)

Direct discharge to marine water (ERC 2)

for metals)
4.3.4. Worker exposure: Raw material handling (fully contained)

(PROC 1)
effects
4.3.5. Worker exposure: Raw material handling (solutions) (PROC

8b, PROC 9)
41/91

effects
4.3.6. Worker exposure: Mixing (PROC 3, PROC 5)

effects
4.3.7. Worker exposure: Filling of solutions (PROC 8b, PROC 9)

effects
4.3.8. Worker exposure: Laboratory testing (PROC 15)

effects

effects
42/91

effects

effects

43/91

in metal surface treatment (nickel electroplating,
nickel electroforming and nickel electroless
technologies)
5.1. Title section
Sector of use: Manufacture of fabricated metal products, except machinery and equipment (SU 15),
General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment. (SU 17)
Environment
1: Use of nickel sulphate in metal surface treatment (nickel electroplating, nickel ERC 5
electroforming and nickel electroless technologies) - Discharge to fresh water via
municipal sewage treatment plant
electroforming and nickel electroless technologies) - Direct discharge to fresh
water
electroforming and nickel electroless technologies) - Direct discharge to marine
water
Worker
4: Handling of low dusty materials PROC 26
5: Handling of solutions as raw material PROC 8b, PROC 9
6: Mixing and blending PROC 5, PROC 4,
PROC 3
7: Nickel electroplating, nickel electroforming and electroless nickel plating PROC 13
8: Testing of solution composition PROC 15

metal surface treatment (nickel electroplating, nickel electroforming
and nickel electroless technologies) - Discharge to fresh water via
municipal sewage treatment plant (ERC 5)
44/91

and nickel electroless technologies) - Direct discharge to fresh
water (ERC 5)
Daily amount per site <= 9E-3 tonnes/day (All the amounts and concentrations are expressed as Ni as
Annual amount per site <= 2.1 tonnes/year

and nickel electroless technologies) - Direct discharge to marine
water (ERC 5)
45/91

5.2.4. Control of worker exposure: Handling of low dusty materials

(PROC 26)
Semi-closed system
5.2.5. Control of worker exposure: Handling of solutions as raw

material (PROC 8b, PROC 9)
covered.
5.2.6. Control of worker exposure: Mixing and blending (PROC 5,

PROC 4, PROC 3)
covered.
5.2.7. Control of worker exposure: Nickel electroplating, nickel

electroforming and electroless nickel plating (PROC 13)
46/91

Automated task
Use of a surfactant/wetting/foaming agent is required.
Use of a rim ventilation is required.
5.2.8. Control of worker exposure: Testing of solution composition

(PROC 15)

covered.

28)
47/91

in metal surface treatment (nickel electroplating, nickel
electroforming and nickel electroless technologies) - Discharge to
fresh water via municipal sewage treatment plant (ERC 5)

Sediment (freshwater) 104.8 mg/kg dw (PEC sediment calculation 0.961
method for metals)
Sewage Treatment Plant 0.038 mg/L (EUSES 2.1.2) 0.114

electroforming and nickel electroless technologies) - Direct

for metals)

electroforming and nickel electroless technologies) - Direct

for metals)
48/91
5.3.4. Worker exposure: Handling of low dusty materials (PROC 26)

effects
5.3.5. Worker exposure: Handling of solutions as raw material

(PROC 8b, PROC 9)
effects
5.3.6. Worker exposure: Mixing and blending (PROC 5, PROC 4,

PROC 3)
effects
5.3.7. Worker exposure: Nickel electroplating, nickel electroforming

and electroless nickel plating (PROC 13)
effects
49/91
5.3.8. Worker exposure: Testing of solution composition (PROC 15)

effects

effects

effects

50/91

for surface treatment of anodised aluminium sheets
6.1. Title section
Sector of use: Manufacture of fabricated metal products, except machinery and equipment (SU 15),
Environment
1: Use of nickel sulphate for surface treatment of anodised aluminium sheets - ERC 5
Discharge to fresh water via municipal sewage treatment plant
Direct discharge to fresh water
Direct discharge to marine water
Worker
6: Anodizing (dipping) PROC 13

surface treatment of anodised aluminium sheets - Discharge to

surface treatment of anodised aluminium sheets - Direct discharge
51/91
to fresh water (ERC 5)


surface treatment of anodised aluminium sheets - Direct discharge
to marine water (ERC 5)

(PROC 26)
52/91

Semi-closed system

covered.
6.2.6. Control of worker exposure: Anodizing (dipping) (PROC 13)

Automated task

covered.

28)
53/91


for surface treatment of anodised aluminium sheets - Discharge to

method for metals)

for surface treatment of anodised aluminium sheets - Direct

for metals)

for surface treatment of anodised aluminium sheets - Direct
54/91

for metals)

effects

(PROC 8b, PROC 9)
effects
6.3.6. Worker exposure: Anodizing (dipping) (PROC 13)

effects

effects
55/91

effects

effects

56/91

in selective plating in industrial settings
7.1. Title section
Sector of use: Manufacture of computer, electronic and optical products, electrical equipment (SU 16),
Environment
1: Use of nickel sulphate in selective plating in industrial settings - Discharge to ERC 5
fresh water via municipal sewage treatment plant
Worker
4: Mixing and blending PROC 5, PROC 4
5: Manual selective plating by brushing PROC 10, PROC
8a

selective plating in industrial settings - Discharge to fresh water via
municipal sewage treatment plant (ERC 5)
Daily amount per site <= 1.86E-3 tonnes/day (All the amounts and concentrations are expressed as Ni

(PROC 26)
57/91

Semi-closed system

covered.

PROC 4)
covered.
7.2.5. Control of worker exposure: Manual selective plating by

brushing (PROC 10, PROC 8a)
Limit the substance content in the product to 10 %
58/91
Ensure movable capturing hood with standard efficiency is used.


covered.

28)

in selective plating in industrial settings - Discharge to fresh water
via municipal sewage treatment plant (ERC 5)
Water 6.51E-5 kg/day Estimated release factor

method for metals)
Sewage Treatment Plant 1.95E-5 mg/L (EUSES 2.1.2) < 0.01
59/91


effects

(PROC 8b, PROC 9)
effects
7.3.4. Worker exposure: Mixing and blending (PROC 5, PROC 4)

effects
7.3.5. Worker exposure: Manual selective plating by brushing

(PROC 10, PROC 8a)
effects
60/91

effects

effects

effects

61/91

in the production of abrasive tools
8.1. Title section
Sector of use: General manufacturing, e.g. machinery, equipment, vehicles, other transport equipment.
(SU 17)
Environment
1: Use of nickel sulphate in the production of abrasive tools - Direct discharge to ERC 5
fresh water
2: Use of nickel sulphate in the production of abrasive tools - No emissions to ERC 5
water
Worker
5: Mixing and blending PROC 5, PROC 4,
PROC 3
6: Deposition of nickel bonding layer for abrasive grains PROC 13
7: Testing of solution composition PROC 15

the production of abrasive tools - Direct discharge to fresh water
(ERC 5)

the production of abrasive tools - No emissions to water (ERC 5)
62/91

(PROC 26)
Semi-closed system

covered.

PROC 4, PROC 3)
covered.
63/91

8.2.6. Control of worker exposure: Deposition of nickel bonding

layer for abrasive grains (PROC 13)
Automated task
8.2.7. Control of worker exposure: Testing of solution composition

(PROC 15)

covered.

28)
64/91


in the production of abrasive tools - Direct discharge to fresh water
(ERC 5)
Water 5E-3 kg/day Estimated release factor
Air 2E-3 kg/day Estimated release factor

method for metals)

in the production of abrasive tools - No emissions to water (ERC 5)
Water 0 kg/day Estimated release factor


effects

(PROC 8b, PROC 9)
effects
65/91

effects
8.3.5. Worker exposure: Mixing and blending (PROC 5, PROC 4,

PROC 3)
effects
8.3.6. Worker exposure: Deposition of nickel bonding layer for

abrasive grains (PROC 13)
effects
8.3.7. Worker exposure: Testing of solution composition (PROC 15)

effects

effects
66/91

effects

effects

67/91

for the production of plated electrodes in the battery
sector
9.1. Title section
Sector of use: Manufacture of computer, electronic and optical products, electrical equipment (SU 16)
Environment
1: Use of nickel sulphate for the production of plated electrodes in the battery ERC 5
sector - Discharge to fresh water via municipal sewage treatment plant
sector - Direct discharge to fresh water
sector - Direct discharge to marine water
Worker
6: Nickel electroplating PROC 4

the production of plated electrodes in the battery sector - Discharge
to fresh water via municipal sewage treatment plant (ERC 5)

the production of plated electrodes in the battery sector - Direct
68/91


the production of plated electrodes in the battery sector - Direct
9.2.4. Control of worker exposure: Raw material handling (low dusty

69/91

Semi-closed system

covered.
9.2.6. Control of worker exposure: Nickel electroplating (PROC 4)

Automated task

covered.

28)
70/91


for the production of plated electrodes in the battery sector -
5)

method for metals)

for the production of plated electrodes in the battery sector - Direct

for metals)

for the production of plated electrodes in the battery sector - Direct
71/91

for metals)
9.3.4. Worker exposure: Raw material handling (low dusty materials)

(PROC 26)
effects

(PROC 8b, PROC 9)
effects
9.3.6. Worker exposure: Nickel electroplating (PROC 4)

effects

effects
72/91

effects

effects

73/91
10. ES 10: Use at industrial sites; Use of nickel

sulphate for the manufacture of nickel dihydroxide in
the battery sector
10.1. Title section
Sector of use: Manufacture of computer, electronic and optical products, electrical equipment (SU 16)
Environment
1: Use of nickel sulphate for the manufacture of nickel dihydroxide in the battery ERC 6a
sector - Discharge to fresh water via municipal sewage treatment plant
sector - Direct discharge to fresh water
sector - Direct discharge to marine water
Worker
6: Reaction PROC 3

10.2.1. Control of environmental exposure: Use of nickel sulphate
for the manufacture of nickel dihydroxide in the battery sector -
6a)
74/91

Direct discharge to fresh water (ERC 6a)

Direct discharge to marine water (ERC 6a)
10.2.4. Control of worker exposure: Raw material handling (low

dusty materials) (PROC 26)
75/91

Semi-closed system

covered.
10.2.6. Control of worker exposure: Reaction (PROC 3)


covered.

28)
76/91


6a)

method for metals)

Direct discharge to fresh water (ERC 6a)

for metals)

Direct discharge to marine water (ERC 6a)
77/91


for metals)
10.3.4. Worker exposure: Raw material handling (low dusty

effects

(PROC 8b, PROC 9)
effects
10.3.6. Worker exposure: Reaction (PROC 3)

effects
78/91

effects

effects

79/91
11. ES 11: Formulation or re-packing; Use of nickel

sulphate in the formulation of micronutrient
additives for biogas production
11.1. Title section
Environment
1: Use of nickel sulphate in the formulation of micronutrient additives for biogas ERC 2
production - No emissions to water
Worker
2: Nickel sulphate reception (solutions) PROC 4
3: Nickel sulphate reception (low dusty solid) PROC 26
4: Preparing the additive in solution PROC 3
5: Preparing the additive as solid PROC 3
6: Filling of solutions PROC 9
7: Filling of biodegradable bags PROC 9
8: Palletising PROC 21

the formulation of micronutrient additives for biogas production -
No emissions to water (ERC 2)
11.2.2. Control of worker exposure: Nickel sulphate reception

(solutions) (PROC 4)
covered.
80/91

11.2.3. Control of worker exposure: Nickel sulphate reception (low

dusty solid) (PROC 26)
Semi-closed system
11.2.4. Control of worker exposure: Preparing the additive in

solution (PROC 3)
11.2.5. Control of worker exposure: Preparing the additive as solid

(PROC 3)
81/91
11.2.6. Control of worker exposure: Filling of solutions (PROC 9)

covered.
11.2.7. Control of worker exposure: Filling of biodegradable bags

(PROC 9)
Semi-closed system
11.2.8. Control of worker exposure: Palletising (PROC 21)

Physical form covered in this ES: Massive object (biodegradable bags).

covered.
11.2.10. Control of worker exposure: Cleaning/removal of dust

(PROC 28)
82/91


in the formulation of micronutrient additives for biogas production -
No emissions to water (ERC 2)
Air 0 kg/day Estimated release factor
11.3.2. Worker exposure: Nickel sulphate reception (solutions)

(PROC 4)
effects
11.3.3. Worker exposure: Nickel sulphate reception (low dusty solid)

(PROC 26)
effects
11.3.4. Worker exposure: Preparing the additive in solution (PROC
83/91
3)
effects
11.3.5. Worker exposure: Preparing the additive as solid (PROC 3)

effects
11.3.6. Worker exposure: Filling of solutions (PROC 9)

effects
11.3.7. Worker exposure: Filling of biodegradable bags (PROC 9)

effects
11.3.8. Worker exposure: Palletising (PROC 21)

effects
84/91

effects

effects

effects

85/91
12. ES 12: Use at industrial sites; Use of nickel

sulphate and nickel sulphate-derived micronutrients
in biogas production
12.1. Title section
Sector of use: Agriculture, forestry, fishery (SU 1)
Environment
1: Use of nickel sulphate and nickel sulphate-derived micronutrients in biogas ERC 4
production
Worker
2: Handling of solutions (reception and charging/discharging the bioreactor) PROC 8b
3: Handling of biodegradable bags (reception and charging/discharging the PROC 21
bioreactor)

and nickel sulphate-derived micronutrients in biogas production
(ERC 4)
12.2.2. Control of worker exposure: Handling of solutions (reception

and charging/discharging the bioreactor) (PROC 8b)
covered.
12.2.3. Control of worker exposure: Handling of biodegradable bags
86/91
(reception and charging/discharging the bioreactor) (PROC 21)


covered.

28)

and nickel sulphate-derived micronutrients in biogas production
(ERC 4)

12.3.2. Worker exposure: Handling of solutions (reception and

charging/discharging the bioreactor) (PROC 8b)
87/91

effects
12.3.3. Worker exposure: Handling of biodegradable bags (reception

and charging/discharging the bioreactor) (PROC 21)
effects

effects

effects

88/91
89/91
13. ES 13: Widespread use by professional workers;

Use of nickel sulphate and nickel sulphate-derived
micronutrients in compostable bags in biogas
production
13.1. Title section
Sector of use: Agriculture, forestry, fishery (SU 1)
Environment
1: Use of nickel sulphate and nickel sulphate-derived micronutrients in ERC 8b
compostable bags in biogas production
Worker
2: Handling of solutions (reception and charging/discharging the bioreactor) PROC 8b
3: Handling of biodegradable bags (reception and charging/discharging the PROC 21
bioreactor)

and nickel sulphate-derived micronutrients in compostable bags in
biogas production (ERC 8b)
13.2.2. Control of worker exposure: Handling of solutions (reception

and charging/discharging the bioreactor) (PROC 8b)
covered.
13.2.3. Control of worker exposure: Handling of biodegradable bags

(reception and charging/discharging the bioreactor) (PROC 21)
90/91

and nickel sulphate-derived micronutrients in compostable bags in
biogas production (ERC 8b)
Soil 0.55 kg/day Estimated release factor

13.3.2. Worker exposure: Handling of solutions (reception and

charging/discharging the bioreactor) (PROC 8b)
effects
13.3.3. Worker exposure: Handling of biodegradable bags (reception

and charging/discharging the bioreactor) (PROC 21)
effects

91/91

Sulfato de Niquel - MSDS (En 7.08.2020) - Anders Peru S.A.C.

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Sulfato de Niquel - MSDS (En 7.08.2020) - Anders Peru S.A.C.

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NICKEL SULPHATE 6H2O

Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.2.2. Uses advised against

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

Country Official advisory body Address Emergency number Comment

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

7/8/2020 (Version: 6.0) EN (English)

Adverse physicochemical, human health and environmental effects

2.2. Label elements

GHS08 GHS07 GHS09

2.3. Other hazards

SECTION 3: Composition/information on ingredients

7/8/2020 (Version: 6.0) EN (English)

Name Product identifier % Classification according to

Specific concentration limits:

SECTION 4: First aid measures

4.1. Description of first aid measures

SECTION 5: Firefighting measures

5.1. Extinguishing media

5.2. Special hazards arising from the substance or mixture

7/8/2020 (Version: 6.0) EN (English)

5.3. Advice for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

6.1.2. For emergency responders

6.2. Environmental precautions

6.3. Methods and material for containment and cleaning up

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

7.2. Conditions for safe storage, including any incompatibilities

7.3. Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

NICKEL SULPHATE 6H2O (10101-97-0)

Acute - local effects, inhalation 0.7 mg/m³ (Ni)

7/8/2020 (Version: 6.0) EN (English)

Long-term - local effects, dermal 0.00044 mg/cm² (Ni)

Long-term - systemic effects, inhalation 0.05 mg/m³ (Ni)

Long-term - local effects, inhalation 0.05 mg/m³ (Ni)

DNEL/DMEL (General population)

Acute - systemic effects, oral 0.012 mg/kg/d (Ni)

Acute - local effects, inhalation 0.4 mg/m³ (Ni)

Long-term - systemic effects,oral 0.02 mg/kg/d (Ni)

Long-term - systemic effects, inhalation 0.00002 mg/m³ (Ni)

Long-term - local effects, inhalation 0.00002 mg/m³ (Ni)

PNEC aqua (marine water) 8.6 µg/L (Ni)

Nickel sulphate hexahydrate (10101-97-0)

Acute - local effects, inhalation 0.7 mg/m³

Long-term - local effects, dermal 0.00044 mg/cm²

Long-term - systemic effects, inhalation 0.05 mg/m³

Long-term - local effects, inhalation 0.05 mg/m³

DNEL/DMEL (General population)

Acute - systemic effects, oral 0.012 mg/kg/d

Acute - local effects, inhalation 0.4 mg/m³

Long-term - systemic effects,oral 0.02 mg/kg bodyweight/day

Long-term - systemic effects, inhalation 0.00002 mg/m³

PNEC aqua (marine water) 8.6 µg/L (Ni)

7/8/2020 (Version: 6.0) EN (English)